WO2009108264A3 - Epoxidation catalyst - Google Patents

Epoxidation catalyst Download PDF

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Publication number
WO2009108264A3
WO2009108264A3 PCT/US2009/000599 US2009000599W WO2009108264A3 WO 2009108264 A3 WO2009108264 A3 WO 2009108264A3 US 2009000599 W US2009000599 W US 2009000599W WO 2009108264 A3 WO2009108264 A3 WO 2009108264A3
Authority
WO
WIPO (PCT)
Prior art keywords
titanium
epoxidation catalyst
catalyst
vanadium
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/000599
Other languages
French (fr)
Other versions
WO2009108264A2 (en
Inventor
Bi Le-Khac
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Lyondell Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Technology LP filed Critical Lyondell Chemical Technology LP
Priority to JP2010548668A priority Critical patent/JP2011513170A/en
Priority to EP09714532A priority patent/EP2247380A2/en
Priority to CN2009801098108A priority patent/CN101977687A/en
Publication of WO2009108264A2 publication Critical patent/WO2009108264A2/en
Publication of WO2009108264A3 publication Critical patent/WO2009108264A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Titanium or vanadium zeolite catalysts are prepared by reacting a titanium or vanadium compound, a silicon source, a templating agent, and a hydrophobic hydrocarbon wax at a temperature and for a time sufficient to form a molecular sieve. The catalyst is useful in olefin epoxidation with hydrogen peroxide.
PCT/US2009/000599 2008-02-27 2009-01-29 Epoxidation catalyst Ceased WO2009108264A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2010548668A JP2011513170A (en) 2008-02-27 2009-01-29 Epoxidation catalyst
EP09714532A EP2247380A2 (en) 2008-02-27 2009-01-29 Epoxidation catalyst
CN2009801098108A CN101977687A (en) 2008-02-27 2009-01-29 Epoxidation catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/072,575 2008-02-27
US12/072,575 US20090216033A1 (en) 2008-02-27 2008-02-27 Epoxidation catalyst

Publications (2)

Publication Number Publication Date
WO2009108264A2 WO2009108264A2 (en) 2009-09-03
WO2009108264A3 true WO2009108264A3 (en) 2010-03-18

Family

ID=40935725

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/000599 Ceased WO2009108264A2 (en) 2008-02-27 2009-01-29 Epoxidation catalyst

Country Status (6)

Country Link
US (1) US20090216033A1 (en)
EP (1) EP2247380A2 (en)
JP (1) JP2011513170A (en)
KR (1) KR20100127766A (en)
CN (1) CN101977687A (en)
WO (1) WO2009108264A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100076207A1 (en) * 2008-09-24 2010-03-25 Bi Le-Khac Epoxidation catalyst
US8124555B2 (en) * 2010-02-01 2012-02-28 Lyondell Chemical Technology L.P. Process for making titanium-MWW zeolite
KR101214896B1 (en) * 2010-04-07 2012-12-24 서강대학교산학협력단 Novel method of preparing vanadosilicate molecular sieves and novel vanadosilicate molecular sieves
BR112013001173A2 (en) * 2010-07-19 2016-05-31 Shell Int Research "epoxidation process for the preparation of alkylene oxide."
CN102755908B (en) * 2011-04-28 2014-05-14 中国科学院大连化学物理研究所 Alkene epoxidation method
CN102993130A (en) * 2012-12-14 2013-03-27 山东理工大学 Method for synthesizing styrene oxide by directly oxidizing styrene
EP3415234A4 (en) 2016-03-09 2019-04-17 LG Chem, Ltd. ORGANOZINCIC CATALYST, PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING POLYALKYLENE CARBONATE RESIN USING THE CATALYST
CN108339567B (en) * 2018-02-10 2020-05-12 浙江大学 Method for preparing hydrophobic zeolite catalytic material for encapsulating titanium dioxide
FI130830B1 (en) 2021-11-16 2024-04-15 Teknologian Tutkimuskeskus Vtt Oy EPOXIDATION OF OLEFIN MIXTURE
CN115504482B (en) * 2022-08-12 2023-08-11 浙江师范大学 Titanium-silicon molecular sieve, preparation method and application thereof
CN118022824A (en) * 2022-11-10 2024-05-14 中国石油化工股份有限公司 A fully crystalline Ti-MWW molecular sieve catalyst and its preparation method and application
CN121198341B (en) * 2025-11-26 2026-02-17 广西民族大学 An epoxy-ring-opening bifunctional catalyst, its preparation method and application

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002085513A2 (en) * 2001-03-02 2002-10-31 Basf Aktiengesellschaft Shaped body and method for producing the same
EP1314475A1 (en) * 2001-11-23 2003-05-28 Polimeri Europa S.p.A. Process for the preparation of MFI-Type zeolitic catalysts
WO2004026852A1 (en) * 2002-09-20 2004-04-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
WO2005092501A2 (en) * 2004-03-09 2005-10-06 Lyondell Chemical Technology, L.P. Polymer-encapsulated titanium zeolites for oxidation reactions
WO2006111584A1 (en) * 2005-04-22 2006-10-26 Basf Aktiengesellschaft Process for preparing a nanosized zeolitic material
WO2007058710A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst
WO2007058709A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351635A (en) * 1966-03-14 1967-11-07 Halcon International Inc Epoxidation process
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
IT1127311B (en) * 1979-12-21 1986-05-21 Anic Spa SYNTHETIC, CRYSTALLINE, POROUS MATERIAL CONSTITUTED BY SILICON AND TITANIUM OXIDES, METHOD FOR ITS PREPARATION AND ITS USES
IT1152299B (en) * 1982-07-28 1986-12-31 Anic Spa PROCEDURE FOR THE EXPOSSIDATION OF HYDRAULIC COMPOUNDS
DE4425672A1 (en) * 1994-07-20 1996-01-25 Basf Ag Oxidation catalyst, process for its preparation and oxidation process using the oxidation catalyst
BE1011577A3 (en) * 1997-11-27 1999-11-09 Solvay Epoxidation catalyst, use and method epoxidation catalyst presence.

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002085513A2 (en) * 2001-03-02 2002-10-31 Basf Aktiengesellschaft Shaped body and method for producing the same
EP1314475A1 (en) * 2001-11-23 2003-05-28 Polimeri Europa S.p.A. Process for the preparation of MFI-Type zeolitic catalysts
WO2004026852A1 (en) * 2002-09-20 2004-04-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
WO2005092501A2 (en) * 2004-03-09 2005-10-06 Lyondell Chemical Technology, L.P. Polymer-encapsulated titanium zeolites for oxidation reactions
WO2006111584A1 (en) * 2005-04-22 2006-10-26 Basf Aktiengesellschaft Process for preparing a nanosized zeolitic material
WO2007058710A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst
WO2007058709A1 (en) * 2005-11-17 2007-05-24 Lyondell Chemical Technology, L.P. Epoxidation catalyst

Also Published As

Publication number Publication date
US20090216033A1 (en) 2009-08-27
JP2011513170A (en) 2011-04-28
CN101977687A (en) 2011-02-16
WO2009108264A2 (en) 2009-09-03
EP2247380A2 (en) 2010-11-10
KR20100127766A (en) 2010-12-06

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