WO2009122140A2 - Process for preparing catalysts - Google Patents

Process for preparing catalysts Download PDF

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Publication number
WO2009122140A2
WO2009122140A2 PCT/GB2009/000789 GB2009000789W WO2009122140A2 WO 2009122140 A2 WO2009122140 A2 WO 2009122140A2 GB 2009000789 W GB2009000789 W GB 2009000789W WO 2009122140 A2 WO2009122140 A2 WO 2009122140A2
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WO
WIPO (PCT)
Prior art keywords
catalyst
metal
carbon dioxide
insoluble
metal compounds
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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PCT/GB2009/000789
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French (fr)
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WO2009122140A3 (en
Inventor
Graeme Douglas Campbell
James Beaumond Hunter
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Johnson Matthey PLC
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Johnson Matthey PLC
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Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Priority to BRPI0910443A priority Critical patent/BRPI0910443A2/en
Priority to CA2718952A priority patent/CA2718952A1/en
Priority to AU2009232223A priority patent/AU2009232223B2/en
Priority to CN2009801111475A priority patent/CN101980784B/en
Priority to US12/936,067 priority patent/US8815191B2/en
Priority to RU2010145183/04A priority patent/RU2482918C2/en
Priority to EP09728991A priority patent/EP2288441A2/en
Priority to NZ588032A priority patent/NZ588032A/en
Priority to UAA201013079A priority patent/UA99013C2/en
Publication of WO2009122140A2 publication Critical patent/WO2009122140A2/en
Publication of WO2009122140A3 publication Critical patent/WO2009122140A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • This invention relates to a process for preparing precipitated catalyst compositions and in particular to the regeneration of metal carbonate precipitants used in the manufacture of precipitated catalyst compositions.
  • Manufacturing processes whereby catalyst compositions are precipitated using a metal carbonate precipitant are known and typically include the steps of forming an aqueous, often an acidic solution of soluble metal compounds, combining the solution with a metal carbonate precipitant, generally an aqueous solution of an alkali metal carbonate, to effect precipitation of insoluble metal compounds.
  • the insoluble compounds which generally comprise metal carbonate compounds, are recovered and dried. Calcination, whereby the insoluble compounds are heated to elevated temperature to effect a physiochemical change may also be performed.
  • the dried or calcined materials may subsequently be exposed to a reducing gas such as hydrogen or carbon monoxide to convert the metal into its elemental or zero-valent state. Subsequent passivation of the reduced catalyst composition may also be performed.
  • a reducing gas such as hydrogen or carbon monoxide
  • carbon dioxide may be evolved as the metal carbonate compounds decompose.
  • partial decomposition of metal hydroxycarbonates may occur on drying and carbon dioxide may be evolved during calcination.
  • Carbon dioxide may also be evolved during reduction of reducible catalyst compositions containing carbonate residues.
  • the carbon dioxide so-evolved has been discharged as waste gas.
  • the evolved carbon dioxide represents a useful raw material that may be re-used to generate the metal precipitant.
  • the invention provides a process for manufacturing a catalyst comprising the steps of
  • metal carbonate precipitant we include metal bicarbonate or metal hydrogen carbonate.
  • insoluble metal carbonates we include insoluble metal hydroxycarbonates.
  • Insoluble metal carbonates by which term we include metal hydroxycarbonates, may be precipitated by combining an aqueous solution of one or more soluble metal compounds, such as a metal nitrate, sulphate, acetate, chloride or the like, and an aqueous solution of a metal carbonate precipitant.
  • the solutions may be combined in any manner known to those skilled in the art of catalyst manufacture.
  • the carbonate reacts with the soluble metal compound forming insoluble metal carbonate, including metal hydroxy-carbonate, compounds.
  • the precipitation may be performed at temperatures in the range 0-100 0 C, preferably 10-9O 0 C.
  • the pH of the combined solution is preferably 6-12, more preferably 7-11.
  • the insoluble metal carbonates precipitated are desirably compounds suitable for the preparation of catalysts or catalyst precursors.
  • the soluble metal compounds from which they are derived may comprise any of the catalytically active metals found in catalyst or catalyst precursors, including alkali-earth metals, transition metals and non-transition metals.
  • the soluble metal compounds comprise compounds of metals selected from Ca, Mg, Ti, V, Ce, Zr, Al, La, Y, Mn, Fe, Cr, Co, Ni, Cu, Zn, or Pb. Mixtures of two or more metal compounds may be used.
  • a metal oxide thermostabilising material such as a metal oxide powder, gel or sol may be included or formed during the precipitation of the insoluble metal compounds.
  • Alumina, silica, titania, zirconia, ceria and other insoluble metal oxide compounds and/or the corresponding metal hydroxides may be present.
  • the catalyst or catalyst precursor may contain one or more promoters such as an alkali metal compounds, alkali-earth metal compounds, transition metal compounds, rare earth compounds and precious metals.
  • the alkaline metal carbonate precipitant is preferably a metal carbonate of an alkali metal such as sodium or potassium.
  • the metal solutions and precipitant may be combined in any order using known methods. Once the metal solution and precipitant solutions are combined and precipitation of insoluble metal compounds has begun, the mixture may be aged. Some carbon dioxide may be evolved during the ageing step. Ageing of the precipitated composition may be performed in the same vessel or on one or more further vessels according to practices known in the art. If desired, a thermostabilising material such as a metal oxide may be added during the ageing step and therefore by "during the precipitation" we include any ageing step whereby the precipitated insoluble metal compounds are allowed to age for a period following the precipitation. Ageing may be continued for up to 24 hours, preferably up to 8 hours, more preferably up to 6 hours. The ageing temperature may be in the range 0-100 0 C, preferably 20-95 0 C. The ageing pH may be in the range 3-11.
  • carbon dioxide is recovered from the ageing step and used to prepare the alkaline metal carbonate precipitant.
  • the precipitated compositions comprising the insoluble metal compounds may be recovered by filtration, centrifuge or decanting using known methods.
  • wash the recovered precipitated composition it is preferable to wash the recovered precipitated composition to remove soluble compounds such as metal salts. Washing may be performed using water, preferably de-mineralised water, at ambient, or preferably, elevated temperature.
  • the recovered solids are then further processed into catalyst or catalyst precursor materials.
  • the further processing of the insoluble metal compounds into a catalyst or catalyst precursor may include a step of drying the insoluble metal compounds. This may be achieved by heating the damp precipitated material in air or an inert gas to temperatures in the range 25-12O 0 C in an oven or vacuum oven.
  • the washed catalyst composition may be spray dried using known methods. Drying removes solvent, which is typically water.
  • the precipitated catalyst compositions comprising the insoluble metal compounds may be further processed by calcining, i.e. by heating them in a calciner to temperatures in the range 200-600 0 C, preferably 250-400 0 C for a period up to 24 hours, preferably up to 8 hours to effect a physiochemical change whereby the insoluble metal carbonate compounds, including metal hydroxycarbonates, are converted into their corresponding oxides with the evolution of carbon dioxide. If desired carbon dioxide may be recovered from the calciner off-gases and used to prepare the alkaline metal carbonate precipitant.
  • the catalyst or catalyst precursor is formed into shaped units such as tablets, pellets, granules or extrudates using known methods.
  • the precipitated composition comprising the insoluble metal compounds include one or more reducible metals
  • it may be further processed by reduction with a reducing gas such as hydrogen or carbon monoxide, or gas mixtures containing these, in a reducer.
  • a reducing gas such as hydrogen or carbon monoxide, or gas mixtures containing these
  • Inert gases such as nitrogen or argon may be used to dilute the reducing gas.
  • the insoluble compounds may be reduced directly with the evolution of carbon dioxide or may be calcined and then reduced.
  • the carbon dioxide evolved from the reducer is recovered and used to make the alkaline metal carbonate precipitant.
  • Carbon dioxide is evolved during one or more steps of the further processing of the precipitated compositions comprising the insoluble metal compounds.
  • This carbon dioxide is recovered from the off gases and is reacted with an alkaline metal compound to form a metal carbonate.
  • the reaction between carbon dioxide and alkaline metal compound may be performed in one or more vessels in series or parallel arrangement preferably containing a suitable packing such as pall rings. Scrubber or absorber column arrangements may be used wherein liquid is fed to the top of the vessel and passes down through a bed of shaped units where it is contacted with the CO 2 -containing gas passing up through the vessel.
  • carbon dioxide is recovered from the ageing and/or reduction steps and passed to a CO 2 recovery and absorption system comprising a plurality of absorption or scrubbing columns fed with alkali metal hydroxide solutions.
  • a CO 2 recovery and absorption system comprising a plurality of absorption or scrubbing columns fed with alkali metal hydroxide solutions.
  • Any inert gases such as nitrogen present in the reduction gas stream is therefore unaffected by the C0 2 -recovery process and may be returned to the reducer.
  • Reduction water is preferably removed from the reducer of-gases prior to contacting the carbon dioxide- containing gas stream with alkali metal hydroxide.
  • the alkaline metal compound with which the carbon dioxide is reacted is a compound of an alkali metal, preferably sodium or potassium, most preferably the metal compound is chosen so that the metal carbonate that is formed is the same as that originally used as precipitant.
  • Particularly suitable metal compounds with which the recovered carbon dioxide may be reacted are alkali metal hydroxides.
  • a CO 2 -recovery and metal carbonate production system 10 is depicted.
  • the system is fed with carbon dioxide-containing streams 12 and 14 from catalyst reducer and ageing vessels respectively, and alkali metal hydroxide stream 16 from storage.
  • Reduction water is recovered from the system via line 18 and may be re-used in the catalyst manufacturing process.
  • 42% wt alkali metal carbonate solution is recovered from the system via line 20 and a hydrogen-containing gas is recovered from the system via line 22.
  • make up carbon dioxide may be provided to the system via line 24 and waste carbon dioxide removed via line 26.
  • the mixed off-gases from the reducer which comprise hydrogen and carbon dioxide, are fed to the system via line 12.
  • the gases are first cooled in heat exchanger 30 to cause the reduction water to condense.
  • the liquid reduction water is separated in a separator 32 and recovered via line 18.
  • the mixed gases comprising hydrogen and carbon dioxide are then fed from the separator via line 34 to two CO 2 absorption units 36 and 38 arranged in series.
  • the mixed gas stream 34 is fed near the bottom of a first absorber unit 36 containing a fixed bed of pall rings 40.
  • the mixed gas stream passes up though the bed 40 where it contacts with a descending aqueous stream of mixed alkali metal hydroxide and alkali metal carbonate fed to the first unit 36 from the bottom of second unit 38.
  • the resulting alkali metal carbonate solution comprising 36% wt alkali metal carbonate and 6% wt alkali metal hydroxide is recovered from the bottom of the first unit 36 via line 42 and cooled by means of a heat exchanger (not shown).
  • the unreacted gas stream, depleted in carbon dioxide, is passed from the top of unit 36 via line 44 to near the bottom of the second unit 38, which contains a further packed bed of pall rings 46.
  • the gas stream then passes up through the bed 46 where it contacts with a descending aqueous stream of alkali metal hydroxide obtained from line 16 and fed to near the top of the second unit via line 48.
  • the remaining carbon dioxide in the gas stream passing through the second unit 38 reacts with the alkali metal hydroxide generating alkali metal carbonate.
  • the resulting mixed alkali metal hydroxide and alkali metal carbonate solution is passed via line 50 from the bottom of the second unit 38 via a cooling heat exchanger (not shown) to near the top of the first unit 34.
  • the remaining hydrogen-containing gas stream is passed from the top of the second unit 38 via line 52 to a compressor 54 and the compressed gas passed to a drying vessel 56 containing a bed of molecular sieves 58 that remove any remaining traces of water.
  • the dried hydrogen-containing gas stream is recovered from the system 10 via line 22.
  • the gas stream recovered from the ageing vessel, which is substantially carbon dioxide, is conveyed to the system 10 via line 14.
  • Fresh carbon dioxide in line 24 may be mixed with the recovered carbon dioxide in line 14 and the resulting mixture fed to near the bottom of a CO 2 scrubbing unit 60 containing a fixed bed of pall rings 62.
  • the carbon dioxide ascends through the bed 62 where it is in contact with a descending mixture of alkali metal carbonate and alkali metal hydroxide fed to near the top of the scrubber unit 60 via line 64.
  • the mixture in line 64 comprises the 36% wt mixed alkali metal carbonate/ 6% wt alkali metal hydroxide stream 42 recovered from the bottom of the first absorber unit 36 and a fresh 40% wt aqueous alkali metal hydroxide stream 66 obtained from line 16.
  • the carbon dioxide in the gas stream passing through the bed 62 reacts with the alkali metal hydroxide descending through the bed to form alkali metal carbonate.
  • the resulting 42% wt alkali metal carbonate/alkali metal hydroxide mixture is recovered from the bottom of scrubber unit 60 via line 20, cooled if necessary, and fed to a catalyst precipitation unit (not shown).
  • Unreacted carbon dioxide is recovered from the top of the scrubber unit 60 via line 26 and sent to a stack for disposal or recycled to line 14. . '

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Abstract

A process is described for manufacturing a catalyst composition comprising the steps of (i) combining one or more soluble metal compounds with a solution of an alkaline metal carbonate precipitant to form a precipitate of insoluble metal carbonates, (ii) processing the insoluble metal carbonates into a catalyst or catalyst precursor with the evolution of carbon dioxide, (iii) recovering at least a portion of the evolved carbon dioxide, and (iv) reacting the recovered carbon dioxide with a suitable alkaline metal compound in an absorber column to generate an alkaline metal carbonate, wherein at least a portion of the generated alkaline metal carbonate is used as a precipitant in step (i).

Description

Process for preparing catalysts
This invention relates to a process for preparing precipitated catalyst compositions and in particular to the regeneration of metal carbonate precipitants used in the manufacture of precipitated catalyst compositions.
Manufacturing processes whereby catalyst compositions are precipitated using a metal carbonate precipitant are known and typically include the steps of forming an aqueous, often an acidic solution of soluble metal compounds, combining the solution with a metal carbonate precipitant, generally an aqueous solution of an alkali metal carbonate, to effect precipitation of insoluble metal compounds. The insoluble compounds, which generally comprise metal carbonate compounds, are recovered and dried. Calcination, whereby the insoluble compounds are heated to elevated temperature to effect a physiochemical change may also be performed. Furthermore, for certain reducible catalyst compositions, for example those comprising Ni, Cu, Co or Fe, the dried or calcined materials may subsequently be exposed to a reducing gas such as hydrogen or carbon monoxide to convert the metal into its elemental or zero-valent state. Subsequent passivation of the reduced catalyst composition may also be performed.
In the processing of the catalyst composition following precipitation of the insoluble metal compounds, carbon dioxide may be evolved as the metal carbonate compounds decompose. For example partial decomposition of metal hydroxycarbonates may occur on drying and carbon dioxide may be evolved during calcination. Carbon dioxide may also be evolved during reduction of reducible catalyst compositions containing carbonate residues.
Heretofore the carbon dioxide so-evolved has been discharged as waste gas. We have realised that the evolved carbon dioxide represents a useful raw material that may be re-used to generate the metal precipitant.
Accordingly the invention provides a process for manufacturing a catalyst comprising the steps of
(i) combining one or more soluble metal compounds with a solution of an alkaline metal carbonate precipitant to form a precipitate of insoluble metal carbonates, (ii) processing the insoluble metal carbonates into a catalyst or catalyst precursor with the evolution of carbon dioxide,
(iii) recovering at least a portion of the evolved carbon dioxide, and (iv) reacting the recovered carbon dioxide with a suitable alkaline metal compound in an absorber column to generate an alkaline metal carbonate, wherein at least a portion of the generated alkaline metal carbonate is used as a precipitant in step
CO- By the term "metal carbonate precipitant" we include metal bicarbonate or metal hydrogen carbonate.
By the term "insoluble metal carbonates" we include insoluble metal hydroxycarbonates.
We have found that re-using the carbon dioxide evolved during the catalyst manufacturing process offers savings in terms of raw material costs as well as reducing emissions from catalyst manufacturing facilities.
Insoluble metal carbonates, by which term we include metal hydroxycarbonates, may be precipitated by combining an aqueous solution of one or more soluble metal compounds, such as a metal nitrate, sulphate, acetate, chloride or the like, and an aqueous solution of a metal carbonate precipitant. The solutions may be combined in any manner known to those skilled in the art of catalyst manufacture. Upon combining the metal solution and precipitant solution, the carbonate reacts with the soluble metal compound forming insoluble metal carbonate, including metal hydroxy-carbonate, compounds. The precipitation may be performed at temperatures in the range 0-1000C, preferably 10-9O0C. The pH of the combined solution is preferably 6-12, more preferably 7-11.
The insoluble metal carbonates precipitated are desirably compounds suitable for the preparation of catalysts or catalyst precursors. Accordingly, the soluble metal compounds from which they are derived may comprise any of the catalytically active metals found in catalyst or catalyst precursors, including alkali-earth metals, transition metals and non-transition metals. Preferably the soluble metal compounds comprise compounds of metals selected from Ca, Mg, Ti, V, Ce, Zr, Al, La, Y, Mn, Fe, Cr, Co, Ni, Cu, Zn, or Pb. Mixtures of two or more metal compounds may be used.
It may be desirable, in order to enhance the properties of the catalyst or catalyst precursor, to include beside the precipitated metal carbonate compounds other insoluble components in the catalyst composition and therefore a metal oxide thermostabilising material such as a metal oxide powder, gel or sol may be included or formed during the precipitation of the insoluble metal compounds. Alumina, silica, titania, zirconia, ceria and other insoluble metal oxide compounds and/or the corresponding metal hydroxides may be present.
In addition to the catalytic metal compounds and the thermostabilising material the catalyst or catalyst precursor may contain one or more promoters such as an alkali metal compounds, alkali-earth metal compounds, transition metal compounds, rare earth compounds and precious metals. The alkaline metal carbonate precipitant is preferably a metal carbonate of an alkali metal such as sodium or potassium.
The metal solutions and precipitant may be combined in any order using known methods. Once the metal solution and precipitant solutions are combined and precipitation of insoluble metal compounds has begun, the mixture may be aged. Some carbon dioxide may be evolved during the ageing step. Ageing of the precipitated composition may be performed in the same vessel or on one or more further vessels according to practices known in the art. If desired, a thermostabilising material such as a metal oxide may be added during the ageing step and therefore by "during the precipitation" we include any ageing step whereby the precipitated insoluble metal compounds are allowed to age for a period following the precipitation. Ageing may be continued for up to 24 hours, preferably up to 8 hours, more preferably up to 6 hours. The ageing temperature may be in the range 0-1000C, preferably 20-950C. The ageing pH may be in the range 3-11.
In one embodiment of the present invention, carbon dioxide is recovered from the ageing step and used to prepare the alkaline metal carbonate precipitant.
Once precipitation and any ageing steps are completed, the precipitated compositions comprising the insoluble metal compounds may be recovered by filtration, centrifuge or decanting using known methods.
It is preferable to wash the recovered precipitated composition to remove soluble compounds such as metal salts. Washing may be performed using water, preferably de-mineralised water, at ambient, or preferably, elevated temperature. The recovered solids are then further processed into catalyst or catalyst precursor materials.
The further processing of the insoluble metal compounds into a catalyst or catalyst precursor may include a step of drying the insoluble metal compounds. This may be achieved by heating the damp precipitated material in air or an inert gas to temperatures in the range 25-12O0C in an oven or vacuum oven. The washed catalyst composition may be spray dried using known methods. Drying removes solvent, which is typically water.
The precipitated catalyst compositions comprising the insoluble metal compounds may be further processed by calcining, i.e. by heating them in a calciner to temperatures in the range 200-6000C, preferably 250-4000C for a period up to 24 hours, preferably up to 8 hours to effect a physiochemical change whereby the insoluble metal carbonate compounds, including metal hydroxycarbonates, are converted into their corresponding oxides with the evolution of carbon dioxide. If desired carbon dioxide may be recovered from the calciner off-gases and used to prepare the alkaline metal carbonate precipitant.
Preferably the catalyst or catalyst precursor is formed into shaped units such as tablets, pellets, granules or extrudates using known methods.
Where the precipitated composition comprising the insoluble metal compounds include one or more reducible metals, it may be further processed by reduction with a reducing gas such as hydrogen or carbon monoxide, or gas mixtures containing these, in a reducer. Inert gases such as nitrogen or argon may be used to dilute the reducing gas. The insoluble compounds may be reduced directly with the evolution of carbon dioxide or may be calcined and then reduced. In one embodiment, the carbon dioxide evolved from the reducer is recovered and used to make the alkaline metal carbonate precipitant.
Carbon dioxide is evolved during one or more steps of the further processing of the precipitated compositions comprising the insoluble metal compounds. This carbon dioxide is recovered from the off gases and is reacted with an alkaline metal compound to form a metal carbonate. The reaction between carbon dioxide and alkaline metal compound may be performed in one or more vessels in series or parallel arrangement preferably containing a suitable packing such as pall rings. Scrubber or absorber column arrangements may be used wherein liquid is fed to the top of the vessel and passes down through a bed of shaped units where it is contacted with the CO2-containing gas passing up through the vessel.
In a preferred embodiment of the present invention, carbon dioxide is recovered from the ageing and/or reduction steps and passed to a CO2 recovery and absorption system comprising a plurality of absorption or scrubbing columns fed with alkali metal hydroxide solutions. Any inert gases such as nitrogen present in the reduction gas stream is therefore unaffected by the C02-recovery process and may be returned to the reducer. Reduction water is preferably removed from the reducer of-gases prior to contacting the carbon dioxide- containing gas stream with alkali metal hydroxide.
Preferably the alkaline metal compound with which the carbon dioxide is reacted is a compound of an alkali metal, preferably sodium or potassium, most preferably the metal compound is chosen so that the metal carbonate that is formed is the same as that originally used as precipitant. Particularly suitable metal compounds with which the recovered carbon dioxide may be reacted are alkali metal hydroxides. The invention is further illustrated by reference to the following drawings in which Figure 1 is a diagrammatic flowsheet of a CO2-recovery and alkaline metal carbonate production system according to one embodiment of the invention.
In Figure 1 , a CO2-recovery and metal carbonate production system 10 is depicted. The system is fed with carbon dioxide-containing streams 12 and 14 from catalyst reducer and ageing vessels respectively, and alkali metal hydroxide stream 16 from storage. Reduction water is recovered from the system via line 18 and may be re-used in the catalyst manufacturing process. 42% wt alkali metal carbonate solution is recovered from the system via line 20 and a hydrogen-containing gas is recovered from the system via line 22. In addition, make up carbon dioxide may be provided to the system via line 24 and waste carbon dioxide removed via line 26.
The mixed off-gases from the reducer, which comprise hydrogen and carbon dioxide, are fed to the system via line 12. The gases are first cooled in heat exchanger 30 to cause the reduction water to condense. The liquid reduction water is separated in a separator 32 and recovered via line 18. The mixed gases comprising hydrogen and carbon dioxide are then fed from the separator via line 34 to two CO2 absorption units 36 and 38 arranged in series. The mixed gas stream 34 is fed near the bottom of a first absorber unit 36 containing a fixed bed of pall rings 40. The mixed gas stream passes up though the bed 40 where it contacts with a descending aqueous stream of mixed alkali metal hydroxide and alkali metal carbonate fed to the first unit 36 from the bottom of second unit 38. A chemical reaction takes place whereby the alkali metal hydroxide reacts with the carbon dioxide to form alkali metal carbonate. The resulting alkali metal carbonate solution, comprising 36% wt alkali metal carbonate and 6% wt alkali metal hydroxide is recovered from the bottom of the first unit 36 via line 42 and cooled by means of a heat exchanger (not shown). The unreacted gas stream, depleted in carbon dioxide, is passed from the top of unit 36 via line 44 to near the bottom of the second unit 38, which contains a further packed bed of pall rings 46. The gas stream then passes up through the bed 46 where it contacts with a descending aqueous stream of alkali metal hydroxide obtained from line 16 and fed to near the top of the second unit via line 48. The remaining carbon dioxide in the gas stream passing through the second unit 38 reacts with the alkali metal hydroxide generating alkali metal carbonate. The resulting mixed alkali metal hydroxide and alkali metal carbonate solution is passed via line 50 from the bottom of the second unit 38 via a cooling heat exchanger (not shown) to near the top of the first unit 34. The remaining hydrogen-containing gas stream is passed from the top of the second unit 38 via line 52 to a compressor 54 and the compressed gas passed to a drying vessel 56 containing a bed of molecular sieves 58 that remove any remaining traces of water. The dried hydrogen-containing gas stream is recovered from the system 10 via line 22. The gas stream recovered from the ageing vessel, which is substantially carbon dioxide, is conveyed to the system 10 via line 14. Fresh carbon dioxide in line 24 may be mixed with the recovered carbon dioxide in line 14 and the resulting mixture fed to near the bottom of a CO2 scrubbing unit 60 containing a fixed bed of pall rings 62. The carbon dioxide ascends through the bed 62 where it is in contact with a descending mixture of alkali metal carbonate and alkali metal hydroxide fed to near the top of the scrubber unit 60 via line 64. The mixture in line 64 comprises the 36% wt mixed alkali metal carbonate/ 6% wt alkali metal hydroxide stream 42 recovered from the bottom of the first absorber unit 36 and a fresh 40% wt aqueous alkali metal hydroxide stream 66 obtained from line 16. The carbon dioxide in the gas stream passing through the bed 62 reacts with the alkali metal hydroxide descending through the bed to form alkali metal carbonate. The resulting 42% wt alkali metal carbonate/alkali metal hydroxide mixture is recovered from the bottom of scrubber unit 60 via line 20, cooled if necessary, and fed to a catalyst precipitation unit (not shown). Unreacted carbon dioxide is recovered from the top of the scrubber unit 60 via line 26 and sent to a stack for disposal or recycled to line 14. . '
Where CO2 recovery is only from one of the ageing vessel or reducer that the relevant section of the unit of Figure 1 may be removed or suitably adapted.

Claims

Claims.
1. A process for manufacturing a catalyst composition comprising the steps of
(i) combining one or more soluble metal compounds with a solution of an alkaline metal carbonate precipitant to form a precipitate of insoluble metal carbonates,
(ii) processing the insoluble metal carbonates into a catalyst or catalyst precursor with the evolution of carbon dioxide,
(iii) recovering at least a portion of the evolved carbon dioxide, and
(iv) reacting the recovered carbon dioxide with a suitable alkaline metal compound in an absorber column to generate an alkaline metal carbonate, wherein at least a portion of the generated alkaline metal carbonate is used as a precipitant in step (i).
2. A process according to claim 1 wherein the one or more soluble metal compounds comprises a compound of Ca, Mg, Ti, V, Cr, Mn, Fe, Cr, Co, Ni, Cu, Zn, or Pb.
3. A process according to claim 1 or claim 2 wherein the soluble metal compound is selected from a metal chloride, acetate, sulphate or nitrate.
4. A process according to any one of claims 1 to 3 wherein a thermostabilising material is present during the precipitation of insoluble metal compounds.
5. A process according to any one of claims 1 to 4 wherein the alkaline metal carbonate precipitant is an alkali metal carbonate.
6. A process according to any one of claims 1 to 5 wherein the further processing of the insoluble metal compounds into a catalyst or catalyst precursor includes a step of ageing the insoluble metal compounds.
7. A process according to any one of claims 1 to 6 wherein the further processing of the insoluble metal compounds into a catalyst or catalyst precursor includes a step of drying the insoluble metal compounds.
8. A process according to any one of claims 1 to 7 wherein the further processing of the insoluble metal compounds into a catalyst or catalyst precursor includes a step of calcining the insoluble metal compounds. A process according to any one of claims 1 to 8 wherein insoluble metal compounds comprise a reducible metal, the further processing of the insoluble metal compounds into a catalyst or catalyst precursor includes a step of reducing the insoluble metal compounds.
PCT/GB2009/000789 2008-04-04 2009-03-26 Process for preparing catalysts Ceased WO2009122140A2 (en)

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BRPI0910443A BRPI0910443A2 (en) 2008-04-04 2009-03-26 process for preparing catalysts involving the regeneration of metal carbonate precipitates
CA2718952A CA2718952A1 (en) 2008-04-04 2009-03-26 Process for preparing catalysts
AU2009232223A AU2009232223B2 (en) 2008-04-04 2009-03-26 Process for preparing catalysts involving the regeneration of metal carbonate precipitants
CN2009801111475A CN101980784B (en) 2008-04-04 2009-03-26 Process for preparing catalysts involving the regeneration of metal carbonate precipitants
US12/936,067 US8815191B2 (en) 2008-04-04 2009-03-26 Process for preparing catalysts involving the regeneration of metal carbonate precipitants
RU2010145183/04A RU2482918C2 (en) 2008-04-04 2009-03-26 Method of making catalysts comprising regeneration of metal carbonate agents
EP09728991A EP2288441A2 (en) 2008-04-04 2009-03-26 Process for preparing catalysts involving the regenaration of metal carbonate precipitants
NZ588032A NZ588032A (en) 2008-04-04 2009-03-26 Process for preparing catalysts involving the regeneration of metal carbonate precipitants
UAA201013079A UA99013C2 (en) 2008-04-04 2009-03-26 Method for manufacturing catalyst or catalyst precursor

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US8815191B2 (en) 2014-08-26
US20110104039A1 (en) 2011-05-05
GB0806148D0 (en) 2008-05-14
RU2010145183A (en) 2012-05-20
CN101980784B (en) 2013-04-24
CA2718952A1 (en) 2009-10-08
AU2009232223A1 (en) 2009-10-08
BRPI0910443A2 (en) 2015-09-29
EP2288441A2 (en) 2011-03-02
CN101980784A (en) 2011-02-23
NZ588032A (en) 2011-12-22
RU2482918C2 (en) 2013-05-27
AU2009232223B2 (en) 2013-02-14
UA99013C2 (en) 2012-07-10

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