WO2010047967A1 - Surgical laser tip apparatus with alignment assembly - Google Patents

Surgical laser tip apparatus with alignment assembly Download PDF

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Publication number
WO2010047967A1
WO2010047967A1 PCT/US2009/060014 US2009060014W WO2010047967A1 WO 2010047967 A1 WO2010047967 A1 WO 2010047967A1 US 2009060014 W US2009060014 W US 2009060014W WO 2010047967 A1 WO2010047967 A1 WO 2010047967A1
Authority
WO
WIPO (PCT)
Prior art keywords
tip
housing
surgical device
assembly
laser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/060014
Other languages
French (fr)
Inventor
Alexandre B. Di Sessea
Mihai I.A. Boiter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zap Lasers LLC
Original Assignee
Zap Lasers LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zap Lasers LLC filed Critical Zap Lasers LLC
Priority to BRPI0914478A priority Critical patent/BRPI0914478A2/en
Priority to EP09822419A priority patent/EP2346433A4/en
Priority to CA2741452A priority patent/CA2741452C/en
Priority to CN200980141923.6A priority patent/CN102202594B/en
Publication of WO2010047967A1 publication Critical patent/WO2010047967A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
    • A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
    • A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
    • A61B18/22—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser the beam being directed along or through a flexible conduit, e.g. an optical fibre; Couplings or hand-pieces therefor
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G02B6/36—Mechanical coupling means
    • G02B6/38—Mechanical coupling means having fibre to fibre mating means
    • G02B6/3807—Dismountable connectors, i.e. comprising plugs
    • G02B6/3895—Dismountable connectors, i.e. comprising plugs identification of connection, e.g. right plug to the right socket or full engagement of the mating parts
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G02B6/42—Coupling light guides with opto-electronic elements
    • G02B6/4296—Coupling light guides with opto-electronic elements coupling with sources of high radiant energy, e.g. high power lasers, high temperature light sources
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00—Surgical instruments, devices or methods
    • A61B2017/0023—Surgical instruments, devices or methods disposable
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00—Surgical instruments, devices or methods
    • A61B2017/0046—Surgical instruments, devices or methods with a releasable handle; with handle and operating part separable
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
    • A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
    • A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
    • A61B18/22—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser the beam being directed along or through a flexible conduit, e.g. an optical fibre; Couplings or hand-pieces therefor
    • A61B2018/2205—Characteristics of fibres
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
    • A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
    • A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
    • A61B18/22—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser the beam being directed along or through a flexible conduit, e.g. an optical fibre; Couplings or hand-pieces therefor
    • A61B2018/2255—Optical elements at the distal end of probe tips
    • A61B2018/2285—Optical elements at the distal end of probe tips with removable, replacable, or exchangable tips
    • A61B2018/22853—Means to identify tip configuration
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G02B6/42—Coupling light guides with opto-electronic elements
    • G02B6/4296—Coupling light guides with opto-electronic elements coupling with sources of high radiant energy, e.g. high power lasers, high temperature light sources
    • G02B2006/4297—Coupling light guides with opto-electronic elements coupling with sources of high radiant energy, e.g. high power lasers, high temperature light sources having protection means, e.g. protecting humans against accidental exposure to harmful laser radiation
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G02B6/36—Mechanical coupling means
    • G02B6/38—Mechanical coupling means having fibre to fibre mating means
    • G02B6/3807—Dismountable connectors, i.e. comprising plugs
    • G02B6/381—Dismountable connectors, i.e. comprising plugs of the ferrule type, e.g. fibre ends embedded in ferrules, connecting a pair of fibres

Definitions

  • This invention relates to surgical instruments for laser ablation procedures. More particularly, the invention relates to a tip apparatus having an assembly for proper optical fiber alignment with a laser diode for such surgical instruments.
  • laser light is transmitted from a laser source though an optical fiber to a treatment site.
  • the optical fiber terminates proximally in a laser source connector for connection to the laser source and terminates distally in a handpiece manipulated by the surgeon.
  • the sterile, disposable tip provided means for precise alignment of the optical fiber in the tip to the source of laser energy in the surgical device. Yet another useful advantage would be for the sterile, disposable tip to be releasably attached to the device with precise optical, mechanical, magnetic, electromechanical, or electro-magnetic locking and alignment assembly.
  • Fig. 1 is an exploded perspective view of an embodiment of disposable tip apparatus 100 with alignment assembly adapted to a reusable surgical device laser housing 500.
  • Fig. 2 is a cut away perspective view of a first embodiment of an assembled reusable surgical device laser housing 500 of Fig. 1 taken at "2 - 2" with the disposable tip apparatus 100 adapted thereto.
  • Fig, 3 is a cut away perspective view of a second embodiment of an assembled reusable surgical device laser housing 500 with the disposable tip apparatus 100A with alignment assembly adapted thereto.
  • disposable tip apparatus 100 and 100A for optical alignment with reusable laser surgical device are presented.
  • the reference numerals 100 and 100A designate generally typical apparatus for optical alignment of a disposable tip with a reusable laser surgical device.
  • An embodiment for apparatus 100 for optical alignment of a disposable tip with a reusable laser surgical device includes the following combined elements: a disposable tip housing 10 with a first end 12 having a longitudinal axis 14 and adapted to releasably fit on the distal end 510 of the surgical device laser housing 500; optical fiber means 30 for delivery of light energy axially positioned within the tip housing 10 from within the first end 14 and extending beyond the housing 10; assembly 16 for releasably locking the tip housing first end 14 to the surgical device laser housing assembly 500; and assembly for aligning optical fiber means 30 within the tip housing 10 to a source of laser light energy, such as a diode laser, within the surgical device laser housing assembly 500 for surgical laser treatment.
  • a source of laser light energy such as a diode laser
  • the tip apparatus 100 provides a channel 520 within the surgical device laser housing assembly 500 sized to receive the tip housing first end 12 along the longitudinal axis 14 for aligning the optical fiber means 30 within the tip housing 10 to the surgical device laser housing assembly 500.
  • the surgical device laser housing assembly 500 is adaptably sized and configured to direct diode laser light energy from within the laser housing assembly 500 to the optical fiber means 30 within the tip housing 10 once the tip housing first end 12 is fully positioned within the surgical device channel 520.
  • An embodiment of the tip apparatus 100 provides a conductive wire sensor 530 made from gold plated steel and having two ends, 532 and 534, within the surgical device laser housing assembly 500 positioned transverse to the tip housing longitudinal axis 14, whereby the conductive wire sensor 530 contacts the tip housing first end 12 when it is fully positioned within the surgical device channel 520. Contact between the conductive wire sensor 530 and tip housing first end 12 causes the conductive wire sensor 530 to close an electrical circuit (not shown) within the surgical device laser housing assembly 500 and allows use of the tip apparatus 100, Figs. 1 and 2.
  • the conductive wire sensor 530 is housed within the surgical device housing assembly 500 by insulated tubing 540.
  • An embodiment of the apparatus 100 provides an assembly 16 for releasably locking the first end 12 to the laser housing channel 520 comprising at least one member of the group consisting of means for magnetic coupling, means for mechanical coupling, means for electro-mechanical coupling, and means for electro-magnetic coupling.
  • a second embodiment 100A includes an emitter element 50 and a detector element 52 providing an optical sensing assembly, Fig. 3, to indicate when the tip housing first end 12 is fully positioned within the surgical device channel 520 and properly aligned with the laser housing assembly 500.
  • the optical sensing assembly closes an electrical circuit (not shown) within the surgical device laser housing assembly 500 and allows use of the tip apparatus 100A.
  • An embodiment of the tip housing 10 is made of at least one member of the group consisting of polyimide, polycarbon, stainless steel, steel, iron, plastic, and aluminum.
  • An embodiment of the tip apparatus 100 is packaged as a sterile assembly.

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Surgery (AREA)
  • General Physics & Mathematics (AREA)
  • Biomedical Technology (AREA)
  • Otolaryngology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Laser Surgery Devices (AREA)

Abstract

An assembly for alignment of a sterile, releasably locking optical tip assembly housing an optical fiber connection to a laser surgical device includes a conductive wire sensing element. A second embodiment includes an emitter and a detector.

Description

SURGICAL LASER TIP APPARATUS WITH ALIGNMENT ASSEMBLY
BACKGROUND OF THE INVENTION
This invention relates to surgical instruments for laser ablation procedures. More particularly, the invention relates to a tip apparatus having an assembly for proper optical fiber alignment with a laser diode for such surgical instruments.
BRIEF SUMMARY OF THE INVENTION
In practice, medical laser treatment using hand-held instruments has generally been developed for ophthalmic, dental, orthopedic, and similar surgical procedures where the treatment area is confined or particularly difficult to reach. Typically, laser light is transmitted from a laser source though an optical fiber to a treatment site. The optical fiber terminates proximally in a laser source connector for connection to the laser source and terminates distally in a handpiece manipulated by the surgeon.
With known systems, a handpiece used during one procedure often cannot be used with another patient in a subsequent procedure unless some form of sterilization is performed. Types of sterilization techniques range from autoclaves to gas. Gas procedures are time consuming and costly. Autoclave temperatures generally have proven too severe for laser surgical handpieces to withstand. These problems could be overcome using a sterile, disposable tip for use with a laser surgical device. Use of disposable tips, however, present optical alignment problems between the tips and the diode laser source in the surgical instrument.
Accordingly it would be useful to provide a sterile, disposable tip having a quick and easy to use alignment and connection assembly for use with a laser surgical device, such as our disposable surgical tip apparatus disclosed and claimed in pending U.S. Non-provisional Patent Application Serial No. 12/115,336, filed on May 5, 2008 ["the '336 Application"] which is incorporated herein by reference for all purposes.
It would be of further use if the sterile, disposable tip provided means for precise alignment of the optical fiber in the tip to the source of laser energy in the surgical device. Yet another useful advantage would be for the sterile, disposable tip to be releasably attached to the device with precise optical, mechanical, magnetic, electromechanical, or electro-magnetic locking and alignment assembly.
For a more complete understanding of the above and other features, advantages, and objects of the invention, reference should be made to the following detailed description of a preferred embodiment, and to the accompanying drawings.
BRIEF DESCRIPTION OF DRAWINGS
Fig. 1 is an exploded perspective view of an embodiment of disposable tip apparatus 100 with alignment assembly adapted to a reusable surgical device laser housing 500. Fig. 2 is a cut away perspective view of a first embodiment of an assembled reusable surgical device laser housing 500 of Fig. 1 taken at "2 - 2" with the disposable tip apparatus 100 adapted thereto.
Fig, 3 is a cut away perspective view of a second embodiment of an assembled reusable surgical device laser housing 500 with the disposable tip apparatus 100A with alignment assembly adapted thereto.
DETAILED DESCRIPTION OF THE INVENTION
With reference to drawing Figs. 1 - 3, disposable tip apparatus 100 and 100A for optical alignment with reusable laser surgical device are presented. The reference numerals 100 and 100A designate generally typical apparatus for optical alignment of a disposable tip with a reusable laser surgical device.
Our disposable surgical tip apparatus disclosed and claimed in the '336 Application is incorporated herein by reference for all purposes.
An embodiment for apparatus 100 for optical alignment of a disposable tip with a reusable laser surgical device, includes the following combined elements: a disposable tip housing 10 with a first end 12 having a longitudinal axis 14 and adapted to releasably fit on the distal end 510 of the surgical device laser housing 500; optical fiber means 30 for delivery of light energy axially positioned within the tip housing 10 from within the first end 14 and extending beyond the housing 10; assembly 16 for releasably locking the tip housing first end 14 to the surgical device laser housing assembly 500; and assembly for aligning optical fiber means 30 within the tip housing 10 to a source of laser light energy, such as a diode laser, within the surgical device laser housing assembly 500 for surgical laser treatment.
The tip apparatus 100 provides a channel 520 within the surgical device laser housing assembly 500 sized to receive the tip housing first end 12 along the longitudinal axis 14 for aligning the optical fiber means 30 within the tip housing 10 to the surgical device laser housing assembly 500. The surgical device laser housing assembly 500 is adaptably sized and configured to direct diode laser light energy from within the laser housing assembly 500 to the optical fiber means 30 within the tip housing 10 once the tip housing first end 12 is fully positioned within the surgical device channel 520.
An embodiment of the tip apparatus 100 provides a conductive wire sensor 530 made from gold plated steel and having two ends, 532 and 534, within the surgical device laser housing assembly 500 positioned transverse to the tip housing longitudinal axis 14, whereby the conductive wire sensor 530 contacts the tip housing first end 12 when it is fully positioned within the surgical device channel 520. Contact between the conductive wire sensor 530 and tip housing first end 12 causes the conductive wire sensor 530 to close an electrical circuit (not shown) within the surgical device laser housing assembly 500 and allows use of the tip apparatus 100, Figs. 1 and 2. The conductive wire sensor 530 is housed within the surgical device housing assembly 500 by insulated tubing 540.
An embodiment of the apparatus 100 provides an assembly 16 for releasably locking the first end 12 to the laser housing channel 520 comprising at least one member of the group consisting of means for magnetic coupling, means for mechanical coupling, means for electro-mechanical coupling, and means for electro-magnetic coupling.
A second embodiment 100A includes an emitter element 50 and a detector element 52 providing an optical sensing assembly, Fig. 3, to indicate when the tip housing first end 12 is fully positioned within the surgical device channel 520 and properly aligned with the laser housing assembly 500. When the tip housing first end
12 is properly positioned within the surgical device channel 520 and properly aligned with the laser housing assembly 500, the optical sensing assembly closes an electrical circuit (not shown) within the surgical device laser housing assembly 500 and allows use of the tip apparatus 100A. An embodiment of the tip housing 10 is made of at least one member of the group consisting of polyimide, polycarbon, stainless steel, steel, iron, plastic, and aluminum.
An embodiment of the tip apparatus 100 is packaged as a sterile assembly.
It should be understood, of course, that the specific forms of the invention illustrated herein and described are intended to be representative only, as certain changes may be made therein without departing from the clear teachings of the disclosure. Accordingly, reference should be made to the following appended claims in determining the full scope of the invention.

Claims

We claim:
1. Tip apparatus for optical alignment with a reusable laser surgical device, comprising in combination: a) a disposable tip housing with a first end having a longitudinal axis and adapted to releasably fit on the distal end of the surgical device; b) optical fiber means for delivery of light energy axialiy positioned within the tip housing from within the first end and extending beyond the tip housing; c) means for releasably locking the tip housing first end to the surgical device; and d) means for aligning fiber optic means within the tip housing with the surgical device for surgical laser treatment.
2. The tip apparatus of claim 1 , wherein means for aligning the optical fiber means within the tip housing with the surgical device comprises a channel within a laser housing of the surgical device sized to receive the tip housing first end along the longitudinal axis. 3. The tip apparatus of claim 2, wherein means for aligning the optical fiber means within the tip apparatus with the surgical device comprises a conductive wire sensor having two ends within the surgical device laser housing positioned transverse to the tip housing longitudinal axis, whereby the conductive wire sensor contacts the tip housing first end when it is fully positioned within the surgical device laser housing channel. 4. The tip apparatus of claim 3, wherein the conductive wire sensor is housed within the surgical device by insulated tubing.
2. The tip apparatus of claim 4, wherein contact between the conductive wire sensor and tip housing first end causes the conductive wire sensor to close an electrical circuit. 3. The tip apparatus of claim 5, wherein the wire sensor comprises gold plated steel.
4. The tip apparatus of claim 2, wherein means for aligning the optical fiber means within the tip apparatus with the surgical device comprises an emitter element and a detector element.
5. The tip apparatus of claim 1 , wherein means for releasably locking the first end to the surgical device comprises at least one member of the group consisting of means for magnetic coupling, means for mechanical coupling, means for electro-mechanical coupling, and means for electro-magnetic coupling. 6. The tip apparatus of claim 1 , wherein the tip housing is made of at least one member of the group consisting of polyimide, polycarbon, stainless steel, steel, iron, plastic, and aluminum.
7. The tip apparatus of claim 1 packaged as a sterile assembly.
8. Tip assembly for reusable surgical laser treatment device, the tip assembly comprising in combination: a) a disposable tip housing with a first end having a longitudinal axis and adapted to releasably fit on the distai end of the surgical device; b) optical fiber means for delivery of light energy axially positioned within the tip housing from within the first end and extending beyond the tip housing; c) means for releasably locking the tip housing first end to a laser housing within the surgical device; d) channel assembly within the surgical device laser housing sized to receive the tip housing first end along the longitudinal axis means for aligning fiber optic means within the tip housing with the surgical device laser housing for surgical laser treatment; and e) conductive wire sensor assembly having two ends within the surgical device laser housing positioned transverse to the tip housing longitudinal axis, whereby the conductive wire sensor contacts the tip housing first end when it is fully positioned within the surgical device laser housing channel assembly.
11. The tip assembly of claim 10, wherein the tip housing is made of at least one member of the group consisting of polyimide, polycarbon, stainless steel, steel, iron, plastic, and aluminum.
12. The tip apparatus of claim 10, wherein means for releasabiy locking the tip housing first end coupling, and means for electro-magnetic coupling.
13. The tip assembly of claim 10, wherein the disposable tip housing is packaged as a sterile assembly.
14. The tip assembly of claim 10, wherein the wire sensor comprises gold plated steel.
15. Tip assembly for reusable surgical laser treatment device, the tip assembly comprising in combination: a) a disposable tip housing with a first end having a longitudinal axis and adapted to releasably fit on the distal end of the surgical device; b) optical fiber means for delivery of light energy axially positioned within the tip housing from within the first end and extending beyond the tip housing; c) means for releasably locking the tip housing first end to a laser housing within the surgical device; d) channel assembly within the surgical device laser housing sized to receive the tip housing first end along the longitudinal axis means for aligning fiber optic means within the tip housing with the surgical device laser housing for surgical laser treatment; and e) an emitter element and a detector element, whereby the emitter and detector elements are configured to indicate when the tip housing first end is fully positioned within the surgical device laser housing channel assembly.
16. The tip assembly of claim 15, wherein the disposable tip housing is packaged as a sterile assembly.
PCT/US2009/060014 2008-10-24 2009-10-08 Surgical laser tip apparatus with alignment assembly Ceased WO2010047967A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0914478A BRPI0914478A2 (en) 2008-10-24 2009-10-08 laser pointer surgical apparatus with alignment set
EP09822419A EP2346433A4 (en) 2008-10-24 2009-10-08 SURGICAL DEVICE WITH LASER TIP WITH ALIGNMENT ASSEMBLY
CA2741452A CA2741452C (en) 2008-10-24 2009-10-08 Surgical laser tip apparatus with alignment assembly
CN200980141923.6A CN102202594B (en) 2008-10-24 2009-10-08 Surgical laser tip apparatus with alignment assembly

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/257,665 2008-10-24
US12/257,665 US8535300B2 (en) 2008-10-24 2008-10-24 Surgical laser tip apparatus with alignment assembly

Publications (1)

Publication Number Publication Date
WO2010047967A1 true WO2010047967A1 (en) 2010-04-29

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ID=42118193

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/060014 Ceased WO2010047967A1 (en) 2008-10-24 2009-10-08 Surgical laser tip apparatus with alignment assembly

Country Status (7)

Country Link
US (1) US8535300B2 (en)
EP (1) EP2346433A4 (en)
KR (1) KR20110089276A (en)
CN (1) CN102202594B (en)
BR (1) BRPI0914478A2 (en)
CA (1) CA2741452C (en)
WO (1) WO2010047967A1 (en)

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CA2741452C (en) 2016-03-22
KR20110089276A (en) 2011-08-05
EP2346433A4 (en) 2012-07-18
US8535300B2 (en) 2013-09-17
CN102202594B (en) 2015-01-14
BRPI0914478A2 (en) 2015-10-27
CN102202594A (en) 2011-09-28
US20100106147A1 (en) 2010-04-29
EP2346433A1 (en) 2011-07-27
CA2741452A1 (en) 2010-04-29

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