WO2010071580A1 - Method of making cemented carbide products - Google Patents

Method of making cemented carbide products Download PDF

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Publication number
WO2010071580A1
WO2010071580A1 PCT/SE2009/051441 SE2009051441W WO2010071580A1 WO 2010071580 A1 WO2010071580 A1 WO 2010071580A1 SE 2009051441 W SE2009051441 W SE 2009051441W WO 2010071580 A1 WO2010071580 A1 WO 2010071580A1
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WIPO (PCT)
Prior art keywords
powder
cemented carbide
wax
injection moulding
granulated
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PCT/SE2009/051441
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French (fr)
Inventor
Mattias Puide
Per Jonsson
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Seco Tools AB
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Seco Tools AB
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Publication date
Application filed by Seco Tools AB filed Critical Seco Tools AB
Priority to JP2011542068A priority Critical patent/JP2012512962A/en
Priority to US13/140,642 priority patent/US8951463B2/en
Priority to CN2009801512273A priority patent/CN102256728B/en
Priority to EP09833743.9A priority patent/EP2379253B1/en
Publication of WO2010071580A1 publication Critical patent/WO2010071580A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B22F3/225—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/103—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14—Treatment of metallic powder
    • B22F1/148—Agglomerating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/05—Mixtures of metal powder with non-metallic powder
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/05—Mixtures of metal powder with non-metallic powder
    • C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/005—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides comprising a particular metallic binder
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds

Definitions

  • the present invention relates to a method for the production of tungsten carbide based hard metal tools or components using the powder injection moulding method.
  • Hard metals based on tungsten carbide are composites consisting of small ( ⁇ m-scale) grains of at least one hard phase in a binder phase. These materials always contain the hard phase tungsten car- bide (WC) .
  • WC tungsten car- bide
  • other metal carbides with the general composition (Ti, Nb, Ta, W) C may also be included, as well as metal car- bonitrides, e.g., Ti(C, N) .
  • the binder phase usually consists of cobalt (Co) .
  • Other binder phase compositions may also be used, e.g., combinations of Co, Ni, and Fe, or Ni and Fe.
  • the granulating agent adheres to the surface of the powders and also binds many particles together to a free flowing granulated powder. Since the binder adheres to the metal surfaces, it slows down the oxidation rate of the metal surfaces, and decreases the risk of self ignition and dust explosions. Since the granulating agent binds many particles together, it reduces the risk of air borne dust to be inhaled.
  • metal powders granulated with PEG are usually used, when the slurry processing is performed in a water-ethanol mixture.
  • Industrial production of tungsten carbide based hard metals often includes blending of given proportions of powders of raw materials and additives in the wet state using a milling liquid. This liquid is often an alcohol, e.g., ethanol or water or a mixture thereof.
  • the mixture is then milled into homogeneous slurry.
  • the wet milling operation is made with the purpose of deagglomeration and mixing the raw materials intimately. Individual raw material grains are also disintegrated to some extent.
  • the obtained slurry is then dried and granulated, e.g. by means of a spray dryer.
  • the granu- late thus obtained may then be used in uniaxial pressing of green bodies or for extrusion or injection moulding.
  • Injection moulding is common in the plastics industry, where material containing thermoplastics or thermosetting polymers are heated and forced into a mould with the desired shape.
  • the method is often referred to as Powder Injection Moulding (PIM) when used in powder technology.
  • PIM Powder Injection Moulding
  • the method is preferably used for parts with complex geometry.
  • the binder system acts as a carrier for the powder and constitutes 25-60 volume % of the resulting material, often referred to as the feedstock.
  • the exact concentration is dependent on the desired process properties during moulding.
  • the mixing is made with all organic constituents in molten state.
  • the resulting feedstock is obtained as pellets of approximate size 4x4 mm.
  • Injection moulding is performed using the mixed feedstock.
  • the material is heated to 100-240 0 C and then forced into a cavity with the desired shape.
  • the thus obtained part is cooled and then removed from the cavity.
  • the solids loading, ⁇ , of the feedstock is the volumetric amount of hard constituents, compared to the organic constituents, ⁇ can be calculated using the following equation:
  • the viscosity of the feedstock is affected by the viscosity of the organic binder.
  • the organic binder viscosity is close related to the green strength of the material.
  • a low green strength can cause the parts to crack during extraction, where the expansion of the wax during melting causes stresses in the part.
  • Another drawback with a low green strength is that the parts may be damaged during the handling of the parts.
  • a high green strength of the material means a high viscosity of the organic binder.
  • the method according to the present invention comprises the following steps : 1) Wet milling of the raw materials, i.e. the hard constituents and metallic binder powder, granulated with a nonpolar wax, preferably paraffin wax, in water or alcohol or a combination thereof, preferably 80 wt-% ethanol and 20 wt-% water, together with 0.1- 1.2 wt-%, preferably 0.25-0.55 wt-% carboxylic acid, preferably stearic acid as a granulating agent for the subsequent drying. More carboxylic acid is required the smaller the grain size of the hard constituents.
  • the invention can be used for all compositions of cemented carbide and all WC grain sizes commonly used as well as for titanium car- bonitride based materials.
  • a WC-13 wt-% Co submicron cemented carbide powder was made by wet milling 780 g PEG-granulated Co-powder (OMG extra fine, granulated with 2% PEG), 38.66 g Cr3C2 (H C Starck) , 5161 g WC (H C Starck DS80), 20.44 g W metal powder, 16 g Fisher-Tropsch wax (Sasol Hl) and 22 g stearic acid in 1,6 1 milling liquid consisting of etha- nol and water (80:20 by weight) for 40 h.
  • the stearic acid is added in this stage of the process to work as a granule forming agent, when spray drying the slurry.
  • the resulting slurry was spray dried to a granulated powder.
  • a WC-13 wt-% Co submicron cemented carbide powder was made by wet milling 780 g wax-granulated Co-powder (OMG extra fine, granulated with 1,5 % paraffin wax), 38.66 g Cr3C2 (H C Starck), 5161 g WC (H C Starck DS80), 20.44 g W metal powder, 16 g Fisher-Tropsch wax
  • Example 1 The powder made in Example 1 was mixed by kneading 2500 g powder from Example 1 with 50.97 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 16 ml at 121 0 C according to ASTM D-1646 (Engage 8440, Dow Plastics) and 45.87 g Paraffin wax (Sasol Wax) and 5.06 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a ⁇ of 0.553.
  • Example 4 Comparative
  • Example 1 The powder made in Example 1 was mixed by kneading 2500 g powder from Example 1 with 50.97 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 10 ml at 121 0 C according to ASTM D-1646 (En- gage 8445, Dow Plastics) and 45.87 g Paraffin wax (Sasol Wax) and 5.06 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a ⁇ of 0.553.
  • Example 2 The powder made in Example 2 was mixed by kneading 2500 g powder from Example 1 with 51.87 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 16 ml at 121 0 C according to ASTM D-1646 (Engage 8440, Dow Plastics) and 46.60 g Paraffin wax (Sasol Wax) and 5.14 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a ⁇ of 0.553.
  • Example 6 (Comparative) The feedstock made in example 3 was fed into an injection moulding machine (Battenfeld HM 60/130/22) .
  • the machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body.
  • the injection pressure was 39,8 MPa at an injection speed of 15 ml/s.
  • the green bodies had enough green strength for handling without being damaged.
  • the feedstock made in example 4 was fed into an injection moulding machine (Battenfeld HM 60/130/22) .
  • the machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body.
  • the injection pressure was 35,1 MPa at an injection speed of 15 ml/s.
  • the green bodies had to be handled with care not to be damaged.
  • the feedstock made in example 5 was fed into an injection moulding machine (Battenfeld HM 60/130/22) .
  • the machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body.
  • the injection pressure was 34,8 MPa at an injection speed of 15 ml/s.
  • the green bodies had enough green strength for handling without being damaged.
  • Example 9 The parts from example 6, example 7 and example 8 were debound by extraction in carbon dioxide at supercritical physical conditions, i.e. at 35 MPa and 58 0 C for 20 hours. After the extraction the parts were inspected. The parts from example 6 and 8 showed no surface cracks or other defects. The parts from example 7 showed small cracks visible with an optical microscope at 50 x magnification .

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  • Materials Engineering (AREA)
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Abstract

The present inventions relates to a method for the production of tungsten carbide based cemented carbide or cermet tools or components using the powder injection moulding method comprising mixing of hard constituent powder and a metallic binder powder with an organic binder system, consisting of 30-60 wt-% olefinic polymers and 40-70 wt-% nonpolar waxes, acting as a carrier for the powder. According to the invention, a metallic binder powder that is granulated with a nonpolar wax is used.

Description

Method for making cemented carbide products
The present invention relates to a method for the production of tungsten carbide based hard metal tools or components using the powder injection moulding method.
Hard metals based on tungsten carbide are composites consisting of small (μm-scale) grains of at least one hard phase in a binder phase. These materials always contain the hard phase tungsten car- bide (WC) . In addition, other metal carbides with the general composition (Ti, Nb, Ta, W) C may also be included, as well as metal car- bonitrides, e.g., Ti(C, N) . The binder phase usually consists of cobalt (Co) . Other binder phase compositions may also be used, e.g., combinations of Co, Ni, and Fe, or Ni and Fe.
The handling of the fine metal powders used for the production of cemented carbide and cermets are problematic in two ways. Since fine grained powders have large specific surface areas, they are sensitive to reaction with the oxygen in the air. The metal powder oxidation is an exothermal reaction. Also, the oxidation rate increases with the temperature. This means that the oxidation of fine metal powders is an autoaccelerating process. Due to this, self igniting and dust explosions of the metal powders are a serious risk. Further, it has been reported that the inhalation of most of these metal powders is a serious health risk.
These problems are usually solved with a granulation of these powders with an organic binder. The granulating agent adheres to the surface of the powders and also binds many particles together to a free flowing granulated powder. Since the binder adheres to the metal surfaces, it slows down the oxidation rate of the metal surfaces, and decreases the risk of self ignition and dust explosions. Since the granulating agent binds many particles together, it reduces the risk of air borne dust to be inhaled.
In the production of cemented carbide, metal powders granulated with PEG are usually used, when the slurry processing is performed in a water-ethanol mixture. Industrial production of tungsten carbide based hard metals often includes blending of given proportions of powders of raw materials and additives in the wet state using a milling liquid. This liquid is often an alcohol, e.g., ethanol or water or a mixture thereof. The mixture is then milled into homogeneous slurry. The wet milling operation is made with the purpose of deagglomeration and mixing the raw materials intimately. Individual raw material grains are also disintegrated to some extent. The obtained slurry is then dried and granulated, e.g. by means of a spray dryer. The granu- late thus obtained may then be used in uniaxial pressing of green bodies or for extrusion or injection moulding.
Injection moulding is common in the plastics industry, where material containing thermoplastics or thermosetting polymers are heated and forced into a mould with the desired shape. The method is often referred to as Powder Injection Moulding (PIM) when used in powder technology. The method is preferably used for parts with complex geometry.
In powder injection moulding of tungsten carbide based hard metal parts, four consecutive steps are applied:
1. Mixing of the granulated cemented carbide powder with a binder system. The binder system acts as a carrier for the powder and constitutes 25-60 volume % of the resulting material, often referred to as the feedstock. The exact concentration is dependent on the desired process properties during moulding. The mixing is made with all organic constituents in molten state. The resulting feedstock is obtained as pellets of approximate size 4x4 mm.
2. Injection moulding is performed using the mixed feedstock. The material is heated to 100-240 0C and then forced into a cavity with the desired shape. The thus obtained part is cooled and then removed from the cavity.
3. Removing the binder from the obtained part. The removal can be obtained by extraction of the parts in a suitable solvent and/or by heating in a furnace with a suitable atmosphere. This step is often referred to as the debinding step. 4. Sintering of the parts. Common sintering procedures for cemented carbides are applied.
The solids loading, φ, of the feedstock is the volumetric amount of hard constituents, compared to the organic constituents, φ can be calculated using the following equation:
A -A where ps is the density of the cemented carbide as sintered, pv is the mean density of the organic constituents and pf is the density of the feedstock, measured with the helium pycnometer.
The viscosity of the feedstock is affected by the viscosity of the organic binder. The organic binder viscosity is close related to the green strength of the material. A low green strength can cause the parts to crack during extraction, where the expansion of the wax during melting causes stresses in the part. Another drawback with a low green strength is that the parts may be damaged during the handling of the parts. A high green strength of the material means a high viscosity of the organic binder.
In the case of having a high viscosity, problems with mould filling, extended mould wear, weld lines, which may open during sin- tering, forming cracks and surface defects as well as mould release problems may occur.
It is an object of the present invention to provide a material with a lower viscosity of the feedstock without sacrificing the green strength.
It has now surprisingly been found that by using metallic binder raw material granulated with a wax, the feedstock shows a significantly lower viscosity during injection moulding without sacrific- ing the green strength.
The method according to the present invention comprises the following steps : 1) Wet milling of the raw materials, i.e. the hard constituents and metallic binder powder, granulated with a nonpolar wax, preferably paraffin wax, in water or alcohol or a combination thereof, preferably 80 wt-% ethanol and 20 wt-% water, together with 0.1- 1.2 wt-%, preferably 0.25-0.55 wt-% carboxylic acid, preferably stearic acid as a granulating agent for the subsequent drying. More carboxylic acid is required the smaller the grain size of the hard constituents.
2) Drying of the slurry formed during the above mentioned wet milling process step.
3) Mixing the dried powder by kneading with a binder system, con- sisting of 30-60 wt-% olefinic polymers and 40-70 wt-% nonpolar waxes. The mixing is performed in a batch mixer or twin screw extruder, heated to 50-200 0C that forms pellets with a size of approximately 4x4 mm.
4) Injection moulding of the feedstock in a conventional injection moulding machine. The material is heated to 100-240 0C, preferably 120-140 0C, and then forced into a cavity with the desired shape. The obtained part is cooled and then removed from the cavity.
5) Debinding the obtained part. The debinding is performed in two steps .
5a) By extraction of the wax in a nonpolar solvent, at 31-70 0C, preferably at 31-55 0C. It is within the purview of the skilled artisan to determine by experiments the conditions necessary to avoid the formation of cracks and other defects according to this specification .
5b) By heating in a furnace, preferably in a flowing gaseous me- dium atmosphere at 2 mbar to atmospheric pressure up to 450 0C. It is within the purview of the skilled artisan to determine by experiments the conditions necessary to avoid the formation of cracks and other defects according to this specification. 6) Presintering of the part in the debinding furnace in vacuum at 900-1250 0C, preferably at about 1200 0C.
7) Sintering of the parts using conventional sintering technique.
The invention can be used for all compositions of cemented carbide and all WC grain sizes commonly used as well as for titanium car- bonitride based materials.
Example 1 (Comparative)
A WC-13 wt-% Co submicron cemented carbide powder was made by wet milling 780 g PEG-granulated Co-powder (OMG extra fine, granulated with 2% PEG), 38.66 g Cr3C2 (H C Starck) , 5161 g WC (H C Starck DS80), 20.44 g W metal powder, 16 g Fisher-Tropsch wax (Sasol Hl) and 22 g stearic acid in 1,6 1 milling liquid consisting of etha- nol and water (80:20 by weight) for 40 h. The stearic acid is added in this stage of the process to work as a granule forming agent, when spray drying the slurry. The resulting slurry was spray dried to a granulated powder.
Example 2 (Invention)
A WC-13 wt-% Co submicron cemented carbide powder was made by wet milling 780 g wax-granulated Co-powder (OMG extra fine, granulated with 1,5 % paraffin wax), 38.66 g Cr3C2 (H C Starck), 5161 g WC (H C Starck DS80), 20.44 g W metal powder, 16 g Fisher-Tropsch wax
(Sasol Hl) and 22 g stearic acid in 1,6 1 milling liquid consisting of ethanol and water (80:20 by weight) for 40 h. The stearic acid is added in this stage of the process to work as a granule forming agent, when spray drying the slurry. The resulting slurry was spray dried to a granulated powder.
Example 3 (Comparative)
The powder made in Example 1 was mixed by kneading 2500 g powder from Example 1 with 50.97 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 16 ml at 121 0C according to ASTM D-1646 (Engage 8440, Dow Plastics) and 45.87 g Paraffin wax (Sasol Wax) and 5.06 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a φ of 0.553. Example 4 (Comparative)
The powder made in Example 1 was mixed by kneading 2500 g powder from Example 1 with 50.97 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 10 ml at 121 0C according to ASTM D-1646 (En- gage 8445, Dow Plastics) and 45.87 g Paraffin wax (Sasol Wax) and 5.06 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a φ of 0.553.
Example 5 (Invention)
The powder made in Example 2 was mixed by kneading 2500 g powder from Example 1 with 51.87 g poly (ethylene-co- (alpha-octene) ) with a Mooney viscosity of 16 ml at 121 0C according to ASTM D-1646 (Engage 8440, Dow Plastics) and 46.60 g Paraffin wax (Sasol Wax) and 5.14 g petroleum jelly (Merkur VARA AB) in a Z-blade kneader mixer (Werner & Pfleiderer LUK 1,0) . This resulted in a feedstock with a density of 8.23 g/ml, corresponding to a φ of 0.553.
Example 6 (Comparative) The feedstock made in example 3 was fed into an injection moulding machine (Battenfeld HM 60/130/22) . The machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body. The injection pressure was 39,8 MPa at an injection speed of 15 ml/s. The green bodies had enough green strength for handling without being damaged.
Example 7 (Comparative)
The feedstock made in example 4 was fed into an injection moulding machine (Battenfeld HM 60/130/22) . The machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body. The injection pressure was 35,1 MPa at an injection speed of 15 ml/s. The green bodies had to be handled with care not to be damaged.
Example 8 (Invention)
The feedstock made in example 5 was fed into an injection moulding machine (Battenfeld HM 60/130/22) . The machine was used for the injection moulding of a Seco Tools Minimaster 10 mm endmill green body. The injection pressure was 34,8 MPa at an injection speed of 15 ml/s. The green bodies had enough green strength for handling without being damaged.
Example 9 The parts from example 6, example 7 and example 8 were debound by extraction in carbon dioxide at supercritical physical conditions, i.e. at 35 MPa and 58 0C for 20 hours. After the extraction the parts were inspected. The parts from example 6 and 8 showed no surface cracks or other defects. The parts from example 7 showed small cracks visible with an optical microscope at 50 x magnification .

Claims

Claims
1. Method for the production of tungsten carbide based cemented carbide or cermet tools or components using the powder injection moulding method comprising mixing of hard constituent powder and a metallic binder powder with an organic binder system, consisting of 30-60 wt-% olefinic polymers and 40-70 wt-% nonpolar waxes, acting as a carrier for the powder c h a r a c t e r i s e d in using a metallic binder powder that is granulated with a nonpolar wax .
2. Method according to claim 1, c h a r a c t e r i s e d in that said nonpolar wax is a paraffin wax.
PCT/SE2009/051441 2008-12-18 2009-12-17 Method of making cemented carbide products Ceased WO2010071580A1 (en)

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JP2011542068A JP2012512962A (en) 2008-12-18 2009-12-17 Method for manufacturing cemented carbide products
US13/140,642 US8951463B2 (en) 2008-12-18 2009-12-17 Method for making cemented carbide products
CN2009801512273A CN102256728B (en) 2008-12-18 2009-12-17 Method for preparing cemented carbide product
EP09833743.9A EP2379253B1 (en) 2008-12-18 2009-12-17 Method of making cemented carbide products

Applications Claiming Priority (2)

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SE0802601-5 2008-12-18
SE0802601A SE533922C2 (en) 2008-12-18 2008-12-18 Ways to manufacture cemented carbide products

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WO2010071580A1 true WO2010071580A1 (en) 2010-06-24

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KR (1) KR101653014B1 (en)
CN (1) CN102256728B (en)
SE (1) SE533922C2 (en)
WO (1) WO2010071580A1 (en)

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SE533922C2 (en) 2011-03-01
EP2379253B1 (en) 2017-02-22
EP2379253A1 (en) 2011-10-26
KR101653014B1 (en) 2016-08-31
US8951463B2 (en) 2015-02-10
SE0802601A1 (en) 2010-06-19
CN102256728B (en) 2013-09-04
KR20110110120A (en) 2011-10-06
US20120025411A1 (en) 2012-02-02
JP2012512962A (en) 2012-06-07
CN102256728A (en) 2011-11-23
EP2379253A4 (en) 2014-11-26

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