WO2010071586A1 - Cermet - Google Patents
Cermet Download PDFInfo
- Publication number
- WO2010071586A1 WO2010071586A1 PCT/SE2009/051448 SE2009051448W WO2010071586A1 WO 2010071586 A1 WO2010071586 A1 WO 2010071586A1 SE 2009051448 W SE2009051448 W SE 2009051448W WO 2010071586 A1 WO2010071586 A1 WO 2010071586A1
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- WO
- WIPO (PCT)
- Prior art keywords
- based carbonitride
- carbonitride alloy
- titanium based
- alloy according
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/04—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1084—Alloys containing non-metals by mechanical alloying (blending, milling)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
Definitions
- the present invention relates to a sintered carbonitride alloy with Ti as main component and a cobalt binder phase, which has im- proved properties particularly when used as tool material for steel and cast iron cutting. More particularly, the present invention relates to a carbonitride-based alloy of specific composition and controlled relative saturation magnetization and coercivity for optimal combination of abrasive wear resistance, toughness and resistance to plastic deformation.
- Titanium-based carbonitride alloys so called cermets
- cermets are widely used for metal cutting purposes.
- cermets have excellent chemical stability when in contact with hot steel, even if it is uncoated, but have substan- tially lower toughness. This makes them most suited for finishing operations, which generally are characterized by limited mechanical loads on the cutting edge and a high surface finish requirement on the finished component.
- Cermets comprise carbonitride hard constituents embedded in a metallic binder phase generally of Co and/or Ni.
- the hard constituent grains generally have a complex structure with a core, most often surrounded by one or more rims of other composition.
- group Via elements normally both Mo and W, are added to facilitate wetting between binder and hard constituents and to strengthen the binder phase by means of solution hardening.
- group IVa and/or Va elements e.g. Zr, Hf, V, Nb and Ta, are also added in all commercial alloys available today. Cermets are produced using powder metallurgical methods. Powders forming binder phase and powders forming hard constituents are mixed, pressed and sintered.
- US 6,344,170, US 6,344,445 and US 6,325,838 relate to a sintered body of a carbonitride alloy with titanium as main component with improved properties when used as cutting tool material. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened Co binder phase. By optimizing composition and sintering process in the Ti-Ta-W-C-N-Co system improved toughness and resistance to plastic deformation are accomplished. The two parameters that are used to optimize toughness and resistance to plastic deformation are the Ta- and Co-contents.
- the use of pure Co-based binder is a major advantage over mixed Co-Ni-based binders with respect to the toughness behavior due to the differences in solution hardening between Co and Ni .
- US 7,332,122, and US 7,157,044 are similar. They relate to a titanium based carbonitride alloy containing Ti, Nb, W, C, N and Co. By replacing Ta in US 6,344,170 by Nb and carefully controlling the amount of undissolved Ti (C, N) cores a further optimization of technological properties has been achieved. More particularly, said patents relate to a carbonitride-based hard phase of specific composition, for which the amount of undissolved Ti (C, N) cores is optimized for maximal abrasive wear resistance, while the Co and Nb contents are simultaneously optimized to give the desired toughness and resistance to plastic deformation.
- Fig. 1 shows the microstructure in detail and Fig. 2 shows the microstructure in a lower magnification of an alloy according to the invention as observed in back scattering mode in a scanning electron microscope in which
- A depicts undissolved Ti (C, N) -cores
- B depicts a complex carbonitride phase sometimes surrounding the A-cores and C depicts the Co binder phase.
- optimum combination of abrasive wear resistance, toughness, resistance to plastic deformation and work piece surface finish for the intended application area has been achieved by op- timizing the amount of carbo-nitride formers dissolved in the Co based binder, the ratio between Ta and Nb and the hard constituent grain size.
- the content of dissolved carbo-nitride formers in the binder phase may be expressed by the S-value, the magnetic saturation of the sample divided by the magnetic saturation of the same amount of pure Co as in the sample.
- the S-value depends on the content of dissolved metals in the binder phase and increases with decreasing amount of solutes.
- the sintered grain size of the hard constituents may be expressed by the magnetic coercivity.
- the Co content must be chosen to give the desired properties for the envisioned application area. This is best achieved by a Co content of 7 to 21 wt%. In a first embodiment the Co-content is 8 to 15 wt% and, particularly, for fine machining applications the Co content must be 8 to 10 wt% and for applications requiring balanced resistance to plastic deformation and toughness 12 to 15 wt%. In a second embodiment requiring higher toughness the preferred Co content is 15 to 20 wt%.
- the W content must be 14 to 22 wt%, preferably 16 to 19 wt%.
- the Ta content must be 5 to 11 wt%, preferably 6 to 9 wt%.
- the Nb content must be 2 to 7 wt%, preferably 3 to 5 wt%.
- the Ti content must be 33 to 50 wt%, preferably 37 to 47 wt%.
- the ratio between added Ta wt% and Nb wt% must be 1.8 to 2.1.
- the overall N/C weight ratio in the sintered alloy must be in the range 0.6 to 0.75.
- the C content must be adjusted such that the relative satura- tion magnetization is within 0.60 to 0.90, preferably 0.65 to 0.80.
- a method of manufacturing a sintered titanium-based carbonitride alloy In another aspect of the invention, there is provided a method of manufacturing a sintered titanium-based carbonitride alloy. Hard constituent powders of TiC x N]__ x , having x in the range 0.45- 0.55 and an FSSS grain size of 1 to 2 ⁇ m, TaC, NbC and WC are mixed with powder of Co to a composition within the limits given above and pressed into bodies of desired shape.
- Sintering is per- formed in a N2 ⁇ Ar atmosphere, having a total pressure of 10-40 mbar and a partial pressure of N2 of 0.5 to 4 mbar, at a temperature in the range 1370-1500 0 C for 0.5-1 h. It is within the purview of the skilled artisan to determine by experiments the conditions necessary to obtain the desired microstructure according to this specification.
- the powders were spray dried and pressed into SNUN120408 inserts.
- the inserts were dewaxed in H 2 and subsequently sintered in a N2 ⁇ Ar atmosphere, total pressure of 10 mbar and a partial pressure of N2 of 1 mbar, for 1.0 h at 148O 0 C which was followed by grinding and conventional edge treatment.
- Polished cross sections of inserts were prepared by standard metallographic techniques and characterized using scanning electron microscopy.
- Fig. 1 and Fig. 2 show a scanning electron micrographs of such a cross section, taken in back scattering mode. The porosity was determined according to ISO 4505 standard. Magnetic properties were determined by standard methods.
- the porosity levels of alloys outside the preferred relative magnetic saturation range are higher and, thus, detrimental for the toughness.
- Inserts of type DCMT 11T304 of alloys D and E according to example 2 were prepared.
- the magnetic properties of alloy E is within the present invention. However, the saturation magnetization of alloy D is outside.
- the surface roughness of the work piece, Ra was monitored as a function of cutting time. At shorter times, ⁇ 5 min the Ra value was similar for the two alloys, 1.2 ⁇ m. After 1 h of turning the Ra value for alloy D was 3.3 ⁇ m and for alloy E 1.8 ⁇ m. The considerably better surface finish of the work piece for alloy E is due to a better resistance to wear.
- Example 4 Cutting tests utilizing inserts of type DCMT 11T304 of alloys G (outside invention) and F (according to invention) in a high toughness demanding work piece were done with following cutting data :
- the resistance to plastic deformation was determined as the maxi- mum cutting speed at which no plastic deformation of the edge was detected.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Hard Magnetic Materials (AREA)
Abstract
The present invention relates to a titanium based carbonitride alloy containing Ti, Nb, Ta, W, C, N and Co. The alloy contains - Co 7 to 21 wt % - W 14 to 20 wt % - Ta 5 to 11 wt % - Nb 2 to 7 wt % and, - Ti 33 to 50 wt % whereby the overall N/C weight ratio is 0.6 to 0.75, the Ta/Nb weight ratio 1.8 to 2.1, the relative saturation magnetization 0.60 to 0.90 and the magnetic coercivity Hc= ( 18.2-0.2*Co wt%) +/- E kA/m, where E is 2.0. The invention also relates to a method of making said alloy.
Description
Cermet
The present invention relates to a sintered carbonitride alloy with Ti as main component and a cobalt binder phase, which has im- proved properties particularly when used as tool material for steel and cast iron cutting. More particularly, the present invention relates to a carbonitride-based alloy of specific composition and controlled relative saturation magnetization and coercivity for optimal combination of abrasive wear resistance, toughness and resistance to plastic deformation.
Titanium-based carbonitride alloys, so called cermets, are widely used for metal cutting purposes. Compared to WC-Co based materials, cermets have excellent chemical stability when in contact with hot steel, even if it is uncoated, but have substan- tially lower toughness. This makes them most suited for finishing operations, which generally are characterized by limited mechanical loads on the cutting edge and a high surface finish requirement on the finished component.
Cermets comprise carbonitride hard constituents embedded in a metallic binder phase generally of Co and/or Ni. The hard constituent grains generally have a complex structure with a core, most often surrounded by one or more rims of other composition. In addition to Ti, group Via elements, normally both Mo and W, are added to facilitate wetting between binder and hard constituents and to strengthen the binder phase by means of solution hardening. One or more of group IVa and/or Va elements, e.g. Zr, Hf, V, Nb and Ta, are also added in all commercial alloys available today. Cermets are produced using powder metallurgical methods. Powders forming binder phase and powders forming hard constituents are mixed, pressed and sintered.
During recent years many attempts have been made to control the main properties of cermets in cutting tool applications, namely toughness, wear resistance and plastic deformation resistance. Much work has been done especially regarding the chemistry of the binder phase
US 6,344,170, US 6,344,445 and US 6,325,838 relate to a sintered body of a carbonitride alloy with titanium as main component with improved properties when used as cutting tool material. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened
Co binder phase. By optimizing composition and sintering process in the Ti-Ta-W-C-N-Co system improved toughness and resistance to plastic deformation are accomplished. The two parameters that are used to optimize toughness and resistance to plastic deformation are the Ta- and Co-contents. The use of pure Co-based binder is a major advantage over mixed Co-Ni-based binders with respect to the toughness behavior due to the differences in solution hardening between Co and Ni .
US 7,332,122, and US 7,157,044 are similar. They relate to a titanium based carbonitride alloy containing Ti, Nb, W, C, N and Co. By replacing Ta in US 6,344,170 by Nb and carefully controlling the amount of undissolved Ti (C, N) cores a further optimization of technological properties has been achieved. More particularly, said patents relate to a carbonitride-based hard phase of specific composition, for which the amount of undissolved Ti (C, N) cores is optimized for maximal abrasive wear resistance, while the Co and Nb contents are simultaneously optimized to give the desired toughness and resistance to plastic deformation.
It is an object of the present invention to design and produce a cermet material with specific composition and controlled relative saturation magnetization and coercivity for optimal combination of abrasive wear resistance, toughness and resistance to plastic deformation.
This has been achieved by working with the alloy system Ti-Ta- Nb-W-C-N-Co. A set of limitations has been found rendering optimum combination of abrasive wear resistance, toughness and resistance to plastic deformation for the intended application areas.
Fig. 1 shows the microstructure in detail and Fig. 2 shows the microstructure in a lower magnification of an alloy according to the invention as observed in back scattering mode in a scanning electron microscope in which
A depicts undissolved Ti (C, N) -cores
B depicts a complex carbonitride phase sometimes surrounding the A-cores and C depicts the Co binder phase.
According to the present invention it has unexpectedly been found that optimum combination of abrasive wear resistance, toughness, resistance to plastic deformation and work piece surface finish for the intended application area has been achieved by op- timizing the amount of carbo-nitride formers dissolved in the Co
based binder, the ratio between Ta and Nb and the hard constituent grain size. The content of dissolved carbo-nitride formers in the binder phase may be expressed by the S-value, the magnetic saturation of the sample divided by the magnetic saturation of the same amount of pure Co as in the sample. The S-value depends on the content of dissolved metals in the binder phase and increases with decreasing amount of solutes. The sintered grain size of the hard constituents may be expressed by the magnetic coercivity.
The Co content must be chosen to give the desired properties for the envisioned application area. This is best achieved by a Co content of 7 to 21 wt%. In a first embodiment the Co-content is 8 to 15 wt% and, particularly, for fine machining applications the Co content must be 8 to 10 wt% and for applications requiring balanced resistance to plastic deformation and toughness 12 to 15 wt%. In a second embodiment requiring higher toughness the preferred Co content is 15 to 20 wt%.
The W content must be 14 to 22 wt%, preferably 16 to 19 wt%.
The Ta content must be 5 to 11 wt%, preferably 6 to 9 wt%.
The Nb content must be 2 to 7 wt%, preferably 3 to 5 wt%. The Ti content must be 33 to 50 wt%, preferably 37 to 47 wt%.
The ratio between added Ta wt% and Nb wt% must be 1.8 to 2.1.
The overall N/C weight ratio in the sintered alloy must be in the range 0.6 to 0.75.
The C content must be adjusted such that the relative satura- tion magnetization is within 0.60 to 0.90, preferably 0.65 to 0.80.
The average grain size expressed by the magnetic coercivity depends on the amount of Co added and must be Hc= ( 18.2-0.2*Co w%) +/- E kA/m, where E is 2.0, preferably 1.5, and most preferably 1.0.
For certain machining operations requiring even higher wear resistance it is advantageous to coat the body of the present invention with a thin wear resistant coating using PVD, CVD, MTCVD or similar techniques. In another aspect of the invention, there is provided a method of manufacturing a sintered titanium-based carbonitride alloy. Hard constituent powders of TiCxN]__x, having x in the range 0.45- 0.55 and an FSSS grain size of 1 to 2 μm, TaC, NbC and WC are mixed with powder of Co to a composition within the limits given above and pressed into bodies of desired shape. Sintering is per-
formed in a N2~Ar atmosphere, having a total pressure of 10-40 mbar and a partial pressure of N2 of 0.5 to 4 mbar, at a temperature in the range 1370-15000C for 0.5-1 h. It is within the purview of the skilled artisan to determine by experiments the conditions necessary to obtain the desired microstructure according to this specification.
Example 1
Three powder mixtures of nominal composition (wt%) Ti 46.4, Ta 8.2, Nb 4.2, W 17.1, Co 9.0, N 6.1 and a N/C ratio of 0.69(Alloy A, invention), 0.74 (Alloy B, reference) and 0.64 (Alloy C, reference) were prepared by wet milling of
TiCQ.50N0.50 with a grain size FSSS of 1.25 μm
TaC, grain size 2.1 μm
NbC, grain size 2.0 μm
WC grain size 2.5 μm
Co grain size 0.80 μm
Pressing aid, PEG.
The powders were spray dried and pressed into SNUN120408 inserts. The inserts were dewaxed in H2 and subsequently sintered in a N2~Ar atmosphere, total pressure of 10 mbar and a partial pressure of N2 of 1 mbar, for 1.0 h at 148O0C which was followed by grinding and conventional edge treatment. Polished cross sections of inserts were prepared by standard metallographic techniques and characterized using scanning electron microscopy. Fig. 1 and Fig. 2 show a scanning electron micrographs of such a cross section, taken in back scattering mode. The porosity was determined according to ISO 4505 standard. Magnetic properties were determined by standard methods.
** number of pores >25 μm per cm2
The porosity levels of Alloy B and Alloy C, which are outside the preferred relative magnetic saturation range, are detrimental for the toughness.
Example 2
Six powder mixtures were prepared by wet milling of raw materials according to Example 1. For Alloy H and Alloy I a coarser TiCo.5ONO.5O with a grain size of 3.5 μm was utilized. The nominal composition (wt%) is shown in the following table
Sintered inserts were prepared and analyzed according to Example 1. The results are found below:
* AOl indicates porosity level in between AOO and A02
* BOl indicates porosity level in between BOO and B02 ** number of pores >25 μm per cm2
The porosity levels of alloys outside the preferred relative magnetic saturation range are higher and, thus, detrimental for the toughness.
Example 3
Inserts of type DCMT 11T304 of alloys D and E according to example 2 were prepared. The magnetic properties of alloy E is within the present invention. However, the saturation magnetization of alloy D is outside. The inserts were used for turning of steel SS1672 at
vc=200 m/min, f=0.10 mm and ap=0.25 mm. The surface roughness of the work piece, Ra, was monitored as a function of cutting time. At shorter times, <5 min the Ra value was similar for the two alloys, 1.2 μm. After 1 h of turning the Ra value for alloy D was 3.3 μm and for alloy E 1.8 μm. The considerably better surface finish of the work piece for alloy E is due to a better resistance to wear.
Example 4 Cutting tests utilizing inserts of type DCMT 11T304 of alloys G (outside invention) and F (according to invention) in a high toughness demanding work piece were done with following cutting data :
Work piece material: DIN42Cr41 Cutting speed=220 m/min,
Feed=0.2 mm/r,
Depth of cut=0.4 mm and with coolant.
Result: Life time in number of passes, average of six edges. Alloy G: 18
Alloy F: 28
Example 5
Plastic deformation resistance for the two alloys D (outside in- vention) and E (according to invention) was investigated in a turning test.
Work piece material: SS2541 depth of cut=l mm, feed=0.3 mm/r, cutting time=2.0 min
The resistance to plastic deformation was determined as the maxi- mum cutting speed at which no plastic deformation of the edge was detected.
Result: maximum cutting speed, average of two edges.
Alloy D: 240 m/min
Alloy E: 310 m/min From the examples above it is clear that inserts produced according to the invention have both substantially improved toughness and deformation resistance.
Claims
1. A titanium based carbonitride alloy containing Ti, Nb, Ta, W, C, N and Co c h a r a c t e r i z e d in that the relative saturation magnetization is 0.60 to 0.90, preferably 0.65 to 0.80, and the magnetic coercivity Hc= ( 18.2-0.2*Co wt%) +/- E kA/m, where E is 2.0, preferably 1.5.
2. A titanium based carbonitride alloy according to claim 1 c h a r a c t e r i s e d in containing
- Co 7 to 21 wt%, - W 14 to 20 wt%,
- Ta 5 to 11 wt%,
- Nb 2 to 7 wt%, and
- Ti 33 to 50 wt%.
3. A titanium based carbonitride alloy according to claim 2 c h a r a c t e r i s e d in containing
- W 16 to 18 wt%,
- Ta 6 to 9 wt%,
- Nb 3 to 5 wt%, and
- Ti 37 to 47 wt%.
4. A titanium based carbonitride alloy according to claims 2 or 3 c h a r a c t e r i s e d in containing
- Co 8 to 15 wt%.
5. A titanium based carbonitride alloy according to claims 2 or 3 c h a r a c t e r i s e d in containing - Co 15 to 20 wt%.
6. A titanium based carbonitride alloy according to any of claims 2 to 5 c h a r a c t e r i s e d in an overall N/C weight ratio of 0.6 to 0.75.
7. A titanium based carbonitride alloy according to any of claims 2 to 6 c h a r a c t e r i s e d in a Ta/Nb weight ratio of 1.8 to 2.1.
8. A titanium based carbonitride alloy according to any of the preceding claims c h a r a c t e r i s e d in being coated with a thin wear resistant coating using PVD, CVD, MTCVD or similar techniques.
9. Method of manufacturing a sintered titanium-based carbonitride alloy containing Ti, Nb, Ta, W, C, N and Co by mixing hard constituent powders of TiCxN]__x having x in the range 0.45-0.55 and an FSSS grain size of 1 to 2 μm, TaC, NbC and WC with powder of Co to a composition and pressing into bodies of desired shape, sintering in a N2~Ar atmosphere, c h a r a c t e r i s e d said atmosphere having a total pressure of 10-40 mbar and a partial pressure of N2 of 0.5 to 4 mbar, at a temperature of 1370-15000C for 0.5-1 h.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/140,682 US9499884B2 (en) | 2008-12-18 | 2009-12-17 | Cermet |
| CN2009801511872A CN102257171B (en) | 2008-12-18 | 2009-12-17 | Cermet |
| JP2011542071A JP2012512963A (en) | 2008-12-18 | 2009-12-17 | cermet |
| EP09833749.6A EP2379762B1 (en) | 2008-12-18 | 2009-12-17 | Cermet |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE0802600A SE534073C2 (en) | 2008-12-18 | 2008-12-18 | cermet |
| SE0802600-7 | 2008-12-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010071586A1 true WO2010071586A1 (en) | 2010-06-24 |
Family
ID=42269039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/SE2009/051448 Ceased WO2010071586A1 (en) | 2008-12-18 | 2009-12-17 | Cermet |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9499884B2 (en) |
| EP (1) | EP2379762B1 (en) |
| JP (1) | JP2012512963A (en) |
| KR (1) | KR101629530B1 (en) |
| CN (1) | CN102257171B (en) |
| SE (1) | SE534073C2 (en) |
| WO (1) | WO2010071586A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2434032A1 (en) | 2010-12-08 | 2012-03-28 | SECO TOOLS AB (publ) | Coated fine grained cermet for finish turning applications |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6278232B2 (en) * | 2013-11-01 | 2018-02-14 | 住友電気工業株式会社 | cermet |
| CN116162838B (en) * | 2023-04-26 | 2023-06-30 | 崇义章源钨业股份有限公司 | Metal ceramic and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6325838B1 (en) * | 1999-05-03 | 2001-12-04 | Sandvik Ab | TI(C, N)—(TI, TA, W) (C, N)—CO alloy for toughness demanding cutting tool applications |
| US6340445B1 (en) * | 1999-05-03 | 2002-01-22 | Sandvik Ab | Ti(C,N)-(Ti,Ta,W)(C,N)-Co alloy for superfinishing cutting tool applications |
| US6344170B1 (en) * | 1999-05-03 | 2002-02-05 | Sandvik Ab | Ti(C,N)-(Ti,Ta,W)(C,N)-Co alloy for general finishing cutting tool applications |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59129751A (en) * | 1983-01-13 | 1984-07-26 | Mitsubishi Metal Corp | Superheat-resistant sintered alloy and its production |
| SE9202090D0 (en) * | 1992-07-06 | 1992-07-06 | Sandvik Ab | SINTERED CARBONITRIDE ALLOY WITH IMPROVED TOUGHNESS BEHAVIOUR |
| US6344445B1 (en) | 1995-10-19 | 2002-02-05 | Cantab Pharmaceutical Research Limited | Herpes virus vectors and their uses |
| SE514053C2 (en) * | 1999-05-03 | 2000-12-18 | Sandvik Ab | Method of Manufacturing Ti (C, N) - (Ti, Ta, W) (C, N) -Co alloys for cutting tool applications |
| SE525744C2 (en) | 2002-11-19 | 2005-04-19 | Sandvik Ab | Ti (C, N) - (Ti, Nb, W) (C, N) -Co alloy for milling cutter applications |
| SE525745C2 (en) * | 2002-11-19 | 2005-04-19 | Sandvik Ab | Ti (C- (Ti, Nb, W) (C, N) -Co alloy for lathe cutting applications for fine machining and medium machining |
| CN1312078C (en) * | 2004-10-29 | 2007-04-25 | 华中科技大学 | Submicron grain Ti(C,N)-base cermet and its prepn process |
| JP4569767B2 (en) * | 2005-06-14 | 2010-10-27 | 三菱マテリアル株式会社 | Titanium carbonitride-based cermet throwaway tip that exhibits excellent wear resistance in high-speed cutting with high heat generation |
| CN101302595A (en) * | 2008-07-08 | 2008-11-12 | 湖南科技大学 | High wear-resistant Ti(C,N)-based cermet tool and its preparation |
-
2008
- 2008-12-18 SE SE0802600A patent/SE534073C2/en not_active IP Right Cessation
-
2009
- 2009-12-17 US US13/140,682 patent/US9499884B2/en active Active
- 2009-12-17 CN CN2009801511872A patent/CN102257171B/en active Active
- 2009-12-17 JP JP2011542071A patent/JP2012512963A/en not_active Withdrawn
- 2009-12-17 EP EP09833749.6A patent/EP2379762B1/en active Active
- 2009-12-17 KR KR1020117013781A patent/KR101629530B1/en active Active
- 2009-12-17 WO PCT/SE2009/051448 patent/WO2010071586A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6325838B1 (en) * | 1999-05-03 | 2001-12-04 | Sandvik Ab | TI(C, N)—(TI, TA, W) (C, N)—CO alloy for toughness demanding cutting tool applications |
| US6340445B1 (en) * | 1999-05-03 | 2002-01-22 | Sandvik Ab | Ti(C,N)-(Ti,Ta,W)(C,N)-Co alloy for superfinishing cutting tool applications |
| US6344170B1 (en) * | 1999-05-03 | 2002-02-05 | Sandvik Ab | Ti(C,N)-(Ti,Ta,W)(C,N)-Co alloy for general finishing cutting tool applications |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP2379762A4 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2434032A1 (en) | 2010-12-08 | 2012-03-28 | SECO TOOLS AB (publ) | Coated fine grained cermet for finish turning applications |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012512963A (en) | 2012-06-07 |
| CN102257171B (en) | 2013-08-14 |
| SE0802600A1 (en) | 2010-06-19 |
| EP2379762B1 (en) | 2017-02-22 |
| EP2379762A4 (en) | 2015-08-26 |
| CN102257171A (en) | 2011-11-23 |
| US20110262296A1 (en) | 2011-10-27 |
| EP2379762A1 (en) | 2011-10-26 |
| US9499884B2 (en) | 2016-11-22 |
| SE534073C2 (en) | 2011-04-19 |
| KR20110095358A (en) | 2011-08-24 |
| KR101629530B1 (en) | 2016-06-13 |
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