WO2010090496A2 - 폴리락타이드 수지 및 이의 제조 방법 - Google Patents

폴리락타이드 수지 및 이의 제조 방법 Download PDF

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Publication number
WO2010090496A2
WO2010090496A2 PCT/KR2010/000793 KR2010000793W WO2010090496A2 WO 2010090496 A2 WO2010090496 A2 WO 2010090496A2 KR 2010000793 W KR2010000793 W KR 2010000793W WO 2010090496 A2 WO2010090496 A2 WO 2010090496A2
Authority
WO
WIPO (PCT)
Prior art keywords
polylactide resin
preparation
metal composite
organic metal
showing improved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2010/000793
Other languages
English (en)
French (fr)
Other versions
WO2010090496A3 (ko
Inventor
윤성철
이인수
김성우
박승영
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020090040123A external-priority patent/KR101183225B1/ko
Priority claimed from KR1020090072140A external-priority patent/KR101183226B1/ko
Priority to CN201080009426.3A priority Critical patent/CN102333785B/zh
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority to EP10738780.5A priority patent/EP2395009B1/en
Priority to US13/148,367 priority patent/US20120016101A1/en
Publication of WO2010090496A2 publication Critical patent/WO2010090496A2/ko
Publication of WO2010090496A3 publication Critical patent/WO2010090496A3/ko
Anticipated expiration legal-status Critical
Priority to US14/027,604 priority patent/US20140066645A1/en
Priority to US14/027,700 priority patent/US9415382B2/en
Priority to US14/027,673 priority patent/US20140018515A1/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

본 발명은 보다 향상된 물성을 나타내는 폴리락타이드 수지를 전환율 높게 제조할 수 있게 하는 유기 금속복합체와 촉매 조성물, 상기 유기 금속복합체의 제조 방법, 우수한 기계적 물성과 함께 보다 향상된 내가수분해성 및 내열성 등을 나타내는 폴리락타이드 수지, 이의 제조 방법 및 이를 포함하는 폴리락타이드 수지 조성물에 관한 것이다.
PCT/KR2010/000793 2009-02-09 2010-02-09 폴리락타이드 수지 및 이의 제조 방법 Ceased WO2010090496A2 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US13/148,367 US20120016101A1 (en) 2009-02-09 2010-02-09 Polylactide resin and preparation method thereof
EP10738780.5A EP2395009B1 (en) 2009-02-09 2010-02-09 Polylactide resin and preparation method thereof
CN201080009426.3A CN102333785B (zh) 2009-02-09 2010-02-09 聚乳酸树脂及其制备方法
US14/027,604 US20140066645A1 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof
US14/027,700 US9415382B2 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof
US14/027,673 US20140018515A1 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR10-2009-0010182 2009-02-09
KR20090010182 2009-02-09
KR10-2009-0040123 2009-05-08
KR1020090040123A KR101183225B1 (ko) 2009-05-08 2009-05-08 폴리락타이드 수지, 이의 제조 방법 및 이를 포함하는 폴리락타이드 수지 조성물
KR10-2009-0072140 2009-08-05
KR1020090072140A KR101183226B1 (ko) 2009-02-09 2009-08-05 유기 금속복합체, 촉매 조성물 및 폴리락타이드 수지의 제조 방법

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US13/148,367 A-371-Of-International US20120016101A1 (en) 2009-02-09 2010-02-09 Polylactide resin and preparation method thereof
US14/027,604 Division US20140066645A1 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof
US14/027,673 Division US20140018515A1 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof
US14/027,700 Division US9415382B2 (en) 2009-02-09 2013-09-16 Polylactide resin and preparation method thereof

Publications (2)

Publication Number Publication Date
WO2010090496A2 true WO2010090496A2 (ko) 2010-08-12
WO2010090496A3 WO2010090496A3 (ko) 2010-11-25

Family

ID=44951557

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/000793 Ceased WO2010090496A2 (ko) 2009-02-09 2010-02-09 폴리락타이드 수지 및 이의 제조 방법

Country Status (4)

Country Link
US (4) US20120016101A1 (ko)
EP (1) EP2395009B1 (ko)
CN (1) CN102333785B (ko)
WO (1) WO2010090496A2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9062147B2 (en) * 2011-06-07 2015-06-23 Lg Chem, Ltd. Lactide copolymer, a preparation method thereof, and a resin composition including the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101027163B1 (ko) * 2009-12-18 2011-04-05 주식회사 엘지화학 폴리락타이드 수지, 이의 제조 방법 및 이를 포함하는 폴리락타이드 수지 조성물
DE202011110978U1 (de) * 2010-06-21 2017-11-27 Lg Chem, Ltd. Polylactidharz mit ausgezeichneter Wärmebeständigkeit
US9382386B2 (en) 2012-12-06 2016-07-05 Lg Chem, Ltd Lactide copolymer, method for preparing same, and resin composition comprising same
CN114315789A (zh) * 2020-12-15 2022-04-12 江苏景宏新材料科技有限公司 一种l-丙交酯的制备方法

Citations (3)

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Publication number Priority date Publication date Assignee Title
US5142023A (en) 1992-01-24 1992-08-25 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5338822A (en) 1992-10-02 1994-08-16 Cargill, Incorporated Melt-stable lactide polymer composition and process for manufacture thereof
US6166169A (en) 1996-07-15 2000-12-26 Brussels Biotech Aliphatic polyesters and/or copolyesters and a process for the production thereof

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US5142023A (en) 1992-01-24 1992-08-25 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5338822A (en) 1992-10-02 1994-08-16 Cargill, Incorporated Melt-stable lactide polymer composition and process for manufacture thereof
US6166169A (en) 1996-07-15 2000-12-26 Brussels Biotech Aliphatic polyesters and/or copolyesters and a process for the production thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9062147B2 (en) * 2011-06-07 2015-06-23 Lg Chem, Ltd. Lactide copolymer, a preparation method thereof, and a resin composition including the same

Also Published As

Publication number Publication date
EP2395009A4 (en) 2013-08-14
CN102333785A (zh) 2012-01-25
EP2395009B1 (en) 2014-12-17
US20140018516A1 (en) 2014-01-16
CN102333785B (zh) 2015-06-10
EP2395009A2 (en) 2011-12-14
US20120016101A1 (en) 2012-01-19
WO2010090496A3 (ko) 2010-11-25
US20140018515A1 (en) 2014-01-16
US20140066645A1 (en) 2014-03-06
US9415382B2 (en) 2016-08-16

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