WO2012058416A3 - Cathodically coloring yellow soluble electrochromic and light emitting polymers - Google Patents

Cathodically coloring yellow soluble electrochromic and light emitting polymers Download PDF

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Publication number
WO2012058416A3
WO2012058416A3 PCT/US2011/058070 US2011058070W WO2012058416A3 WO 2012058416 A3 WO2012058416 A3 WO 2012058416A3 US 2011058070 W US2011058070 W US 2011058070W WO 2012058416 A3 WO2012058416 A3 WO 2012058416A3
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WO
WIPO (PCT)
Prior art keywords
yellow
conjugated polymers
units
light emitting
yellow conjugated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/058070
Other languages
French (fr)
Other versions
WO2012058416A9 (en
WO2012058416A2 (en
Inventor
Chad Martin Amb
Justin Adam Kerszulis
John R. Reynolds
Aubrey Lynn Dyer
Emily Thompson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Florida
University of Florida Research Foundation Inc
Original Assignee
University of Florida
University of Florida Research Foundation Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Florida, University of Florida Research Foundation Inc filed Critical University of Florida
Priority to KR1020137013311A priority Critical patent/KR101880319B1/en
Priority to CN201180060133.2A priority patent/CN103328604B/en
Priority to EP11837080.8A priority patent/EP2632996B1/en
Priority to RU2013119838/04A priority patent/RU2578592C2/en
Priority to MX2014012168A priority patent/MX338184B/en
Priority to JP2013536820A priority patent/JP5856179B2/en
Priority to MX2013004837A priority patent/MX2013004837A/en
Priority to CA2816350A priority patent/CA2816350C/en
Priority to BR112013010583A priority patent/BR112013010583A2/en
Publication of WO2012058416A2 publication Critical patent/WO2012058416A2/en
Publication of WO2012058416A3 publication Critical patent/WO2012058416A3/en
Publication of WO2012058416A9 publication Critical patent/WO2012058416A9/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
    • G02F1/15165—Polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1458—Heterocyclic containing sulfur as the only heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1466—Heterocyclic containing nitrogen as the only heteroatom
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)

Abstract

Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross- condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
PCT/US2011/058070 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers Ceased WO2012058416A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
KR1020137013311A KR101880319B1 (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers
CN201180060133.2A CN103328604B (en) 2010-10-28 2011-10-27 Cathodically colored yellow soluble electrochromic and light-emitting polymers
EP11837080.8A EP2632996B1 (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers
RU2013119838/04A RU2578592C2 (en) 2010-10-28 2011-10-27 Cathode-coloured yellow soluble electrochromic and light-emitting polymers
MX2014012168A MX338184B (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers.
JP2013536820A JP5856179B2 (en) 2010-10-28 2011-10-27 Cathode-colored yellow soluble electrochromic and light-emitting polymer
MX2013004837A MX2013004837A (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers.
CA2816350A CA2816350C (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers
BR112013010583A BR112013010583A2 (en) 2010-10-28 2011-10-27 cathodically soluble yellow light-emitting and electrochromic polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US40761510P 2010-10-28 2010-10-28
US61/407,615 2010-10-28

Publications (3)

Publication Number Publication Date
WO2012058416A2 WO2012058416A2 (en) 2012-05-03
WO2012058416A3 true WO2012058416A3 (en) 2012-06-28
WO2012058416A9 WO2012058416A9 (en) 2012-08-16

Family

ID=45994752

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/058070 Ceased WO2012058416A2 (en) 2010-10-28 2011-10-27 Cathodically coloring yellow soluble electrochromic and light emitting polymers

Country Status (10)

Country Link
US (2) US8399603B2 (en)
EP (1) EP2632996B1 (en)
JP (1) JP5856179B2 (en)
KR (1) KR101880319B1 (en)
CN (1) CN103328604B (en)
BR (1) BR112013010583A2 (en)
CA (1) CA2816350C (en)
MX (2) MX338184B (en)
RU (1) RU2578592C2 (en)
WO (1) WO2012058416A2 (en)

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AU2014281580A1 (en) * 2013-06-18 2016-01-21 Georgia Tech Research Corporation Method for preparing dioxyheterocycle-based electrochromic polymers
WO2016027704A1 (en) * 2014-08-19 2016-02-25 株式会社リコー Polythiophene derivative, secondary cell cathode active material, and secondary cell
CN103666445B (en) * 2013-12-17 2015-02-18 京东方科技集团股份有限公司 Blue electrochromic material as well as preparation method and assembly thereof
EP3149066A4 (en) 2014-05-28 2018-06-06 Georgia Tech Research Corporation Yellow to transmissive electrochromic polymers
WO2016081787A2 (en) 2014-11-19 2016-05-26 Biltmore Technologies, Inc. Controlled color and opacity-changing coating system
CA2991051C (en) 2015-07-02 2023-09-05 Neuvokas Corporation Method of manufacturing a composite material
CN105504233B (en) * 2016-01-04 2018-09-07 京东方科技集团股份有限公司 Electrochromic polymeric compounds and preparation method thereof and component comprising it
WO2018039230A1 (en) * 2016-08-22 2018-03-01 Georgia Tech Research Corporation High-gap yellow and orange electrochromic polymers
WO2018142619A1 (en) * 2017-02-06 2018-08-09 日立化成株式会社 Production method for branched polymer, branched polymer, and organic electronics element
WO2018142621A1 (en) * 2017-02-06 2018-08-09 日立化成株式会社 Production method for branched polymer, branched polymer, and organic electronics element
KR102202928B1 (en) * 2017-04-24 2021-01-14 주식회사 엘지화학 A transparent film and electrochromic device comprising the same
KR102141631B1 (en) * 2017-05-31 2020-08-05 주식회사 엘지화학 Transmittance changeable film and method for manufacturing the same)
KR101991843B1 (en) 2017-09-15 2019-06-21 연세대학교 산학협력단 Electrochromic material and electrochromic device comprising the same
WO2019145931A2 (en) * 2018-01-25 2019-08-01 Nxt Gen Nano, Inc. Method of distributing and using custom device colors
CN110964177B (en) * 2018-09-28 2022-07-19 深圳市光羿科技有限公司 Preparation and application of fluoroalkyl electrochromic polymer
US11220573B2 (en) * 2019-07-18 2022-01-11 Ambilight Inc. Electrochromic polymers with amide-containing side chains and methods of fabricating same and electrochromic device containing same
CA3160198A1 (en) 2019-11-12 2021-05-20 Neuvokas Corporation Method of manufacturing a composite material
WO2023063954A1 (en) * 2021-10-14 2023-04-20 Ambilight Inc. Electrochromic polymer having pyrrole derivative and thiophene
US11879098B2 (en) * 2022-02-09 2024-01-23 Ambilight Inc. High transparency electrochromic polymers
US12372842B2 (en) 2022-02-09 2025-07-29 Ambilight Inc High transparency electrochromic polymers
US12529932B2 (en) 2022-02-09 2026-01-20 Ambilight Inc High transparency electrochromic polymers
US20230250223A1 (en) * 2022-02-09 2023-08-10 Ambilight Inc. High transparency electrochromic polymers
US12174505B2 (en) 2022-02-09 2024-12-24 Ambilight Inc High transparency electrochromic polymers
US11874578B2 (en) * 2022-02-09 2024-01-16 Ambilight Inc. High transparency electrochromic polymers
CN114853988B (en) * 2022-05-13 2024-04-12 江苏慧智新材料科技有限公司 Electrochromic polymer containing thiophene embedded units, preparation method, film and device
CN115490836B (en) * 2022-08-18 2024-06-07 浙江工业大学 An electrochromic polymer capable of reversibly changing from yellow to high transmittance and its application

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Also Published As

Publication number Publication date
RU2013119838A (en) 2014-12-10
US8399603B2 (en) 2013-03-19
CN103328604A (en) 2013-09-25
US20130165614A1 (en) 2013-06-27
EP2632996A4 (en) 2017-01-25
MX2013004837A (en) 2013-09-26
US20120108778A1 (en) 2012-05-03
RU2578592C2 (en) 2016-03-27
MX338184B (en) 2016-04-05
US8519090B2 (en) 2013-08-27
WO2012058416A9 (en) 2012-08-16
CA2816350A1 (en) 2012-05-03
BR112013010583A2 (en) 2016-08-09
CA2816350C (en) 2019-01-15
KR101880319B1 (en) 2018-07-19
JP2013540885A (en) 2013-11-07
EP2632996B1 (en) 2019-12-25
WO2012058416A2 (en) 2012-05-03
JP5856179B2 (en) 2016-02-09
EP2632996A2 (en) 2013-09-04
CN103328604B (en) 2015-04-08
KR20140005886A (en) 2014-01-15

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