WO2012121710A1 - Traitement d'un mélange de dioxyde de carbone gazeux par la récupération du pétrole assistée par vapeur - Google Patents

Traitement d'un mélange de dioxyde de carbone gazeux par la récupération du pétrole assistée par vapeur Download PDF

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Publication number
WO2012121710A1
WO2012121710A1 PCT/US2011/027574 US2011027574W WO2012121710A1 WO 2012121710 A1 WO2012121710 A1 WO 2012121710A1 US 2011027574 W US2011027574 W US 2011027574W WO 2012121710 A1 WO2012121710 A1 WO 2012121710A1
Authority
WO
WIPO (PCT)
Prior art keywords
flue gas
carbon dioxide
steam
oxygen
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/027574
Other languages
English (en)
Inventor
David C. Lamont
James. P. SEABA
Thomas J. Wheeler
Edward G. Latimer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
ConocoPhillips Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ConocoPhillips Co filed Critical ConocoPhillips Co
Priority to CA2827765A priority Critical patent/CA2827765A1/fr
Publication of WO2012121710A1 publication Critical patent/WO2012121710A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/2406—Steam assisted gravity drainage [SAGD]
    • E21B43/2408—SAGD in combination with other methods

Definitions

  • Embodiments of the invention relate to methods and systems for processing carbon dioxide in flue gas from oxy-fuel combustion utilizing steam assisted oil recovery.
  • Oxy-fuel combustion refers to burning of fuel in oxygen (e.g., 95% pure oxygen) instead of air to reduce amount of nitrogen in resulting flue gas.
  • the flue gas from the oxy-fuel combustion thus contains carbon dioxide and water vapor, which can be removed if condensed through cooling.
  • the oxy-fuel combustion facilitates carbon dioxide capture since the flue gas is almost pure carbon dioxide with trace amounts of impurities, such as oxygen (e.g., about 0.1-2 volume percent) remaining due to equilibrium constraints as well as local mixing conditions during combustion.
  • Alternate approaches utilize the flue gas from the oxy-fuel combustion. For example, injecting the flue gas into reservoirs of natural gas helps displace the natural gas. However, gas phase interactions of the flue gas in the reservoirs and the interactions not occurring at where the reservoir is being heated limits any possible oxygen removal from the carbon dioxide.
  • a method includes forming a mixture of flue gas from oxy- fuel combustion and steam generated prior to being mixed with the flue gas.
  • the flue gas contains carbon dioxide with an initial concentration of oxygen that is at least 0.1 volume percent.
  • injecting the mixture into a subterranean formation heats oil in the formation and reacts with the oil at least some of the oxygen that is from the flue gas and is dissolved in liquid condensate of the steam.
  • the method further includes recovering fluids including the oil that is heated and carbon dioxide from the flue gas and separating the fluids recovered to isolate from a liquid phase the carbon dioxide containing less than the initial concentration of oxygen for transporting the carbon dioxide to a sequestration site.
  • a method includes producing flue gas from oxy- fuel combustion, generating steam without contact of the steam with the flue gas, and introducing the steam into the flue gas to form a mixture.
  • the flue gas contains carbon dioxide with quantities of oxygen greater than a transport specification.
  • the method includes injecting the mixture into a subterranean formation for heating oil in the formation, recovering fluids including the oil that is heated and the carbon dioxide from the flue gas, and separating the fluids into liquids and vapors.
  • the vapors formed of the carbon dioxide meet the transport specification due to removal of at least some of the oxygen by oxidation of the oil upon the oxygen being dissolved in condensate of the steam for liquid phase reactions at temperatures elevated by the steam.
  • the method further includes transporting to a sequestration site the carbon dioxide obtained by the separating.
  • a system includes a supply of flue gas from an oxy-fuel combustion chamber, a source of steam generated without contact of the steam with the flue gas, and an injection well disposed in a subterranean formation containing oil.
  • the injection well couples in fluid communication with the supply of the flue gas and the source of the steam.
  • a vapor-liquid separator of the system receives produced fluids heated by the steam.
  • the vapor- liquid separator also outputs carbon dioxide that is in the produced fluids from the flue gas and is processed by liquid phase reactions between the oil heated by the steam and at least some oxygen that is from the flue gas and is dissolved in condensate of the steam.
  • the oxy-fuel combustion produces the flue gas 107 containing carbon dioxide with at least 0.1 volume percent oxygen as a result of burning fuel in oxygen, such as at least about 95% by volume pure oxygen separated from air.
  • the carbon dioxide may make up by volume at least about 85%, at least about 90%, or at least about 95% of the flue gas 107.
  • Sources for the fuel include coal, petroleum coke, asphaltenes, methane, natural gas and hydrogen. To limit resulting flame temperatures to levels common during conventional combustion and within thermal thresholds, some cooled combustion gases may circulate back and be injected into a combustion chamber used for the oxy-fuel combustion.
  • the mixture makes the petroleum products mobile enough to enable or facilitate recovery with, for example, the production well 102.
  • the injection well 101 includes a horizontal borehole portion that is disposed above (e.g., 0 to 6 meters above) and parallel to a horizontal borehole portion of the production well 102. While shown in an exemplary steam assisted gravity drainage (SAGD) well pair orientation, some embodiments utilize other configurations of the injection well 101 and the production well 102, which may be combined with the injection well 101 or arranged crosswise relative to the injection well 101, for example.
  • SAGD steam assisted gravity drainage
  • a vapor chamber develops in the formation 103 and grows as the products are recovered. Walls of the vapor chamber form an interface with the products where the steam 105 condenses transferring heat to the products that then drain to the production well 102. Since the flue gas 107 containing the oxygen is injected into the vapor chamber during development of the chamber, the oxygen contacts this condensate of the steam 105 and is dissolved in the condensate enabling both the condensate to carry oxygen into the products and liquid phase reaction of the oxygen with the products. For some embodiments, effective removal of the oxygen from the carbon dioxide in the flue gas 107 relies on the reactions being in liquid phase compared to inefficient gas contact of the oxygen with the products.
  • this oxidation of the products further depends on temperature at which the oxygen contacts the products since oxygen uptake by the products increases with rising temperature.
  • the reactions for some embodiments occur at temperatures that are elevated by the steam 105 and may be above about 100° C, above about 150° C or above about 200° C.
  • Injection of the flue gas 107 through a separate well and outside of the vapor chamber formed by the steam 105 heating the products tends to keep the oxygen in gas phase and insulated from thermal heating by the steam 105 due to physical separation of the oxygen from the condensate.
  • injection of the flue gas 107 after stopping injection of the steam 105 prevents ability of the oxygen to be dissolved in the condensate and carried into the products at as high a temperature as possible. While helpful for processing the carbon dioxide in the flue gas 107, the oxidation of the products lacks influence on recovery due to only trace amounts of the oxygen in the flue gas 107.
  • transport of the carbon dioxide includes compressing the vapor phase 112 that is then passed through a pipeline.
  • the pipeline may carry the carbon dioxide to a sequestration facility such as a geologic reservoir distant from the formation 103 in which the products are recovered.
  • injection of the flue gas 107 from the oxy-fuel combustion into a depleted hydrocarbon reservoir passes the flue gas 107 into contact with unrecovered petroleum products that react with the oxygen from the flue gas 107.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Les présents procédés et dispositif concernent le traitement des effluents gazeux de l'oxycombustion. La vapeur générée sans contact de la vapeur avec des effluents gazeux est combinée aux effluents gazeux pour injection dans une formation, pour faciliter la récupération du pétrole de ladite formation. Les fluides produits incluent le pétrole et du dioxyde de carbone de concentration en oxygène inférieure à celle des effluents gazeux injectés.
PCT/US2011/027574 2011-03-07 2011-03-08 Traitement d'un mélange de dioxyde de carbone gazeux par la récupération du pétrole assistée par vapeur Ceased WO2012121710A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2827765A CA2827765A1 (fr) 2011-03-07 2011-03-08 Traitement d'un melange de dioxyde de carbone gazeux par la recuperation du petrole assistee par vapeur

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/042,096 US20120227964A1 (en) 2011-03-07 2011-03-07 Carbon dioxide gas mixture processing with steam assisted oil recovery
US13/042,096 2011-03-07

Publications (1)

Publication Number Publication Date
WO2012121710A1 true WO2012121710A1 (fr) 2012-09-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/027574 Ceased WO2012121710A1 (fr) 2011-03-07 2011-03-08 Traitement d'un mélange de dioxyde de carbone gazeux par la récupération du pétrole assistée par vapeur

Country Status (3)

Country Link
US (1) US20120227964A1 (fr)
CA (1) CA2827765A1 (fr)
WO (1) WO2012121710A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014205208A1 (fr) * 2013-06-21 2014-12-24 Conocophillips Company Chaudière à oxygène à production assistée par vapeur
WO2015020850A1 (fr) * 2013-08-05 2015-02-12 Conocophillips Company Génération de vapeur à l'aide du recyclage de dioxyde de carbone
US11156072B2 (en) 2016-08-25 2021-10-26 Conocophillips Company Well configuration for coinjection
CA2976575C (fr) 2016-08-25 2025-09-23 Conocophillips Company Configuration de puits en vue de la coinjection
US11125063B2 (en) 2017-07-19 2021-09-21 Conocophillips Company Accelerated interval communication using openholes

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US4330038A (en) * 1980-05-14 1982-05-18 Zimpro-Aec Ltd. Oil reclamation process
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US20080257543A1 (en) * 2007-01-19 2008-10-23 Errico De Francesco Process and apparatus for enhanced hydrocarbon recovery
US20090272532A1 (en) * 2008-04-30 2009-11-05 Kuhlman Myron I Method for increasing the recovery of hydrocarbons
US20100212894A1 (en) * 2009-02-20 2010-08-26 Conocophillips Company Steam generation for steam assisted oil recovery
US20100224370A1 (en) * 2006-09-29 2010-09-09 Osum Oil Sands Corp Method of heating hydrocarbons
US20100276148A1 (en) * 2007-02-10 2010-11-04 Vast Power Portfolio, Llc Hot fluid recovery of heavy oil with steam and carbon dioxide

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DE1216817B (de) * 1963-03-21 1966-05-18 Deutsche Erdoel Ag Verfahren und Vorrichtung zum Foerdern von fluessiger Bitumina aus untertaegigen Lagerstaetten
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US3442332A (en) * 1966-02-01 1969-05-06 Percival C Keith Combination methods involving the making of gaseous carbon dioxide and its use in crude oil recovery
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US4099568A (en) * 1974-02-15 1978-07-11 Texaco Inc. Method for recovering viscous petroleum
US4330038A (en) * 1980-05-14 1982-05-18 Zimpro-Aec Ltd. Oil reclamation process
US7341102B2 (en) * 2005-04-28 2008-03-11 Diamond Qc Technologies Inc. Flue gas injection for heavy oil recovery
US20100224370A1 (en) * 2006-09-29 2010-09-09 Osum Oil Sands Corp Method of heating hydrocarbons
US20080257543A1 (en) * 2007-01-19 2008-10-23 Errico De Francesco Process and apparatus for enhanced hydrocarbon recovery
US20100276148A1 (en) * 2007-02-10 2010-11-04 Vast Power Portfolio, Llc Hot fluid recovery of heavy oil with steam and carbon dioxide
US20090272532A1 (en) * 2008-04-30 2009-11-05 Kuhlman Myron I Method for increasing the recovery of hydrocarbons
US20100212894A1 (en) * 2009-02-20 2010-08-26 Conocophillips Company Steam generation for steam assisted oil recovery

Also Published As

Publication number Publication date
CA2827765A1 (fr) 2012-09-13
US20120227964A1 (en) 2012-09-13

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