WO2013162473A1 - Electrode material and method of synthesizing - Google Patents

Electrode material and method of synthesizing Download PDF

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Publication number
WO2013162473A1
WO2013162473A1 PCT/SG2013/000164 SG2013000164W WO2013162473A1 WO 2013162473 A1 WO2013162473 A1 WO 2013162473A1 SG 2013000164 W SG2013000164 W SG 2013000164W WO 2013162473 A1 WO2013162473 A1 WO 2013162473A1
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group
particles
metal
compound selected
electrode material
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Palani Balaya
Saravanan Kuppan
Bing Liu
Chad William MASON
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National University of Singapore
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National University of Singapore
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Priority to US14/395,921 priority Critical patent/US10090516B2/en
Priority to SG11201406193YA priority patent/SG11201406193YA/en
Priority to EP13781503.1A priority patent/EP2842186B1/en
Publication of WO2013162473A1 publication Critical patent/WO2013162473A1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/54—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of silver
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
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    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present disclosure relates to an electrode material for use in rechargeable batteries.
  • the present disclosure relates to a phosphate framework electrode material for use in rechargeable sodium ion batteries and a method of synthesizing the phosphate framework electrode material.
  • Phosphate framework material possesses fairly well thermal stability and high voltage capabilities required for applications as electrodes e.g. anode or cathode in rechargeable sodium ion batteries.
  • a phosphate framework material for use as electrode e.g. anode or a cathode material, for use in rechargeable sodium ion batteries.
  • the material comprises a compound according to the following formula:
  • Na x A b M y (P0 4 ) z X n denotes the structure of Na-transitional metal-Phosphate nanoparticles, in which,
  • M is a transition metal obtained from a compound selected from a group consisting of metal acetates, metal nitrate metal chloride and metal acetyl acetonate;
  • A is an additional doped or mixed cation(s) obtained from a compound selected from a group consisting of group 1 elements, transition metals, ammonium and hydrogen;
  • X is a substituted anion or polyanion(s) obtained from a compound selected from a group consisting of fluorine, hydroxide, vanadate, arsenate, chloride, pyrophosphate;
  • x, b, y, z and n denote the numbers of ions of a corresponding element, in which:
  • embodiments of the present disclosure provide a method for synthesizing a phosphate framework electrode material.
  • a surfactant and precursors including a sodium precursor, a phosphate precursor and a transition metal precursor are dissolved in a solvent, and maybe stirred for sufficient mixing and reaction.
  • the precursors are reacted to yield a precipitate of particles of Na x C b M y (P0 4 ) z X n compound, and with the surfactant attached to the particles.
  • the solvent is then removed and the remaining precipitate is dried and sintered to crystallize the particles.
  • the surfactant remaining on the particles is decomposed to form a carbon network between the crystallized particles, and the crystallized particles and the carbon matrix are integrated to form the electrode material in bulk form.
  • Fig. 1 is a block diagram showing a method of synthesizing an electrode material according to one embodiment of the present disclosure
  • Fig.2 is a chart showing a Rietveld refinement pattern of X-ray diffraction data of a Na 3 V 2 (P0 4 ) 3 /C sample synthesized as an electrode material according to one embodiment of the present disclosure
  • Fig. 3 A is an FESEM image of a Na 3 V 2 (P0 4 ) 3 /C sample synthesized using C16 surfactant;
  • Fig 3B is an enlarged view of Fig. 3 A
  • Fig, 4A is a TEM image of a mesoporous Na 3 V 2 (P0 4 ) 3 /C particle;
  • Fig. 4B is an enlarged view of Fig. 4A;
  • Fig. 4C is an image of S AED pattern showing single crystalline nature of mesoporous Na 3 V 2 (P0 4 ) 3 /C particles;
  • Fig. 5 is a chart showing N 2 absorption / desorption isotherms of a Na 3 V 2 (P0 4 ) 3 /C sample;
  • Fig. 6A is a chart showing galvanostatic charge / discharge cycle curves of Na 3 V 2 (P0 4 ) 3 /C material used as cathode under different current rates;
  • Fig. 6B is a chart showing long term cyclability curve of Na 3 V 2 (P0 4 ) 3 /C material used as cathode at 1C;
  • Fig. 7A is a chart showing galvanostatic charge / discharge cycle curves of
  • Fig. 7B is a chart showing long term cyclability curve of Na 3 V 2 (P0 4 ) 3 /C material used as anode at 1C.
  • Fig. 1 illustrates a method 100 of synthesizing an electrode material according to one embodiment of the present disclosure.
  • a surfactant and metal precursors including a sodium precursor, a phosphate precursor and a transitional metal precursor are dissolved in a solvent to cause reaction of the precursors in the solvent.
  • the solvent may be alcohol and/or a mixture of de-ionized water and alcohol.
  • the mixture of the precursors may be stirred to help uniform mixing of the reactants at atomic level.
  • the reaction yields a precipitate of amorphous sodium-transitional metal-phosphate compound particles with the surfactant attached thereto.
  • the solvent is removed and at block 106, the remaining precipitate is sintered, e.g. in a flowing, inert gas or a reducing atmosphere.
  • the surfactant remaining on the particles is decomposed to form an integrated conductive carbon matrix between the crystallized nanoparticles, and the crystallized nanoparticles and the carbon matrix are integrated to form the electrode material in bulk form.
  • the above method enables homogeneous mixing of the precursors and control of the particle size and morphology.
  • the carbon matrix decomposed from the surfactant and formed between the nanoparticles prevents the particle agglomeration and growth during the sintering process.
  • the carbon matrix also forms an in-situ coating of electrically conductive carbon layer on the crystallized nanoparticles.
  • the carbon matrix therefore can greatly improve the electrical conductivity to make the electrode material suitable for rechargeable sodium ion battery applications.
  • the above method may be used to synthesize the entire phosphate polyanion family of electrode materials for the sodium ion battery applications.
  • the base formula for these compounds takes the form of: Na x A b M y (P0 4 ) z X n / C where
  • Na x A b My(P0 4 ) z X n denotes the structure of Na-Transitional Metal-Phosphate nanoparticle, in which,
  • M is a transition metal obtained from a compound selected from a group consisting of metal acetates, metal nitrate metal chloride and metal acetyl acetonate;
  • A is an additional doped or mixed cation(s) obtained from a compound selected from a group consisting of group 1 elements, transition metals, ammonium and hydrogen;
  • X is a substituted anion or polyanion(s) obtained from a compound selected from a group consisting of fluorine, hydroxide, vanadate, arsenate, chloride, pyrophosphate;
  • x, b, y, z and n denote the numbers of ions of a corresponding element, in which:
  • C denotes a carbon matrix formed between the Na x A b M y (P0 4 ) z X n nanoparticles.
  • the sodium precursor may be a sodium salt.
  • the phosphate precursor may be an ammonium di-hydrogen phosphate or a phosphoric acid.
  • the transitional metal precursor comprises a compound selected from the group consisting of metal acetates, metal nitrate, metal chloride, metal acetyl acetonate and metal hydroxide.
  • the surfactant provides the necessary carbon content to form the carbon matrix during sintering to integrate with the crystallized nanoparticles.
  • the surfactant comprises a compound selected from the group consisting of Sodium dodecyl sulfate (SDS), octyltrimethyl ammonium bromide (OTAB), dodecyltrimethyl ammonium bromide (DOTAB), cetyltrimethyl ammonium bromide (CTAB) and gluconic acid lactone.
  • SDS Sodium dodecyl sulfate
  • OTAB octyltrimethyl ammonium bromide
  • DOTAB dodecyltrimethyl ammonium bromide
  • CTAB cetyltrimethyl ammonium bromide
  • gluconic acid lactone gluconic acid lactone
  • Sample electrode material synthesized by the above method include, but not limited to, Na 3 V 2 (P0 4 ) 3 /C, Na 3 V 2 (P0 4 ) 2 F 3 /C, Na 2 FeP0 4 F/C, NaVP0 4 F/C,
  • Na 2 FeP0 4 (OH)/C Na 2 Feo. 5 Mn 0 . 5 P0 4 F/C
  • Na 2 Ti 0.5 Mno. 5 P0 4 F/C Na 2 V 0 . 5 Mno . 5P0 4 F/C
  • NaFePCVC Na 3 Ti 2 (P0 4 ) 3 /C.
  • Na 2 Feo .5 Mno. 5 P0 4 F/C Ti in Na 2 Ti 0 . 5 Mno. 5 P0 4 F/C and V in Na 2 V 0 . 5 Mn 0.5 PO 4 F/C and for those containing anion/polyanion e.g. F in Na 3 V 2 (P0 4 ) 2 F 3 /C, compounds or precursors containing the respective cation / anion are added and dissolved in the solvent for reaction together with the sodium precursor, phosphate precursor and transitional metal precursor.
  • the crystallized particles have a grain size between about 20 nm to 200 nm, and the carbon layer coated on the particles has a thickness of about 2 to 10 nm.
  • the carbon matrix portion in the electrode material is not more than about 5% in weight, and forms a carbon coating layer covering the crystallized nanoparticles in a surface area of about 10 to 100 m 2 / gram. Therefore, electrode materials provided by embodiments of the present disclosure have electrically conductive carbon matrix sufficiently mixed and integrated with the crystallized Na- transitional metal-Phosphate nanoparticles.
  • the crystallized Na- transitional metal-Phosphate nanoparticles provide enhanced sodium intercalation / de- intercalation. In the meantime, the interconnected carbon matrix between the
  • nanoparticles provides electrical conductivity suitable for rechargeable sodium ion battery applications.
  • a Na 3 V 2 (P0 4 ) 3 /C (NVP/C) material formed according to the above method is now taken as a non-limiting example to illustrate the characteristics and performances for use as electrode in rechargeable sodium ion batteries. It should be appreciated that other types of phosphate framework material synthesized by the method according to embodiments of the present disclosure may be taken for performance study in a similar manner.
  • Figs. 2 to 5 show test results of structural characterization study and morphological analysis of NVP/C material synthesized according to an embodiment of the present disclosure.
  • Fig. 2 depicts a powder X-ray diffraction pattern (PXRD) of a porous NVP/C electrode material sample. Rietveld refinement of the PXRD pattern is performed to show the pure phase formation of NVP/C, without any impurity. This characteristic is evidenced by the close match of the calculated / fitted curve 22 and measured curve 24 and the difference 23 of curves 22 and 24.
  • PXRD powder X-ray diffraction pattern
  • Figs. 3A and 3B are field emission scanning electron microscope (FESEM) images of NVP/C sample, showing a network of NVP particles with an irregular morphology and various sized ranging from 500 to 900 nm.
  • FESEM field emission scanning electron microscope
  • TEM Transmission Electron Microscopy
  • Figs. 4A and 4B show clear lattice fringes of NVP particle with a uniform carbon layer 42 of about 8nm formed on NVP particle 44.
  • a selected area electron diffraction (SAED) pattern (Fig. 4C) shows single crystalline nature of the NVP nanoparticles which is consistent with the PXRD pattern shown in Fig. 2.
  • Nitrogen absorption / desorption isotherms 52, 54 shown in Fig. 5 indicate that the nanostructured NVP/C prepared according to embodiments of the present disclosure exhibits a distinct large hysteresis loop 56 and this type of behavior is a typical
  • Figs. 6A, 6B, 7A and 7B show test results of electrochemical behaviour study of an NVP/C material synthesized according to embodiment of the present disclosure.
  • the NVP/C material may be used as either a cathode or an anode for sodium ion battery.
  • Galvanostatic cycling curves obtained under current density of 117 mAg "1 from C/10 to 40C, for porous NVP/C material as a cathode in a Na-ion battery is shown in Fig. 6 A.
  • 1C refers to a capacity of 117 mAg "1 in one hour.
  • the voltage profile has a flat charge plateau at about 3.39V before it rises steeply to the cutoff voltage of 3.9V, with a direct voltage drop to 3.36V followed by a very flat voltage plateau that spreads over a long range of sodium composition (up to 1.88 mole of Na + ) and then falls steeply to the cutoff voltage of 2.3V, leading to the storage capacity of 117 mAhg "1 .
  • the flat voltage profile for a wide range of sodium ion molar concentrations observed for the NVP/C material synthesized according to embodiment of the present disclosure is much higher than conventional electrode material used for the same applications.
  • the observed voltage profiles remain unaltered, demonstrating excellent reversibility of the cycling process.
  • the capacity can remain around 70 mAhg "1 for at least 500 cycles.
  • an electrode material has Nasicon-type, phosphate framework nanoparticles integrated with carbon matrix between the particles.

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Description

ELECTRODE MATERIAL AND METHOD OF SYNTHESIZING
TECHNICAL FIELD
The present disclosure relates to an electrode material for use in rechargeable batteries. In particular, the present disclosure relates to a phosphate framework electrode material for use in rechargeable sodium ion batteries and a method of synthesizing the phosphate framework electrode material.
BACKGROUND
Phosphate framework material possesses fairly well thermal stability and high voltage capabilities required for applications as electrodes e.g. anode or cathode in rechargeable sodium ion batteries. The major drawbacks which hinder the successful application of such type of material in commercial scale, however, lie in the poor electronic and ionic conductivity in its bulk form. Before such drawbacks are successfully overcome, this type of material may not be considered to be suitable for use in
rechargeable sodium ion batteries. Attempts have been made to downsizing of the material to enhance the sodium intercalation / de-intercalation properties. However, downsizing will reduce the diffusion length for Na+ - ions but may not effectively enhance the electron transportation to the current collector since particle-to-particle boundaries also increased with the downsizing, which can cause electron transportation to be sluggish. As a consequence, electronic conductivity may remain poor and the overall sodium-ion storage is limited.
It is therefore desirable to provide an electrode material having the necessary thermal stabilities and high voltage capacity as well as the electronic / ionic conductivities at a level acceptable for rechargeable sodium ion battery applications. Such a solution is currently not available. SUMMARY OF THE DISCLOSURE
According to one aspect, embodiments of the present disclosure provide a phosphate framework material for use as electrode, e.g. anode or a cathode material, for use in rechargeable sodium ion batteries. The material comprises a compound according to the following formula:
NaxAbMy(P04)zXn /C where
NaxAbMy(P04)zXn denotes the structure of Na-transitional metal-Phosphate nanoparticles, in which,
M is a transition metal obtained from a compound selected from a group consisting of metal acetates, metal nitrate metal chloride and metal acetyl acetonate;
A is an additional doped or mixed cation(s) obtained from a compound selected from a group consisting of group 1 elements, transition metals, ammonium and hydrogen;
X is a substituted anion or polyanion(s) obtained from a compound selected from a group consisting of fluorine, hydroxide, vanadate, arsenate, chloride, pyrophosphate;
x, b, y, z and n denote the numbers of ions of a corresponding element, in which:
l≤x < 3;
0 < b < l ;
1 < y < 2;
l < z < 3;
0 < n < 3;
and
C denotes a carbon content formed between the NaxAbMy(Pp4)zXn nanoparticles. According to another aspect, embodiments of the present disclosure provide a method for synthesizing a phosphate framework electrode material. A surfactant and precursors including a sodium precursor, a phosphate precursor and a transition metal precursor are dissolved in a solvent, and maybe stirred for sufficient mixing and reaction. The precursors are reacted to yield a precipitate of particles of NaxCbMy(P04)zXn compound, and with the surfactant attached to the particles. The solvent is then removed and the remaining precipitate is dried and sintered to crystallize the particles. In the meantime, the surfactant remaining on the particles is decomposed to form a carbon network between the crystallized particles, and the crystallized particles and the carbon matrix are integrated to form the electrode material in bulk form.
Other aspects and advantages of the present disclosure will become apparent from the following detailed description, illustrating by way of example the inventive concept of the present disclosure.
BRIEF DESCRIPTION OF THE DRAWINGS
These and other aspects of the present disclosure will be described in detail with reference to the accompanying drawings, in which:
Fig. 1 is a block diagram showing a method of synthesizing an electrode material according to one embodiment of the present disclosure;
Fig.2 is a chart showing a Rietveld refinement pattern of X-ray diffraction data of a Na3V2(P04)3/C sample synthesized as an electrode material according to one embodiment of the present disclosure;
Fig. 3 A is an FESEM image of a Na3V2(P04)3/C sample synthesized using C16 surfactant;
Fig 3B is an enlarged view of Fig. 3 A
Fig, 4A is a TEM image of a mesoporous Na3V2(P04)3/C particle;
Fig. 4B is an enlarged view of Fig. 4A;
Fig. 4C is an image of S AED pattern showing single crystalline nature of mesoporous Na3V2(P04)3/C particles;
Fig. 5 is a chart showing N2 absorption / desorption isotherms of a Na3V2(P04)3/C sample;
Fig. 6A is a chart showing galvanostatic charge / discharge cycle curves of Na3V2(P04)3/C material used as cathode under different current rates;
Fig. 6B is a chart showing long term cyclability curve of Na3V2(P04)3/C material used as cathode at 1C; Fig. 7A is a chart showing galvanostatic charge / discharge cycle curves of
Na3V2(P04)3/C material used as anode under different current rates; Fig. 7B is a chart showing long term cyclability curve of Na3V2(P04)3/C material used as anode at 1C.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS Fig. 1 illustrates a method 100 of synthesizing an electrode material according to one embodiment of the present disclosure. At block 102, a surfactant and metal precursors including a sodium precursor, a phosphate precursor and a transitional metal precursor are dissolved in a solvent to cause reaction of the precursors in the solvent. The solvent may be alcohol and/or a mixture of de-ionized water and alcohol. The mixture of the precursors may be stirred to help uniform mixing of the reactants at atomic level. The reaction yields a precipitate of amorphous sodium-transitional metal-phosphate compound particles with the surfactant attached thereto. At block 104, the solvent is removed and at block 106, the remaining precipitate is sintered, e.g. in a flowing, inert gas or a reducing atmosphere. During the sintering process, the surfactant remaining on the particles is decomposed to form an integrated conductive carbon matrix between the crystallized nanoparticles, and the crystallized nanoparticles and the carbon matrix are integrated to form the electrode material in bulk form.
The above method enables homogeneous mixing of the precursors and control of the particle size and morphology. The carbon matrix decomposed from the surfactant and formed between the nanoparticles prevents the particle agglomeration and growth during the sintering process. The carbon matrix also forms an in-situ coating of electrically conductive carbon layer on the crystallized nanoparticles. The carbon matrix therefore can greatly improve the electrical conductivity to make the electrode material suitable for rechargeable sodium ion battery applications. The above method may be used to synthesize the entire phosphate polyanion family of electrode materials for the sodium ion battery applications. The base formula for these compounds takes the form of: NaxAbMy(P04)zXn / C where
NaxAbMy(P04)zXn denotes the structure of Na-Transitional Metal-Phosphate nanoparticle, in which,
M is a transition metal obtained from a compound selected from a group consisting of metal acetates, metal nitrate metal chloride and metal acetyl acetonate;
A is an additional doped or mixed cation(s) obtained from a compound selected from a group consisting of group 1 elements, transition metals, ammonium and hydrogen;
X is a substituted anion or polyanion(s) obtained from a compound selected from a group consisting of fluorine, hydroxide, vanadate, arsenate, chloride, pyrophosphate;
x, b, y, z and n denote the numbers of ions of a corresponding element, in which:
1 < x < 3;
0 < b < l;
l < y < 2;
1 < z < 3;
0 < n < 3;
and
C denotes a carbon matrix formed between the NaxAbMy(P04)zXn nanoparticles.
The sodium precursor may be a sodium salt. The phosphate precursor may be an ammonium di-hydrogen phosphate or a phosphoric acid. The transitional metal precursor comprises a compound selected from the group consisting of metal acetates, metal nitrate, metal chloride, metal acetyl acetonate and metal hydroxide. The surfactant provides the necessary carbon content to form the carbon matrix during sintering to integrate with the crystallized nanoparticles. The surfactant comprises a compound selected from the group consisting of Sodium dodecyl sulfate (SDS), octyltrimethyl ammonium bromide (OTAB), dodecyltrimethyl ammonium bromide (DOTAB), cetyltrimethyl ammonium bromide (CTAB) and gluconic acid lactone.
Sample electrode material synthesized by the above method include, but not limited to, Na3V2(P04)3/C, Na3V2(P04)2F3/C, Na2FeP04F/C, NaVP04F/C,
Na2FeP04(OH)/C, Na2Feo.5Mn0.5P04F/C, Na2Ti0.5Mno.5P04F/C, Na2V0.5Mno.5P04F/C, NaFePCVC, Na3Ti2(P04)3/C. These materials possess unique properties of small crystallite size, high purity, high crystallinity, large surface-to-volume ratio, and promising structural stability after prolonged charge-discharge cycles required to use in sodium ion rechargeable batteries.
Note that for materials containing additional cation, e.g. Fe in
Na2Feo.5Mno.5P04F/C, Ti in Na2Ti0.5Mno.5P04F/C and V in Na2V0.5Mn0.5PO4F/C and for those containing anion/polyanion e.g. F in Na3V2(P04)2F3/C, compounds or precursors containing the respective cation / anion are added and dissolved in the solvent for reaction together with the sodium precursor, phosphate precursor and transitional metal precursor.
The crystallized particles have a grain size between about 20 nm to 200 nm, and the carbon layer coated on the particles has a thickness of about 2 to 10 nm. The carbon matrix portion in the electrode material is not more than about 5% in weight, and forms a carbon coating layer covering the crystallized nanoparticles in a surface area of about 10 to 100 m2 / gram. Therefore, electrode materials provided by embodiments of the present disclosure have electrically conductive carbon matrix sufficiently mixed and integrated with the crystallized Na- transitional metal-Phosphate nanoparticles. The crystallized Na- transitional metal-Phosphate nanoparticles provide enhanced sodium intercalation / de- intercalation. In the meantime, the interconnected carbon matrix between the
nanoparticles provides electrical conductivity suitable for rechargeable sodium ion battery applications. A Na3V2(P04)3/C (NVP/C) material formed according to the above method is now taken as a non-limiting example to illustrate the characteristics and performances for use as electrode in rechargeable sodium ion batteries. It should be appreciated that other types of phosphate framework material synthesized by the method according to embodiments of the present disclosure may be taken for performance study in a similar manner.
Figs. 2 to 5 show test results of structural characterization study and morphological analysis of NVP/C material synthesized according to an embodiment of the present disclosure.
Fig. 2 depicts a powder X-ray diffraction pattern (PXRD) of a porous NVP/C electrode material sample. Rietveld refinement of the PXRD pattern is performed to show the pure phase formation of NVP/C, without any impurity. This characteristic is evidenced by the close match of the calculated / fitted curve 22 and measured curve 24 and the difference 23 of curves 22 and 24.
Figs. 3A and 3B are field emission scanning electron microscope (FESEM) images of NVP/C sample, showing a network of NVP particles with an irregular morphology and various sized ranging from 500 to 900 nm. Transmission Electron Microscopy (TEM) analysis reveals that the NVP nano grains are well dispersed in the carbon matrix.
Figs. 4A and 4B show clear lattice fringes of NVP particle with a uniform carbon layer 42 of about 8nm formed on NVP particle 44. A selected area electron diffraction (SAED) pattern (Fig. 4C) shows single crystalline nature of the NVP nanoparticles which is consistent with the PXRD pattern shown in Fig. 2.
Nitrogen absorption / desorption isotherms 52, 54 shown in Fig. 5 indicate that the nanostructured NVP/C prepared according to embodiments of the present disclosure exhibits a distinct large hysteresis loop 56 and this type of behavior is a typical
characteristic of mesoporous materials, namely a type-IV isotherm due to capillary condensation in the mesoporous channels and or cages. Figs. 6A, 6B, 7A and 7B show test results of electrochemical behaviour study of an NVP/C material synthesized according to embodiment of the present disclosure. The NVP/C material may be used as either a cathode or an anode for sodium ion battery.
Galvanostatic cycling curves obtained under current density of 117 mAg"1 from C/10 to 40C, for porous NVP/C material as a cathode in a Na-ion battery is shown in Fig. 6 A. Here 1C refers to a capacity of 117 mAg"1 in one hour. As shown, the voltage profile has a flat charge plateau at about 3.39V before it rises steeply to the cutoff voltage of 3.9V, with a direct voltage drop to 3.36V followed by a very flat voltage plateau that spreads over a long range of sodium composition (up to 1.88 mole of Na+) and then falls steeply to the cutoff voltage of 2.3V, leading to the storage capacity of 117 mAhg"1.
Accordingly, the flat voltage profile for a wide range of sodium ion molar concentrations observed for the NVP/C material synthesized according to embodiment of the present disclosure is much higher than conventional electrode material used for the same applications. During subsequent cycles, the observed voltage profiles remain unaltered, demonstrating excellent reversibility of the cycling process. As shown in Fig. 6B, at 1C rate the capacity can remain around 70 mAhg"1 for at least 500 cycles.
When an NVP/C material synthesized according to embodiment of the present disclosure is used as an anode in a sodium-ion battery, as shown in Figs. 7A and 7B. A flat voltage profile was observed during the different charge/discharge current rates. Excellent long term cyclability was also observed when employed as anode.
As illustrated above, with respect to specific but non-limiting sample of NVP/C, an electrode material has Nasicon-type, phosphate framework nanoparticles integrated with carbon matrix between the particles.
Although embodiments of the present disclosure have been illustrated in conjunction with the accompanying drawings and described in the foregoing detailed description, it should be appreciated that the present disclosure is not limited to the embodiments disclosed. Therefore, the present disclosure should be understood to be capable of numerous rearrangements, modifications, alternatives and substitutions without departing from the spirit of the disclosure as set forth and recited by the following claims.

Claims

A method for synthesizing an electrode material, the method comprising:
dissolving a surfactant and precursors including a sodium precursor, a phosphate precursor and a transition metal precursor in a solvent to cause reaction of the precursors to yield a precipitate of particles, wherein the surfactant is attached to the particles;
removing the solvent;
sintering the precipitate to crystallize the particles, wherein during sintering the surfactant is decomposed to form a carbon matrix between the crystallized particles, and wherein the crystallized particles and the carbon matrix are integrated to form the electrode material.
The method of claim 1, wherein the surfactant comprises a compound selected from the group consisting of SDS, OTAB, DOTAB, CTAB and gluconic acid lactone.
3. The method of claim 1, wherein the sodium precursor is a sodium salt.
The method of claim 1, wherein the phosphate precursor is an ammonium phosphate salt or a phosphoric acid.
The method of claim 1 , wherein the solvent is one of alcohol and a mixture of de- ionized water and alcohol.
6. The method of claim 1, wherein the transitional metal precursor comprises a
compound selected from the group consisting of metal acetates, metal nitrate, metal chloride, metal acetyl acetonate and metal hydroxide.
The method of claim 6, wherein the metal is selected from a group consisting of vanadium, titanium, manganese and iron.
8. The method of claim 7, wherein the particles are formed of a compound selected from the group consisting of Na3V2(P04)3, NaFeP04, and Na3Ti2(P04)3.
9. The method of claim 1, further comprising dissolving a substituted anion or
polyanion in the solvent for reaction.
10. The method of claim 9, wherein the substituted anion or polyanion is obtained from a compound selected from a group consisting of fluorine, hydroxide, vanadate, arsenate, chloride and pyrophosphate.
1 1. The method of claim 10, wherein the particles are formed of a compound selected from the group consisting of Na3V2(P04)2F3, NaVP04F, Na2FeP04F.
12. The method of claim 1, further comprising dissolving additional doped cation or mixed cations in the solvent for reaction.
13. The method of claim 12, wherein the additional doped cation or mixed cations is/are obtained from a compound selected from a group consisting of group 1 elements, transition metals ammonium and hydrogen.
14. The method of claim 13, wherein the additional doped cation or mixed cations is/are obtained from a compound selected from a group consisting of transition metals, and wherein the particles are formed of a compound selected from the group consisting of Na2Feo.5Mno.5PC»4F, Na2Tio.5Mno.5P04F and
Na2Vo.5Mn0.5P04F.
15. The method of claim 1, wherein the crystallized particles have a grain size between 20 nm to 200 nm.
16. The method of claim 1, wherein the carbon matrix forms a carbon layer coated on the crystallized particles, and wherein the carbon layer has a thickness of 2 to 10 nm.
17. The method of claim 1, wherein removing the solvent comprises separating the precipitate from the solvent and drying the precipitate.
18. The method of claim 1, wherein sintering is carried out in one of a flowing
oxidizing atmosphere, an inert atmosphere and a reducing atmosphere.
19. An electrode material comprising a compound according to the following formula:
NaxAbMy(P04)zX„/ C
wherein
M is a transition metal selected from a group consisting of metal acetates, metal nitrate metal chloride and metal acetyl acetonate
A is an additional doped or mixed cations selected from a group consisting of group 1 elements, transition metals, ammonium and hydrogen; X is a substituted anion or polyanion selected from a group consisting of
fluorine, hydroxide, vanadate, arsenate, chloride, pyrophosphate;
x, b, y, z and n denote the numbers of ions of a corresponding element, in
which:.
l < x < 3;
0 < b < l;
l < y < 2;
l < z < 3;
0 < n < 3.
and
C denotes a carbon matrix formed between the NaxAbMy(P04)zXn nanoparticles.
20. The electrode material of claim 19, wherein the material is one selected from the group consisting of Na3V2(P04)3, Na3V2(P04)2F3, NaVP04F, Na2FeP04F, Na2FeP04(OH), Na2Fe0.5Mn0.5PO4F, Na2Ti0.5Mno.5P04F, Na2Vo.5Mno.5P04F , NaFeP04, Na3Ti2(P04)3. An electrode material comprising:
crystallized mesoporous particles having a grain size between 20 nm to 200 nm;
a carbon matrix disposed between the crystallized particles forming a carbon layer coated on the crystallized particles, and wherein the carbon layer has a thickness of 2 to 10 nm.
The electrode material of claim 21, wherein the crystallized particles are formed of a compound selected from the group consisting of Na3V2(P04)3, Na3V2(P04)2F3, NaVP04F, Na2FeP04F, Na2FeP04(OH), Na2Fe0.5Mn0.5PO4F, Na2Ti0.5Mn0.5PO4F, Na2V0 5Mno.5P04F, NaFeP04, Na3Ti2(P04)3.
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