WO2013165552A3 - Moisture curable organopolysiloxane composition - Google Patents

Moisture curable organopolysiloxane composition Download PDF

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Publication number
WO2013165552A3
WO2013165552A3 PCT/US2013/029623 US2013029623W WO2013165552A3 WO 2013165552 A3 WO2013165552 A3 WO 2013165552A3 US 2013029623 W US2013029623 W US 2013029623W WO 2013165552 A3 WO2013165552 A3 WO 2013165552A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
present
acrylic acid
silicones
organopolysiloxane composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2013/029623
Other languages
French (fr)
Other versions
WO2013165552A2 (en
Inventor
Mihirkumar Maheshbai PATEL
Amjad Basha MOHAMMAD
Sumi Dinkar
Anantharaman Dhanabalan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Momentive Performance Materials Inc
Original Assignee
Momentive Performance Materials Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Performance Materials Inc filed Critical Momentive Performance Materials Inc
Priority to US14/398,191 priority Critical patent/US20150094421A1/en
Priority to KR1020147033902A priority patent/KR20150006048A/en
Priority to CN201380027708.XA priority patent/CN104995235A/en
Priority to EP13784368.6A priority patent/EP2844701A2/en
Priority to JP2015510257A priority patent/JP2015524003A/en
Priority to CA2872178A priority patent/CA2872178A1/en
Publication of WO2013165552A2 publication Critical patent/WO2013165552A2/en
Anticipated expiration legal-status Critical
Publication of WO2013165552A3 publication Critical patent/WO2013165552A3/en
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/544—Silicon-containing compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/6705—Unsaturated polymers not provided for in the groups C08G18/671, C08G18/6795, C08G18/68 or C08G18/69
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides curable compositions comprising non-tin metal catalysts that accelerate the condensation curing of moisture-curable silicones/non-silicones. In particular, the present composition employs a catalyst system comprising an (alkyl)acrylic acid, a salt of an (alkyl)acrylic acid, or a mixture of two or more thereof. The (alkyl)acrylic acids or their salts exhibit catalytic activity comparable or superior to organotin such as dibutyltin dilaurate (DBTDL) and exhibit certain behavior in the presence of components such as adhesion promoters that allow for tuning or adjusting the cure characteristics of the present compositions and provide good adhesion and storage stability.
PCT/US2013/029623 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition Ceased WO2013165552A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US14/398,191 US20150094421A1 (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition
KR1020147033902A KR20150006048A (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition
CN201380027708.XA CN104995235A (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition
EP13784368.6A EP2844701A2 (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition
JP2015510257A JP2015524003A (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition
CA2872178A CA2872178A1 (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261641438P 2012-05-02 2012-05-02
US61/641,438 2012-05-02

Publications (2)

Publication Number Publication Date
WO2013165552A2 WO2013165552A2 (en) 2013-11-07
WO2013165552A3 true WO2013165552A3 (en) 2015-06-04

Family

ID=49515008

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/029623 Ceased WO2013165552A2 (en) 2012-05-02 2013-03-07 Moisture curable organopolysiloxane composition

Country Status (7)

Country Link
US (1) US20150094421A1 (en)
EP (1) EP2844701A2 (en)
JP (1) JP2015524003A (en)
KR (1) KR20150006048A (en)
CN (1) CN104995235A (en)
CA (1) CA2872178A1 (en)
WO (1) WO2013165552A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105793326B (en) * 2013-11-26 2020-07-21 莫门蒂夫性能材料股份有限公司 Moisture-curable compositions with metal-aromatic complexes

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014210492A1 (en) * 2013-06-28 2014-12-31 Momentive Performance Materials Inc. Moisture curable composition with strontium
EP3087150A1 (en) 2013-12-23 2016-11-02 Dow Corning Corporation Moisture curable compositions
CN106163656A (en) * 2014-02-06 2016-11-23 莫门蒂夫性能材料股份有限公司 The silicon composition of moisture-curable
CN105295414A (en) * 2015-11-24 2016-02-03 刘志辉 Anchoring agent
CN107936675A (en) * 2017-11-20 2018-04-20 航天材料及工艺研究所 A kind of solidification composition filling and its application
EP3501641A1 (en) 2017-12-22 2019-06-26 Covestro Deutschland AG Moisture-curable compositions
CN112823193B (en) 2018-10-31 2023-09-15 美国陶氏有机硅公司 Adhesive
WO2020087316A1 (en) 2018-10-31 2020-05-07 Dow Silicones Corporation Adhesive
WO2021026001A1 (en) 2019-08-02 2021-02-11 Building Materials Investment Corporation Water-resistant acrylic coatings
US12110410B2 (en) 2019-08-02 2024-10-08 Bmic Llc Water-resistant acrylic coatings
FR3103489B1 (en) * 2019-11-21 2021-11-05 Bostik Sa Moisture crosslinkable composition based on silylated polymer
CN121219365A (en) * 2023-06-01 2025-12-26 汉高股份有限及两合公司 Conductive, wettable curable composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840428A (en) * 1995-02-28 1998-11-24 Dow Corning Corporation Organically-modified, radiation-curable siloxane resin and method of making the same
US6072013A (en) * 1997-11-27 2000-06-06 Dow Corning Toray Silicone Co., Ltd. Silicone-grafted vinyl polymer and method for the preparation thereof
US20070197820A1 (en) * 2004-05-17 2007-08-23 Jurgen Van Holen Process for producing urethane (meth)acrylates and new urethane (meth)acrylates
US20120065308A1 (en) * 2010-09-08 2012-03-15 Sumi Moisture curable organopolysiloxane composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2013949C (en) * 1989-04-06 1999-08-24 Toshiro Nambu Thermosetting composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840428A (en) * 1995-02-28 1998-11-24 Dow Corning Corporation Organically-modified, radiation-curable siloxane resin and method of making the same
US6072013A (en) * 1997-11-27 2000-06-06 Dow Corning Toray Silicone Co., Ltd. Silicone-grafted vinyl polymer and method for the preparation thereof
US20070197820A1 (en) * 2004-05-17 2007-08-23 Jurgen Van Holen Process for producing urethane (meth)acrylates and new urethane (meth)acrylates
US20120065308A1 (en) * 2010-09-08 2012-03-15 Sumi Moisture curable organopolysiloxane composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105793326B (en) * 2013-11-26 2020-07-21 莫门蒂夫性能材料股份有限公司 Moisture-curable compositions with metal-aromatic complexes

Also Published As

Publication number Publication date
WO2013165552A2 (en) 2013-11-07
CN104995235A (en) 2015-10-21
JP2015524003A (en) 2015-08-20
EP2844701A2 (en) 2015-03-11
CA2872178A1 (en) 2013-11-07
US20150094421A1 (en) 2015-04-02
KR20150006048A (en) 2015-01-15

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