WO2013173955A1 - 一种激光熔覆方法 - Google Patents
一种激光熔覆方法 Download PDFInfo
- Publication number
- WO2013173955A1 WO2013173955A1 PCT/CN2012/001475 CN2012001475W WO2013173955A1 WO 2013173955 A1 WO2013173955 A1 WO 2013173955A1 CN 2012001475 W CN2012001475 W CN 2012001475W WO 2013173955 A1 WO2013173955 A1 WO 2013173955A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laser
- column
- hydraulic support
- benefit
- laser cladding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/34—Laser welding for purposes other than joining
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
- C23C24/106—Coating with metal alloys or metal elements only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/34—Laser welding for purposes other than joining
- B23K26/342—Build-up welding
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
Definitions
- the invention relates to a laser cladding method, belonging to the field of laser processing and manufacturing.
- the hydraulic support column is a key component in mining equipment.
- the hydraulic support column is usually surface treated by chrome plating to prevent surface rust and corrosion.
- the wear resistance of the chrome layer is poor.
- the chrome layer will peel off and peel off. Therefore, the emulsion will corrode the surface of the column, which will affect the use of the hydraulic support.
- the Chinese patent disclosed in CN101875128B discloses a laser cladding method for a mine hydraulic support column, which is capable of cladding three layers of metallurgical materials through specific laser cladding process conditions, thereby solving the wear resistance of the surface of the mining hydraulic support column.
- Sexual and corrosion-resistant problems increase the service life.
- the specific technical solution is to preheat the mine hydraulic support column after the surface treatment, and then sequentially coat the bottom layer, the middle layer and the surface layer with the alloy powder material under the specific process conditions.
- the weight percentage of the alloy powder material for cladding used in the bottom layer is 0.1% C, 3.2% Si, 0.5% Mn, 10.2% Cr, 8.8%, 0.8% Nb, 0.1% B, 0.5 % P and the balance of Fe.
- the laser used is a carbon dioxide laser, that is, a laser using carbon dioxide as a working substance.
- a carbon dioxide laser is used for laser cladding, the laser light from the carbon dioxide laser is irradiated onto the column of the hydraulic support, and the energy absorption rate of the laser beam is low. Also, the power consumption is large in the process.
- the present invention provides a laser cladding method which can improve the absorption and utilization of laser beam energy and has high power utilization rate, thereby saving power consumption.
- a laser cladding method is characterized in that a laser cladding layer is formed by melting a laser powder for laser cladding on a surface of a column of a hydraulic support by using a laser beam emitted from a semiconductor laser.
- the laser cladding method according to claim 1 is characterized in that the distance from the laser beam exit of the semiconductor laser to the surface of the column of the hydraulic support is 150 to 250 mm, and the energy of the laser beam emitted from the semiconductor laser The density is 109.38 W/mm 2 or more.
- the laser cladding method according to claim 3 is characterized in that the supply rate of the alloy powder for laser cladding is 38 to 40 g/min, and the diameter of the alloy powder for laser cladding is 44 to 178 ⁇ m. ;
- the laser beam is a rectangular spot, the length of the rectangular spot is 16 mm, the width of the rectangular spot is 2 mm, the scanning linear velocity of the laser beam is 540 to 780 mm/min, and the scanning direction of the laser beam is perpendicular to the The length direction of the rectangular spot.
- the laser cladding composition powder comprises:
- the laser cladding method according to claim 7 is characterized in that the outer diameter of the column of the hydraulic support is 350 to 400 mm.
- the laser beam energy absorption rate of the semiconductor laser is high, and since the energy conversion efficiency of the semiconductor laser is high, the power utilization rate is also improved, and the power consumption is saved.
- the continuous working time can be long.
- the continuous working time can reach more than 15000 hours, but if a carbon dioxide laser is used, The continuous working time is therefore shorter, because a vacuuming operation is usually required every 24 hours.
- the laser cladding method according to the second to third embodiments is an improvement of the first embodiment, and the good process parameters are selected, that is, the distance from the laser beam exit of the semiconductor laser to the surface of the column of the hydraulic support and the semiconductor laser are optimized.
- the matching relationship between the energy densities of the emitted laser beams enables laser cladding to be efficiently performed.
- the technical solution 4 is a specific embodiment in which a plurality of processes are defined, and a clear operation process is provided to those skilled in the art.
- the composition is of a specific composition, so that good surface hardness, service life, bonding strength of the cladding layer to the metal substrate, and salt spray resistance can be obtained.
- the hardness of the surface cladding layer of the column of the hydraulic support can reach 30 HRC or more, the service life in the mine is more than 5 years, the bonding strength between the cladding layer and the column base can reach 310 MPa or more, and the salt spray resistance is unchanged for 96 hours or more.
- the column of the hydraulic support obtained by the method of the above-mentioned technical solution 6, on the one hand, can satisfy various performances of the column of the hydraulic support obtained by the method of the fifth aspect, for example, the service life in the mine is more than 5 years.
- the bonding strength between the cladding layer and the column base can reach 310 MPa or more, and the salt spray resistance is unchanged for 96 hours or more.
- the hardness of the cladding layer can reach above 45 HRC.
- the Ni content is low, the cost is low.
- the hydraulic support column used in this embodiment is a column of a mining hydraulic support used by Xinwen Mining Group New Julong Energy Co., Ltd., which is a column of a hydraulic support with 27SiMn as a base body, and has a diameter of 300 mm.
- Laser cladding is performed using the following method:
- a laser processing machine tool which is a semiconductor laser processing machine tool (ie, A processing machine including a semiconductor laser).
- the powder feeding and the laser cladding are synchronized in one step;
- the output power of the semiconductor laser is 4000 W, from the semiconductor laser
- the laser beam exits to the surface of the column of the hydraulic support at a distance of 200 mm, the laser scanning linear velocity is 540 mm/min, and the laser beam is a 16*2 mm rectangular spot (length is 16 mm, width is 2 mm); scanning cladding is performed. Way to perform cladding;
- the composition for laser cladding used was powdery and had a particle diameter of 44 to: 178 ⁇ .
- the composition contained 0.05% C, 1.5% Si, 0.4% Mn, 15.8% Cr, 4.0% Ni, the balance Fe and the inevitable very small amount of impurities.
- the powder feeding rate of the alloy powder for laser cladding was 38 to 40 g/min.
- the total installed power of the semiconductor laser is 45 KW (kilowatt)
- the continuous output power of the semiconductor laser is 4000 W
- the absorption rate of the metal material is 80%
- the size of the semiconductor laser For 260mmx l l8mmx450mm, the weight of the semiconductor laser is 27kg, and the continuous working time can reach 15000 hours.
- the amount of heat absorbed by the metal material is 3,200 KW.
- the hardness of the cladding layer can reach above 45 HRC, the service life in the mine is more than 5 years, the bonding strength between the cladding layer and the column base can reach 310 MPa or more, and the salt spray resistance is unchanged for 96 hours.
- the column has been promoted and used by Xinwen Mining Group New Julong Energy Co., Ltd., and the effect is good. It has been used for 4 years in the mining face without any quality problems.
- the Chinese national standard GB/T10125-1997 was used for the salt spray resistance test.
- the test drug used was an aqueous solution of sodium chloride, the concentration was 50g/L 5g/L, the pH was 6.5 ⁇ 7.2, and the temperature was 35°. C ⁇ 2. (:.
- the hydraulic support column used in this embodiment is made by Xinwen Mining Group New Julong Energy Co., Ltd.
- a column for a mining hydraulic support which is a column of a hydraulic support with a base of 27SiMn and a diameter of 400 mm.
- Laser cladding is performed using the following method:
- the output power of the semiconductor laser laser is 4000 W, and the laser beam from the semiconductor laser is synchronized in one step.
- the distance from the surface of the column to the hydraulic support is 250 mm, the laser scanning linear velocity is 600 mm/min, and the laser beam is a 16*2 mm rectangular spot (length is 16 mm, width is 2 mm); cladding is performed by scanning cladding ;
- the alloy for laser cladding used was powdery and had a particle size of 44 to 178 ⁇ .
- the composition contained 0.15% C, 1.0% Si, 0.8% Mn, 15.0% Cr, 4.5% Ni, balance Fe and unavoidable impurities.
- the powder feeding rate of the alloy for laser cladding was 38 to 40 g/min.
- the total installed power of the semiconductor laser is 45 KW (kilowatt)
- the continuous output power is 4000 W
- the metal material absorption rate is 80%
- the size of the semiconductor laser is 260 mm x l 8 mm x 450 mm
- the weight of the semiconductor laser is 27 kg.
- the continuous operation time of the semiconductor laser can reach 15,000 hours.
- the hydraulic support column used in this embodiment is a column of a mining hydraulic support used by Xinwen Mining Group New Julong Energy Co., Ltd., which is a column of a hydraulic support with a base of 27SiMn and a diameter of 350 mm.
- ⁇ Use the following method to enter the laser cladding:
- the powder feeding and the laser cladding are synchronized in one step; the output power of the semiconductor laser is 4000 W, from the semiconductor laser
- the laser beam exits to the surface of the column of the hydraulic support at a distance of 250 mm, the laser scanning linear velocity is 600 mm/min, and the laser beam is a 16*2 mm rectangular spot (length is 16 mm, width is 2 mm); scanning cladding is performed.
- the composition for laser cladding used was powdery and had a particle size of 44 to 178 ⁇ ! ⁇ .
- the composition contained 0.15% C, 1.0% Si, 0.8% Mn, 18.0% Cr, 22.0% Ni, balance Fe and unavoidable impurities.
- the powder feeding rate of the alloy powder for laser cladding is 38 to 40 g/min.
- the total installed power of the semiconductor laser is 45 KW
- the continuous output power is 4000 W
- the metal material absorption rate is 80%
- the size of the semiconductor laser is 260 mm ll 8 mm x 450 mm
- the weight of the semiconductor laser is 27 kg.
- the continuous operation time of the semiconductor laser can reach 15,000 hours.
- the hydraulic support column used in this embodiment is a column of a mining hydraulic support used by Xinwen Mining Group New Julong Energy Co., Ltd., which is a column of a hydraulic support with 27SiMn as a base body, and has a diameter of 300 mm.
- Laser cladding is performed using the following method:
- the laser processing machine is a carbon dioxide laser processing machine (a processing machine including a carbon dioxide laser).
- the powder feeding and the laser cladding are synchronized in one step;
- the output power of the carbon dioxide laser laser is 8000 W, from the laser
- the distance from the laser beam exit to the surface of the column of the hydraulic support is 300 mm, the laser scanning linear velocity is 480 mm/min, and the laser beam is a rectangular spot of 15*2.5 mm (length 15 mm, width 2.5 mm); scanning cladding Way into t cladding;
- the alloy powder for laser cladding is used, and has a particle diameter of 44 to 178 ⁇ m.
- the composition contained 0.02% C, 1.5% Si, 0.4% Mn, 15.8% Cr, 4.0% Ni, balance Fe and unavoidable impurities.
- the powder feeding rate of the alloy powder for laser cladding was 38 to 40 g/min.
- the carbon dioxide laser refers to a laser that emits light by using carbon dioxide as a working substance and transitioning between energy bands by carbon dioxide.
- the total installed power of the carbon dioxide laser is 175 KW
- the continuous output power of the carbon dioxide laser is 8000 W
- the absorption rate of the metal material (absorption rate of the column) is 40%
- the size of the carbon dioxide laser is 2500 mm x 150 mm x 2300 mm
- the carbon dioxide laser The weight is 4000kg and the continuous working time is 24 hours, because the laser needs to be vacuumed every 24 hours.
- the amount of heat absorbed by the metal material is 3,200 KW.
- the carbon dioxide laser is bulky and the operation is very inconvenient.
- the continuous output power of the CO2 laser cannot be reduced to 4000 W, and the power consumption cannot be greatly reduced.
- the hardness of the cladding layer can reach above 45 HRC, the service life in the mine is more than 5 years, the bonding strength between the cladding layer and the column base can reach 310 MPa or more, and the salt spray resistance is unchanged for 96 hours.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- Laser Beam Processing (AREA)
- Powder Metallurgy (AREA)
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12877167.2A EP2708621B1 (en) | 2012-05-22 | 2012-10-31 | Laser cladding method |
| US14/356,709 US20140299585A1 (en) | 2012-05-22 | 2012-10-31 | Laser cladding method |
| RU2014102952A RU2624747C2 (ru) | 2012-05-22 | 2012-10-31 | Способ лазерного плакирования |
| AU2012380415A AU2012380415B2 (en) | 2012-05-22 | 2012-10-31 | Laser cladding method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210159369.8 | 2012-05-22 | ||
| CN201210159369.8A CN102677045B (zh) | 2012-05-22 | 2012-05-22 | 一种激光熔覆方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2013173955A1 true WO2013173955A1 (zh) | 2013-11-28 |
Family
ID=46809577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2012/001475 Ceased WO2013173955A1 (zh) | 2012-05-22 | 2012-10-31 | 一种激光熔覆方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20140299585A1 (zh) |
| EP (1) | EP2708621B1 (zh) |
| CN (1) | CN102677045B (zh) |
| AU (1) | AU2012380415B2 (zh) |
| PL (1) | PL2708621T3 (zh) |
| RU (1) | RU2624747C2 (zh) |
| WO (1) | WO2013173955A1 (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114799762A (zh) * | 2022-05-12 | 2022-07-29 | 河南中原特钢装备制造有限公司 | 外圆激光熔覆内孔熔铜的二级缸体的机械加工工艺 |
| CN115369401A (zh) * | 2022-08-19 | 2022-11-22 | 岭澳核电有限公司 | 用于激光熔覆的耐蚀层材料及其制备方法和应用 |
| CN116024565A (zh) * | 2022-12-05 | 2023-04-28 | 苏州科技大学 | 一种齿轮齿面疲劳裂纹的激光熔覆修复设备 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102677045B (zh) * | 2012-05-22 | 2014-10-01 | 山东能源机械集团大族再制造有限公司 | 一种激光熔覆方法 |
| CN104233291A (zh) * | 2014-09-18 | 2014-12-24 | 丹阳惠达模具材料科技有限公司 | 一种用于模具的智能化半导体激光制造再制造修复工艺 |
| CN105695988A (zh) * | 2016-04-11 | 2016-06-22 | 南京辉锐光电科技有限公司 | 轨道车辆车轮的修复设备、方法及采用的铁基合金粉末 |
| CN106826091A (zh) * | 2017-01-22 | 2017-06-13 | 西安必盛激光科技有限公司 | 一种废旧液压立柱修复方法 |
| US10479155B2 (en) | 2017-02-16 | 2019-11-19 | Caterpillar Inc. | Cladding structure and method |
| CN108165979A (zh) * | 2017-12-22 | 2018-06-15 | 北京机科国创轻量化科学研究院有限公司 | 一种用于制造液压支架立柱的超高速率激光熔覆方法 |
| CN111455378B (zh) * | 2020-05-19 | 2022-05-17 | 亚琛联合科技(天津)有限公司 | 一种高效率矩形光斑激光熔覆方法 |
| CN112059545A (zh) * | 2020-08-26 | 2020-12-11 | 郑州煤矿机械集团股份有限公司 | 一种细长活塞杆激光熔覆变形控制方法 |
| CN112322996B (zh) * | 2020-10-19 | 2021-11-30 | 中国科学院半导体研究所 | 一种用于钢轨激光熔覆强化的合金粉末及激光熔覆方法 |
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- 2012-05-22 CN CN201210159369.8A patent/CN102677045B/zh not_active Expired - Fee Related
- 2012-10-31 EP EP12877167.2A patent/EP2708621B1/en not_active Not-in-force
- 2012-10-31 AU AU2012380415A patent/AU2012380415B2/en not_active Ceased
- 2012-10-31 WO PCT/CN2012/001475 patent/WO2013173955A1/zh not_active Ceased
- 2012-10-31 RU RU2014102952A patent/RU2624747C2/ru active
- 2012-10-31 US US14/356,709 patent/US20140299585A1/en not_active Abandoned
- 2012-10-31 PL PL12877167.2T patent/PL2708621T3/pl unknown
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| CN115369401A (zh) * | 2022-08-19 | 2022-11-22 | 岭澳核电有限公司 | 用于激光熔覆的耐蚀层材料及其制备方法和应用 |
| CN116024565A (zh) * | 2022-12-05 | 2023-04-28 | 苏州科技大学 | 一种齿轮齿面疲劳裂纹的激光熔覆修复设备 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140299585A1 (en) | 2014-10-09 |
| RU2014102952A (ru) | 2015-08-10 |
| CN102677045A (zh) | 2012-09-19 |
| PL2708621T3 (pl) | 2016-12-30 |
| AU2012380415B2 (en) | 2015-09-10 |
| CN102677045B (zh) | 2014-10-01 |
| EP2708621A1 (en) | 2014-03-19 |
| EP2708621A4 (en) | 2014-12-03 |
| RU2624747C2 (ru) | 2017-07-06 |
| AU2012380415A1 (en) | 2013-12-12 |
| EP2708621B1 (en) | 2016-06-15 |
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