WO2013181274A3 - Controlling melt fracture in bimodal resin pipe - Google Patents

Controlling melt fracture in bimodal resin pipe Download PDF

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Publication number
WO2013181274A3
WO2013181274A3 PCT/US2013/043154 US2013043154W WO2013181274A3 WO 2013181274 A3 WO2013181274 A3 WO 2013181274A3 US 2013043154 W US2013043154 W US 2013043154W WO 2013181274 A3 WO2013181274 A3 WO 2013181274A3
Authority
WO
WIPO (PCT)
Prior art keywords
smooth
melt fracture
catalyzed polyethylene
stress
multimodal metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2013/043154
Other languages
French (fr)
Other versions
WO2013181274A2 (en
Inventor
Yongwoo INN
Paul J. Deslauriers
Qing Yang
Ashish M. Sukhadia
David C. Rohlfing
Pamela L. Maeger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
Original Assignee
Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co LLC, Chevron Phillips Chemical Co LP filed Critical Chevron Phillips Chemical Co LLC
Priority to IN10132DEN2014 priority Critical patent/IN2014DN10132A/en
Priority to KR1020147033497A priority patent/KR102145077B1/en
Priority to SG11201407968RA priority patent/SG11201407968RA/en
Priority to CA2874630A priority patent/CA2874630C/en
Priority to BR112014029866-1A priority patent/BR112014029866B1/en
Priority to CN201380028242.5A priority patent/CN104508453A/en
Priority to MX2014014496A priority patent/MX374206B/en
Priority to EP13728893.2A priority patent/EP2856105B1/en
Publication of WO2013181274A2 publication Critical patent/WO2013181274A2/en
Publication of WO2013181274A3 publication Critical patent/WO2013181274A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N11/00—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
    • G01N11/02—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by measuring flow of the material
    • G01N11/04—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by measuring flow of the material through a restricted passage, e.g. tube, aperture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00—Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/24—Investigating strength properties of solid materials by application of mechanical stress by applying steady shearing forces
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F17/00—Digital computing or data processing equipment or methods, specially adapted for specific functions
    • G06F17/10—Complex mathematical operations
    • G—PHYSICS
    • G16—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR SPECIFIC APPLICATION FIELDS
    • G16C—COMPUTATIONAL CHEMISTRY; CHEMOINFORMATICS; COMPUTATIONAL MATERIALS SCIENCE
    • G16C20/00—Chemoinformatics, i.e. ICT specially adapted for the handling of physicochemical or structural data of chemical particles, elements, compounds or mixtures
    • G16C20/20—Identification of molecular entities, parts thereof or of chemical compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Theoretical Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Data Mining & Analysis (AREA)
  • Bioinformatics & Computational Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Computing Systems (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Databases & Information Systems (AREA)
  • Mechanical Engineering (AREA)
  • Mathematical Analysis (AREA)
  • Pure & Applied Mathematics (AREA)
  • Computational Mathematics (AREA)
  • Software Systems (AREA)
  • Algebra (AREA)
  • Mathematical Optimization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

A method of improving processing of polyethylene resins comprising obtaining a plurality of multimodal metallocene-catalyzed polyethylene samples measuring the shear stress as a function of shear rate for the plurality of multimodal metallocene-catalyzed polyethylene samples using capillary rheometry wherein the measuring yields values for a magnitude of slip-stick, a stress for smooth to matte transition, and a shear rate for smooth to matte transition; and identifying from the plurality of multimodal metallocene-catalyzed polyethylene samples individual multimodal metallocene-catalyzed polyethylene resins having a reduced tendency to melt fracture characterized by a magnitude of slip-stick greater than about 300 psi, a stress for smooth to matte transition greater than about 90 kPa, and a shear rate for smooth to matte transition greater than about 10 s-1.
PCT/US2013/043154 2012-05-31 2013-05-29 Controlling melt fracture in bimodal resin pipe Ceased WO2013181274A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
IN10132DEN2014 IN2014DN10132A (en) 2012-05-31 2013-05-29
KR1020147033497A KR102145077B1 (en) 2012-05-31 2013-05-29 Controlling melt fracture in bimodal resin pipe
SG11201407968RA SG11201407968RA (en) 2012-05-31 2013-05-29 Controlling melt fracture in bimodal resin pipe
CA2874630A CA2874630C (en) 2012-05-31 2013-05-29 Controlling melt fracture in bimodal resin pipe
BR112014029866-1A BR112014029866B1 (en) 2012-05-31 2013-05-29 method of preparing a medium density polyethylene pipe and pipe prepared from a multimodal metallocene catalyzed polyethylene resin
CN201380028242.5A CN104508453A (en) 2012-05-31 2013-05-29 Controlled Melt Fracture of Bimodal Resin Pipes
MX2014014496A MX374206B (en) 2012-05-31 2013-05-29 CONTROL OF FUSION FRACTURE IN BIMODAL RESIN PIPE.
EP13728893.2A EP2856105B1 (en) 2012-05-31 2013-05-29 Controlling melt fracture in multimodal pe resin

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US201261654018P 2012-05-31 2012-05-31
US61/654,018 2012-05-31
US13/660,747 US20130319131A1 (en) 2012-05-31 2012-10-25 Controlling Melt Fracture in Bimodal Resin Pipe
US13/660,750 2012-10-25
US13/660,747 2012-10-25
US13/660,777 2012-10-25
US13/660,750 US20130325363A1 (en) 2012-05-31 2012-10-25 Controlling Melt Fracture in Bimodal Resin Pipe
US13/660,777 US8771816B2 (en) 2012-05-31 2012-10-25 Controlling melt fracture in bimodal resin pipe

Publications (2)

Publication Number Publication Date
WO2013181274A2 WO2013181274A2 (en) 2013-12-05
WO2013181274A3 true WO2013181274A3 (en) 2014-05-15

Family

ID=49668641

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/043154 Ceased WO2013181274A2 (en) 2012-05-31 2013-05-29 Controlling melt fracture in bimodal resin pipe

Country Status (10)

Country Link
US (3) US8771816B2 (en)
EP (1) EP2856105B1 (en)
KR (1) KR102145077B1 (en)
CN (1) CN104508453A (en)
BR (1) BR112014029866B1 (en)
CA (1) CA2874630C (en)
IN (1) IN2014DN10132A (en)
MX (1) MX374206B (en)
SG (1) SG11201407968RA (en)
WO (1) WO2013181274A2 (en)

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US8912285B2 (en) 2012-12-06 2014-12-16 Chevron Phillips Chemical Company Lp Catalyst system with three metallocenes for producing broad molecular weight distribution polymers
US8815357B1 (en) * 2013-02-27 2014-08-26 Chevron Phillips Chemical Company Lp Polymer resins with improved processability and melt fracture characteristics
US9346897B2 (en) 2013-05-14 2016-05-24 Chevron Phillips Chemical Company Lp Peroxide treated metallocene-based polyolefins with improved melt strength
EP2860200B1 (en) * 2013-10-10 2017-08-02 Borealis AG Polyethylene composition for pipe and pipe coating applications
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
US10550252B2 (en) 2017-04-20 2020-02-04 Chevron Phillips Chemical Company Lp Bimodal PE resins with improved melt strength
US11360011B2 (en) 2017-10-11 2022-06-14 Chevron Phillips Chemical Company, Lp Processes for predicting small scale steady state (S4) critical temperatures
CN108388761B (en) * 2018-02-27 2021-12-28 华东理工大学 High-precision rapid prediction model construction method for polyethylene molecular weight distribution and application thereof
WO2019226766A1 (en) 2018-05-22 2019-11-28 Exxonmobil Chemical Patents Inc. Methods for forming films and their related computing devices
US11453733B2 (en) 2019-04-17 2022-09-27 Chevron Phillips Chemical Company Lp Polyolefin process monitoring and control
CN110174309B (en) * 2019-06-12 2022-02-22 宁波大学 Sample design method for local melting of metal material fracture under fatigue load
US11674023B2 (en) * 2020-10-15 2023-06-13 Chevron Phillips Chemical Company Lp Polymer composition and methods of making and using same
US12031019B2 (en) * 2021-05-03 2024-07-09 Meta Platforms Technologies, Llc High strength and high thermal conductivity polyethylene thin film having a bimodal molecular weight
US12359753B2 (en) * 2021-07-23 2025-07-15 Chevron Phillips Chemical Company Lp Coextruded polyethylene pipe and methods of making and using same
EP4786506A1 (en) 2025-01-31 2026-08-05 Borealis GmbH Polyethylene compositions
WO2026162545A1 (en) 2025-01-31 2026-08-06 Borealis Gmbh Polyethylene compositions

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Also Published As

Publication number Publication date
US20130323450A1 (en) 2013-12-05
SG11201407968RA (en) 2014-12-30
KR20150024322A (en) 2015-03-06
CA2874630C (en) 2020-09-22
BR112014029866A2 (en) 2017-06-27
BR112014029866B1 (en) 2020-10-27
US20130319131A1 (en) 2013-12-05
MX374206B (en) 2025-03-05
WO2013181274A2 (en) 2013-12-05
US8771816B2 (en) 2014-07-08
KR102145077B1 (en) 2020-08-18
EP2856105B1 (en) 2025-07-23
US20130325363A1 (en) 2013-12-05
EP2856105A2 (en) 2015-04-08
CA2874630A1 (en) 2013-12-05
EP2856105C0 (en) 2025-07-23
IN2014DN10132A (en) 2015-08-21
CN104508453A (en) 2015-04-08
MX2014014496A (en) 2015-06-04

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