WO2014142714A1 - Toile composite par voie sèche destinée au thermoformage d'objets de forme tridimensionnelle, processus pour sa production, son thermoformage, et objet thermoformé de forme tridimensionnelle - Google Patents

Toile composite par voie sèche destinée au thermoformage d'objets de forme tridimensionnelle, processus pour sa production, son thermoformage, et objet thermoformé de forme tridimensionnelle Download PDF

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Publication number
WO2014142714A1
WO2014142714A1 PCT/SE2013/050217 SE2013050217W WO2014142714A1 WO 2014142714 A1 WO2014142714 A1 WO 2014142714A1 SE 2013050217 W SE2013050217 W SE 2013050217W WO 2014142714 A1 WO2014142714 A1 WO 2014142714A1
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WO
WIPO (PCT)
Prior art keywords
web
polymer
thermoforming
dry
ctmp
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SE2013/050217
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English (en)
Inventor
Lars-Erik ENARSSON
Ulrika ANDREASSON
Kent Malmgren
Tomas GERDSDORFF
Linda Gärdlund
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SCA Forest Products AB
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SCA Forest Products AB
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Publication date
Application filed by SCA Forest Products AB filed Critical SCA Forest Products AB
Priority to PCT/SE2013/050217 priority Critical patent/WO2014142714A1/fr
Publication of WO2014142714A1 publication Critical patent/WO2014142714A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/732—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by fluid current, e.g. air-lay
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/002—Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/60—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D21H27/42—Multi-ply comprising dry-laid paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
    • B29C51/082—Deep drawing or matched-mould forming, i.e. using mechanical means only by shaping between complementary mould parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles

Definitions

  • the invention relates to a dry-laid composite web being an intermediate for thermoforming of three-dimensionally shaped objects, including a process for its production. Furthermore, the invention relates to a process for thermoforming a three-dimensional object from the intermediate product, and such thermoformed three-dimensionally shaped object. Such three-dimensionally objects may for example be utilized for packaging purposes.
  • EPS expanded polystyrene
  • Moulded pulp has the advantage of being considered as a sustainable packaging material, since it is produced from biomaterials and can be recycled after use. As a consequence moulded pulp has been quickly increasing in popularity for both primary and secondary packaging applications (packaging next to the article and assembly of such packages).
  • Moulded pulp articles are generally formed by immersing a suction mould into a pulp suspension, while suction is applied, whereby a body of pulp is formed with the shape of the desired article by fibre deposition. The suction mould is then withdrawn from the suspension and the suction is generally continued to compact the deposited fibres while exhausting residual liquid.
  • Durapulp® Sodra Cell AB
  • PLA thermoplastic polylactide
  • pulp fibres may also be dry-laid to a web, having virtually no bonding between the individual fibres.
  • dry-laid webs comprising pulp fibres are used in hygiene care products, in particular as absorbing articles of various kinds.
  • dry- laid webs are typically of limited use for forming three dimensional shapes, such as packaging inserts, because of the low web strength.
  • the objective of the present invention is thus to provide a way to produce advanced three dimensionally shaped products mainly consisting of pulp fibres in an efficient way with respect to time and energy consumption. This object is achieved by the present invention as defined in the appended claims.
  • the present invention relates to a dry-laid composite web being an intermediate product for thermoforming of three-dimensionally shaped objects, said web comprising 40-95 wt-% CTMP fibres, 5-50 wt-% thermoplastic material, and 0-10 wt-% additives, wherein the dry-laid composite web has been impregnated with a dispersion, an emulsion, or a solution containing the thermoplastic material and dried, obtaining a density of 50-250 kg/m 3 , or, if compressed by calendaring 400-1000 kg/m 3 .
  • the CTMP fibres in combination with the thermoplastic material and the low density of the web allow thermoforming of three-dimensionally shaped object.
  • the thermoplastic material preferably comprises a first polymer material having a glass transition temperature, Tg, of -60°C - +80°C, preferably -30°C - +50°C; more preferred -10°C - +25°C, and a second polymer material having Tg of 45°C - 130°C, and the composite web has then been subjected to a temperature of above Tg of the first polymer, but not above Tg of the second polymer after impregnation, so that the first polymer binds to the CTMP fibres, while the CTMP fibres remain unbonded to the second polymer.
  • Tg glass transition temperature
  • thermoplastic material comprises 5-20 wt-% of the first polymer material based on the total weight of the composite web, to ensure sufficient bonding.
  • the dry-laid composite web may advantageously comprise a polymer film layer positioned on at least one side of the web, preferably on both sides of the web forming a sandwich laminate, the film having a thickness of 1-500 ⁇ , preferably 4-200 ⁇ , in order to enhance the thermoforming properties of the composite web.
  • the polymer film layer(s) preferably comprises polylactide.
  • the present invention also relates to a process for producing the above mentioned dry-laid composite intermediate web.
  • the process comprises the following steps:
  • thermoplastic material to the web by impregnation, wherein the thermoplastic material is added in the form of a dispersion, an emulsion, or a solution in an amount to reach 5-50 wt-% thermoplastic material based on the total dry weight of the web;
  • the impregnation serves two purposes in the present invention, to add the binder in a convenient way and at the same time expand the compacted airlaid sheet to a low-density web suitable for thermoforming.
  • the latter is obtained with a liquid that makes the fibres swell significantly, in particular water.
  • the impregnation is preferably a process where the composite web can expand freely, and is advantageously performed by spraying.
  • the thermoplastic material added preferably comprises a first polymer material having Tg of -60 - +80 °C, preferably -30 - +50 °C; more preferred -10 - +25°C, and a second polymer material having Tg of 45 - 130 °C
  • the drying is performed at a temperature of above Tg of the first polymer, but preferably not above Tg of the second polymer after impregnation, so that the first polymer binds to the CTMP fibres, while the CTMP fibres remain unbonded to the second polymer.
  • the drying is preferably performed without applying any physical constraints to the web until the web reaches ambient humidity, and the web may be calendared subsequent to drying, obtaining a web density of 400-1000 kg/m 3 .
  • the invention also relates to a process for producing a three-dimensionally shaped object from a pre-manufactured dry-laid composite intermediate web as described above, said web having a density of 50-250 kg/m 3 , comprising the steps:
  • thermoforming tool having the desired shape
  • thermoforming tool Forming the web in the thermoforming tool by pressing at a pressure of 1-200 MPa, preferably 1-100 MPa, or by utilizing a vacuum pressure;
  • the process preferably includes moistening of the heated web by treating it with water, preferably by spraying, to obtain a moisture content of the web of 10-30 %, more preferably 15-20 %, as the form-shaping tool is closing, and may also advantageously include cooling of the obtained object. If desired, the web may be cut into blanks before being introduced into a thermoforming tool.
  • the opening and the bottom are perpendicular to the press direction.
  • the thermoformed three-dimensionally shaped object preferably has a second extensibility in the plane of the opening in a second direction perpendicular to the first direction, the second extensibility being calculated in the same manner as the first extensibility, and both first and second extensibilities being at least 18%, preferably at least 22%, even more preferably at least 26%.
  • the thermoformed three-dimensionally shaped object preferably has at least one draft angle is less than 15°, preferably less than 5°.
  • Figure 1 shows a thermoformed object, with an inlaid plane indicating how to evaluate the extensibility.
  • Figure 2 shows thermoforming test moulds with a medium draft angle, in an open position.
  • Figure 3 shows thermoforming test moulds with a steep draft angle, in a closed position.
  • thermoformed or pressformed object an object, pressed from a planar substrate with an extension in the x-y plane and only its planar thickness in the z-direction, such that the formed object also has an additional formed extension in the z-direction.
  • the extension in the z-direction should be at least 5 %, more preferably at least 30%, of its largest extension in the x-y plane.
  • the final three-dimensionally shaped object of the invention is prepared from a dry-laid composite web which is first formed as an intermediate product.
  • the intermediate product is a substantially flat web, which comprises CTMP fibres, thermoplastic material, and possibly additives, and has a low density.
  • the production of the intermediate product involves dry- laying of CTMP fibre to form a web, using conventional dry-laying technology, and thereafter applying a dispersion, emulsion, or solution containing a thermoplastic material to a dry-laid composite web comprising CTMP, so as to impregnate the web.
  • CTMP is a wood-based pulp prepared by a combination of chemical pre-treatment and mechanical refining. Chemical pre-treatment involves impregnation of wood chips with steam and sulphite.
  • CTMP fibres are characterized by their high stiffness and resistance to fibre collapse as compared to chemical pulps. Applied in papermaking these properties leads to sheets with lower density (higher bulk) and larger pores compared to fully delignified chemical pulps (e.g. Kraft pulp).
  • substantially all fibres of the dry-laid web are preferably CTMP fibres.
  • Dry-laid CTMP sheets are often compressed or calendared before further processing, in order to facilitate the handling thereof.
  • calendared CTMP sheets When such calendared CTMP sheets are subjected to wetting, they swell to a great extent and effectively absorb the wetting liquid, and they are therefore well suited as starting materials for the present invention.
  • the calendared CTMP sheet for use in the present invention typically has a grammage of 300-800 g/m 2 , but depending on the desired final three-dimensional product a lower grammage may be preferred, such as 100-300 g/m 2 .
  • Grammage should be selected after the required mechanical properties for the thermoformed product. The highest grammages are suitable for structures that should withstand heavy loads or should be used over long time. The lowest grammages are especially suitable as packaging inserts for lightweight products.
  • CTMP produced in this manner is suitable for the intermediate composite web and allows for good uptake of colloidal binder particles, such as thermoplastic latex particles, when being impregnated with a dispersion or emulsion containing a polymeric material due to the large pores obtained in a porous dry-laid web of such CTMP fibres.
  • the calendared sheet swells and absorbs liquid up to 10 g/g upon wetting, and the uptake of colloidal binder dispersion is high. Also, the low refining energy required gives a pulp with little fine material and long average fibre length, which contributes to a high tensile and tear strength, as well as an good ductility of the fibre network.
  • the amount of CTMP in the dry-laid composite intermediate web, and consequently in the formed three-dimensional product should be in the interval of 40-95 wt-% of the total dry weight of the web, preferably in the interval of 60-85 wt-%, a nd most preferably in the interval of 65-75 wt-%. If the amount of CTMP is over 95 wt-% the fibres in the dry-laid web would not be bonded well enough, and it may be difficult to thermoform the product without breaking the substrate due to inferior ductility and web strength, and the finished product might show inferior mechanical properties.
  • thermoplastic content is increased from 5 to 40 wt-%, and more preferably 15-40 wt-%.
  • the latter corresponds to a preferred amount of 60-85% CTMP in the product. It is not of interest to go to lower amount of CTMP than 40 wt-% since the aim is to accomplish a three-dimensionally shaped product based mainly on sustainable pulp fibres. If has been found that the best compromise between a high amount of sustainable CTMP, good forming and mechanical properties is found in the interval of 65-75 wt-% CTMP.
  • thermoplastic material is added to the dry-laid web in the form of a polymer in a liquid carrier, of the type dispersion, emulsion, or solution.
  • a liquid carrier of the type dispersion, emulsion, or solution.
  • the thermoplastic material in the form of a dispersion, emulsion or solution is hereinafter referred to as the binder liquid. If the dry-laid web is impregnated directly in connection with the web forming it will collapse slightly. The advantage of direct impregnation in immediate connection with the web forming is that steps for compressing or calendaring the dry-laid web can be omitted.
  • the dry-laid CTMP web may be advantageous to subject the dry-laid CTMP web to compression or calendaring before impregnation, since a calendared dry-laid web can more easily be stored and handled, and the impregnation step need not necessarily be performed at the same site as the dry-laying.
  • a positive side-effect of using a compressed material is also that the absorbed liquid distributes more evenly in the CTMP web due to the higher capillary pressure induced by the smaller pores in the compressed web.
  • the dry-laid CTMP web is preferably compressed or calendared prior to adding thermoplastic material by impregnation.
  • the density of the compressed or calendared CTMP web before impregnation is preferably 400-1000 kg/m 3 .
  • the dry-laid CTMP web referred to which is subjected to impregnation is a compressed or calendared web, unless stated otherwise.
  • the compressed or calendared dry-laid web comprising CTMP fibres As the compressed or calendared dry-laid web comprising CTMP fibres is wetted it starts to expand via moisture-induced debonding and relaxation of built-in stresses in the fibre web.
  • the thermoplastic material is added to the dry-laid web in the form of an aqueous dispersion, emulsion or solution, since the wetting and swelling is more effective using water than with other solvents and since water is environmentally friendly and readily available. It is preferred that the impregnation step allows a free expansion of the web in the transversal direction seen from the plane of the web.
  • Important factors for large expansion of fibre webs are a combination of high fibre stiffness, a relative low degree of bonding in calendared dry-laid CTMP sheets, and a relaxation effect of curled CTMP fibres when they are softened by thorough wetting, (e.g. more than 0.7 g water/g dry-laid CTMP).
  • One purpose of free expansion is to get an increased uptake of binder liquid using the large pores that are created during wet expansion.
  • the expansion contributes to a sorption capacity of the CTMP web that is several times higher than what ordinary paper sheets of chemical pulp or TMP can show.
  • the large pores created during expansion are also capable of absorbing colloidal-size latex particles, which otherwise would be restricted to the surface of a normal paper web with smaller pore radii.
  • the lower density of the sheet obtained by allowing free expansion leads to increased bulk, larger separation between CTMP fibres, and lower degree of bonding between them. These properties improve the stretchability of the CTMP web, and the capability of being formed into three-dimensional objects.
  • an ordinary paper (made of chemical pulp) with high degree of bonding would show a brittle behaviour in stretching and three- dimensional forming against a mould with significant depth, leading to crack failure of the material.
  • the lower degree of bonding in the impregnated CTMP web allows the web to be more extensible.
  • CTMP fibres show a thermoplastic effect, since they are more flexible at temperatures above 130°C as the lignin softens, so it is highly beneficial to heat the CTMP web during thermoforming.
  • the loosely bonded fibres of the low density web are able to move relative each other in the sparse fibre network and can redistribute according to the shape of the mould.
  • the added thermoplastic material provides soft bonds between CTMP fibres and makes the sheet cohesive enough to allow stretch in the material.
  • the impregnation is preferably performed by spraying, although other techniques such as impregnation bath, applicator roll, printing (offset, flexo- and rotogravure, inkjet), film coating and curtain coating are also applicable.
  • Spray application is preferred since it provides excellent control of the applied content, for example by varying the application time and flow rate of the spray nozzle. Spraying also allows for a broad range of solid contents of the thermoplastic material in the liquid carrier, namely from 1-50 wt-% in the case of latex, and easy flowing polymer dispersions, offering a wide process window for optimizing the combination of applied liquid content and the target content of applied thermoplastic material. Another advantage with spraying is that the web can be allowed to expand freely in thickness, resting on a support without constriction.
  • the spraying techniques involve one or more spraying nozzles that can be moved in relation to the CTMP web, by either moving the nozzles or the web.
  • a spraying technique suitable for small scale production may involve application with a single spray nozzle, and can be automated by moving the CTMP sheet on an x-y table, or by using an automatically traversing nozzle.
  • a set of spray guns may be used under which the web is passing, preferably guided by a conveying belt. Spraying may also preferably be performed on both sides on the web, in order to obtain even coverage and effective wetting of the web.
  • Impregnation bath methods include immersion of the dry-laid web in a dispersion, emulsion or solution comprising the thermoplastic material. Impregnation baths have the advantage of allowing free expansion of the web. Impregnation by immersion may be performed batch-wise or continuously. In batch-wise immersion, the CTMP web may be placed into a tray and the binder liquid is poured over the web, which leads to spontaneous absorption under free expansion. The added amount of binder liquid should preferably be chosen so that the web absorbs all content, i.e. additions below saturation absorption for the CTMP web. This minimizes the recycling of excess liquid after the impregnation bath, gives a higher wet strength of the sheet, and also reduces the energy needed for drying the impregnated sheet.
  • a moving CTMP web is led through a bath with binder liquid.
  • the sheet is preferably supported by one or two wires, since the wet expanded CTMP web has a low wet strength and does not stand the tension in free drawing. Depending on the applied drawing geometry and tension, the expansion of the CTMP web might occur under some constraint.
  • a CTMP web is passed over an applicator roll that transfers the liquid to the web surface.
  • the applicator roll is partly immersed in a reservoir with binder liquid to pick up the liquid on the surface of the roll and transfer it the web passing the roll.
  • the roll may be provided with grooves in order to control the amount of pick-up of the binder liquid.
  • a pressure may be applied to the web to keep it in contact with the applicator roll, and the pressure is preferably kept low to allow for free expansion of the impregnated web.
  • Impregnation may also be performed by printing techniques to transfer the binder liquid to the CTMP web with full or partial surface coverage, such as different variants of roll applications (offset, flexo- and rotogravure techniques) as well as spraying techniques (Inkjet).
  • printing techniques to transfer the binder liquid to the CTMP web with full or partial surface coverage, such as different variants of roll applications (offset, flexo- and rotogravure techniques) as well as spraying techniques (Inkjet).
  • thermoplastic material The main purpose of the thermoplastic material is to bind the CTMP fibres in a desired three- dimensional shape during thermoforming, and to function as a strengthening structure component in the final product. It is beneficial if the thermoplastic material can serve a dual purpose, where it in addition to bind the CTMP fibres during thermoforming, also serves to preliminarily bind the CTMP fibres in the low density intermediate web, to facilitate handling and transport of the intermediate web.
  • Extra binder contributes by making the sheet strong enough to withstand transport and handling.
  • thermoplastic material has two main functions in the intermediate dry-laid composite web product, firstly preliminary bonding (or pre-bonding) before the final bonding during thermoforming occurs and secondly, bonding the CTMP fibres during thermoforming to contribute to final rigidity and thermal resistance of the shaped three-dimensional object by fixation of the rearranged fibre network of the shaped structure.
  • preliminary bonding or pre-bonding
  • bonding the CTMP fibres during thermoforming to contribute to final rigidity and thermal resistance of the shaped three-dimensional object by fixation of the rearranged fibre network of the shaped structure.
  • the combination of two polymers also makes it possible to tune the stiffness and toughness of the final product.
  • the preliminary bonding of the CTMP fibres may be enhanced by subjecting the web to heat, during or subsequent to drying.
  • the total amount of polymeric material added should be 5-50 wt-% based on the total dry weight of the web, in order to be able to successfully perform the thermoforming of the CTMP web.
  • 10-40 wt-% thermoplastic polymer is added, and most preferably 20-30 wt-%.
  • the extensibility in thermoforming is continuously increased over the interval 5-30%. In order to reach extensibilities over 20%, a content of 20 wt% or more of thermoplastic polymer is typically needed.
  • Both these functions can be performed by one single thermoplastic polymer, even though it is more complicated to fulfil the functions with just one polymer. Still, a single component might be preferred for its simplicity, or if the polymer shows poor chemical compatibility with other thermoplastic materials.
  • This polymer should then be chosen so that it can preliminarily bind the CTMP fibre in the expanded dried web, without decreasing the porosity of the web.
  • the polymer may then preferably have a glass transitional temperature (Tg) of -10 °C to 80 °C, more preferably +10 °C to 60 °C.
  • Tg glass transitional temperature
  • the final choice depends on the required rigidity of the final product. A polymer with Tg below ambient temperature will typically contribute to a less rigid but more tough fibre-based product.
  • a polymer with Tg above the ambient temperature will typically contribute to a rigid but more brittle product. If the target is a rigid product with temperature stability up to a certain temperature, Tg of the polymer should be chosen above that upper application temperature. Tg of the polymer should in any case be below 100°C in order to activate bonding when drying off the water. Since the sheet needs to be thermally bonded without any constricting load, the polymer must bind spontaneously. Extra heating of the dry impregnated sheet to temperatures in the range 100-150°C might be necessary to induce bonding for highly viscoelastic polymers. Thereby, a bonding of the CTMP web can be obtained by subjecting the web to a temperature above Tg, during or subsequent to drying.
  • thermoplastic material may be comprised of at least two different thermoplastic polymers in order to fulfil the two functions stated. In this case a combination of a first polymer with low softening temperature and a second polymer with high softening temperature is preferred.
  • thermoplastic material comprises a first polymer with low softening temperature and a second polymer with high softening temperature
  • the first polymer is preferably comprised in an amount of 5-20 wt-% based on the total weight of the composite web.
  • low softening temperature is meant in the context of the present invention that the polymer is soft enough to bind the sheet in room temperature or at moderate drying temperatures of e.g. 25-40°C, or at higher drying temperatures, of e.g. 40-80°C.
  • the first thermoplastic polymer having low softening temperature preferably has a Tg of -60 - +80 °C.
  • Polymers having Tg of -30 - +50 °C are preferred since they can bind the CTMP fibres with the use of less heating, and polymers having Tg -10 - +25 °C are more preferred, since they can form the preliminary bonding of the sheet at room temperature or ambient temperature.
  • the second thermoplastic polymer in the combined polymer is thus used to bind the web further in the final thermoforming step, and also contributes to give the final product a better thermal resistance.
  • the second polymer is not activated until the sheet is fully heated to thermoforming temperature, and has consequently a higher softening temperature, which is preferably Tg of 45-130 °C, more preferably 60-100 °C.
  • the impregnated sheet can be pre-bonded at the same time as the liquid carrier, typically water, is removed.
  • Polymers such as acrylic, styrene-acrylic, styrene, and styrene butadiene can be synthesized over a wide range of softening temperatures, including temperatures below 45°C, and are suitable for use as the first polymer.
  • Further examples of polymers with low softening temperatures below 45°C are polyvinyl acetate (PVA, Tg +30 to +40°C), vinyl acetate-ethylene copolymer (VAE, Tg -20°C to +15°C), and ethylene-vinyl chloride co-polymer (Tg 0°C to +30°C).
  • PVA polyvinyl acetate
  • VAE vinyl acetate-ethylene copolymer
  • Tg 0°C to +30°C ethylene-vinyl chloride co-polymer
  • PE- and PP-based co-polymers from the family of polyolefin latexes (e.g. Hypod and Primacor products from Dow).
  • This type of polymers has low glass transition temperature (-63°C to -26°C) and low melting point (+85°C to +122°C).
  • Polyolefin latex polymers have sufficient stiffness at room temperature to be used in the CTMP web. These polymers also show good performance in thermoforming in their molten state, probably because the polyolefin-base polymers have a relatively low tackiness in molten stage.
  • high softening temperature is meant in the context of the present invention that the polymer is glassy in room temperature, which contributes to the stiffness of the composite at ambient temperatures.
  • the target softening temperature is in the range between 45°C and 130°C, where the upper limit matches the softening temperature CTMP fibres.
  • Polymers such as acrylic, styrene-acrylic, styrene, styrene-butadiene, and polyesters can be synthesized over a wide range of softening temperatures including temperatures above 45°C, and are suitable as the second polymer in the present invention.
  • Further examples of polymers with high softening temperature are polyvinyl chloride, polyethylene terephthalate, thermoplastic starch, polylactic acid, polyhydroxy alkanoates.
  • a cross-linking polymer could be added as an additive for either further stiffening of the shaped three dimensional products or for increasing water-resistance and/or decrease moisture-induced swelling of the CTMP fibres.
  • thermoplastic polymer is comprised in the binder liquid in the form of a dispersion, an emulsion, or a solution of polymers.
  • Polymer dispersions, or latexes refer to colloidal polymer particles and droplets dispersed in a liquid phase, most dominantly water.
  • Aqueous latex suspensions typically have particle sizes of 0.05 - 2 ⁇ . Dispersed particles are often stabilized in water with surfactants. Inclusion of ionic groups in the synthesized polymer, such as carboxylic and sulphate groups, can also be used to stabilize dispersed plastics by means of electrostatic repulsion.
  • Polymer emulsions are commonly defined as polymers synthesized from monomers in emulsion.
  • compositions of polymer dispersions suitable for use in the present invention are: acrylic, methacrylic, styrene-acrylic co polymers, styrene, styrene-butadiene co-polymers, vinylacetate, acrylonitrile-butadiene, vinylacetate-ethylene copolymers, ethylene-acrylic, vinylacrylates, and polyvinylchloride, polylactic acid and polyhydroxybutanoate, oleofin-rich polymers like the co-polymers from polypropylene and polyethylene.
  • the polymer might be reactive and self-crosslinking to improve the stiffness of the binder in the final composite product.
  • Polymer solutions are efficient for impregnation.
  • Water-based systems are for example biopolymers like cooked starch and proteins, or synthetic polymers like polyvinyl alcohol.
  • Starch is not a true thermoplastic by nature, as dry starch decomposes thermally before the softening temperature is reached. Still, starch can show thermoplastic behaviour when it is combined with plasticizers like glycerol and urea, often in presence of hygroscopic moisture. It is preferred to use an aqueous polymer solution for impregnation of the CTMP web, even though some hydrophobic plastics, for example polylactic acid, can be dissolved in organic solvents and used as impregnation liquid.
  • the total amount of dispersion, emulsion or solution may be 0.1 to 10 grams per gram of dry-laid CTMP web (g/g).
  • g/g grams per gram of dry-laid CTMP web
  • 1-3 g/g dispersion, emulsion or solution is added, whereby it is ensured that the CTMP web is sufficiently wetted so as to obtain the desired swelling, and at the same time the amount of water added to the web is not unnecessarily high, which means that less time and energy need to be spent on drying the expanded CTMP web. It has also been found that keeping the amount of impregnation liquid at maximum 3 g/g increases the wet strength of the expanded dry-laid CTMP web.
  • the solid content of polymer particles in aqueous dispersion can be between 1 % and 60 %.
  • the upper range depends on the viscosity of the dispersion, which must be low enough to achieve efficient uptake and redistribution in the CTMP web.
  • Many commercial types of latexes are supplied at about 50% solid content and show viscosities in the range 300-500 mPa-s, which the CTMP web can absorb as is.
  • the dispersion may still require dilution in order to match the targeted uptake of both polymer and water by the CTMP web.
  • the polymer uptake should match the targeted dry content polymer for the intermediate sheet, 5-50 wt-% while the water uptake should be sufficient for expansion of the calendared web, e.g. 1-2 g/g.
  • the solid content of the dispersion is preferably between 2.5-50 wt-%, more preferably between 5 % and 25 %, in order to assure an efficient uptake, web expansion and distribution of the thermoplastic material in the dry-laid CTMP web.
  • the intermediate dry-laid composite web product may also contain additives to give extra functions in the material. Extra functions are for example achieved by additional dyes, extra strength agents, flame retardancy agents, barrier additives, antimicrobial additives, absorbent particles, softeners for enhanced perception and others.
  • the additives can be added during the airlaying process of the CTMP web or preferably during impregnation.
  • the drying can be performed at ambient temperature, but is preferably performed at an elevated temperature, for example in a hot air oven, in which the temperature is high enough to cause a preliminary bonding of the web by a portion of the thermoplastic material contained therein, so that the web can be handled without severe dusting, or in worst case completely falling apart.
  • the surrounding drying temperature may be set in the interval of 50 °C to 250 °C, and is preferably set in the interval of 80 °C to 150 °C.
  • the temperature of the wet impregnated web will however be lower.
  • the temperature in the wet web during drying should preferably be above Tg for the first polymer and below Tg for the second polymer.
  • the temperature in the wet web should be above Tg of the single polymer in order to establish bonding during drying.
  • the drying sequence can also be terminated with an extra high- temperature peak in order to establish bonding of the sheet.
  • the impregnation, removal of water and pre-heating before thermoforming may be integrated in one step.
  • the surrounding temperature should then be between 130-250°C during drying and pre-heating, and the final temperature of the web after pre-heating should be over 130°C.
  • the obtained dry-laid composite web intermediate product is reeled up to form rolls, or cut into sheets, which are then preferably stacked into bundles, to enable convenient transfer to a thermoforming tool.
  • the composite web can be calendared subsequent to drying, obtaining a web density of 400-1000 kg/m 3 .
  • This may be interesting when certain surface properties, e.g. improved printability, are desired.
  • a calendared web would be easier to handle and transport, due to its more robust and compact character.
  • the composite web is calendared after impregnation and drying, it must be re-swelled before thermoforming, so that the fibres can again move in relation to each other.
  • a dry-laid composite web is obtained, which is an intermediate product having a low density of 50-250 kg/m 3 .
  • the density of tissue papers is in the range of 250-500 kg/ m 3 , newsprint 500-600 kg/m 3 , and bleached Kraft paper is around 800 kg/m 3 .
  • the low density means an increased bulk, larger separation between CTMP fibres, and a low degree of bonding between them. These properties improve the extensibility, i.e. stretchability, and three-dimensional forming capability of the dry-laid composite web.
  • the loosely bonded fibres are able to move relative each other in the sparse fibre network facilitating redistribution according to the shape of the mould.
  • the thermoplastic material provides only soft bonds between CTMP fibres and makes the sheet cohesive enough to allow sufficient stretch in the material, so that the composite web can adapt to the shape of the thermoforming mould.
  • a polymer film is preferably added to one or both sides of the dry-laid composite web after drying thereof.
  • the polymer film contributes to the three-dimensional formability and/or functions as a barrier layer for various substances that may come in contact with the final thermoformed product, such as fat, liquid water, vapour or oxygen.
  • the polymer film may have a thickness of 5-200 ⁇ .
  • Polymer films which are commonly used as outer layers on cellulose-fibre based packages may be used, e.g. polyethylene (PE), polypropylene (PP), and polyethylene terephtalate (PET).
  • PET polyethylene terephtalate
  • the polymeric film preferred in the present invention is made of polylactide (i.e. polylactic acid or PLA) film, since it is a sustainable material.
  • the adhesive and highly viscous properties of plasticized PLA are utilized to improve the extensibility in thermoforming.
  • the PLA film adheres well to the fibre web and follows the extension of the fibre web in the mould. This has surprisingly led to an improved extensibility of the fibre web in three-dimensional thermoforming.
  • PLA remains in a plasticized and adhesive state over a wide temperature interval from the glass transition temperature (55°C) to the melting point (170°C).
  • the PLA film therefore aids the extension of the fibre web over a wide range of thermoforming temperatures. This is especially useful if the substrate is not fully heated when it enters the thermoforming mould, as the PLA film reduces the risk of brittle fracture during the initial contact between the sample and the closing hot mould.
  • Preferred thickness of the PLA film may be 40-60 ⁇ .
  • the intermediate composite web product described above is intended to be used in a thermoforming step utilizing a thermoforming tool, such as a thermo mould or vacuum- forming equipment, to obtain a desired shape.
  • a thermoforming tool such as a thermo mould or vacuum- forming equipment
  • the low density intermediate web is transformed from a relatively thick low density web to a relatively thin object with considerably higher material density in the walls of the three-dimensional product.
  • the final bonding of the composite web develops characteristically at high densities in the range 500- 1000 kg/m 3 . If desired the web may be cut into blanks before being introduced into the thermoforming tool.
  • the intermediate composite web needs to be heated in order to soften the thermoplastic material, typically to about 145-200 °C.
  • the heating can be achieved by pre- heating in an oven or over a hot surface, either batch-wise or continuously.
  • the thermoforming tool is also heated.
  • the CTMP fibres soften when heated to about 130 °C, and it has also been found to be advantageous to the thermoforming properties of the intermediate web if it is moisturized just before thermoforming.
  • the moisture makes the CTMP fibres softer so that they can easier assume the shape of the thermoforming mould.
  • the web is treated with water, preferably by spraying hot water or flowing steam over the sheet, the temperature preferably being 90-100 °C.
  • a moisture content 10-30 wt% in the web is suitable as the form-shaping tool is closing, and more preferably 15-25 wt %.
  • the moisture content is calculated as the relative content of water in a moist web and can be analysed gravimetrically using a drying procedure.
  • the lower limit depends on the required softening effect of water, while the upper limit is set to avoid excess moisture, which leads to steam explosion and damage to the web when the pressure is released.
  • the heated and preferably moistened web is pressed in the thermoforming tool by a predetermined force, so as to reach its destined three-dimensional shape.
  • a suitable pressure may be in the range 1-200 MPa.
  • the final degree of bonding in the CTMP fibre web depends strongly on the achieved density after compression, and thus the applied pressure during thermoforming.
  • the required pressure also depends on the grammage of the substrate. In a preferred application the pressure exceeds 10 MPa, more preferably 20 MPa in order to compress the composite fibre web and reach densities above 800 kg/m 3 , so that efficient bonding of the sheet is obtained.
  • thermoforming tool for use in the thermoforming according to the invention may typically include a mould cavity (female part) and a pressing tool (male part).
  • the pressing tool forces the intermediate web into the mould cavity, so that it attains the shape of the mould cavity.
  • the direction of movement of the pressing tool is referred to as the press direction of the thermoforming tool. The pressure is maintained until the desired shape has been fixated, and the final three- dimensional object is then released from the forming tool.
  • the released object is preferably subjected to a cooling step that occurs in the tool or immediately or shortly after release from the tool, and is preferably cooled to ambient temperature.
  • a fast cooling is especially beneficial because it restores the mechanical properties, and avoids undesired setting of the object.
  • thermoforming operation may be performed in various thermoforming equipments, including compression or vacuum moulding of a pre-heated web or sheet material.
  • compression or vacuum moulding of a pre-heated web or sheet material In thermoforming by compressing moulding, generally two mould parts are closed after the intermediate web has been introduced there between and a pressure is applied for a time long enough for stress-relaxation to occur in the material.
  • a press with heated mould parts having the desired form and capable of applying loads ranged between 1-200 MPa is preferred.
  • the suitable thermoforming temperature will depend on the specific polymer material comprised in the intermediate web, in addition to the softening temperature of CTMP (130 °C).
  • the temperature should exceed the Tg of the polymer material, and if the polymer material comprises two or more different polymers the temperature should exceed Tg of all polymers and the softening temperature of CTMP fibres.
  • a suitable temperature is in the interval 130-200 °C, more preferably 150-180 °C. At higher temperatures than 200 °C, the CTMP fibres may be damaged, and at lower temperatures than 130 °C the CTMP fibres are not soft enough to give a ductile web.
  • the pressing time should be as short as possible, and should typically be in the range of 1-30 seconds at production conditions. Lab-scale pressing may due to the manual setup require longer times, 30-200 seconds.
  • thermoforming a web heated to a forming temperature is stretched onto or into a single-surface mould, and held against the mould by applying a vacuum between the mould surface and the sheet, and optionally applying pressurized air from the other side.
  • the method is rather simple in terms of equipment needed in comparison to the compression moulding technique, but does not offer the same wide range of possible three-dimensional geometries.
  • Three-dimensional objects of various shape and dimension may be obtained by thermoforming an intermediate composite web as described above.
  • a thermoformed three-dimensionally shaped object may have areas in which the material has been extended (i.e., stretched) over 20 % in at least one direction.
  • the one-dimensional extensibility is herein derived from the actual length across the object in one direction divided by the corresponding projected diameter.
  • a formed object may have a circumference in the plane of the planar web before pressing and a maximum depth in a plane perpendicular thereto, wherein the relation of the circumference to the depth is less than 10 and the extensibility of the composite web during thermoforming is exceeding 20 %, preferably 30 %, in at least one direction.
  • the object may also have at least one draft angle that is less than 15°, preferably even less than 5°. In engineering, draft is the amount of taper for moulded parts perpendicular to a parting line. By tapering the sides of a mould by an appropriate so-called draft angle, the mould will be easier to remove once the plastic has hardened in the mould.
  • the extensibility is evaluated from the outer area of the formed three-dimensional object, which matches the shape of the female press tool.
  • the extension in one direction is the relation between the contour length along the profile of the cross section of the shaped object, and the distance across the opening of the object in that cross section. The largest extension will be found at the deepest moulding depth, and the distance across the opening is then the shortest distance over the opening passing over the deepest moulding depth.
  • Fig. 1 illustrates a cup having an elongated shape, which has a bottom and side walls.
  • the bottom has a surface plane that is perpendicular to the press direction of the thermoforming tool, and the side walls are inclined in relation to a line perpendicular to the surface plane of the bottom, by an angle a, which is referred to as the draft angle.
  • the thermoformed three- dimensionally shaped object has an opening in a plane perpendicular to the press direction of the thermoforming tool, at least one side wall, and a bottom, and a maximum depth area, with a maximum depth between the opening and the bottom in a plane perpendicular therebetween.
  • the plane of the first direction is an imaginary plane corresponding to the opening before cutting.
  • L A- A ' is the contour length, which follows the profile of the shaped object along a cross section in said first direction
  • D A -A ' is the shortest distance over the opening passing over said cross section in said first direction.
  • the contour length L A- A ' follows the profile of the shaped object along the cross section, while the distance D A- A ' is the distance between the points A, A' on the periphery of the opening, which distance is the shortest distance over the opening passing over the deepest moulding depth h (maximum depth).
  • the moulding depth is parallel to the press direction of the thermoforming tool.
  • the contour length L A- A ' should preferably be measured with a measuring tape or a thread following the cross sectional plane over the outside of the object, at the deepest portion of the shaped object.
  • the measuring device must be in contact with the sample but must not deform the sample (a support of similar shape may be used if necessary). If the opening area has a symmetrical shape, the cross sections are chosen to pass through the centre of the object. Draft angles should be measured with a stiff measuring device, like a ruler, fitted to a tangent to the outside of the side wall over a length of 10 mm at the steepest part of the side wall.
  • the draft angle is the angle between the tangent to the side wall and a vertical line perpendicular to the surface plane of the bottom of the cup, or a tangential plane perpendicular to the press direction of the thermoforming tool, in cases where the bottom of the shaped object is uneven.
  • the object should not be deformed but instead be determined by estimating an average inclination of the side wall over a distance of 10 mm at the steepest part of the side wall.
  • a two-dimensional measure on extensibility is given by evaluating the extensibility in two directions that are perpendicular to each other and both lies in the plane defining the opening over the cavity.
  • the first direction is defined as above for extensibility in one direction, matching the shortest distance over the opening that also passes over the deepest moulding depth.
  • the second direction describes a distance over the opening that passes over the deepest moulding depth, which is perpendicular to the first direction. Evaluation of the extensibility in both these directions results in two measures on extensibility, ⁇ ⁇ - ⁇ over the first direction and ⁇ ⁇ - ⁇ over the second direction. Evaluation of ⁇ ⁇ - ⁇ is performed in the same manner as ⁇ ⁇ - ⁇ , i.e.
  • the intermediate composite web of the invention have extensibilities ⁇ ⁇ - ⁇ and ⁇ ⁇ - ⁇ that each is at least 18%, more preferably at least 22%, and even more preferably at least 26%.
  • FIG. 2-3 shows an illustration of the test mould, where the mould is open in Fig. 2, and the mould parts are closed in Fig. 3.
  • the test mould comprises a female moulding cavity part 1 and a male pressing part 2.
  • the female moulding part includes an upper flat surface 3 encircling the moulding cavity 4, having a circular upper opening with a diameter (D) and a circular bottom section.
  • the upper opening of the moulding cavity corresponds substantially to the diameter of the thermoformed object.
  • the interior moulding cavity 4 of the female part has the shape of a cylindrical cup having the shape of a truncated cone with a height h, and draft angle a defining the slope of the side of the cone.
  • the truncated cone is rounded off at the edge between the side and bottom section.
  • a second curvature with radius 192 mm (Ri) and bow length 19.1 mm connects the two last mentioned planes.
  • the male pressing part 2 has a shape that corresponds to the female moulding cavity, but is slightly smaller so that a gap 5 is formed between the moulding cavity and the pressing part.
  • the gap (A) in the side wall and top section is somewhat smaller than the gap (B) in the bottom section, see Table 1.
  • a set of moulds is used to cover different draft angles, a, press depth h, and gap widths (A, B).
  • the extensibility is thus a measure of the stretching of the material in one dimension.
  • a two-dimensional measure on extensibility is given by evaluating the extension in two directions that are perpendicular to each other and both lies in the plane defining the opening over the cavity.
  • Mould geometries used for evaluation of extensibility of the composite intermediate web during thermoforming are shown in Table 1.
  • Table 1 The examples below show that the intermediate webs of the present invention have an extensibility of at least 30%, or even 40% that is valid in at least two directions, including two perpendicular cross sections of the thermoformed object.
  • the draft angles of the object are at least 15°, more preferably at least 5° on at least one side.
  • Continuous paper webs do not reach such high extensibility in either machine or cross direction.
  • Continuous paper webs produced by wet-forming and micro-creping can normally reach 12%, at most 20% extensibility in one optimal direction, but typically show lower extensibility in a second perpendicular direction, normally about 9%, at most about 15%.
  • Such anisotropy in extensibility limits the effective extensibility achieved in thermoforming, especially when producing symmetric shapes like the conical 3D shaped objects, which require equal extensibility in at least two directions.
  • the moulded object then needs to be dimensioned after the lower extensibility value in order to avoid failures and cracks during thermoforming.
  • thermoformed object is evaluated to see if the moulding was successful.
  • the evaluation criteria are to check if the sheet has been completely stretched over the mould geometry to produce an intact three-dimensional cup.
  • An unsuccessful moulding may either contain open cracks in the sample, or a severe thinning zone where the grammage has been reduced to less than half compared to the surrounding areas.
  • a thinning zone is the first stage of failure due to insufficient extensibility, eventually leading to an open crack if more strain would be applied. It has been found that addition of moisture during thermoforming and PLA film can increase the extensibility so that severe thinning and cracks are avoided for a given sheet composition and mould geometry. This is illustrated in the examples.
  • a measure on the extensibility of the sheet in one dimension can be calculated according to Equation 1 above, and due to rotation symmetry this extensibility is valid in at least two directions (i.e. a first and a second direction), which includes two perpendicular cross sections of the thermoformed object.
  • Example 1 Preparation of a composite intermediate sheet by spray impregnation
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 400 g/m 2 was placed on a support grid.
  • the sheet had a weight of 97 g.
  • Impregnation was performed by applying latex with a spraying gun driven by pressurized air.
  • the spray application was calibrated by applying latex at a transfer rate of about 1-2 ml/s, the exact rate was verified by weight measurements. After this calibration, spraying was operated against time to control the applied amount.
  • the spray gun was filled with a water dispersion containing 5.3 wt% styrene-butadiene (SB) latex (EKA PL Litex PX9272) and 16.1 wt% polystyrene (PS) latex (Styron DPP 3740), based on the weight of the total dispersion.
  • SB styrene-butadiene
  • PS polystyrene
  • the impregnated sheet was transferred to a table and was dried at ambient conditions to produce a porous sheet, having a total grammage of 570 g/m 2 and a density of 124 kg/m 3 .
  • the polymer content of the intermediate sheet obtained was 7.5 wt% styrene-butadiene and 22.5 wt% polystyrene latex based on weight of the dry intermediate web.
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 400 g/m 2 , weighing 40 g was placed in a tray. 200 ml of a dispersion containing 30 wt% styrene- butadiene latex (EKA PL PX9272) was poured over the sheet, carefully distributing the dispersion evenly. All dispersion was absorbed by the sheet, which expanded spontaneously. A porous composite sheet was obtained after drying at ambient conditions.
  • EKA PL PX9272 a dispersion containing 30 wt% styrene- butadiene latex
  • Example 3 Thermoforming test, sheet with 22.5% PS and 7.5% SB latex.
  • Example 4- Thermoforming with application of PLA film.
  • Example 2 Another 13 x 13 cm sample piece of the impregnated intermediate material obtained in Example 1 was preheated at 170°C for 10 min, wetted by spraying with water to receive a total amount of 2 g, where after PLA film with thickness 40 ⁇ was placed on both sides of the sheet.
  • the same mould as in Example 3 was used and was preheated to a temperature of 150°C.
  • the combined CTMP sheet and PLA film was placed between the open mould halves and the mould was then closed and loaded to 43 MPa. The pressure was maintained for 30 s, during which the temperature increased to 154°C. After releasing the pressure the mould was cooled to 40°C before the sample was released. Inspection showed that the sample was intact and had a laminated PLA film over the upper and lower surface.
  • the sample was wetted by spraying with water to receive a total amount of 2 g before thermoforming the sheet under same conditions as in Example 3. Inspection of the thermoformed cup showed that the sheet had been stretched over all the moulded area, but had a defect consisting of a 20 mm long thinning zone over the bottom area.
  • Example 6 Thermoforming test, mould with 5° draft angle, with PLA film.
  • Example 5 The experiment in Example 5 was repeated, but with application of a PLA film on the top side against the male mould part.
  • the sheet was placed in the mould that was pre-heated to 140°C, loaded to 43 MPa and pressed for 30 s, reaching a temperature of 142°C.
  • the mould was cooled to 40°C before the sample was released. Inspection showed that the sheet was stretched over all the moulded area with only a minor thinning effect in basis weight at the bottom surface.
  • Example 7 Thermoforming test with 15 wt-% PS + 5 wt-% SB latex
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 600 g/m 2 was impregnated with 2 g/g water dispersion containing 3.1 wt% styrene-butadiene latex (EKA PL Litex PX9272) and 9.4 wt% polystyrene latex (Styron DPP 3740) based on the weight of the total dispersion, using the method described in Example 1.
  • the porous sheet produced had a total grammage of 750 g/m 2 and the polymer content was 5 wt-% styrene-butadiene and 15 wt% polystyrene latex based on weight of the dry intermediate web.
  • the porous sheet was thermoformed according to the method described in Example 3. Moisture was added to the substrate prior to thermoforming. The mould was pre-heated to 100°C. The pressure was maintained for 2 min while the temperature in the mould increased to 148°C. A cup-shaped sample was obtained. Inspection showed that the sample had a few minor cracks on the side wall.
  • Example 8 Thermoforming test with 15 wt-% PS and 5 wt-% SB latex using PLA film The test in Example 7 was repeated, with the modification that moisture was added before the applying PLA film on both sides of the sheet. The mould was pre-heated to 100°C. The pressure was maintained for 3 min while the temperature in the mould increased to 147°C. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over the upper and lower surface.
  • Example 9 Thermoforming test with 1% debonder additive
  • Example 7 The test in Example 7 was repeated, with the modification that a debonder for pulp (EKA Soft F639) was added in the impregnation liquor to give a concentration of 1 wt-% debonder in the dry intermediate web, the latex addition being unmodified.
  • the mould was pre-heated to 145°C. The pressure was maintained for 2 min while the temperature in the mould increased to 150°C. A cup-shaped sample was obtained. Inspection that showed the sample was stretched over the mould shape with two small holes present.
  • Example 10 Thermoforming test with 1% debonder additive using PLA film
  • Example 8 The test in Example 8 was repeated, with the modification that a debonder for pulp (EKA Soft F639) was added in the impregnation liquor to give a concentration of 1 wt-% debonder in the dry intermediate web, the latex addition being unmodified.
  • the mould was pre-heated to 100°C. The pressure was maintained for 3 min while the temperature in the mould increased to 147°C. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film with weak adhesion over the upper and lower surface. This indicates that it may be preferred not to use debonder for such a product, since i may weaken the adherence of the PLA film.
  • Example 11 Thermoforming test with 20 wt-% SB latex.
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 600 g/m 2 was impregnated with 2 g/g water dispersion containing 12,5 wt-% styrene-butadiene latex (EKA PL Litex PX9272), using the method described in Example 1.
  • the porous sheet produced had a total grammage of 750 g/m 2 , and the polymer content was 20 wt-% styrene-butadiene, based on the weight of the dry intermediate web.
  • the porous sheet was thermoformed according to the method described in Example 4.
  • Moisture and PLA film was added to the substrate prior to thermoforming.
  • the mould was pre-heated to 80°C.
  • the pressure was maintained for 2 min while the temperature in the mould increased to 145°C.
  • a cup-shaped sample was obtained. Inspection showed that the sample was stretched over all the moulded area except for a minor crack on the side wall.
  • the sample had a laminated PLA film over the upper and lower surface.
  • the test in example 11 was repeated with a higher solid content of the latex dispersion, 21.4 wt-%.
  • the porous sheet produced had a total grammage of 850 kg/m 3 and a polymer content of 30 wt-% styrene-butadiene (EKA PL Litex PX9272) based on weight of the dry intermediate web.
  • EKA PL Litex PX9272 styrene-butadiene
  • Example 13 Thermoforming test with 20 wt-% SB latex
  • the test in example 11 was repeated by impregnating with 12,5 wt-% styrene-butadiene latex (Synthomer Litex S 21 C).
  • the porous sheet produced had a total grammage of 750 kg/m 3 and a polymer content of 20 wt-% styrene-butadiene latex based on weight of the dry intermediate web.
  • a cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 14 Thermoforming test with 20 wt-% PS latex.
  • the test in Example 11 was repeated by impregnating with 12.5 wt-% styrene latex (Styron DPP 3740).
  • the porous sheet produced had a total grammage of 750 kg/m 3 and a polymer content of 20 wt-% styrene-butadiene latex based on weight of the dry intermediate web.
  • a cup-shaped sample was obtained. Inspection showed that the sample was intact with a rough surface structure, and had a laminated PLA film over both the upper and lower surface.
  • Example 15 Thermoforming test with 11 wt-% PVA latex
  • a sheet of dry-laid calendared web of HT-CTMP fibres having grammage of 600 g/m 2 was impregnated with 2 g/g water dispersion containing 5.9 wt% polyvinylacetate (PVA) emulsion (Celanese Vinamul 9300), using the method described in Example 1.
  • the porous sheet produced had a total grammage of 670 g/m 2 and the polymer content was 11 wt-% polyvinylacetate emulsion based on weight of the dry intermediate web.
  • the porous sheet was thermoformed according to the method described in Example 4 with the following modifications: The porous sheet was pre-heated to 140°C and applied in dry state for thermoforming without any addition of water.
  • PLA film was applied on both sides of the sheet.
  • the mould was pre-heated to 120°C, pressure was maintained for 1 min while the temperature in the mould increased to 145°C.
  • a cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 16 Thermoforming test with 20 wt-% PVA latex
  • Example 15 The test in Example 15 was repeated with a higher solid content of the latex dispersion, 12.5 wt-%.
  • the porous sheet produced had a total grammage of 750 kg/m 3 and a polymer content of 20 wt-% polyvinylacetate emulsion (Celanese Vinamul 9300) based on weight of the dry intermediate web.
  • the sheet was used without moisture addition and PLA film was added on both sides of the substrate. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 17 Thermoforming test with 15 wt-% PS and 5 wt-% PVA latex
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 600 g/m 2 was impregnated with 2 g/g water dispersion containing 3.1 wt% polyvinylacetate dispersion (Celanese Vinamul 9300) and 9.4 wt% polystyrene latex (Styron DPP 3740) based on the weight of the total dispersion, using the method described in Example 1.
  • the porous sheet produced had a total grammage of 750 g/m 2 and the polymer content was 5 wt-% polyvinylacetate and 15 wt% polystyrene latex based on weight of the dry intermediate web.
  • the porous sheet was thermoformed according to the method described in Example 4. Moisture and PLA film was added to the substrate prior to thermoforming. The mould was pre-heated to 110°C. The pressure was maintained for 3 min while the temperature in the mould increased to 147°C. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 18 Thermoforming test with 10 wt-% PS and 10 wt-% VAE latex
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 600 g/m 2 was impregnated with 2 g/g water dispersion containing 6.3 wt% vinylacetate-ethylene copolymer emulsion (Celanese Mowilith PE 292S) and 6.3 wt% polystyrene latex (Styron DPP 3740) based on the weight of the total dispersion, using the method described in Example 1.
  • the porous sheet produced had a total grammage of 750 g/m 2 and the polymer content was 10 wt-% vinylacetate-ethylene copolymer and 10 wt% polystyrene latex based on weight of the dry intermediate web.
  • the porous sheet was thermoformed according to the method described in Example 4, except that no moisture was added after pre-heating. PLA film was added on both sides of the substrate prior to thermoforming. The mould was pre-heated to 110°C. The pressure was maintained for 3 min while the temperature in the mould increased to 147°C. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 19 Thermoforming test with 20 wt-% self-crosslinking VAE
  • Example 11 The test in Example 11 was repeated by impregnating with 12.5 wt-% self-crosslinking vinylacetate-ethylene latex (Celanese Elite Ultra).
  • the porous sheet produced had a total grammage of 750 kg/m 3 and a polymer content of 20 wt-% self-crosslinking vinylacetate- ethylene polymer based on weight of the dry intermediate web.
  • Moisture and PLA film was applied on both sides of the substrate before thermoforming. A cup-shaped sample was obtained. Inspection showed that the sample was intact and had a laminated PLA film over both the upper and lower surface.
  • Example 20 Thermoforming test with 30 wt-% PP latex
  • a sheet of dry-laid calendared web of HT-CTMP fibres having a grammage of 400 g/m 2 was impregnated with 2 g/g water dispersion containing 21,4 wt% polypropene copolymer latex (Dow Hypod 4501), using the method described in Example 1.
  • the porous sheet produced had a total grammage of 570 g/m 2 and the polymer content was 30 wt-% polypropylene copolymer latex based on weight of the dry intermediate web.
  • a 13 x 13 cm sample piece of the impregnated intermediate material obtained was sprayed with water to receive a total amount of 2 g before it was preheated in an oven at 145°C for 9 min. Thereafter PLA film with thickness 40 ⁇ was placed on both sides of the sheet. Same mould as in Example 3 was used and was preheated to a temperature of 80°C. The combined CTMP sheet and PLA film was placed between the open mould halves and the mould was then closed and loaded to 43 MPa. The pressure was maintained for 80 s, during which the temperature increased to 141°C. After releasing the pressure the mould was cooled to 40°C before the sample was released. A cup- shaped sample was obtained. Inspection showed that the sample had been smoothly stretched over the mould, except for a minor crack on the side wall, and had a laminated PLA film over the upper and lower surface.
  • the experimental results show that the intermediate web of the present invention can successfully be thermoformed into three-dimensional objects, and that by wetting and moisturizing the CTMP fibres in the intermediate web good test cups can be obtained by thermoforming a web, where the same dry web could not be formed to an acceptable cup in a dry state. Further, the experiments show that the addition of a PLA film on the surface of the intermediate web contributes to substantially enhanced formability, so that a cup having a draft angle as low as 5° can be formed.
  • Intact cup-shaped samples illustrate that the intermediate sheet has been successfully stretched over both its machine- and cross direction during the thermoforming process. The extension in the mould corresponds to a high stretch of the material, at least 39 % in either direction. Furthermore, the thermoformed material has been evenly stretched to produce a smooth surface without any crinkling effect.
  • thermoformed three-dimensional objects obtained according to the present invention may be used for packaging of various goods, e.g. sensitive goods, such as electronic equipment, cellular phones and other household and hardware items, that need protective packaging in order to avoid damage of the sensitive goods, due to for example mechanical shock, vibrations, compression, or extreme temperatures during transport, storage, or other handling.
  • sensitive goods such as electronic equipment, cellular phones and other household and hardware items
  • protective packaging in order to avoid damage of the sensitive goods, due to for example mechanical shock, vibrations, compression, or extreme temperatures during transport, storage, or other handling.
  • thermoformed three-dimensional objects according to the invention are also suitable as construction materials, especially in the form of panels, frames, lids, covers and similar.
  • the three-dimensional shape provides both design and function to the item, e.g. structure, decoration, coverage, protection, fixation, support, storage etc.
  • Compressed wood fibre composites show good tensile strength and stiffness, and the sustainability associated with the wood fibres give environmental benefits.
  • a few typical examples of construction materials are indoor building materials, furniture applications and panels for use in the automotive industry.
  • Indoor building materials are three-dimensionally shaped panels, frames, profiles, covers or the like, typically for permanent attachment.
  • 3D shaped building materials are used both for decoration, protection and support.
  • three-dimensionally shaped items can be used as self-supporting structures in furniture.
  • 3D shaped details can also be used in multilayer-structures either as core materials or as a top ply.
  • Three-dimensionally shaped items are also commonly used as panels in automotive industry, for example in dashboards and door panels.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne une toile composite par voie sèche constituant un produit intermédiaire pour le thermoformage d'objets de forme tridimensionnelle, comportant 40 à 95% en poids de fibres de CTMP, 5 à 50% en poids d'un matériau thermoplastique et 0 à 10% en poids d'additifs, la toile composite par voie sèche ayant été imprégnée d'une dispersion, d'une émulsion ou d'une solution contenant le matériau thermoplastique et séchée, obtenant une masse volumique de 50 à 250 kg/m3, ou, si elle est comprimée par calandrage, 400-1000 kg/m3, et un processus de production de toile comportant les étapes consistant à: former une toile par voie sèche comportant des fibres de CTMP; ajouter un matériau thermoplastique à la toile par imprégnation, le matériau thermoplastique étant ajouté sous la forme d'une dispersion, d'une émulsion ou d'une solution dans une quantité de nature à atteindre 5 à 50% en poids de matériau thermoplastique sur la base du poids total à sec de la toile; sécher; et réaliser des rouleaux ou des feuilles de celle-ci, ainsi qu'un processus de production d'un objet 3D à partir de la toile intermédiaire, comportant les étapes consistant à: optionnellement, dans le cas où la toile intermédiaire pour composite est calandrée, faire gonfler la toile par mouillage à l'eau, suivi d'un séchage; chauffer et introduire la toile dans un outil de thermoformage présentant la forme souhaitée; mettre en forme la toile dans l'outil de thermoformage en la soumettant à une pression de 1 à 200 MPa, ou en utilisant un vide; démouler l'objet de forme tridimensionnelle ainsi obtenu de l'outil de thermoformage, et un objet 3D thermoformé.
PCT/SE2013/050217 2013-03-11 2013-03-11 Toile composite par voie sèche destinée au thermoformage d'objets de forme tridimensionnelle, processus pour sa production, son thermoformage, et objet thermoformé de forme tridimensionnelle Ceased WO2014142714A1 (fr)

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CN110998024A (zh) * 2017-06-02 2020-04-10 普乐模塑纤维技术私人有限责任公司 用于由绒毛浆材料制造3-维成形产品的方法以及这样的产品
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SE2050889A1 (en) * 2020-07-09 2022-01-10 Stora Enso Oyj Folded 3D shaped packaging product
SE2050890A1 (en) * 2020-07-09 2022-01-10 Stora Enso Oyj Recyclable 3D shaped product
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WO2022009129A1 (fr) 2020-07-09 2022-01-13 Stora Enso Oyj Produit d'emballage de forme 3d à partir d'une découpe de feuille formée par voie pneumatique
WO2022009131A1 (fr) 2020-07-09 2022-01-13 Stora Enso Oyj Produit façonné en 3d recyclable à partir d'une ébauche formée par voie sèche
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WO2025210267A1 (fr) 2024-04-04 2025-10-09 Bluethink S.P.A. Procédé de fabrication d'objets tridimensionnels (3d) par pressage et/ou thermoformage d'une bande sensiblement plane comprenant un matériau à base de cellulose, et objet 3d ainsi obtenu

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