WO2014160635A1 - In situ heated process probe - Google Patents
In situ heated process probe Download PDFInfo
- Publication number
- WO2014160635A1 WO2014160635A1 PCT/US2014/031561 US2014031561W WO2014160635A1 WO 2014160635 A1 WO2014160635 A1 WO 2014160635A1 US 2014031561 W US2014031561 W US 2014031561W WO 2014160635 A1 WO2014160635 A1 WO 2014160635A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- transmitter
- combustion
- measurement cell
- process combustion
- heater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N25/00—Investigating or analyzing materials by the use of thermal means
- G01N25/20—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity
- G01N25/22—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures
- G01N25/28—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly
- G01N25/30—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly using electric temperature-responsive elements
- G01N25/32—Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity on combustion or catalytic oxidation, e.g. of components of gas mixtures the rise in temperature of the gases resulting from combustion being measured directly using electric temperature-responsive elements using thermoelectric elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
- Y10T436/208339—Fuel/air mixture or exhaust gas analysis
Definitions
- combustion processes include operation of a furnace or boiler to generate energy from combustion, which is then used for the process. While combustion provides relatively low-cost energy, its use is typically regulated and combustion efficiency is sought to be maximized. Accordingly, one goal of the process management industry is to reduce the cost of fuel being burned, which also inherently minimizes production of greenhouse gases by maximizing combustion efficiency of existing furnaces and boilers.
- 10002 J In situ or in-process analyzers are commonly used for monitoring, optimizing, and/or controlling combustion processes. Typically, these analyzers employ sensors that are heated to relatively high temperatures and are operated directly above, or near, the furnace or boiler combustion zone.
- Known analyzers such as those sold under the trade designation Oxymitter or Model 6888 02 Combustion Flue Gas Transmitter available from Roscmount Analytical, Inc. of Solon, Ohio (an Emerson Process Management company), often employ zirconia oxide sensors heated to a temperature above approximately 736° Celsius (1300° Fahrenheit). If the combustion process should suffer a flame out condition, raw fuel and air could be exposed to this sensor which, by virtue of its elevated temperature, could become an ignition source with the possibility of precipitating an explosion.
- hazardous area- approved analyzers include a flame arrestor that is added over the diffuscr with the intent of quenching, or otherwise inhibiting, an explosion that might occur in front of the heated measurement cell, thereby preventing the ignition of the larger fuel volume in the boiler or combustion zone.
- flame arrestors have been tested and approved in the past. However, it is believed that such arrestors can be improved.
- the utilization of the flame arrestors may inhibit, to some degree, access to the measurement cell thereby increasing measurement lag.
- the utilization of flame arrestors adds expense and complexity to the system.
- a process combustion transmitter includes a process probe extendible into a flow of process combustion exhaust.
- the process probe has a measurement cell with an operating temperature that is above a flashpoint of process combustion fuel.
- the process probe includes a heater configured to heat the measurement cell to the operating temperature.
- Electronic circuitry is coupled to the measurement cell and to the heater. The electronic circuitry is configured to disengage power to the heater once process combustion heat is sufficient to maintain the measurement cell at the operating temperature and thereafter to maintain the heater in a de-energized state.
- FIG. 1 is a diagrammatic view of an in situ combustion process analyzer with which embodiments of the present invention are particularly useful.
- FIG. 2 is a diagrammatic exploded view of a process analytic oxygen transmitter in accordance with an embodiment of the present invention.
- FIG. 3 is a diagrammatic view of an in situ combustion process analyzer in accordance with an embodiment of the present invention.
- FIG. 4 is a flow diagram of a method of operating an in situ process analytic oxygen transmitter in accordance with an embodiment of the present invention.
- FIG. 1 is a diagrammatic view of an in situ process combustion analyzer with which embodiments of the present invention are particularly useful.
- Transmitter 10 can be any suitable analyzer including the 6888 02 Combustion Flue Gas Transmitter listed above.
- Transmitter 10 includes a probe assembly 12 that is disposed within a stack or flue 14 and measures at least one parameter related to combustion occurring at burner 16.
- transmitter 10 is an oxygen transmitter, but can be any device that measures any suitable parameter related to the combustion process.
- Burner 16 is operably coupled to a source 18 of air or oxygen and a source 20 of combustible fuel.
- Transmitter 10 measures the amount of oxygen in the combustion exhaust flow and provides an indication of the oxygen level to combustion controller 22. Controller 22 controls one or both of valves 24, 26 to provide closed-loop combustion control.
- Transmitter 10 includes an oxygen sensor that typically employs a zirconia oxide sensor substrate to provide an electrical signal indicative of oxygen concentration, content or percentage in the exhaust. Zirconia oxide sensors operate at a temperature of about 700° Celsius and transmitter 10 includes, within probe assembly 12, an electrical heater that is operably coupled to AC power source 29.
- AC power source 29 can be a 1 10 or 220 VAC source that provides electrical energy to one or more electrical heating elements within probe assembly 12 to heat the zirconia oxide sensor substrate to a suitable temperature.
- prior art methods generally include a flame scanner 28 disposed to provide a signal indicative of the presence of flame 30 at burner 16.
- This flame scanner signal has been provided allow suitable reaction to the flameout condition.
- the flame scanner signal has been used to close a fuel valve and/or remove power from the analyzer thereby de-energizing the heater within probe assembly 12. In many cases, this removal of power allows rapid cooling of the zirconia oxide sensor to a temperature that is below the fuel ignition temperature, thereby creating a safe condition.
- FIG. 2 is a diagrammatic view of an in situ process combustion analyzer in accordance with an embodiment of the present invention.
- Probe assembly 12 is generally configured to house the sensor core assembly which includes diffuser 32 disposed next to measurement cell 36.
- measurement ceil 36 is operable at an elevated temperature and the elevated temperature is provided by electrical heater assembly 38, during startup.
- Measurement cell 36 and heater assembly 38 are electrically coupled to electronic circuitry of transmitter 10.
- the electronic circuitry is earned on electronics board 42 in housing 44.
- temperature sensor 46 is also coupled to electronic circuitry on board 42. Temperature sensor 46 provides an indication of the temperature of the probe assembly 12 to the circuitry.
- Temperature sensor 46 in one embodiment, is separate from and in addition to the temperature sensor disposed within or proximate heater assembly 38 for thermal control of heater 38 during energization. In this way, temperature sensor 46 can provide an indication of process heat that is less affected by heal: generated from heater assembly 38.
- the electronic circuitry is configured, through hardware, software or a combination thereof, to determine whether the temperature of probe assembly 12, as indicated by temperature sensor 46, has reached a heater shutoff threshold and upon reaching such threshold, latching, or otherwise placing, the heater power in an off condition until the electronic circuitry receives a reset signal .
- the process heat becomes the sole source of elevated temperature for measurement cell 36.
- FIG. 3 is a diagrammatic view of an in situ combustion process analyzer in accordance with an embodiment of the present invention.
- Transmitter 50 includes probe assembly 52 containing therein a process gas sensor that operates at a temperature that is high enough to ignite unburned fuel from source 20 in the presence of air or oxygen from source 18 if flame 30 is lost.
- the combustion process analyzer shown in FIG. 3 does not require a flame seamier signal and thus the flame scanner is omitted from the combustion monitoring/control system.
- Transmitter 50 in accordance with an embodiment of the present invention, once reset, will allow its heater to operate until such time as it determines that process heat from flame 30 is sufficient to maintain a suitable elevated temperature of measurement cell 36, within probe assembly 52.
- heater 38 is disengaged and thereafter maintained in such condition until transmitter 50 is reset.
- Such reset can be in the form of a technician operating a reset button or control disposed on transmitter 50 or by sending a suitable reset command to transmitter 50 via a process communication loop or other suitable communication channel.
- This reset signal will generally be provided by the technician when the combustion process is starting up, and thus occurs under the technician's supervision. Since embodiments of the present invention provide protection against flameout conditions without the need for a flame scanner signal or a constant connection to a source of gas, such as calibration or purge gas, it is believed that embodiments of the present invention can be utilized in more applications than previous systems due to the simplicity and lower cost. Additionally, some embodiments of the present invention may be practicable without requiring the additional expense of a flame arrestor.
- FIG. 4 is a flow diagram of a method of operating an in situ process analytic oxygen transmitter in accordance with an embodiment of the present invention.
- Method 80 begins at block 82 where the in situ transmitter is initialized. Such initialization may include an initial power-up of the transmitter or, in the case of the transmitter already having power, the provision of a reset signal, either locally or via suitable communication techniques.
- the in situ transmitter will allow its heater to be engaged, as indicated at block 84. This allows the measurement cell to quickly reach its operating temperature such that useful process measurements can be provided.
- the transmitter begins providing process variable information, such as oxygen content in combustion gases, to a process controller, such as controller 22, or other suitable device.
- the transmitter determines if process heat is sufficient to maintain an elevated temperature of the measurement cell. If the process heat Is not sufficient, control returns to block 86 via line 90, and the method loops until sufficient process heat is present. Once sufficient process heat is present, control passes to block 92, where the heater is latched in an off or de-energized state.
- the determination of whether sufficient process heat is present is performed automatically by transmitter 52. In such instance, transmitter 52 measures a temperature within or proximate probe 52 and compares the measured temperature with a threshold value. If the measured temperature is at or above the threshold value, for example, the heater can be de-energized and remain so until the transmitter receives a reset.
- embodiments of the present invention also include other techniques by which the heater may be latched off.
- the transmitter may receive a "heater off signal from the combustion controller, which has determined that the combustion heat is sufficient to maintain the measurement cell at a suitable elevated temperature for operation. Once the heater is latched off, control passes to block 94 where the process combustion transmitter continues providing process variable information regarding process combustion gases, such as oxygen content, while the heater is de-energized.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Regulation And Control Of Combustion (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14773891.8A EP2979031B1 (en) | 2013-03-29 | 2014-03-24 | In situ heated process probe |
| CA2903401A CA2903401C (en) | 2013-03-29 | 2014-03-24 | In situ heated process probe |
| ES14773891T ES2788375T3 (en) | 2013-03-29 | 2014-03-24 | Procedure probe with on-site heating |
| CN201480004091.4A CN104903650B (en) | 2013-03-29 | 2014-03-24 | The process probe of scene heating |
| AU2014241683A AU2014241683B2 (en) | 2013-03-29 | 2014-03-24 | In situ heated process probe |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361806626P | 2013-03-29 | 2013-03-29 | |
| US61/806,626 | 2013-03-29 | ||
| US14/222,015 | 2014-03-21 | ||
| US14/222,015 US9797849B2 (en) | 2013-03-29 | 2014-03-21 | Method of operation an in SITU process probe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2014160635A1 true WO2014160635A1 (en) | 2014-10-02 |
Family
ID=51621238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2014/031561 Ceased WO2014160635A1 (en) | 2013-03-29 | 2014-03-24 | In situ heated process probe |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9797849B2 (en) |
| EP (1) | EP2979031B1 (en) |
| CN (1) | CN104903650B (en) |
| AU (1) | AU2014241683B2 (en) |
| CA (1) | CA2903401C (en) |
| ES (1) | ES2788375T3 (en) |
| WO (1) | WO2014160635A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5137616A (en) * | 1991-04-04 | 1992-08-11 | Surface Combustion, Inc. | Gas analysis system for furnaces and the like |
| US20080087005A1 (en) * | 2005-02-15 | 2008-04-17 | Robert Bosch Gmbh | Method For The Voltage-Controlled Performance Regulation Of The Heating Of An Exhaust-Gas Probe |
| US20100073017A1 (en) * | 2008-09-22 | 2010-03-25 | Robert Bosch Gmbh | Method for operating a heatable exhaust gas probe |
| US20110012040A1 (en) * | 2009-07-15 | 2011-01-20 | Bailey Edward J | Flame safety system for in situ process analyzer |
| US20110056313A1 (en) * | 2008-05-13 | 2011-03-10 | Soot-Tech Aktiebolag | method for measuring conditions in a power boiler furnace using a sootblower |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4135382A (en) | 1978-01-23 | 1979-01-23 | Thermo-Lab Instruments, Inc. | Apparatus for developing a counterflow to clean a fluid conveying conduit of a gas analyzer |
| JPS628107A (en) | 1985-07-05 | 1987-01-16 | Nomura Sogo Kenkyusho:Kk | Optical function element |
| JPH05226962A (en) | 1992-02-14 | 1993-09-03 | Rohm Co Ltd | Oscillator |
| US5318752A (en) | 1993-01-22 | 1994-06-07 | Jan Visser | Method and apparatus for sampling a reactive atmosphere into a vacuum chamber of an analyzer |
| US6120664A (en) | 1998-01-16 | 2000-09-19 | Patel; Nitin J. | Oxygen analyzer |
| US6565352B2 (en) | 2001-04-09 | 2003-05-20 | Ken E. Nielsen | Smoke density monitor |
| US20040149579A1 (en) | 2002-12-19 | 2004-08-05 | General Electric Company | System for monitoring combustible gases |
| US6862915B2 (en) | 2003-03-20 | 2005-03-08 | Rosemount Analytical Inc. | Oxygen analyzer with enhanced calibration and blow-back |
| JP2007084559A (en) | 2004-05-31 | 2007-04-05 | Wakunaga Pharmaceut Co Ltd | Blood testosterone level-lowering inhibitor |
| CN101329110B (en) | 2008-07-14 | 2011-07-13 | 深圳市佳运通电子有限公司 | Full-automatic control system of oil field heating furnace |
-
2014
- 2014-03-21 US US14/222,015 patent/US9797849B2/en active Active
- 2014-03-24 AU AU2014241683A patent/AU2014241683B2/en not_active Ceased
- 2014-03-24 CA CA2903401A patent/CA2903401C/en active Active
- 2014-03-24 CN CN201480004091.4A patent/CN104903650B/en active Active
- 2014-03-24 EP EP14773891.8A patent/EP2979031B1/en active Active
- 2014-03-24 WO PCT/US2014/031561 patent/WO2014160635A1/en not_active Ceased
- 2014-03-24 ES ES14773891T patent/ES2788375T3/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5137616A (en) * | 1991-04-04 | 1992-08-11 | Surface Combustion, Inc. | Gas analysis system for furnaces and the like |
| US20080087005A1 (en) * | 2005-02-15 | 2008-04-17 | Robert Bosch Gmbh | Method For The Voltage-Controlled Performance Regulation Of The Heating Of An Exhaust-Gas Probe |
| US20110056313A1 (en) * | 2008-05-13 | 2011-03-10 | Soot-Tech Aktiebolag | method for measuring conditions in a power boiler furnace using a sootblower |
| US20100073017A1 (en) * | 2008-09-22 | 2010-03-25 | Robert Bosch Gmbh | Method for operating a heatable exhaust gas probe |
| US20110012040A1 (en) * | 2009-07-15 | 2011-01-20 | Bailey Edward J | Flame safety system for in situ process analyzer |
| WO2011008743A2 (en) | 2009-07-15 | 2011-01-20 | Rosemount Analytical Inc. | Flame safety system for in situ process analyzer |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2979031B1 (en) | 2020-02-26 |
| US9797849B2 (en) | 2017-10-24 |
| CA2903401A1 (en) | 2014-10-02 |
| CA2903401C (en) | 2018-07-10 |
| CN104903650A (en) | 2015-09-09 |
| CN104903650B (en) | 2018-03-16 |
| EP2979031A4 (en) | 2016-10-19 |
| EP2979031A1 (en) | 2016-02-03 |
| ES2788375T3 (en) | 2020-10-21 |
| US20140295570A1 (en) | 2014-10-02 |
| AU2014241683B2 (en) | 2016-09-15 |
| AU2014241683A1 (en) | 2015-09-17 |
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