WO2015006987A1 - 多效能粉料组成物及其制造方法 - Google Patents
多效能粉料组成物及其制造方法 Download PDFInfo
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- WO2015006987A1 WO2015006987A1 PCT/CN2013/079748 CN2013079748W WO2015006987A1 WO 2015006987 A1 WO2015006987 A1 WO 2015006987A1 CN 2013079748 W CN2013079748 W CN 2013079748W WO 2015006987 A1 WO2015006987 A1 WO 2015006987A1
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- powder
- mud
- waste
- resin
- circuit board
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the invention relates to a composition of a powder and a manufacturing method thereof, in particular to an environmentally-friendly powder comprising a mixture of cement, waste circuit board powder, resin, powder coating waste powder and mud volcanic mud powder.
- the huge production volume of human oil extraction and refining of resin has not only accelerated the crisis of oil shortage, but also produced many wastes when manufacturing defective products and functions.
- the number of mountains is difficult to estimate. If it can effectively handle the recycling and reuse of electronic waste, it will bring great market demand opportunities.
- the circuit board is made of epoxy resin, phenolic resin, bakelite powder, refractory fiber and heavy metal, and various chemicals. It is resistant to acid and alkali and is decomposable. If it is used to dispose of the waste circuit board or bury the drilled powder To streams, rivers and other places, harmful substances will pollute the environment and cause great harm to the ecology; if it is treated by combustion, it will inevitably cause air pollution, and toxic gases will flow around and endanger human health.
- the greenhouse effect caused by carbon dioxide has caused the surface temperature of the earth to rise year by year, various natural disasters have become more frequent, and the probability of volcanic eruption and tsunami has increased.
- the melting of icebergs has caused sea levels to rise, and the city will become a ruin in the sea.
- Many low-lying or island countries will Facing the country of death. Infectious diseases and acid rain erosion, natural ecological damage, etc., all endanger human and animal and plant survival.
- the global front is a great test.
- the anti-warming is like an unprecedented catastrophe in the third world war of centuries.
- the present inventors actively developed research and, in order to improve the above-mentioned deficiencies, and after long-term efforts and experiments, finally developed and designed the environmentally-friendly multi-functional powder composition of the present invention and a method for producing the same.
- the technical problem to be solved by the present invention is to provide a multi-functional powder composition and a manufacturing method thereof, which can solve the problem that the existing waste materials pollute the environment, and the prior art cannot fully recycle the recycling of the technology industry waste.
- the technical solution adopted by the present invention is: an environmentally-friendly multi-functional powder composition composed of cement, waste circuit board powder, resin, powder coating waste powder and mud volcanic mud powder.
- the waste circuit board powder contains phenol resin, epoxy resin, glass fiber, and aluminum metal.
- any one of the cement, the waste circuit board powder, the resin, the powder coating waste powder, and the mud volcanic mud powder is in the multi-purpose powder composition.
- the content ranges from 10% to 50%.
- the mud volcanic mud powder has a particle size of between 100 and 500 nanometers.
- a method for manufacturing an environmentally-friendly multi-functional powder composition comprising: recycling a waste circuit board, removing the surface parts thereof, and cutting, crushing and separating the method to form the waste circuit board powder; recovering powder coating The powdered waste powder produced by the operation is used to prepare the powder coating waste powder; the mud volcanic mud is recovered and subjected to crushing and drying means to form the mud volcanic mud powder; the waste circuit board powder and powder coating waste powder, The mud volcanic mud powder is mixed and stirred, and the cement and the resin phase are uniformly mixed to obtain the environmentally-friendly multi-functional powder.
- the mud volcanic mud powder may be mixed with the resin before the mixing and stirring means to prevent the mud volcanic powder slurry from agglomerating and hardening during storage.
- the environmentally-friendly multi-functional powder composition prepared by the above method can be widely used in construction engineering structures as a coating, filling material or infusion material, and manufacturing various building materials, thereby achieving waste recycling.
- Environmental protection benefits become an innovative insulation with high physical and chemical properties, heat insulation, heat preservation, sound absorption, waterproof, mildew proof, rust, fire, acid and alkali, UV resistance, and can increase structural strength and resistance to aging, moisturizing and water reduction It can catalyze expansion, environmental protection and energy-saving health coatings, composite board structure and building materials, and has many advantages such as better industrial economic benefits.
- the environmentally-friendly multi-functional powder composition comprises a mixture of cement, waste circuit board powder, resin, powder coating waste powder and mud volcanic mud powder.
- the waste circuit board powder contains phenolic resin, epoxy resin, glass fiber and aluminum metal.
- the cement, the waste circuit board powder, the resin, the powder coating waste powder, and the mud volcanic mud powder are all in the multi-performance
- the content of the powder composition ranges from 10% to 50%, and can be proportioned according to the required percentage in use.
- the mud volcanic mud powder has a particle diameter of between 100 and 500 nanometers (Nanometer, referred to as nm).
- the environmentally-friendly multi-functional powder composition of the present invention comprises the following steps:
- the mud volcanic mud powder may be mixed with the powder resin in advance before being mixed with the powder resin, or uniformly mixed with the liquid resin, so that the drying process can be eliminated, and the mud volcanic mud powder can be prevented.
- the block hardens during storage and reduces production costs.
- the environmentally-friendly multi-functional powder can be a coating through a liquid miscible method, and is applied to a building or a building material (such as a plate body or a bonding cloth) by spraying or brushing the coating. Skin), block composites, etc.) to achieve high physical and chemical properties.
- the environmentally-friendly multi-functional powder material can also be used as a filling material to fill the gap between the cement sand and gravel after drying, so that it is excellent in adhesion, strong in structure and high in density and resistance.
- Acid-alkaline and high-quality protective wall structure with antibacterial property, insulation, heat insulation and energy saving can also be used as a filling material to fill the gap between the cement sand and gravel after drying, so that it is excellent in adhesion, strong in structure and high in density and resistance.
- the specific application of the environmentally-friendly multi-functional powder can also be used as a perfusion molding material through a liquid miscible method, and a mold (or a mezzanine space) can be preset, and the organic multi-effect powder which is miscible into a liquid state can be mixed.
- the material is injected into the mold (or the interlayer space), and after the environmentally-friendly multi-functional powder is dried, the mold is demolded, and a three-dimensional structure such as a body, a cylinder, a tube body, a plate body, a wave board, and a roof tile can be formed;
- the environmentally-friendly multi-purpose powder can also be combined with bamboo mat, hemp rope net, glass fiber mesh, coconut palm, straw, non-woven fabric, etc.
- the environmentally-friendly multi-functional powder of the present invention can also replace the current metal wave board, roof tile, stone, wood, ceramic, plastic board (skin), concrete, styrofoam, PS board. , PV, PE and other foaming materials, traditional protective coatings, etc., set into imitation stone, imitation wood, imitation ceramics and other appearance surface to improve the shortcomings of existing materials, such as metal wave board defects are thin and intolerant to heavy pressure Heavy rain hits noise, is not resistant to acid and alkali, easy to rust and water leakage, high thermal conductivity, lightning risk, poor thermal insulation performance, aging deformation, sharp injury and so on.
- the disadvantages of stone are cumbersome, high transportation cost, difficult construction, high thermal conductivity, poor thermal insulation performance, poor water resistance, discoloration, bursting in fire, and danger of falling.
- the disadvantage of wood is that cutting trees will harm the earth, and it is afraid of water, fire, fear of termites, and often adding formaldehyde to the body can cause cancer and health.
- the shortcomings of ceramics are engineering work, high heat conduction, poor thermal insulation performance, inability to withstand heavy pressure collisions, danger of falling earthquakes, leakage of magnetic seams, etc.
- the disadvantages of plastic materials are that they are not environmentally friendly, non-refractory, and are not resistant to heavy pressure and deformation.
- the disadvantages of the conventional protective coatings are that the solvent and the formaldehyde are not environmentally friendly, the ratio of the heavy metal of the antirust paint is too high, and the cost is high.
- the environmentally friendly multi-functional powder of the present invention has the following advantages and characteristics, so it can replace the current A variety of materials to become a new generation of building materials.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
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- Paints Or Removers (AREA)
Abstract
本发明公开了一种环保多效能粉料组成物及其制造方法，所述环保多效能粉料组成物由水泥、废弃电路板粉末、树脂、粉体涂装废料粉以及泥火山泥浆粉末混合构成。一种制造所述环保多效能粉料组成物的方法包含：回收废弃电路板，去除其表面零件后经切割、搅碎分离法手段而制成废弃电路板粉末；回收粉体涂装作业所产生的喷涂废料粉而制成粉体涂装废料粉；回收泥火山泥浆并施以粉碎、干燥手段而制成泥火山泥浆粉末；将该废弃电路板粉末、粉体涂装废料粉、泥火山泥浆粉末施以混合搅拌手段并加入水泥、树脂相混合均匀，即制得环保多效能粉料。本发明产品广泛适用于需要使用环保多效能粉料组成物的场合，并为生产者提供了较佳的生产方法。
Description
本发明涉及一种粉料的组成物及其制造方法，尤其是涉及一种包含水泥、废弃电路板粉末、树脂、粉体涂装废料粉及泥火山泥浆粉末所混合构成的环保粉料。
现今人类所造就的环境，高科技似乎也伴随着高污染，随着环境的日益恶化，环保意识抬头，各国进入减碳限制的世纪，人类文明将面临最大的道德挑战。
当人类享受舒适生活和科技文明时，却忽略了高科技化学产品已严重危害到地球生态，造成严重的环保问题。如何节省能源，且将资源环保再生循环利用，让高经济价值的资源垃圾能够达到减量化、安定化、无毒化，使废弃物能够化腐朽为神奇，转换成高性能的物质回收循环再利用，以降低对人类及环境冲击，已成为时代潮流，且对于可见的未来而言，势必将掀起一场绿色环保的大革命。
时代进步，科技发达加上经济脉动，信息一日千里，电子科技创新产物如计算机、家电、行动电话、工业仪器、自动化设备、交通、航空、太空...等等，整个广泛的发展与电子产品有密不可分的关系，因为电子产物中的印刷电路板，为电子组件互连最主要的支撑基板，且为功能特性不可或缺的重要载体，因此在不断创造与推陈出新的竞争产业行为下，印刷电路板产量如雨后春笋般的快速更新成长，由此可见其衍生而出的废弃物数量显然相当庞大。
人类大量抽取石油使用并提炼树脂所制造的产量庞大，不仅造成石油缺乏危机加速来临，且制造时瑕疵不良品及功能汰旧换新更产生许多废弃物，堆积如山的数量已难估计。若能有效处理电子废弃物回收再利用，将带来极大市场需求商机。电路板为环氧树脂、酚醛树脂、电木粉、耐火纤维与重金属及多种化学物品制成，具耐酸碱难以腐化分解特性，若使用掩埋法处理废弃电路板或将钻孔粉末乱倒至溪水、河川等地，有害物质将污染环境，对生态造成极大危害；若采用燃烧法处理，则必然造成空气污染，有毒气体将四处流窜而危害人体健康。
另外，时下众多产品制程中多采用粉体涂装加工法喷覆，由于涂装过程中，喷枪喷向静电产品的雾状树脂粉料并无法完全吸附于产品工件上，而未吸附的树脂粉料将飘落于涂装室底部形成粉末废料，这些废料均为树脂成份，其若当成废料处理，无论采用掩埋法或燃烧法均会产生污染，但目前并无将它回收再利用的管道及用途存在，如此实存在非常浪费资源的问题。
二氧化碳所产生的温室效应使地球表面温度逐年上升，各种天灾越来越频繁、火山爆发地震海啸机率也随着增加，冰山融化使海平面上升，都市将成为海中废墟，许多低洼或海岛国家将面临亡国。传染病肆虐及酸雨侵蚀，自然生态破坏等等，均危及人类及动植物生存，全球正面对极大考验，抗暖化就彷佛是人类的第三次世界大战，即将面临的一场空前浩劫。
人类因科技而伟大，却也因科技而面临危机，如何阻止浩劫发生以免为时已晚，已成为刻不容缓的重要课题，生活在地球村的每个人都应尽一份心力，建立一套绿色的能源结构体制，落实善用地球资源再生循环利用的概念，实施环保净能计划，让环境恢复洁净状态，促进人类健康，以降低日后对人类及环境的危害冲击，使青山常在、绿水常流，让地球得以永续经营下去，这将是人类重要使命。
针对上述问题，如何研发出一种能够充分将科技产业废料充份回收循环再利用的环保粉料，实有待相关业界须再努力加以思索突破的目标及方向。
有鉴于此，本发明人乃积极开发研究，并为改进上述不足，经过长久努力研究与实验，终于开发设计出本发明环保多效能粉料组成物及其制造方法。
本发明要解决的技术问题是提供一种多效能粉料组成物及其制造方法，能够解决现有废弃材料污染环境、现有技术无法充分将科技产业废料回收循环再利用的问题。
为达到上述目的，本发明采用的技术方案是：一种环保多效能粉料组成物，由水泥、废弃电路板粉末、树脂、粉体涂装废料粉以及泥火山泥浆粉末混合构成。
所述废弃电路板粉末中包含有酚醛树脂、环氧树脂、玻璃纤维以及铝金属。
以该多效能粉料组成物的总重量作为100％计算，则其中水泥、废弃电路板粉末、树脂、粉体涂装废料粉、泥火山泥浆粉末的其中任何一种在该多效能粉料组成物中的含量范围为10％至50％。
所述泥火山泥浆粉末的粒径介于100至500纳米之间。
一种制造环保多效能粉料组成物的方法，该制造方法包含：回收废弃电路板，去除其表面零件后经切割、搅碎分离法手段而制成该废弃电路板粉末；回收粉体涂装作业所产生的喷涂废料粉而制成该粉体涂装废料粉；回收泥火山泥浆并施以粉碎、干燥手段而制成该泥火山泥浆粉末；将该废弃电路板粉末、粉体涂装废料粉、泥火山泥浆粉末施以混合搅拌手段并加入该水泥、树脂相混合均匀，即制得该环保多效能粉料。
其中所述泥火山泥浆粉末于进行所述混合搅拌手段之前，可事先与该树脂相混合，可防止该泥火山粉泥浆末于储置过程中结块硬化。
采用上述方法制作的环保多效能粉料组成物，其具体应用上将可广泛用于建筑工程结构上作为一种涂料、填补材料或灌注材料及制造多种建材等，进而达到具有废物再利用的环保效益、成为一种创新具高物化性能的绝缘、隔热、保温、吸音、防水、防霉、防锈、防火、耐酸碱、抗紫外线、又能增加结构强度且耐老化、保湿减水、可催化膨胀、的环保节能健康涂料及复合板体结构建材、具有较佳产业经济效益等诸多优点。
所述环保多效能粉料组成物，包含水泥、废弃电路板粉末、树脂、粉体涂装废料粉以及泥火山泥浆粉末等混合构成。
其中，所述废弃电路板粉末中包含有酚醛树脂、环氧树脂、玻璃纤维以及铝金属。
其中，若以该多效能粉料组成物的总重量作为100％重量计算，则该其中水泥、废弃电路板粉末、树脂、粉体涂装废料粉、泥火山泥浆粉末其中任何一种在该多效能粉料组成物中的含量范围为10％至50％，使用时依据所需于该百分比内按比例调配即可。
其中，所述泥火山泥浆粉末的粒径介于100至500纳米(Nanometer，简称nm)之间。
本发明所述环保多效能粉料组成物，其制造方法包含：
(a)回收废弃电路板，去除其表面零件后经切割、搅碎采用比重分离法手段而制成该废弃电板粉末；
(b)回收粉体涂装作业所产生的喷涂废料粉而制成该粉体涂装废料粉；
(c)回收火山泥并施以粉碎、干燥手段而制成该泥火山泥浆粉末；
(d)将该废弃电路板粉末、粉体涂装废料粉、泥火山泥浆粉末施以一设定配比的混合搅拌手段并加入该水泥、树脂相混合均匀，即制得该环保多效能粉料。
其中，所述泥火山泥浆粉末于进行所述混合搅拌手段之前，可事先与粉体树脂相混合，或是与液态树脂相混合均匀后保存，如此即可免除干燥的制程，可防止该泥火山泥浆粉末于储置过程中结块硬化并降低生产成本。
所述环保多效能粉料具体应用上，可经由液态混溶方式而成为一种涂料，透过喷布或滚刷涂布的实施方式于建筑物或一建材(如板体、贴合布(皮)、块状复合材料等)表面，以达到具高物化性能的特性。
所述环保多效能粉料具体应用上，也可作为一填补材料，用以进行填补干燥后的水泥砂石间的空隙，使其成为一道接着性优良、结构强韧且具高密实性、耐酸碱性及具抗菌性、绝缘隔热保温节能的优质防护墙结构
所述环保多效能粉料具体应用上，也可经由液态混溶方式而作为一种灌注成型材料使用，可预设一模具(或夹层空间)，再将该混溶成液态的环保多效能粉料注入该模具(或夹层空间)中，待该环保多效能粉料干涸后予以脱模，可成型一块体、柱体、管体、板体、浪板、屋瓦等立体结构；除此，所述环保多效能粉料也可透过浸渍手段与竹席、麻绳布网、玻璃纤维布网、椰丝棕、稻草、不织布等相结合，经透过热压或滚压、烘干等手段成型一板材以增加挠性，且此等板材还可因为其结构隙缝部位而具有采光效果，可提供一种环保创新复合式采光、隔热保温节能省电的高性能浪板或各种形状板体结构的绿色建材。
除上述应用实施态样之外，本发明所述环保多效能粉料也可取代目前的金属浪板、屋瓦、石材、木材、陶瓷、塑料板(皮)、混泥土、保丽龙、PS板、PV、PE等发泡材料、传统保护性涂料等，设制成仿石材、仿木材、仿陶瓷等外观表面态样，以改善现有材料的缺点，如金属浪板的缺点在于薄不耐重压、大雨敲击产生噪音、不耐酸碱易生锈漏水、热传导性高、雷击危险、隔热保温性能差、老化变形、尖锐伤人等。如石材的缺点在于笨重、运输成本高、施工不易、高热传导性、隔热保温性能差、防水性不良吸水易变色、火灾时会爆裂、地震掉落危险等。木材的缺点在于砍伐树木将危害地球、且怕水、怕火、怕白蚁以及制作时往往加入甲醛对人体会导致癌症危害身体健康等。陶瓷的缺点在于工程施作费工、高热传导隔热保温性能差、不耐重压碰撞、地震掉落危险、磁缝藏污漏水等。塑料材料的缺点在于不环保、不耐火、不耐重压易变形等。传统保护性涂料的缺点则在于有溶剂与甲醛不环保、防锈漆重金属比例过高、成本贵的问题，而本发明所述环保多效能粉料由于具备下述优点及特性，故可取代目前多种材料而成为新世代的建材。
Claims (5)
- 一种多效能粉料组成物，其特征在于：所述多效能粉料组成物 包含水泥、废弃电路板粉末、树脂、粉体涂装废料粉以及泥火山泥浆粉末混合 构成； 以该多效能粉料组成物的总重量作为100％计算，则其中水泥、废弃电路板粉 末、树脂、粉体涂装废料粉、泥火山泥浆粉末的任何一种在该多效能粉料组成物中的含量范围为10％至50％。
- 根据权利要求1所述的多效能粉料组成物，其特征在于：所述废弃电路板粉 末中包含有酚醛树脂、环氧树脂、玻璃纤维以及铝金属。
- 根据权利要求1所述的多效能粉料组成物，其特征在于：所述泥火山泥浆粉 末的粒径介于100至500纳米之间。
- 一种制造权利要求1-3任一项所述的多效能粉料组成物的方法，其特征在 于：所述制造方法包含： 回收废弃电路板，去除其表面零件后经切割、搅碎分离法手段而制成该废弃 电路板粉末； 回收粉体涂装作业所产生的喷涂废料粉而制成该粉体涂装废料粉； 回收泥火山泥浆并施以粉碎、干燥手段而制成该泥火山泥浆粉末； 将该废弃电路板粉末、粉体涂装废料粉、泥火山泥浆粉末施以混合搅拌手段并 加入该水泥、树脂相混合均匀，即制得该多效能粉料组成物。
- 根据权利要求4所述的制造多效能粉料组成物的方法，其特征在于 ：其中所述泥火山泥浆粉末于进行所述混合搅拌手段之前，可事先与该树脂相 混合，可防止该泥火山粉泥浆末于储置过程中结块硬化。
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