WO2015017985A1 - Coating composition for metal surface pre-treatment, its preparation and use thereof - Google Patents

Coating composition for metal surface pre-treatment, its preparation and use thereof Download PDF

Info

Publication number
WO2015017985A1
WO2015017985A1 PCT/CN2013/080922 CN2013080922W WO2015017985A1 WO 2015017985 A1 WO2015017985 A1 WO 2015017985A1 CN 2013080922 W CN2013080922 W CN 2013080922W WO 2015017985 A1 WO2015017985 A1 WO 2015017985A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating composition
functional
silane
composition according
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2013/080922
Other languages
French (fr)
Inventor
Xueting Qiu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel China Co Ltd
Original Assignee
Henkel China Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA2919806A priority Critical patent/CA2919806C/en
Priority to PCT/CN2013/080922 priority patent/WO2015017985A1/en
Priority to ES13890875T priority patent/ES2703333T3/en
Priority to BR112016002168-1A priority patent/BR112016002168B1/en
Priority to CN201380078851.1A priority patent/CN105874029B/en
Priority to PL13890875T priority patent/PL3030623T3/en
Application filed by Henkel China Co Ltd filed Critical Henkel China Co Ltd
Priority to JP2016532176A priority patent/JP6318248B2/en
Priority to EP13890875.1A priority patent/EP3030623B1/en
Publication of WO2015017985A1 publication Critical patent/WO2015017985A1/en
Priority to US15/012,905 priority patent/US12054567B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086—Organic or non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/122—Inorganic polymers, e.g. silanes, polysilazanes, polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1229—Composition of the substrate
    • C23C18/1241—Metallic substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1291—Process of deposition of the inorganic material by heating of the substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1295—Process of deposition of the inorganic material with after-treatment of the deposited inorganic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C23C18/1637—Composition of the substrate metallic substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/42—Coating with noble metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/58—Metal-containing linkages
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes

Definitions

  • Hexavalent chromium-containing compounds are conventional corrosion inhibitors for metal surface treatment which exhibit far better corrosion resistance than any other inhibitors.
  • chromates are environmentally unfriendly and hazardous. More and more strict environmental regulations will ban the use of Cr 6+ -containing compounds in corrosion resistance systems. The need for development of non- Cr 6+ environmental-friendly surface treatments is urgent.
  • sol-gel derived thin films prospective candidates for substitution of the chromate pretreatments i.e. sol-gel derived thin films.
  • the sol-gel process is mainly based on hydrolysis and
  • the hybrids of the first class there exists no chemical bonds between inorganic and organic phases but only the Van de Waals force is present.
  • the synthesis of the first class of hybrids can be preformed by mixing an inorganic sol with an organic phase and carrying out the sol hydrolysis and condensation reactions in the presence of a preformed organic polymer.
  • the precursors with already covalent or complex bonded organic groups are used for further synthesis of the hybrid sol-gel system.
  • the commonly used sol-gel precursors are commercially available organoalkoxysilanes and metal alkoxides.
  • organosilane in the context of this invention is to define any organic derivative of a silane wherein at least one carbon atom is covalently bound to the silicon atom of the silane. According to this invention, the group providing the Si-C bond is considered to be a non-hydrolyzable substituent.
  • the said organosilane is selected from a compound according to the following general structure (I)
  • weight-average molecular weight (weight average molecular weight Mw, as
  • water-free refers to the condition that the content of water is no more than 200 ppm.
  • the said (meth)acrylate are preferably selected from methyl methacrylate, butyl methacrylate, ethyl hexyl acrylate.
  • the amount of the water-soluble compound of the elements Zr and/or Ti in the overall composition is from 0.1 wt.-% to 5wt.-%, preferably from 0.2wt.-% to 2wt.-% with respect to the elements Zr and Ti.
  • ⁇ pH value regulator 0.1 wt.-% to 5wt.-%, preferably from 0.2wt.-% to 2wt.-% with respect to the elements Zr and Ti.
  • the pH value of the composition is acidic.
  • the most preferred pH value lies within the range of 3 to 6.
  • pH value regulators might be added. The person skilled in the art knows that these types of pH value regulator immediatelely react through dissociation and are as such not detectable in the composition.
  • it is selected from acetic acid and phosphonic acids.
  • the total amount by weight of these components adds to 100wt.-%.
  • the organosilane as well as the silane functional oligomer hydrolyzes in water and manifold condensation reactions may occur at a pH value of about 3-6.
  • the resultant aqueous coating composition can be applied on metal surfaces with conventional means like dipping, spraying, electroplating etc.
  • the process of electroless metal surface treatment preferably comprises the following subsequent steps (1 )-(6):
  • the temperature is preferably at least 70°C, but not more than 240°C, preferably not more than 150°C.' .
  • Hexandiol is purchased from BASF Chemical
  • Polvurethane is purchased from Dainippon Ink and Chemicals (product code: DIC -8125)
  • Polyester diol is purchased from Henkel (product code: K-3320)
  • Polyethylene glycol (number average molecular weight 300) is purchased from Dow
  • Polyethylene glycol (number average molecular weight 600) is purchased from Dow Chemical
  • Acrylic hybrid compound is purchased from Henkel (product code: AR/ST 100-080)
  • Epoxy resin is purchased from Dow Chemical (product code: DER 661 )
  • 1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 , 2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12 g resultant solution from the first step is dispersible into 596 g water mixture, which contains 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane , 3wt.-%
  • Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours. Pour above mixture into 31 Og Dl water containing 2g acetic acid and keep stirring for 30 minutes.
  • 224g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 , 2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • the second step preparation of the coating composition
  • 1 12g resultant solution from the first ste is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
  • 1 12g above solution solution is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-%
  • compositions obtained from examples 1 to 10 and comparative example are tested to evaluate their performance of anti-corrosion, surface conductivity, humidity resistance, paintability, solvent resistance after coating onto metal substrates as well as the shelf life of the composition product.
  • the salt spray lasts for 96 hours and it is accepted if the rust ratio of the coated substrate is ⁇ 5wt.-%.
  • the salt spray lasts for 72 hours and further includes steps of alkaline cleaning with Parker FC-364S cleaner at 50 ° C for 2minute and spraying Parker FC-364S cleaner at 50 ° C for 3minute. It is accepted if the rust ratio of the coated substrate is ⁇ 5wt.-%.
  • Test (3) the salt spray lasts for 48 hour after 6-8mm Erichson Cupping and it is accepted if the rust ratio of the coated substrate is ⁇ 5wt.-%.
  • Conductivity resistance is test by Loresta MP-T 360 instrument.
  • paint (1 ) is powder paint (Akzo EA05BH) and the dried film has thickness of 40 ⁇ to 60 ⁇ . And the cross-hatch is done with 100 grids of size 1 mmx1 mm. It is acceptable if no film removed by tape peeling.
  • paint (2) is solvent borne paint (amino alkyd paint) and the dried film has thickness of around 20 ⁇ . And a revere impact with energy of 5 J is bought to bear. It is acceptable if no film crack occurs after impact.
  • paint (3) is coil coating paint (polyester) and the dried film has thickness of around 20 ⁇ . And the 6mm Erichson cupping is added to the cross-hatch with 100 grids of size 1 mmx1 mm. It is acceptable if no film is removed by tape peeling.
  • shelf life denotes the length of time that a commodity may be stored without becoming unfit for use or consumption.
  • the shelf life is tested by two ways.
  • the first is to prepare samples and let it age in a hot box with temperature of 40°C for one month.
  • the shelf life is at least one month at 40 °C if the performance does not turn worse in either one of corrosion resistance, surface conductivity, paintability, solvent resistance, humidity resistance.
  • the second is to prepare samples and let it age in a hot box with temperature of room temperature for three months.
  • the shelf life is at least three months at room temperature if the performance does not turn worse in either one of corrosion resistance, surface conductivity, paintability, solvent resistance, humidity resistance.
  • Example 1 -10 After preparing the said coating composition according to weight ratio and method described in Example 1 -10 as well as in Comparative Example, it is used to treat the hot dip galvanized steel following the common-used way, i.e.
  • Table 3 shows result of re-test the properties including corrosionresistance, surface conductivity, paintability, humidity resistance and solvent resistance after the samples are kept in hot box with temperature of 40°C for one month.
  • the contrast of performance of each example shows shelf life, i.e. the stability of product.
  • the coating composition in this invention provide good performances on corrosion resistance, surface conductivity, paintability, humidity and solvent resistance and also reveal a suitable long shelf life.
  • the comparative example wherein no water-dispersible silane functional oligomers are used, shows obvious weakness in corrosion resistance , paintability as well as with respect to the stability of the product.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

This invention provided an aqueous coating composition for metal surface pre-treatment comprising: (i) at least one organosilane with at least one hydrolyzable substituent; (ii) at least one water soluble and/or water dispersible silane-functional oligomer; (iii) at least one water-soluble compound of the elements Zr and/or Ti; The resultant sol-gel coating composition reveals an extended shelf life and after surface pre-treatment using the invented coating compositions the metal substrates have higher resistance to corrosion, humidity and solvent and at the same time have better surface conductivity and paintability.

Description

Coating composition for metal surface pre-treatment, its
preparation and use thereof
BACKGROUND OF THE INVENTION
Field of the Invention
This invention relates to a coating composition for metal surface pre-treatment, its preparation and use thereof. Statement of Related Art
Hexavalent chromium-containing compounds are conventional corrosion inhibitors for metal surface treatment which exhibit far better corrosion resistance than any other inhibitors. However, chromates are environmentally unfriendly and hazardous. More and more strict environmental regulations will ban the use of Cr6+-containing compounds in corrosion resistance systems. The need for development of non- Cr6+ environmental-friendly surface treatments is urgent.
M.L.Zheludkevin et. al. (J. Master. Chem., 2005, 15, 5099-5111 ) suggested
prospective candidates for substitution of the chromate pretreatments i.e. sol-gel derived thin films. The sol-gel process is mainly based on hydrolysis and
condensation reactions of metal alkoxides. Silicon-organic based sol-gel chemistry is more developed compared with other metal-organic based precursors. There are several types of protective sol-gel coatings including inorganic sol-gel coatings, hybrid sol-gel derived coatings, nano-structured sol-gel coatings etc. Hybrid films are very promising materials as they combine properties of a polymeric organic and a ceramic material. The inorganic component may contribute to the increase of scratch resistance, durability and adhesion to the metal substrate while the organic component increases density, flexibility, and functional compatibility with organic paint systems. Furthermore, the sol-gel derived hybrids can be classified into two different classes, depending on the nature of interfaces between organic and inorganic phases. In the hybrids of the first class there exists no chemical bonds between inorganic and organic phases but only the Van de Waals force is present. The synthesis of the first class of hybrids can be preformed by mixing an inorganic sol with an organic phase and carrying out the sol hydrolysis and condensation reactions in the presence of a preformed organic polymer. In the hybrids of the second class the precursors with already covalent or complex bonded organic groups are used for further synthesis of the hybrid sol-gel system. The commonly used sol-gel precursors are commercially available organoalkoxysilanes and metal alkoxides.
Patent publication CN101760736A discloses an aqueous non-Cr6+ coating for surface treatment of Zn-galvanized steel comprising a silane, a water-dispersed polymer as well as an acid and water. In its coating system, the polymer has no chemical bonds to silane and therefore the inorganic part and organic part is only physically mixed.
Another patent publication EP2223975A1 discloses another kind of aqueous non-Cr6+ coating for surface treatment of Zn or Zn alloy which provides an anti-corrosion, homogeneous film with barrier properties. To reach its goal, EP2223975A1 teaches the use of M2O-nSiO2 (M: alkali metals; n: the molar ratio of SiO2 M2O) in combination with a water-soluble or water-dispersible silane coupling agent and a water-soluble or water-dispersible glycldyl ether. But within such a mixture it cannot be ensured that the interfaces between organic and inorganic phases are small enough, which is expected to bring good performances in various aspects like corrosion resistance, humidity resistance, solvent resistance, surface conductivity, paintability as well as shelf life of coating.
DESCRIPTION OF THE INVENTION
Object of the Invention
This invention is aimed to provide an aqueous non-Cr6+ coating composition for metal surface pre-treatment which is environmentally friendly and at the same time has longer shelf life compared with present similar products, and, moreover, after treatment by the invented coating, the metal substrates should have improved performance with respect to resistance of corrosion, humidity and solvents as well as to paintability. A coating of this invention shall be especially suitable for galvanized steel,
Detailing Description of the Invention
The object is solved by providing an aqueous coating composition for metal surface pre-treatment having a pH in the range of from 3 to 6 comprising:
(i) at least one organosilane with at least one hydrolyzable substituent;
(ii) at least one water soluble and/or water dispersible silane-functional oligomer;
(iii) at least one water-soluble compound of the elements Zr and/or Ti.
The chain of -O-Si-O- can improve the oxidation and acidic corrosion resistance of metals under different temperatures due to its high heat resistance and chemical resistance. And the organic group linked to Si atom helps organosilane consistent with silane-functional oligomer.
To overcome the limitation of pure inorganic coatings such as brittleness and high temperature treatment, the organic component is introduced into the inorganic coatings to form an organic-inorganic hybrid coating .In addition, the organic-inorganic hybrid coatings accessible through compositions of this invention reveal very good adhesion to subsequent organic coatings which cannot be attained through compositions that only comprise the organosilane.
The obtained hybrid coatings can easily form a thicker coat in micrometer scale without cracks and much lower curing temperature is needed for sintering of oxide layers. And moreover, the hybrid sol-gel system has much more flexibility in adaptation of anti-corrosion additives such as inhibitors, pigments etc. so the overall corrosion resistance ability of the sol-gel system can be substantially improved.
The resulting aqueous solution or dispersion makes the resultant coating film well-proportioned and have better performances on resistance against corrosion, humidity and organic solvents, and the surface conductivity is increased which is beneficial for optional electro-coating and also for electrostatic discharge and furthermore the paintability is also improved
For each component of compositions of this invention including indispensable and optional ones, below follows more detailed description.
<Organosilane>
The term "organosilane" in the context of this invention is to define any organic derivative of a silane wherein at least one carbon atom is covalently bound to the silicon atom of the silane. According to this invention, the group providing the Si-C bond is considered to be a non-hydrolyzable substituent.
Furthermore, said organosilane component according to this invention has a molecular weight of less than 400g/mol.
According to the invention, the coating composition comprises at least one organosilane. And the said one organosilane preferably comprises at least one non-hydrolyzable substituent selected from amino-functional, vinyl-functional, epoxy-functional and hydroxyl-functional groups. These functional groups may improve the compatibility of the organic-inorganic hybrid coating provided by compositions of this invention with subsequent organic paints.
More preferably, the said organosilane is selected from a compound according to the following general structure (I)
Figure imgf000006_0001
(I)
n is from 1 to 3;residue R is selected from C1 to C6 and preferably C1 to C3 alkyl groups; residue Y is selected from alkyl groups with not more than 10 carbon atoms carrying at least one epoxy, amino, hydroxyl, vinyl and/or thiol group wherein the residues Y are selected mutually independent from each other.
In an especially preferred embodiment the composition of this invention comprises organosilanes that are selected from from vinyltriacetoxysilane, vinyltnalkoxysilanes, aminoethyltrialkoxysilanes, aminopropylalkoxysilanes, bis-trialkoxysilypropylamines, aminoethylaminopropyltrialkoxysilanes, aminoethylaminopropyltrialkoxysilanes, mercaptopropyltrialkoxysilanes, bis-trialkoxysilylpropyl-tetrasulfide,
3-glycidoxypropyltrialkoxysilanes, wherein the alkoxy groups have not more than 3 carbon atoms.
<Water soluble and/or water dispersible silane-functional oligomer>
The term "water soluble and/or water dispersible" is to define a physical status that the solute is dissolved in water or is evenly distributed in the water phase in the form of small particles with an average particle diameter of less than 10 μιτι. The average particle diameter herein is to be determined from cumulative frequency distribution curves derived from dynamic light scattering methods and equals the D50 value at which 50 Vol.wt.-% of the particles have a diameter smaller than the respective value.
The term "silane-functional oligomer" is to further define a compound that is the resultant product from polymerization or condensation reaction having a
weight-average molecular weight (weight average molecular weight Mw, as
determined by GPC) of at least 400 g/mol and less than 10,000 g/mol while the resultant product comprises terminal silyl groups.
Within the aqueous composition of this invention the silane-functional oligomers may undergo manifold hydrolyzation and/or condensation reactions in the presence of water and the other mandatory components.
Due to their synthesis the oligomers reveal a backbone that is constituted by multiple repeating units. In this respect, the said backbone of a silane-functional oligomer according to the underlying invention is preferably selected from poly-urethanes, poly-acrylates, poly-esters and/or poly-ethers.
The said water soluble and/or water dispersible silane-functional poly-urethane is preferably obtained through the reaction of at least one diisocyanate, at least one hydroxyl-functional tertiary amine, at least one amino-functional organosilane and at least one polyol selected from alkane diols, polyether diols, polyester diol and polycarbonate diols. The silane functional poly-urethanes preferably have a molecular weight of 400 to 4000 g/mol.
The hydroxyl-functional tertiary amine is preferably selected from compounds according to the general formula (Ri)2N(OH)R2, with R-i as C1 ~C6 linear or branched alkyl group, R2 as C1 -C12 linear or branched alkyl group.
The amino-functional organosilanes for the reaction to constitute the silane-functional poly-urethane are preferably selected from vinyltriacetoxysilane, vinyltrialkoxysilanes, aminoethyltrialkoxysilanes, aminopropylalkoxysilanes, bis-trialkoxysilypropylamines, aminoethylaminopropyltrialkoxysilanes, aminoethylaminopropyltrialkoxysilanes, mercaptopropyltrialkoxysilanes, bis-trialkoxysilylpropyl-tetrasulfides,
3-glycidoxypropyltrialkoxysilanes, wherein the alkoxy groups have not more than 3 carbon atoms. The water-dispersible silane functional polyurethane is preferably synthesized through a process comprising at least the following two steps:
i) hydroxyl-functional tertiary amines, amino-functional organosilanes and polyols are pre-mixed under water-free conditions, and
ii) the diisocyanates are added dropwise to this pre-mixture while the temperature is kept in a range of from 60°C~90°C.
The term "water-free" mentioned in this context refers to the condition that the content of water is no more than 200 ppm. As a preferred example to prepare the water-dispersible silane functional
polyurethane, all components for the synthesis are mixed according to the following weight percentages:
5wt.-% to 60wt.-% diisocyanates
1wt.-% to 20wt.-% hydroxyl-functional tertiary amine
1wt.-% to 20wt.-% amino silanes
5wt.-% to 40wt.-% one or more selected from polyols
0wt.-% to 20wt.-% auxiliary compounds
The total amount of these components for synthesis of the said silane functional polyurethane oligomer is set as 100wt.-%.
The molar ratio of -NCO group to -OH group in the mixture of components is preferably above 1 , but preferably no more than 2.5.
The said water soluble and/or water dispersible silane-functional poly-acrylates are preferably obtained through the reaction of at least one (meth)acrylate,
vinyl-functional silane, and acrylates having a tert-amino substituent.
The said (meth)acrylate are preferably selected from methyl methacrylate, butyl methacrylate, ethyl hexyl acrylate.
The said vinyl-functional silane is preferably selected from vinyltriethoxy silane, vinyltrimethoxy silane.
The said acrylates having a tert-amino substituent are preferably selected from 2-(diethylamino)ethyl methacrylate.
The silane functional poly-acrylates preferably has a molecular weight of 1000 to 8000 g/mol.
Conventional means known to the skilled person can be applied to initiate the polymerization reaction based on acrylates.
The said water soluble and/or water dispersible silane-functional epoxy resin is preferably obtained through the reaction of at least one epoxy resin, at least one amino-functional organosilane, and a multifunctional compound having at least two hydroxyl and/or amino groups. The silane functional epoxy resin preferably has a molecular weight of 400 to 2000 g/mol.
To prepare it, it is preferred to dissolve the epoxy resin within an inert solvent at elevated temperature and then add the mixture of amino silanes and hydroxyl amines. The mixture is maintained until the reaction has finished. The resulting product can be stored under non humid conditions.
The molar ratio of -NH2 groups to epoxy groups within the mixture preferably ranges from 0.25 to 2.2.
Most preferably, the epoxy resin is selected from bisphenol A type with a number average molecular weight of less than 2000.
< Water-soluble compound of elements Zr and/or Ti>
One or more selected from fluorozirconate acid, fluorotitanic acid, zirconium acetate complex and titanium acetate complex could be used as the metallic chelated compound. Preferably, the water-soluble compound of elements Zr and/or Ti is selected from H2TiF6, H2ZrF6, Zr(OCOCH3)4 and Ti(OCOCH3)4.
The molar ratio of element Si to the sum of the elements Zr and/or Ti is from 10 to 500, preferably from 40 to 100.
The amount of the water-soluble compound of the elements Zr and/or Ti in the overall composition is from 0.1 wt.-% to 5wt.-%, preferably from 0.2wt.-% to 2wt.-% with respect to the elements Zr and Ti. <pH value regulator
The pH value of the composition is acidic. The most preferred pH value lies within the range of 3 to 6. To adjust the pH value of the composition of this invention, pH value regulators might be added. The person skilled in the art knows that these types of pH value regulator immediatelely react through dissociation and are as such not detectable in the composition.
Preferably, it is selected from acetic acid and phosphonic acids.
<Optional water soluble and/or water dispersible resin>
Optionally, water soluble and/or water dispersible resins are added to provide toughness as organic part of the coating without chemical binding to any inorganic part. The commonly used hydrophilic resin in aqueous coating could be selected in this invention. Preferably, it is selected from polyurethane, polyurethane dispersion and acrylic hybrid.
<Additives>
Furthermore, common coating additives may be selected in this invention to confer desired additional properties. Such additives may be selected from de-foaming agents, such as non-ionic surfactants, leveling agents to yield a defect-free coating film, and anti-friction agents, such as waxes. These type of agents are commonly known to the skilled person. In a preferred embodiment the weight fraction of these types of agents with respect to the water soluble and/or water-dispersible silane-functional oligomer should not exceed 10wt.-%.
<Coating composition
In a coating composition of this invention the above-mentioned components are preferably present in the following weight percentages
5wt.-% to 30wt.-% organosilane with at least one hydrolyzable substituent; 5wt.-% to30wt.-% water soluble and/or water-dispersible silane-functional oligomer;
0.5wt.-% to 10wt.-% water soluble compound of elements Zr and/or Ti;
1wt.-% to 5wt.-% pH value regulator;
0wt.-% to 20wt.-% water soluble and/or water-dispersible resin;
0wt.-% to 5wt.-% additives
The total amount by weight of these components adds to 100wt.-%.
< Preparation of Coating composition>
The organosilane as well as the silane functional oligomer hydrolyzes in water and manifold condensation reactions may occur at a pH value of about 3-6.
In a preferred embodiment of this invention, the coating composition is obtainable through the following process: the organosilane is dissolved in acidic water and the pH value is thereafter adjusted to about 3 to 6 by a pH value regulator. In this solution the acidified silane functional oligomer is dispersed or dissolved. The other
components and additives can be dispersed or dissolved in the solution mixture either before or after the dispersion or dissolving of the silane containing agents. <Process of electroless metal surface treatment
The resultant aqueous coating composition can be applied on metal surfaces with conventional means like dipping, spraying, electroplating etc.
Preferably, the said coating composition in this invention is applicable for metal substrates of hot dip galvanized steel, electrolytically galvanized steel, steel, iron, zinc, aluminum and aluminum alloys.
The process of electroless metal surface treatment preferably comprises the following subsequent steps (1 )-(6):
(1 ) degreasing the metal surface;
(2) rinsing with water;
(3) drying the metal surface; (4) pre-treatment the metal surface with a coating composition of this invention;
(5) curing the applied coating composition;
(6) subsequent application of an organic paint.
wherein, during the step (5), the temperature is preferably at least 70°C, but not more than 240°C, preferably not more than 150°C.' .
<Coating film of pre-treatment on metal surface>
The coating weight of the primer coating applied through the above-described process of this invention is preferably at least 0.3 g/m2, preferably at least 0.7 g/m2, but preferably no more than 1 .5 g/m2 based on the overall coating weight.
Description of Embodiment
Below examples are used to further illustrate the preparation of coating compositions of this invention as well as their performance as a primer coating for a subsequently applied cathodic electrodipcoating.
All raw materials used in below examples could be commercially purchased.
Here lists the provider of each raw material.
All silane compounds used in examples are purchased from Dow Corning
Hexandiol is purchased from BASF Chemical
Polvurethane is purchased from Dainippon Ink and Chemicals (product code: DIC -8125)
Polyester diol is purchased from Henkel (product code: K-3320)
Polyethylene glycol (number average molecular weight 300) is purchased from Dow
Chemical
Polyethylene glycol (number average molecular weight 600) is purchased from Dow Chemical
Acrylic hybrid compound is purchased from Henkel (product code: AR/ST 100-080) Epoxy resin is purchased from Dow Chemical (product code: DER 661 )
All other raw materials are purchased from Aladin Chemical Example
Within the following examples all percentages of the components refer to weight percentages.
Example 1
♦ The first step (Preparation of the silane-functional oligomer)
13.5g 1 ,6-Hexandiol,
2.5g Dimethyl ethanol amine,
9.1 g Aminoethyltrimethoxysilane,
18.5g 1 -Methyl-2-pyrrolidone
Heat the above mixture to 75°C and gradually add 39.3g methylene
Bis-(4-cyclohexylisocyanate) and maintained at 70 °C to 80°C for 2 hours.
Pour above mixture into 100g Dl water containing 5g acetic acid and keep stirring for 30 minutes. The pH value is adjusted to around 6.0
♦ The second step (Preparation of the coating composition)
1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 5.0 with acetic acid and keep mixing for 3-12 hours. Then add 6wt.-% polyurethane.
Example 2
♦ The first step (Preparation of the silane-functional oligomer)
140.3g Polyester diol
19.7 g Dimethyl ethanol amine
12.0g Aminoethyltrimethoxysilane
44.0g 1 -Methyl-2-pyrrolidone
Heat the above mixture to 75°C and gradually add 78.6g methylene Bis-(4-cyclohexylisocyanate) and keep at 70°C to 80°C for 2 hours.
Pour above mixture into 350g Dl water containing 8.1 g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value around 5.0 with acetic acid and keep mixing for 3 to 12 hours. Then add 6wt.-% polyurethane.
Example 3
♦ The first step (Preparation of the silane-functional oligomer)
30g Polyethylene glycol (PEG 300)
49.8g Polyester diol
18.1 g Aminoethyltrimethoxysilane
37. Og 1 -Methyl-2-pyrrolidone
Heat the above mixture to 75°C and gradually add 78.6g methylene
Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours.
Pour above mixture into 31 Og Dl water containing 2g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
1 12 g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 , 2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6. Adjust the pH value to around 3.0 with phosphonic acid. Keep mixing for 3 to 12 hours. Then add 6wt.-% polyurethane.
Example 4
♦ The first step (Preparation of the silane-functional oligomer)
30 g Polyethylene glycol (PEG 600 )
5.9g 1 ,6-hexandiol,
8.1 g Aminoethyltrimethoxysilane,
37.0g Ethylene glycol di-methylether
Heat the above mixture to 75°C and gradually add 78.6g n-methyl methylene Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours.
Pour above mixture into 31 Og Dl water containing 2g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
1 12 g resultant solution from the first step is dispersible into 596 g water mixture, which contains 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane , 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6. Adjust the pH value to around 4.0 with acetic acid. Keep mixing for 3 to 12 hours. Then add 6wt.-% polyurethane.
Example 5
♦ The first step (Preparation of the silane-functional oligomer)
30g Polyethylene glycol (PEG 300),
49.8g Polyester diol
18.1 g Aminoethyltrimethoxysilane
37. Og 1 -Methyl-2-pyrrolidone
Heat the above mixture to 75°C. and gradually add 78.6g methylene
Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours. Pour above mixture into 31 Og Dl water containing 2g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
224g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 4.5 with acetic acid. Keep mixing for 3 to 12 hours. Then add 12wt.-% polyurethane.
Example 6
♦ The first step (Preparation of the silane-functional oligomer)
140.3g Polyester diol
19.7g Dimethyl ethanol amine
12.0g Aminoethyltrimethoxysilane
44. Og 1 -Methyl-2-pyrrolidone
Heat the above mixture to 75°C and gradually add 78.6g methylene
Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours.
Pour above mixture into 350g Dl water containing 8.1 g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 , 2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 3.5 with phosphonic acid. Keep mixing for 3 to 12 hours. Then add 4wt.-% polyurethane.
Example 7
♦ The first step (Preparation of the silane-functional oligomer)
140.3g Polyester diol
19.7g Dimethyl ethanol amine
12.0g aminoethyltrimethoxysilane
44. Og 1 -Methyl-2-pyrrolidone
Put all above components into a flask and heat the mixture to 75°C and then gradually add 78.6g methylene Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours.
Pour above mixture into 350g Dl water containing 8.1 g acetic acid and keep stirring for 30 minutes.
♦ The second step (Preparation of the coating composition)
1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 3.5 with acetic acid. Keep mixing for 3 to 12 hours. Then add 12wt.-% polyurethane.
Example 8
♦ The first step (Preparation of the silane-functional oligomer)
140.3g Polyester diol
19.7 g Dimethyl ethanol amine
12.0g aminoethyltrimethoxysilane,
44. Og 1 -Methyl-2-pyrrolidone
Put all above components into a flask and heat the mixture to 75°C and then gradually add 78.6g methylene Bis-(4-cyclohexylisocyanate) and keep at 70 °C to 80°C for 2 hours.
Pour above mixture into 350g Dl water containing 8.1 g acetic acid and keep stirring for 30 minutes.
The second step (Preparation of the coating composition)
1 12g resultant solution from the first ste is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltriethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 5.0 with phosphonic acid. Keep mixing for 3 to 12 hours. Then add 8wt.-% Polyurethane and acrylic hybrid compound. Example 9
♦ The first step (Preparation of the silane-functional oligomer)
Heat the flask containing 200g diethylene glycol methylether to 130°C and use N2 to purge the flask.
Then mix
20g Methyl methacrylate
30g 3-(ethyl,hexyl) acrylate
40g butyl acrylate
40g styrene
10g vinyl triethoxy silane
15g 2-(Diethylamino)ethyl methacrylate
0.5g Ethanethiol
3.5g di-tert. butyl peroxide
in a separated container.
Gradually meter the mixture into flask over 3 hours. Keep furthermore 1 hour at 130°C until the feed is complete. Cool the flask to 80°C and disperse the product into 500g Dl water containing 6.5g acetic acid.
♦ The second step (Preparation of the coating composition)
1 12g resultant solution from the first step is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-% Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-%
3-glycidyloxypropyltriethoxysilane,1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 4.0 with acetic acid. Keep mixing for 3 to 12 hours. Then add 6wt.-% polyurethane.
Example 10
♦ The first step (Preparation of the silane-functional oligomer)
Heat the flask containing 50g epoxy resin DER 661 and 30g diethylene glycol methylether to 60°C until DER 661 is dissolved or melted. Then add 19g aminoethyltnethoxysilane and 10g poly (5) oxyethylene tallow amine into the flask and keep the reaction for 1 more hour at 60°C. Disperse above mixture into 180g Dl water containing 6.0g acetic acid.
♦ The second step (Preparation of the coating composition)
1 12g above solution solution is dispersible into 596 g water mixture containing 1 .8wt.-% tetraethyl orthosilicate, 3wt.-% aminoethyltnethoxysilane, 1wt.-%
Bis-1 ,2-(triethoxysilyl) ethane, 3wt.-% 3-glycidyloxypropyltriethoxysilane, 1wt.-% vinyl triethoxyl silane and 1 .6wt.-% H2ZrF6.
Adjust the pH value to around 4.0 with acetic acid. Keep mixing for 3 to 12 hour. Then add 6wt.-% polyurethane.
Comparative Example
1 .8 wt.-% tetraethyl orthosilicate,
3wt.-% aminoethyltnethoxysilane, 1 wt.-% Bis-1 ,2-(triethoxysilyl) ethane
3wt.-% 3-glycidyloxypropyltriethoxysilane
1 wt.-% vinyl triethoxyl silane
1 .6wt.-% H2ZrF6 was added into 585g Dl water.
Adjust the pH value to 4.0 with acetic acid. Keep mixing for 3 to 12 hours and then add 8 wt.-% polyurethane.
< Method of Test>
The compositions obtained from examples 1 to 10 and comparative example are tested to evaluate their performance of anti-corrosion, surface conductivity, humidity resistance, paintability, solvent resistance after coating onto metal substrates as well as the shelf life of the composition product.
Corrosion Resistance
Three tests are carried out to evaluate the performance of corrosion resistance of the invented composition according to ASTM B1 17 (Standard Practice for Operating Salt Spray (Fog) Apparatus).
In Test (1 ), the salt spray lasts for 96 hours and it is accepted if the rust ratio of the coated substrate is < 5wt.-%.
In Test (2), the salt spray lasts for 72 hours and further includes steps of alkaline cleaning with Parker FC-364S cleaner at 50°C for 2minute and spraying Parker FC-364S cleaner at 50°C for 3minute. It is accepted if the rust ratio of the coated substrate is < 5wt.-%.
In Test (3), the salt spray lasts for 48 hour after 6-8mm Erichson Cupping and it is accepted if the rust ratio of the coated substrate is < 5wt.-%.
Surface conductivity
Conductivity resistance is test by Loresta MP-T 360 instrument.
16 spots on a 300*300mm panels coated according to the examples were measured. Tables show the number of spots that reveal a surface resistance of not more than 1 ηπΩ. Coated panels with more than 13 spots having a surface resistance that fulfill that condition are regarded as acceptable.
Humidity Resistance
Coat the composition in this invention onto stack flat panels and put it into environment with temperature of49°C and humidity of 98 for 120 hours.
It is acceptable if no dark spots and piebald is found and the white rust ratio is <5wt.-% and the value of chromatism ΔΕ<3. Paintabilitv
Top Coated with below three Paints and adhesion loss is calculated based on the film percentage loss in cross hatched area.
In Test (1 ), paint (1 ) is powder paint (Akzo EA05BH) and the dried film has thickness of 40μηη to 60μηη. And the cross-hatch is done with 100 grids of size 1 mmx1 mm. It is acceptable if no film removed by tape peeling.
In Test (2), paint (2) is solvent borne paint (amino alkyd paint) and the dried film has thickness of around 20 μιτι. And a revere impact with energy of 5 J is bought to bear. It is acceptable if no film crack occurs after impact.
In Test (3), paint (3) is coil coating paint (polyester) and the dried film has thickness of around 20 μιτι. And the 6mm Erichson cupping is added to the cross-hatch with 100 grids of size 1 mmx1 mm. It is acceptable if no film is removed by tape peeling.
Solvent Resistance
Two tests are done to evaluate the solvent resistance of the composition after coating onto the metal substrates.
In Test (1 ), the prime coating is rubbed by the solvent of 80wt.-% ethanol with load of 1 kilogram for 30 times. It is acceptable if no film is removed and the value of chromatism ΔΕ<2.
In Test (2), the prime coating is rubbed by the solvent of methyl/ethyl ketone with load of 1 kilogram for 20 times. It is acceptable if no film is removed and the value of chromatism ΔΕ<2.
Shelf Life Test
The term "shelf life" denotes the length of time that a commodity may be stored without becoming unfit for use or consumption.
In this invention, the shelf life is tested by two ways.
The first is to prepare samples and let it age in a hot box with temperature of 40°C for one month. The shelf life is at least one month at 40 °C if the performance does not turn worse in either one of corrosion resistance, surface conductivity, paintability, solvent resistance, humidity resistance.
The second is to prepare samples and let it age in a hot box with temperature of room temperature for three months. The shelf life is at least three months at room temperature if the performance does not turn worse in either one of corrosion resistance, surface conductivity, paintability, solvent resistance, humidity resistance.
Effect Example
After preparing the said coating composition according to weight ratio and method described in Example 1 -10 as well as in Comparative Example, it is used to treat the hot dip galvanized steel following the common-used way, i.e.
(i) Clean the metal surface;
(ii) Dry the metal surface;
(iii) coating;
(iv) Dry the metal surface,
and make the tests above-mentioned, i.e. corrosion resistance, surface conductivity, humidity resistance, paintability and solvent resistance of the coating film of the composition as well as the shelf life of the composition product. The test results are list in Table 1 to 3. Table 1 : Corrosion resistance and paintabilitv
Figure imgf000023_0001
Table 2: Humidity & solvent resistance and surface conductivity
Figure imgf000024_0001
Table 3 shows result of re-test the properties including corrosionresistance, surface conductivity, paintability, humidity resistance and solvent resistance after the samples are kept in hot box with temperature of 40°C for one month. The contrast of performance of each example shows shelf life, i.e. the stability of product.
Table 3
Figure imgf000025_0001
Figure imgf000026_0001
As shown in tables 1 to 3, the coating composition in this invention provide good performances on corrosion resistance, surface conductivity, paintability, humidity and solvent resistance and also reveal a suitable long shelf life. By contrast, the comparative example, wherein no water-dispersible silane functional oligomers are used, shows obvious weakness in corrosion resistance , paintability as well as with respect to the stability of the product.

Claims

Claims
1 . An aqueous coating composition for metal surface pre-treatment having a pH in the range of from 3 to 6, comprising:
(i) at least one organosilane with at least one hydrolyzable substituent;
(ii) at least one water soluble and/or water dispersible silane-functional oligomer;
(iii) at least one water-soluble compound of the elements Zr and/or Ti.
2. The coating composition according to Claim 1 , wherein the said organosilane is selected from a compound according to the following general structure (I)
Figure imgf000027_0001
Y
(I)
wherein n is an inter integer from 1 to 3; residue R is selected from C1 to C6 and preferably C1 to C3 alkyl groups; residue Y is selected from alkyl groups with not more than 10 carbon atoms carrying at least one epoxy, amino, hydroxyl, vinyl and/or thiol group wherein the residues Y are selected mutually independent from each other.
3. The coating composition according to anyone of Claim 1 to 2, wherein the said organosilane has a weight-average molecular weight of less than 400 g/mol.
4. The coating composition according to anyone of Claim 1 to 4, wherein the said organosilane is one or more selected from vinyltriacetoxysilane,
vinyltrialkoxysilanes, aminoethyltrialkoxysilanes, aminopropylalkoxysilanes, bis-trialkoxysilypropylamines, aminoethylaminopropyltrialkoxysilanes,
aminoethylaminopropyltrialkoxysilanes, mercaptopropyltrialkoxysilanes, bis-trialkoxysilylpropyl-tetrasulfides, 3-glycidoxypropyltrialkoxysilanes, wherein the alkoxy groups have not more than 3 carbon atoms.
The coating composition according to anyone of Claims 1 to 4, wherein the composition further comprises a silane according to the following general structure (II)
OR"
I
R — Si— OR"
I
OR'
(II)
R' is selected from C1 to C6 alkyl groups, preferably from C1 to C3 alkyl groups.
The coating composition according anyone of Claims 1 to 5, wherein the said silane-functional oligomer has a weight-average molecular weight from 400 g/mol to 10,000 g/mol.
The coating composition according to anyone of Claims 1 to 6, wherein the said silane-functional oligomer includes a polyurethane and/or polyacrylate and/or polyester and/or polyether backbone.
The coating composition according to Claim 7, wherein the silane-functional oligomer includes a polyurethane backbone and is the reaction product of at least one diisocyanate, at least one hydroxyl-functional tertiary amine, at least one amino-functional organosilane and at least one polyol being preferably selected from alkane diols, polyether diols, polyester diols and polycarbonate diols.
The coating composition according to Claim 7, wherein the silane-functional oligomer includes a polyacrylate backbone and is the reaction product of at least one (meth)acrylate, at least one vinyl-functional silane, and at least one tertiary amine acrylate.
10. The coating composition according to Claim 7, wherein the silane-functional oligomer includes a polyether backbone and is the reaction product of at least one epoxy resin, at least one amino-functional organosilane, and at least one multifunctional organic compound having at least two functional groups selected from hydroxyl and/or amino groups.
11 . The coating composition according to anyone of the Claims 1 to 10, wherein the said water-soluble compound is one or more selected from hexafluorotitanic acid, hexafluorozirconic acid, zirconium aceto acetate, zirconium acetate and
ammonium zirconium carbonate.
12. The coating composition according to anyone of the Claims 1 to 11 , wherein the molar ratio of element Si to the sum of the elements Zr and/or Ti is from 10 to 500, preferably from 40 to 100.
13. The coating composition according to anyone of the Claims 1 to 12, wherein the amount of the water-soluble compound of the elements Zr and/or Ti in the overall composition is from 0.1 wt.-% to 5wt.-%, preferably from 0.2wt.-% to 2wt.-% with respect to the elements Zr and Ti.
14. The coating composition according to Claim 8, wherein the silane-functional
polyurethane oligomer is obtainable through a process wherein
i) hydroxyl-functional tertiary amines, amino-functional organosilanes and
polyols are pre-mixed under water-free conditions, and
ii) the diisocyanates are added dropwise to this pre-mixture while the
temperature is kept in a range of from 60°C~90°C.
15. The coating composition according to Claim 14, wherein the said amino-functional organosilanes in step i) are selected from aminopropyltrialkoxysilanes, aminophenyltrialkoxysilanes, aminopropylmethyldialkoxysilanes, wherein the alkoxy groups have not more than 3 carbon atoms.
16. Process for the electroless coating of metal substrates wherein the metal
substrate is brought into contact with a coating composition according to anyone of the Claims 1 to 15.
17. The process according to Claim 16, wherein the said metal substrates are
selected from hot dip galvanized steel, electrolytically galvanized steel, steel, iron, zinc, aluminum and aluminum alloys.
18. A metal substrate coated with a coating composition according to anyone of
Claims 1 to 15.
PCT/CN2013/080922 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof Ceased WO2015017985A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
PCT/CN2013/080922 WO2015017985A1 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof
ES13890875T ES2703333T3 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pretreatment, its preparation and use thereof
BR112016002168-1A BR112016002168B1 (en) 2013-08-06 2013-08-06 COATING COMPOSITION FOR PRE-TREATMENT OF METAL SURFACE, PROCESS FOR PLATING COATING OF METAL SUBSTRATES AND METAL SUBSTRATES
CN201380078851.1A CN105874029B (en) 2013-08-06 2013-08-06 For pretreatment of metal surface coating composition, its preparation and application thereof
PL13890875T PL3030623T3 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof
CA2919806A CA2919806C (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof
JP2016532176A JP6318248B2 (en) 2013-08-06 2013-08-06 Coating composition for the preparation of metal surfaces, its production and its use
EP13890875.1A EP3030623B1 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof
US15/012,905 US12054567B2 (en) 2013-08-06 2016-02-02 Coating composition for metal surface pre-treatment, its preparation and use thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2013/080922 WO2015017985A1 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/012,905 Continuation US12054567B2 (en) 2013-08-06 2016-02-02 Coating composition for metal surface pre-treatment, its preparation and use thereof

Publications (1)

Publication Number Publication Date
WO2015017985A1 true WO2015017985A1 (en) 2015-02-12

Family

ID=52460489

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2013/080922 Ceased WO2015017985A1 (en) 2013-08-06 2013-08-06 Coating composition for metal surface pre-treatment, its preparation and use thereof

Country Status (9)

Country Link
US (1) US12054567B2 (en)
EP (1) EP3030623B1 (en)
JP (1) JP6318248B2 (en)
CN (1) CN105874029B (en)
BR (1) BR112016002168B1 (en)
CA (1) CA2919806C (en)
ES (1) ES2703333T3 (en)
PL (1) PL3030623T3 (en)
WO (1) WO2015017985A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9770702B2 (en) 2014-06-16 2017-09-26 International Business Machines Corporation Methods and apparatus for controlling metals in liquids
US10457562B2 (en) 2015-03-27 2019-10-29 Trent University Anti-corrosion sol-gel material

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017079274A1 (en) 2015-11-02 2017-05-11 Metashield Llc Nanosilica based compositions, structures and apparatus incorporating same and related methods
JP6644631B2 (en) * 2016-05-10 2020-02-12 株式会社神戸製鋼所 Aqueous solution for metal surface treatment and method for treating metal surface
CN106380915A (en) * 2016-08-29 2017-02-08 常熟市诺信达机械设备有限公司 Cloth placement machine for industrial production
ES2734254T3 (en) * 2016-12-19 2019-12-05 Henkel Ag & Co Kgaa Procedure for the pretreatment of corrosion protection and cleaning of metal components
US10508205B2 (en) 2017-01-24 2019-12-17 The Boeing Company Corrosion resistant adhesive sol-gel
CN106906462B (en) * 2017-02-15 2019-06-28 武汉大学 A kind of metal surface pretreating reagent and preparation method thereof, application
CN106894009B (en) * 2017-02-24 2019-03-15 武汉大学 A kind of epoxy group POSS modified metal surface pretreating reagent and preparation method thereof, application
CN107012456B (en) * 2017-04-17 2019-06-28 武汉大学 Modified metal surface pretreating reagent of a kind of alkoxyl silicone ethyl Polyhedral Oligomeric silsesquioxane and preparation method thereof, application
CN111164161B (en) * 2017-09-25 2022-06-17 宣伟公司 Room temperature curing zirconate-silica sol-gel pretreatment for metal substrates
CN109487259B (en) * 2018-12-28 2021-05-14 浙江五源科技股份有限公司 Preparation method of chromium-free silane film before aluminum coil coating
EP4202006A4 (en) * 2020-08-19 2024-06-19 Toray Advanced Materials Korea Inc. ORGANIC-INORGANIC ADHESIVE COMPOSITION AND GAS BARRIER FILM COMPRISING SAME
CN115725966B (en) * 2022-11-18 2025-07-22 诺泰生物科技(合肥)有限公司 Cucurbituril modified organic silicon metal antirust water and preparation method and application thereof
EP4655356A1 (en) * 2023-12-01 2025-12-03 Dollmar S.p.A. Method for treating a metal surface

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0931820A1 (en) * 1998-01-27 1999-07-28 JSR Corporation Coating composition and its cured product
EP1054047A2 (en) * 1999-05-21 2000-11-22 JSR Corporation A coating composition, and a coated film and glass each having a coating layer comprised thereof
EP2383370A1 (en) * 2008-12-26 2011-11-02 Henkel (China) Investment Company Ltd. Surface treatment agent for galvanized steel sheet, galvanized steel sheet and production method thereof

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3377303A (en) 1966-05-03 1968-04-09 Gen Mills Inc Polyamide composition
US4433015A (en) * 1982-04-07 1984-02-21 Parker Chemical Company Treatment of metal with derivative of poly-4-vinylphenol
DE3633874A1 (en) * 1986-10-04 1988-04-14 Stockhausen Chem Fab Gmbh METHOD FOR THE PRODUCTION OF POLYURETHANE COATED TEXTILE SURFACES, POLYURETHANE COATED TEXTILE SURFACES AND THE USE THEREOF FOR THE PRODUCTION OF BREATHABLE AND WATER REPELLENT EQUIPMENT
JP3325315B2 (en) * 1992-12-09 2002-09-17 三井化学株式会社 Aqueous polyurethane resin composition
DE19727029B4 (en) * 1997-06-25 2006-11-09 Henkel Kgaa One-component reactive system composition, process for its preparation and its use
CA2301313A1 (en) * 1999-03-18 2000-09-18 Yuka Kanamori Curable composition
JP2002356552A (en) 2001-05-29 2002-12-13 Nitta Gelatin Inc Polyamide hot melt composition
US6887308B2 (en) * 2003-01-21 2005-05-03 Johnsondiversey, Inc. Metal coating coupling composition
JP4737923B2 (en) * 2003-03-20 2011-08-03 コニシ株式会社 Silylated urethane-based aqueous composition, aqueous wrapping adhesive, and aqueous contact adhesive
JP2005120469A (en) * 2003-09-26 2005-05-12 Nippon Parkerizing Co Ltd Composition for surface treatment of metal material and surface treatment method
US7491274B2 (en) * 2004-10-29 2009-02-17 Chemetall Corp. Non-chrome metal treatment composition
US20060099332A1 (en) * 2004-11-10 2006-05-11 Mats Eriksson Process for producing a repair coating on a coated metallic surface
DE102004055450A1 (en) * 2004-11-17 2006-05-18 Degussa Ag Moisture-curing binder
US20080138615A1 (en) * 2005-04-04 2008-06-12 Thomas Kolberg Method for Coating Metallic Surfaces with an Aqueous Composition and Said Composition
JP5313432B2 (en) * 2005-12-28 2013-10-09 日本ペイント株式会社 Metal surface treatment composition, metal surface treatment method and surface-treated galvanized steel sheet
WO2007119812A1 (en) * 2006-04-18 2007-10-25 Hoden Seimitsu Kako Kenkyusho Co., Ltd. Non-chromate rust-preventive surface treating agent for metallic member having zinc surface, and metallic member having zinc surface coated with the rust-preventive coating film
DE102007011553A1 (en) * 2007-03-09 2008-09-11 Chemetall Gmbh A method of coating metallic surfaces with an aqueous polymer-containing composition, the aqueous composition, and the use of the coated substrates
WO2009019855A1 (en) * 2007-08-06 2009-02-12 Nisshin Steel Co., Ltd. Aqueous emulsion coating material and coated steel sheet using the same
JP5322000B2 (en) 2007-12-07 2013-10-23 ディップソール株式会社 Surface treatment aqueous solution and treatment method for forming a corrosion-resistant film on zinc or zinc alloy plating
JP2009161830A (en) * 2008-01-09 2009-07-23 Nippon Paint Co Ltd Blocked isocyanate group-containing organosiloxane and metal surface treatment composition using the same
DE102008020979A1 (en) * 2008-04-25 2009-10-29 Henkel Ag & Co. Kgaa Curable compositions containing silylated polyurethanes
JP2009280889A (en) * 2008-05-26 2009-12-03 Nippon Parkerizing Co Ltd Aquaous surface-treatment agent, pretreatment method for precoating metallic material, manufacturing method for precoating metallic material, and precoating metallic material
EP2315730B1 (en) * 2008-08-19 2020-07-01 BYK-Chemie GmbH Curable polymer mixtures
KR101285420B1 (en) * 2008-12-16 2013-07-12 니혼 파커라이징 가부시키가이샤 Surface treating agent for metallic materials, method for surface treating metallic materials using the surface treating agent, and surface treated metallic materials
DE102009026679A1 (en) * 2009-06-03 2010-12-16 Henkel Ag & Co. Kgaa Adhesives and sealants based on silane-terminated binders for bonding and sealing flexible solar foils / photovoltaic modules
JP2012041586A (en) * 2010-08-17 2012-03-01 Shin-Etsu Chemical Co Ltd Metal surface treatment agent, surface-treated steel, method for treating the same, coated steel, and method for producing the same
CA2810987C (en) * 2010-09-29 2015-12-15 Jfe Steel Corporation Zinc-based metal coated steel sheet

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0931820A1 (en) * 1998-01-27 1999-07-28 JSR Corporation Coating composition and its cured product
EP1054047A2 (en) * 1999-05-21 2000-11-22 JSR Corporation A coating composition, and a coated film and glass each having a coating layer comprised thereof
EP2383370A1 (en) * 2008-12-26 2011-11-02 Henkel (China) Investment Company Ltd. Surface treatment agent for galvanized steel sheet, galvanized steel sheet and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3030623A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9770702B2 (en) 2014-06-16 2017-09-26 International Business Machines Corporation Methods and apparatus for controlling metals in liquids
US10328415B2 (en) 2014-06-16 2019-06-25 International Business Machines Corporation Methods and apparatus for controlling metals in liquids
US10525442B2 (en) 2014-06-16 2020-01-07 International Business Machines Corporation Methods and apparatus for controlling metals in liquids
US10457562B2 (en) 2015-03-27 2019-10-29 Trent University Anti-corrosion sol-gel material

Also Published As

Publication number Publication date
BR112016002168B1 (en) 2022-02-08
CA2919806A1 (en) 2015-02-12
EP3030623B1 (en) 2018-11-14
BR112016002168A2 (en) 2017-08-01
EP3030623A1 (en) 2016-06-15
EP3030623A4 (en) 2017-06-07
JP2016534220A (en) 2016-11-04
CN105874029B (en) 2019-07-09
CA2919806C (en) 2020-10-27
PL3030623T3 (en) 2019-04-30
US20160145444A1 (en) 2016-05-26
CN105874029A (en) 2016-08-17
US12054567B2 (en) 2024-08-06
ES2703333T3 (en) 2019-03-08
JP6318248B2 (en) 2018-04-25

Similar Documents

Publication Publication Date Title
EP3030623B1 (en) Coating composition for metal surface pre-treatment, its preparation and use thereof
KR101296611B1 (en) Epoxy silane oligomer and coating composition containing same
KR101361811B1 (en) Epoxy silane oligomer and coating composition containing same
JP5021107B2 (en) Painted metal plate with excellent conductivity and corrosion resistance
US20080081120A1 (en) Superprimer
CN103119200B (en) Surface treatment fluid for zinc-plated steel sheet, zinc-plated steel sheet, and manufacturing method for the same
JP4683582B2 (en) Water-based metal material surface treatment agent, surface treatment method and surface treatment metal material
JP5554531B2 (en) How to paint metal materials
JP6455855B2 (en) Aqueous metal surface treatment agent
CA2939966A1 (en) Anticorrosive coating composition
TWI392766B (en) Process for coating metallic surfaces with an aqueous composition, and this composition
JP2792231B2 (en) Composition for metal surface treatment
JP5592579B2 (en) How to paint metal materials
JP5496069B2 (en) Metal surface treatment composition and metal substrate having surface treatment film
JP2026041178A (en) Aqueous binder for anti-rust paint, anti-rust paint composition, and method for producing aqueous binder for anti-rust paint
KR20250081311A (en) Preparation method of nano ceramic coating composition for preventing corrosion and the nano ceramic coating composition
JP2025171137A (en) Water-based binder for anti-rust paint and anti-rust paint composition
Van Ooij A Chromium-Free Coating System for DoD Applications

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13890875

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2919806

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2016532176

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112016002168

Country of ref document: BR

WWE Wipo information: entry into national phase

Ref document number: 2013890875

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 112016002168

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20160129