WO2015082200A1 - Vorläuferverbundmaterial, verbundmaterial, verfahren zur herstellung eines vorläuferverbundmaterials, verfahren zur herstellung eines verbundmaterials und verwendung eines vorläuferverbundmaterials und eines verbundmaterials - Google Patents
Vorläuferverbundmaterial, verbundmaterial, verfahren zur herstellung eines vorläuferverbundmaterials, verfahren zur herstellung eines verbundmaterials und verwendung eines vorläuferverbundmaterials und eines verbundmaterials Download PDFInfo
- Publication number
- WO2015082200A1 WO2015082200A1 PCT/EP2014/074771 EP2014074771W WO2015082200A1 WO 2015082200 A1 WO2015082200 A1 WO 2015082200A1 EP 2014074771 W EP2014074771 W EP 2014074771W WO 2015082200 A1 WO2015082200 A1 WO 2015082200A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- composite material
- release layer
- release
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/56—Supporting or fastening means
- A61F13/5605—Supporting or fastening means specially adapted for sanitary napkins or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/56—Supporting or fastening means
- A61F13/58—Adhesive tab fastener elements
- A61F13/60—Adhesive tab fastener elements with release means associated with tab fasteners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/225—Mixtures of macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/58—Adhesives
- A61L15/585—Mixtures of macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
- C09J7/243—Ethylene or propylene polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2274/00—Thermoplastic elastomer material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/748—Releasability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2519/00—Labels, badges
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/005—Presence of polyolefin in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/006—Presence of polyolefin in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2425/00—Presence of styrenic polymer
- C09J2425/005—Presence of styrenic polymer in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/005—Presence of polyester in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2477/00—Presence of polyamide
- C09J2477/005—Presence of polyamide in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
Definitions
- Precursor composite material composite material, process for producing a precursor composite material, process for producing a composite material, and use of a composite material
- a precursor composite material a composite material formed from the precursor composite material, is used
- Composite material specified Composite materials, such as those in
- Hygienic laminates or used for labels have so far the disadvantage that they have to maintain a certain strength, too thick for many applications. This can, for example, in hygiene laminates, such as sanitary napkins or panty liners, too limited
- the object of at least one embodiment of the invention is to provide a precursor composite material from which a composite material having improved properties can be formed, and to provide such a composite material
- Composite material with improved properties are to provide methods for making a precursor composite and a composite having improved properties and to use the precursor composite material for
- a precursor composite material which has a layer sequence comprising an adhesive layer, a
- Relay layer contains, wherein the layer sequence so
- Separating layer is arranged and wherein between the
- Adhesive layer and the release layer an adhesive force is greater than a delamination force between the carrier layer and the release layer.
- Release layer and release layer can each
- the carrier layer may have a first carrier layer and a second carrier layer
- the release layer may have a first release layer, a second
- Carrier be arranged, so a common
- the term "on” with respect to the arrangement of the layer sequence should also be understood to mean a direct arrangement, that is to say a common boundary surface of the side of the adhesive layer facing away from the layer sequence and of the layer sequence remote side of the separation layer at least in partial regions of the layer sequence.
- the precursor composite material thus contains a
- Layer sequence which has a composite of layers, and by their arrangement itself again forms a composite of layer sequences. That means that at one
- Cross-section through the precursor composite material at least two layers sequences arranged one above the other.
- the layer sequence of such a precursor composite material has a higher tensile strength than the individual
- the precursor composite material can further become a
- Composite material can be processed without causing any or all layers of the layer sequence in the processing process to damage.
- Layer sequence to be changed in their arrangement that is, for example, a wound layer sequence to be handled, be achieved that a delamination, ie a separation of the carrier layer and the release layer takes place while the adhesive layer and the release layer maintain their common interface.
- Precursor composite material having the layer sequence adhesive layer-carrier layer release layer release layer is produced, simply by delamination of the carrier layer and the release layer, a composite material having a sequence of the layers release layer-release layer-adhesive layer support layer can be obtained.
- a composite material having a sequence of the layers release layer-release layer-adhesive layer support layer can be obtained.
- Precursor composite material thus becomes a controlled one
- Composite material can be produced. Thus, apart from the sequence of the individual layers in the composite material, the properties of the individual layers of the composite material
- the precursor composite material already determined by the precursor composite material.
- the precursor composite material has a layer sequence that is wound.
- Winding is achieved that the adhesive layer with its side facing away from the layer sequence at least in
- Partial regions is arranged on the side facing away from the layer sequence side of the release layer. Only the outermost layer of the winding has in such a case a portion of the release layer or the adhesive layer, which are free from the other layer.
- the layer sequence lie in the interior of the winding, depending on the length of the layer sequence at least two
- the release layer may have a thickness which is less than 40 ⁇ m, preferably less than 30 ⁇ m, particularly preferably less than 20 ⁇ m, very particularly preferably less than 15 ⁇ m and / or the carrier layer has a thickness
- Release layer less than 100 gsm (grams per m 2 ), preferably less than 50 gsm, more preferably less than 20 gsm, most preferably less than 15 gsm thick.
- release layer less than 100 gsm (grams per m 2 ), preferably less than 50 gsm, more preferably less than 20 gsm, most preferably less than 15 gsm thick.
- conventional support layers have a thickness of 20 to 30 ym and conventional release layers have a thickness of about 40 ym.
- the precursor composite material contains a
- Release layer and / or a carrier layer which may be formed particularly thin.
- the particularly thin shaped release layer and / or carrier layer are in the
- Composite material can be produced, which has particularly thin release and / or carrier layers, which in turn leads to advantageous properties when using the composite material. Even with the controlled delamination of
- Carrier layer and the release layer is therefore not the thinnest layer alone under train, but always a laminate of layers.
- the thickness of the adhesive layer may be less than 50 gsm, preferably less than 30 gsm, preferably less than 15 gsm, very particularly preferably less than 5 gsm,
- the separating layer may have a thickness which is less than 10 gsm, preferably less than 5 gsm, more preferably less than 2 gsm, for example 0.5 to 1 gsm.
- Precursor composite material comprises an adhesive layer comprising a material selected from a group comprising pressure-sensitive adhesives.
- pressure-sensitive adhesive is to be understood here and below to mean an adhesive which adheres permanently to the carrier layer after application and / or
- the pressure-sensitive adhesive may be selected from a group comprising solvent-borne pressure-sensitive adhesives,
- Dispersion pressure-sensitive adhesive can by means of UV irradiation and / or thermally on the carrier layer
- Adhesive layer selected, which are pressure-sensitive, but do not form a chemical bond with the adjacent layers. Furthermore, the release layer of the
- Precursor composite material comprise a material selected from a group comprising polyamide, polystyrene, thermoplastic elastomers, polystyrene copolymers, polyesters, polyester copolymers, polyolefins and combinations thereof and combinations of said materials individually or combinations of said materials with adhesion promoters.
- thermoplastic elastomers are TPE-E (thermoplastic polyester elastomers or thermoplastic copolyesters, for example Hytrel (DuPont) or Riteflex
- TPE-U thermoplastic elastomers
- Urethane base for example Desmopan, Texin, Utechllan
- TPE-V olefin-based crosslinked thermoplastic elastomers, predominantly PP / EPDM, for example Sarlink
- DSM DSM
- SoFter Forprene
- TPE-0 olefin-based thermoplastic elastomers, mainly PP / EPDM, for example
- the release layer can also be composed of first, second and third release layers, wherein the first release layer comprises a material which
- polystyrene is selected from polyethylene, polypropylene, polyamide, thermoplastic elastomers, polystyrene,
- the second release layer is selected from polymeric adhesion promoters and the third
- Release layer polyolefins such as polyethylene or polypropylene may have.
- Such a combination of release layers can reduce the cost of the release layers reduce the stiffness or softness and improve the stampability of the layer, which is for the production of a product in which a composite material consisting of the
- Precursor composite material is produced, may be relevant.
- the precursor composite material may have a
- Carrier layer comprising a material selected from the group consisting of polyolefins,
- thermoplastic elastomers examples include TPE-E, TPE-U, TPE-V, TPE-O, TPE-S and TPE-A.
- TPE-U and TPE-E are particularly advantageous if from the
- Precursor composite material is to be produced a composite material, which is a breathable support layer
- Such carrier layers are advantageous, for example, in the application of the composite material in a hygiene laminate.
- the backing layer may be composed of, for example, two layers, wherein the first backing layer may comprise a material selected from polyethylene, polypropylene, polypropylene copolymers, thermoplastic elastomers and combinations thereof.
- the second backing layer may comprise a material selected from polyethylene, polypropylene, polypropylene copolymers, thermoplastic elastomers and combinations thereof.
- Backing layer may comprise a material selected from a group comprising polyethylene, polypropylene,
- Polypropylene copolymers thermoplastic elastomers and mixtures thereof.
- the materials for the carrier layer and the release layer make sure that between the Selected materials no boundary phase diffusion occurs, the materials are therefore good to delaminate.
- at least 50% of the materials of the carrier layer at least 50% of the materials of the carrier layer
- the different materials of the carrier layer and the release layer may be a polyolefin,
- polyethylene for example, polyethylene, and polystyrene, a polyolefin, such as polyethylene, and a thermoplastic
- the release layer of the precursor composite material may comprise a material selected from a group comprising silicone, cured polysiloxane, and thermoplastic silicone elastomer. These compounds do not bond with the adhesive layer so that the adhesive layer is protected but the release layer remains inert. Thus, the release layer, for example, in a later
- Precursor composite material is manufactured by the
- Adhesive layer are deducted.
- Separating layer and a carrier layer on the adhesive layer comprises.
- the composite material has an arrangement of layers in which a carrier layer and / or a release layer are present, which are particularly thin
- Composite materials may furthermore not be the release layer of paper, but of a film, for example of polyamide, polystyrene, thermoplastic elastomers,
- Polystyrene copolymers polyesters, polyester copolymers, and
- the composite material can be used, for example, in hygiene laminates and contributes there to improved comfort and improved handling. Furthermore, such a composite material can be used directly in a product, without the need for a separate application of an adhesive, since this already in the adhesive layer of the
- Composite material is present.
- a precursor composite material can be prepared as described above.
- Carrier layer, the release layer and the release layer thus apply analogously to the method.
- the method step A) can be the steps
- Adhesive layer include.
- the coextrusion in process step AI) can by means of
- the carrier layer and the release layer can be coextruded and in step A2) the carrier layer with the adhesive layer and the
- Release layer are coated with the release layer.
- the thickness of the carrier layer and the release layer is set during the extrusion.
- the release layer, the release layer and the carrier layer can be coextruded and in step A2) the carrier layer with the
- Adhesive layer to be coated In this case, in step AI), the thickness of the release layer, the Carrier layer and the release layer adjusted and a laminate produced in which the release layer between the support layer and the release layer is arranged.
- Coating in method step A2) takes place in each case on the side of the adhesive layer facing away from the carrier layer and, if appropriate, on that of the release layer
- the separating layer can be adjusted. By the subsequent coating and arrangement of the layer sequence, these thin layers can be destroyed
- Relay layer can be coextruded, in step A2) a coating of the release layer with the release layer, wherein the release layer as a material silicone
- release layer is already in process step AI) with the carrier layer and the release layer
- Silicone elastomer can be selected.
- the layer sequence can be wound. By a winding, the side facing away from the layer sequence side of the adhesive layer and the of the
- Release layer, a release layer on the release layer, an adhesive layer on the release layer and a carrier layer on the adhesive layer comprises.
- the method comprises the
- Precursor composite material can thus be produced particularly easily a composite material in which the carrier layer and the release layer of the precursor composite material
- sanitary napkins for example, sanitary napkins, panty liners,
- Incontinence products, labels and labels can be used without a separate adhesive application is necessary in the production.
- a precursor composite material as described above can thus be used to form a
- Label, label or hygiene laminate for example, by the particularly thin release and / or carrier layer, which in the
- Precursor composite material can be realized
- Figures la and lb show schematic side views of a
- Figure 2 shows the schematic side view of a
- Figure 3 shows the schematic side view of a
- FIGS. 4a, 4b and 4c show schematic side views of coextruded layers of the
- FIGS. 5a, 5b and 5c show schematic side views of FIG.
- FIGS. 6a, 6b and 6c show schematic side views of
- FIGS. 7a and 7b show schematic side views of
- FIGS 8a and 8b show the schematic side view
- Precursor composite 60 which is wound.
- FIG. 1a likewise shows the layer sequence 50 which is wound, but as a cross section through the winding, so that several layer sequences 50 can be seen arranged one above the other. Depending on the size of the winding, significantly more layer sequences 50 can be present one above the other in the winding.
- a layer sequence 50 has an adhesive layer 20, a carrier layer 10, a release layer 40 and a
- Release layer 30 on. These are arranged one above the other so that they have common interfaces with each other. As a result of the arrangement one above the other, the separating layer 30 and the adhesive layer 20 also have a common interface with each other, at least in partial regions of the layer sequence.
- the materials of the adhesive layer 20 are selected so that the adhesive force between adhesive layer 20 and release layer 30 is greater than the delamination between the
- the material of the adhesive layer 20 is a pressure-sensitive adhesive, which remains permanently tacky and / or highly viscous after application to the carrier layer.
- the material of the release layer 30 may be silicone, cured polysiloxane, or a thermoplastic
- the carrier layer 10 may be polyethylene, Polypropylene, polypropylene copolymers or thermoplastic elastomers.
- the release layer 40 has as material, for example, polyethylene, polypropylene, polyamide,
- thermoplastic elastomers polystyrene
- Polystyrene copolymers polyester and / or polyester copolymers on.
- the thickness of the carrier layer 10 is less than 20 ⁇ m, preferably less than 15 ⁇ m, particularly preferably less than 10 ⁇ m, very particularly preferably less than 5 ⁇ m.
- the thickness of the release layer 40 is less than 40 ⁇ m, preferably less than 30 ⁇ m, particularly preferably less than 20 ⁇ m, in particular less than 15 ⁇ m.
- the adhesive layer 20 is formed from the pressure-sensitive adhesive Solucryl 147 from Henkel (an acrylic copolymer), the backing layer 10 from the polyether copolymer-based TPE-U Pearlthane Clear 15N85 from Merquinsa, the release layer 40 from the low-density polyethylene Lupolen 2420 F Company LyondellBasell and the release layer 30 from a silicone based on Tego RC 902 (98%) and Tego Photoinitiator A 18 (2%) from EVONIK.
- Solucryl 147 from Henkel (an acrylic copolymer)
- the backing layer 10 from the polyether copolymer-based TPE-U Pearlthane Clear 15N85 from Merquinsa
- the release layer 40 from the low-density polyethylene Lupolen 2420 F Company LyondellBasell
- the release layer 30 from a silicone based on Tego RC 902 (98%) and Tego Photoinitiator A 18 (2%) from EVONIK.
- FIG. 2 shows a further embodiment of the invention
- Precursor composite material 60 in a schematic side view. This figure is again as a detail of a
- the carrier layer 10 contains in each case two sub-layers, a first carrier layer 11 and a second carrier layer 12.
- the first carrier layer 11 may comprise a polymer such as polyethylene, polypropylene,
- the second backing layer 12 may comprise a polyethylene, polypropylene, polypropylene copolymers, as well as thermoplastic elastomers and combinations thereof.
- the combination of several carrier layers serves to adjust the softness of the carrier layer. This may be relevant, for example, if the carrier layer in a hygiene laminate has the function of a laundry protection film, which must be soft in use. If the material of the carrier layers is a thermoplastic elastomer,
- TPE-E or TPE-U is used
- Carrier layer also breathable.
- the release layer 40 is divided into three partial layers and contains the first release layer 41, the second release layer 42 and the third release layer 43.
- the first release layer 41 has, for example, a polymer which is selected from polyethylene,
- the second release layer 42 contains a polymer which serves as a coupling agent.
- Release layer 43 may in turn contain, for example, polymers such as polyethylene or polyolefins. The division of the release layer 40 into three sub-layers is used for
- Release layer can be lowered by the expensive polyamide through the sequence polyolefin / adhesion promoter / polyamide is replaced.
- the thicknesses of the carrier layer 10 and the release layer 40 correspond to the thicknesses as mentioned with reference to FIGS. 1a and 1b.
- the separation layer 30 is used when using the
- the adhesive layer 20 can thus be glued in the application to an application surface, for example on textiles.
- the adhesive layer 20 is formed from the pressure-sensitive adhesive Solucryl 147 from Henkel, the backing layer 10 from the high-density polyethylene hostel GF 9045 F from LyondellBasell, the release layer 30 from a silicone based on Tego RC 902 (98%) and Tego
- Photoinitiator A 18 (2%) from EVONIK and the
- Release layer 41 is formed from the polyamide Durethan C 38 F from Lanxess in a thickness of 1 .mu.m to 10 .mu.m, the second release layer 42 from the adhesive homopolymer ⁇ based Admer polymer QB 520 E from Mitsui Chemicals in a thickness of 1 ym to 10 ym and the third release layer 43 of a polyolefin or
- High density polyethylene such as Hostalen GF 9045 F from LyondellBasell in a thickness of 1 ym to 30 ym.
- Figure 3 shows the schematic side view of a
- Composite material 70 This has a release layer 40, a release layer 30 on the release layer 40, a
- Adhesive layer 20 on the release layer and a carrier layer 10 on the adhesive layer 20 Adhesive layer 20 on the release layer and a carrier layer 10 on the adhesive layer 20.
- a composite material 70 is made from the precursor composite material 60 such that the materials and layer thicknesses of the layers referred to the precursor composite material also apply to the layers of the composite material 70.
- the carrier layer 10 and / or the release layer 40 are formed particularly thin, which makes the composite material 70 suitable to use it for example in a sanitary laminate or as a label.
- the use in a hygiene laminate leads to improved comfort due to the thin layers 10 and 40.
- Figures 4 to 6 relate to the production of the precursor composite material 60, Figure 7 on the
- Figures 4a, 5a and 6a relate to a first embodiment
- Figures 4b, 5b and 6b relate to a second embodiment
- Figures 4c, 5c and 6c relate to the third
- FIG. 4 shows schematic side views of
- FIG. 4 a shows a first exemplary embodiment in which a carrier layer 10 and a release layer 40 are coextruded
- FIG. 4 b shows a second exemplary embodiment in which the carrier layer 10 is composed of two partial layers and the release layer 40 is composed of three sublayers, so
- FIG. 4c shows a third one
- the release layer 30 includes a material selected from a cured polysiloxane and a thermoplastic silicone elastomer. Such materials can be coextruded and therefore also be made very thin.
- controlled delamination takes place, namely in each case between the carrier layer 10 and the release layer 40, or the second carrier layer 12 and the first release layer 41.
- the delamination is made possible by the fact that between the adhesive layer 20 and the release layer 30 an adhesive force is greater than the
- FIG. 5 shows the schematic side view of FIG
- Preparation of the precursor composite material 60 is the intermediate product obtained after process step A). After the coextrusion of the carrier layer 10 and the release layer 40, as shown in FIG.
- Process step A2) at least the carrier layer 10 coated with an adhesive layer 20.
- the carrier layer 10 with the adhesive layer 20 and the release layer 40 with the separating layer 30 are produced
- the first carrier layer 11 is coated with the adhesive layer 20 and the third release layer 43 is likewise coated with a separating layer 30. Also in this case, the separation layer 30 is a
- the separating layer 30 has already been coextruded with the release layer 40 and the carrier layer 10, so that only one
- Coating of the first carrier layer 11 with the adhesive layer 20 in the method step A2) has taken place.
- Layer coatings 50 are obtained in each case by the coatings, which can now be further processed even with a small thickness of carrier layer 10 and / or release layer 40, without destruction of the thin layers occurring.
- FIG. 5a to 5c each show schematic arrows again, where in further processing of
- Precursor composite material to a composite material the controlled delamination of the layers occurs.
- FIG. 6 shows in each case schematic side views of the finished precursor composite material 60 of FIG.
- the adhesive layer 20 with its side facing away from the layer sequence at least in partial areas on the of the Layer sequence facing away from the separation layer 30th
- FIGS. 6a to 6c are again to be understood as cutouts, since, depending on the length and arrangement or winding of the layer sequence, substantially more layer sequences 50
- Separating layers 30 are each in order
- the layer sequence 50 contains release layers 30, which have been hardened polysiloxane or thermoplastic material
- Release layer 40 two sub-layers, namely the first
- FIGS. 6a to 6c the schematic arrows again show at which point a controlled delamination upon dissolution of the arrangement of the layer sequences 50, ie
- Precursor composite material 60 will result.
- FIGS. 7a and 7b show the method for producing the composite material 70 from the precursor composite material 60 on the basis of a schematic side view of a wound precursor composite material 60. These figures are again to be understood as a section. Figures 7a and 7b show that
- Precursor composite material 60 which as a carrier layer 10 and as a release layer 40 each have multiple sub-layers
- Precursor composite material 60 becomes the combination
- Separation layer 30 and release layer 40 first unwound alone ( Figure 7a), which is particularly easy because the Delaminationskraft between the carrier layer 10 and the release layer 40 is less than the adhesive force between the adhesive layer 20 and the release layer 30, on which the adhesive layer 20 in Subregions of the layer sequence 50 is arranged. Once the half layer sequence of release layer 30 and release layer 40 is unwound and thereby the portion of the wound layer sequence is achieved, in which the release layer 30 on the
- Adhesive layer 20 is arranged, the composite material 70, in the carrier layer 10, adhesive layer 20, release layer 30 and release layer 40 are arranged one above the other, unwound, since again the delamination between the
- Release layer 40 and the carrier layer 10 is less than the adhesive force between the adhesive layer 20 and the
- the composite material 70 can be obtained from the precursor composite material 60 in a particularly simple manner ( Figure 7b).
- FIG. 8 shows the schematic side view (FIG. 8 a) or a schematic top view (FIG. 8 b) of a hygiene laminate in which a composite material 70 produced from the precursor composite material 60 is used.
- the composite material 70 is composed of
- Carrier layer 10 is disposed on the adhesive layer 20 so that on the carrier layer 10 further layers of the
- Hygienic laminate can be arranged. These include one
- the carrier layer 10 may be formed in this case as a laundry protective film. Will that be
- the release film 40 can be removed together with the release layer 30, and the sanitary laminate with the adhesive layer 20 are detachably secured in the laundry again.
- FIG. 8b shows a top view of the hygiene laminate 80, in which only the fleece cover 81 is seen.
- the carrier layer 10 it is advantageous if the carrier layer 10
- TPE-U or TPE-E is used as the material of the carrier layer 10.
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Biomedical Technology (AREA)
- Vascular Medicine (AREA)
- Materials Engineering (AREA)
- Hematology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
Claims
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL14798903T PL3077469T3 (pl) | 2013-12-05 | 2014-11-17 | Wyjściowy materiał kompozytowy, materiał kompozytowy, sposób wytwarzania wyjściowego materiału kompozytowego, sposób wytwarzania materiału kompozytowego i zastosowanie wyjściowego materiału kompozytowego i materiału kompozytowego |
| AU2014359596A AU2014359596B2 (en) | 2013-12-05 | 2014-11-17 | Precursor composite material, composite material, method for producing a precursor composite material, method for producing a composite material and use of a precursor composite material and of a composite material |
| CN201480066715.5A CN106103618B (zh) | 2013-12-05 | 2014-11-17 | 前体复合材料、复合材料及其制备方法和用途 |
| JP2016536946A JP6377160B2 (ja) | 2013-12-05 | 2014-11-17 | 前駆複合材料、複合材料、前駆複合材料を作製する方法、複合材料を作製する方法および前駆複合材料の使用および複合材料の使用 |
| ES14798903.2T ES2654925T3 (es) | 2013-12-05 | 2014-11-17 | Material compuesto precursor, material compuesto, procedimiento para la producción de un material compuesto precursor, procedimiento para la producción de un material compuesto y uso de un material compuesto precursor y de un material compuesto |
| TN2016000218A TN2016000218A1 (en) | 2013-12-05 | 2014-11-17 | Precursor composite material, composite material, method for producing a precursor composite material, method for producing a composite material and use of a precursor composite material and of a composite material. |
| US15/101,868 US9982167B2 (en) | 2013-12-05 | 2014-11-17 | Precursor composite material, method for producing a precursor composite material, method for producing a composite material and use of a precursor composite material and of a composite material |
| CA2932282A CA2932282A1 (en) | 2013-12-05 | 2014-11-17 | Precursor composite material, composite material, method for producing a precursor composite material, method for producing a composite material and use of a precursor composite material and of a composite material |
| RU2016126602A RU2654859C2 (ru) | 2013-12-05 | 2014-11-17 | Прекурсорный композитный материал, композитный материал, способ получения прекурсорного композитного материала, способ получения композитного материала и применение прекурсорного композитного материала и композитного материала |
| DK14798903.2T DK3077469T3 (en) | 2013-12-05 | 2014-11-17 | Precursor composite material, composite material, process for making a precursor composite material, method for making a composite material and using a precursor composite material and a composite material |
| MX2016007263A MX2016007263A (es) | 2013-12-05 | 2014-11-17 | Material compuesto precusor, material compuesto, metodo para producir un material compuesto precursor, metodo para producir un material compuesto y uso de un material compuesto precursor y de un material compuesto. |
| EP14798903.2A EP3077469B1 (de) | 2013-12-05 | 2014-11-17 | Vorläuferverbundmaterial, verbundmaterial, verfahren zur herstellung eines vorläuferverbundmaterials, verfahren zur herstellung eines verbundmaterials und verwendung eines vorläuferverbundmaterials und eines verbundmaterials |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013113532.3 | 2013-12-05 | ||
| DE102013113532.3A DE102013113532A1 (de) | 2013-12-05 | 2013-12-05 | Vorläuferverbundmaterial, Verbundmaterial, Verfahren zur Herstellung eines Vorläuferverbundmaterials, Verfahren zur Herstellung eines Verbundmaterials und Verwendung eines Vorläuferverbundmaterials und eines Verbundmaterials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015082200A1 true WO2015082200A1 (de) | 2015-06-11 |
Family
ID=51900463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2014/074771 Ceased WO2015082200A1 (de) | 2013-12-05 | 2014-11-17 | Vorläuferverbundmaterial, verbundmaterial, verfahren zur herstellung eines vorläuferverbundmaterials, verfahren zur herstellung eines verbundmaterials und verwendung eines vorläuferverbundmaterials und eines verbundmaterials |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9982167B2 (de) |
| EP (1) | EP3077469B1 (de) |
| JP (1) | JP6377160B2 (de) |
| CN (1) | CN106103618B (de) |
| AU (1) | AU2014359596B2 (de) |
| CA (1) | CA2932282A1 (de) |
| DE (1) | DE102013113532A1 (de) |
| DK (1) | DK3077469T3 (de) |
| ES (1) | ES2654925T3 (de) |
| MX (1) | MX2016007263A (de) |
| PL (1) | PL3077469T3 (de) |
| RU (1) | RU2654859C2 (de) |
| TN (1) | TN2016000218A1 (de) |
| WO (1) | WO2015082200A1 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013009679A1 (de) * | 2013-06-11 | 2014-12-11 | Huhtamaki Films Germany Gmbh & Co. Kg | Prepregs |
| DE102019217560A1 (de) * | 2019-11-14 | 2021-05-20 | Loparex Germany Gmbh & Co. Kg | Transferfolie zum Übertragen von Beschichtungsmaterialien auf Bauteile |
| WO2022079558A1 (en) * | 2020-10-14 | 2022-04-21 | 3M Innovative Properties Company | Linerless film stack |
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| JPS6414289A (en) * | 1987-07-09 | 1989-01-18 | Haijima Kk | Production of adhesive tape |
| DE68924104T2 (de) * | 1988-06-23 | 1996-05-09 | Eastman Kodak Co | Abrasionsfeste Schutzlaminate. |
| US5082706A (en) * | 1988-11-23 | 1992-01-21 | Dow Corning Corporation | Pressure sensitive adhesive/release liner laminate |
| KR100219954B1 (ko) * | 1991-09-12 | 1999-09-01 | 스프레이그 로버트 월터 | 문양화된 압감접착제 전이 테이프 |
| US5350612A (en) * | 1992-08-04 | 1994-09-27 | Beckett Corporation | Wet-strength removable coupon |
| CN1118044C (zh) * | 1994-10-26 | 2003-08-13 | 凸版资讯股份有限公司 | 标签纸及其制备方法 |
| IT1291725B1 (it) | 1997-05-05 | 1999-01-21 | Quattrogierre S R L | Prodotti polimerici compositi plastoelastici |
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| US6740379B1 (en) | 1998-03-13 | 2004-05-25 | 3M Innovative Properties Company | Adhesive tape for adhering inserts to a page of a magazine |
| US6432241B1 (en) * | 1998-03-13 | 2002-08-13 | 3M Innovative Properties Company | Splicing tape, splicing method and assembly comprising the splicing tape |
| US6372341B1 (en) | 1998-04-27 | 2002-04-16 | 3M Innovative Properties Company | Tampa-indicating article for reusable substrates |
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-
2013
- 2013-12-05 DE DE102013113532.3A patent/DE102013113532A1/de not_active Withdrawn
-
2014
- 2014-11-17 DK DK14798903.2T patent/DK3077469T3/en active
- 2014-11-17 PL PL14798903T patent/PL3077469T3/pl unknown
- 2014-11-17 AU AU2014359596A patent/AU2014359596B2/en not_active Ceased
- 2014-11-17 CA CA2932282A patent/CA2932282A1/en not_active Abandoned
- 2014-11-17 TN TN2016000218A patent/TN2016000218A1/en unknown
- 2014-11-17 MX MX2016007263A patent/MX2016007263A/es active IP Right Grant
- 2014-11-17 RU RU2016126602A patent/RU2654859C2/ru not_active IP Right Cessation
- 2014-11-17 CN CN201480066715.5A patent/CN106103618B/zh not_active Expired - Fee Related
- 2014-11-17 EP EP14798903.2A patent/EP3077469B1/de not_active Not-in-force
- 2014-11-17 US US15/101,868 patent/US9982167B2/en not_active Expired - Fee Related
- 2014-11-17 ES ES14798903.2T patent/ES2654925T3/es active Active
- 2014-11-17 JP JP2016536946A patent/JP6377160B2/ja not_active Expired - Fee Related
- 2014-11-17 WO PCT/EP2014/074771 patent/WO2015082200A1/de not_active Ceased
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| GB2068833A (en) * | 1980-02-08 | 1981-08-19 | Kimberly Clark Co | Releasable, self-detackifying laminate construction |
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| EP1113059A2 (de) * | 1999-12-29 | 2001-07-04 | Beiersdorf AG | Sicherheitsklebeband zum Nachweis des unbefugten Öffnens einer Verpackung |
Also Published As
| Publication number | Publication date |
|---|---|
| DK3077469T3 (en) | 2018-01-02 |
| US20160369132A1 (en) | 2016-12-22 |
| CA2932282A1 (en) | 2015-06-11 |
| JP2017500225A (ja) | 2017-01-05 |
| EP3077469B1 (de) | 2017-10-04 |
| CN106103618B (zh) | 2019-04-26 |
| MX2016007263A (es) | 2017-02-28 |
| US9982167B2 (en) | 2018-05-29 |
| RU2654859C2 (ru) | 2018-05-23 |
| JP6377160B2 (ja) | 2018-08-22 |
| ES2654925T3 (es) | 2018-02-15 |
| AU2014359596B2 (en) | 2018-02-08 |
| TN2016000218A1 (en) | 2017-10-06 |
| CN106103618A (zh) | 2016-11-09 |
| AU2014359596A1 (en) | 2016-06-23 |
| DE102013113532A1 (de) | 2015-06-11 |
| PL3077469T3 (pl) | 2018-03-30 |
| EP3077469A1 (de) | 2016-10-12 |
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