WO2015133623A1 - 通気性容器用蓋体、通気性容器及び通気性容器用蓋体の製造方法 - Google Patents
通気性容器用蓋体、通気性容器及び通気性容器用蓋体の製造方法 Download PDFInfo
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- WO2015133623A1 WO2015133623A1 PCT/JP2015/056719 JP2015056719W WO2015133623A1 WO 2015133623 A1 WO2015133623 A1 WO 2015133623A1 JP 2015056719 W JP2015056719 W JP 2015056719W WO 2015133623 A1 WO2015133623 A1 WO 2015133623A1
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- Prior art keywords
- container
- gas
- gas permeable
- lid
- permeable
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/08—Housing; Encapsulation
- H01G9/12—Vents or other means allowing expansion
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/14—Arrangements or processes for adjusting or protecting hybrid or EDL capacitors
- H01G11/18—Arrangements or processes for adjusting or protecting hybrid or EDL capacitors against thermal overloads, e.g. heating, cooling or ventilating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/14—Arrangements or processes for adjusting or protecting hybrid or EDL capacitors
- H01G11/20—Reformation or processes for removal of impurities, e.g. scavenging
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/78—Cases; Housings; Encapsulations; Mountings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/394—Gas-pervious parts or elements
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K5/00—Casings, cabinets or drawers for electric apparatus
- H05K5/02—Details
- H05K5/0213—Venting apertures; Constructional details thereof
- H05K5/0215—Venting apertures; Constructional details thereof with semi-permeable membranes attached to casings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Definitions
- the present invention relates to a lid for a breathable container provided with a gas permeable part, a breathable container provided with the lid, and a method for producing a lid for a breathable container.
- gas is generated in a sealed container, the pressure inside the container may increase and the container may be damaged or explode.
- a storage element such as a secondary battery, an electrolytic capacitor, an electric double layer capacitor, etc.
- a specific gas is generated in a container in which an electrode is accommodated, and thus such gas is not discharged outside the container. Otherwise, the container may be damaged or explode.
- various structures for discharging the gas in the container to the outside of the container have been proposed.
- a container that constitutes a storage element is a container that contains an electrode or an electrolyte solution, and includes a gas permeable portion that allows gas to pass therethrough, and allows gas to flow from the inside to the outside through the gas permeable portion.
- a gas permeable portion is formed by attaching a gas permeable sheet that transmits gas to a through hole formed in a container main body that accommodates an electrode and an electrolyte so as to cover the through hole. ing.
- the gas generated inside the breathable container is configured to be discharged to the outside of the breathable container by passing through the gas permeable portion (specifically, the gas permeable sheet) (Patent Document). 1 and 2).
- the gas permeable sheet as described above is an extremely thin sheet and is very easily damaged.
- the gas permeable sheet has to be handled so as not to be contaminated because the gas permeable performance is lowered when impurities or the like adhere to the surface. Therefore, cutting the gas permeable sheet according to the size of the opening of the through hole or disposing it on the opening edge of the through hole while preventing damage and contamination is a very complicated operation.
- a breathable container in which a gas permeable member having a gas permeable sheet attached to a holding body is attached to the through hole of the container body as described above.
- a gas permeable member for example, there is one in which a gas circulation hole for allowing a gas to flow through a holding body is formed, and a gas permeable sheet is held so as to intersect the gas circulation hole.
- the gas permeable member is inserted into the through hole of the container body and attached, so that the gas generated inside the breathable container passes through the gas permeable sheet through the gas flow hole and is discharged to the outside of the container. Composed. Since such a gas permeable member is inserted into the through hole of the lid and attached, the work of attaching the gas permeable sheet to the container body can be facilitated.
- the through-hole is usually set to the minimum necessary size as long as the pressure inside the breathable container can be vented to such an extent that the container does not break or explode. Therefore, for example, when the atmospheric pressure in the container suddenly increases for some reason, a high pressure is applied in the vicinity of the through hole, and there is a problem that the gas permeable member is detached from the through hole and the gas permeable portion is easily damaged.
- this invention makes it a subject to provide easily the cover body for air permeable containers provided with the gas permeation
- Another object of the present invention is to provide a method for producing a lid for a breathable container that can easily produce a lid for a breathable container provided with a gas permeable portion having a relatively high strength.
- the lid for a breathable container is: A lid for a breathable container attached to a container body having an internal space and an opening communicating with the internal space, A closing portion configured to close the opening, and a gas permeable portion configured to be able to vent the internal space and the external space of the container body,
- the gas permeable part is composed of a gas permeable member having a gas permeable sheet, The gas permeable member and the material constituting the closing portion are integrally formed.
- the gas permeable member may have a holding body for holding the gas permeable sheet.
- a protective member may be provided on at least one of the internal space side and the external side of the gas permeable sheet.
- the breathable container according to the present invention includes the lid for each of the breathable containers.
- the method for manufacturing a lid according to the present invention includes injecting a material constituting the closing portion into the mold in a state where the gas permeable member constituting the lid for the breathable container is disposed in the mold.
- the partial cross section perspective view which shows the air permeable container of one Embodiment The A section expanded sectional perspective view shown in FIG. Sectional drawing which shows the cover body for air permeable containers of other embodiment. Sectional drawing which shows the cover body for air permeable containers of other embodiment.
- the lid 1 for a breathable container is a lid for a breathable container that is attached to a container body 11 having an internal space S1 and an opening that communicates with the internal space S1.
- the body 1 includes a closing portion 2 configured to close the opening, and a gas permeable portion 4 configured to be able to ventilate the internal space S1 and the external space S2 of the container main body 11, and the gas
- the permeable portion 4 is a gas permeable member 41 having a gas permeable sheet 3, and is a breathable container lid body 1 in which the gas permeable member and the material constituting the closing portion 2 are integrally formed.
- the lid 1 for a breathable container includes a closing portion 2 and a gas permeable portion 4 including a gas permeable member 41 having a gas permeable sheet 3 that allows gas to permeate. .
- the closing portion 2 closes the opening 10 a when the lid 1 for a breathable container is attached to the container body 11 having the opening 10 a, and the inside of the container body 10.
- the gas permeable part 4 which can ventilate space S1 and external space S2 is provided.
- the closing portion 2 has a shape that can be fitted into the opening 10a of the container body 10 to be attached.
- the closing portion 2 is formed in a plate-like body having a circular shape in top view according to the circular opening 10a.
- the material constituting the closing part 2 is not particularly limited as long as it is a molding material that can be integrated with the gas permeable member 41 constituting the gas permeable part 4 described later by integral molding.
- thermoplastic resins such as PBT (Poly Butylene Terephtalate) resin.
- PBT Poly Butylene Terephtalate
- a phenol resin is preferable from the viewpoints of heat resistance, moisture resistance, and chemical resistance.
- the gas permeable portion 4 is provided at one place in the central portion in the top view of the closing portion 2.
- the gas permeable part 4 of this embodiment is comprised from the gas permeable member 41 which has the said gas permeable sheet 3 and the holding body 5 holding this gas permeable sheet 3. As shown in FIG.
- the gas permeation unit 4 includes a gas permeation path 1a through which gas can permeate between the internal space S1 and the external space S2 of the container body 11.
- a selective permeable sheet 3a that selectively transmits a specific gas or a non-selective permeable sheet 3b that does not have selectivity with respect to a specific gas is used.
- a plurality (specifically, three) of gas permeable sheets 3 are used, one is a selective permeable sheet 3a, and the other two are non-selective permeable sheets 3b.
- the selective permeable sheet 3a is configured to be able to selectively permeate a specific gas from one surface side to the other surface side.
- the gas that can be transmitted through the selective permeable sheet 3a is not particularly limited, and examples thereof include gases such as hydrogen, carbon dioxide, and oxygen.
- Examples of the selective permeable sheet 3a having selectivity for hydrogen gas include a sheet material containing a resin such as aromatic polyimide, and a layer of hydrogen permeable metal (vanadium, vanadium alloy, palladium alloy, niobium, niobium alloy, etc.). What is comprised from the sheet
- seat material containing is mentioned.
- Examples of the sheet material including the hydrogen permeable metal layer include a sheet material (metal foil) composed of only the hydrogen permeable metal layer, a sheet material obtained by depositing a metal layer on a base material layer such as a resin sheet, and the like.
- Examples of the selectively permeable sheet 3a that selectively transmits carbon dioxide include a sheet material made of silicone rubber, a PVA (polyvinyl alcohol) crosslinked sheet material, a PEG (polyethylene glycol) crosslinked sheet material, and the like.
- the non-selective permeable sheet 3b is disposed on at least one side of the selective permeable sheet 3a (both sides in the present embodiment) so as to overlap the selective permeable sheet 3a.
- the non-selective permeable sheet 3b can be appropriately selected according to the properties of the laminated selective permeable sheet 3a.
- a porous film made of polytetrafluoroethylene (PTFE), ceramic, metal, resin, or the like The thing comprised from sheet materials, such as these, is mentioned.
- a porous membrane made of PTFE is preferable as a sheet material constituting the non-selective permeable sheet 3b because it has high water repellency and high heat resistance and chemical resistance.
- the holding body 5 is formed in a cylindrical shape (specifically, a cylindrical shape with the axis L as the center), and a hole 5a is formed in the central portion thereof. Both ends of the hole 5 a are configured to open to both ends of the holding body 5.
- the holding body 5 has an opening (hereinafter also referred to as a discharge port) formed on the other end side of gas flowing from an opening (hereinafter also referred to as an inflow port) 5b formed on one end side of the hole 5a. 5c can be discharged. That is, the holding body 5 includes a hole 5a serving as a flow path for flowing gas in the direction along the axis L from the inlet 5b side to the outlet 5c side. An imaginary line passing through the central portions of the openings 5b and 5c.
- the holding body 5 of this embodiment is composed of a plurality of members (two in this embodiment). That is, the holding body 5 includes a first member 51 and a second member 52 that can be divided in the direction of the axis L.
- the first member 51 is a cylindrical member that forms a portion on the discharge port 5c side of the holding body 5 and has a hole 51a in the center, and a recess 51b on the end side opposite to the discharge port 5c. Is formed.
- the second member 52 is a cylindrical member that can be fitted into the recess 51b and has a hole 52a at the center.
- the gas permeable sheet 3 (specifically, a laminated sheet of the selective permeable sheet 3a and the non-selective permeable sheet 3b) is disposed. Is fixed between the first member 51 and the second member 52, the second member 52 is fitted into the recess 51b.
- the first member 51 and the second member 52 are configured so that the centers of the holes coincide when they are attached, that is, the hole 51a of the first member 51 and the hole 52a of the second member 52.
- the hole 5a of the holding body 5 is configured.
- the gas permeable part 4 and the closing part 2 of this embodiment are formed by integrally molding the material constituting the closing part 2 and the gas permeable member 41.
- the integral molding means that the material constituting the closing portion and the gas permeable member are placed in the mold, and the gas permeable member and the closing portion are integrated when the closing portion is molded in the mold. It means to become.
- the hole 5 a of the holding body constitutes a part of the gas transmission path 1 a in the gas transmission part 4.
- the gas permeable member 41 has a discharge port 5c of the holding body 5 on one surface side 2a of the closing part 2 (a surface side disposed outside the container body 11 when attached to the container body 11 described later). It arrange
- a hole 2c that opens to the center is formed on the other surface side 2b of the closing portion 2 (the surface side that is disposed inside the container body when attached to the container body 11 described later),
- the hole 2 c is configured to communicate with the inlet 5 b of the holding body 5. That is, the gas permeation path 1 a of the air-permeable container lid 1 of the present embodiment is constituted by the hole 2 c of the closing portion 2, the gas permeable sheet 3, and the hole 5 a of the holding body 5.
- the material of the holding body 5 is not particularly limited as long as it is a material that can be integrally formed with the closing portion 2, and examples thereof include a resin such as PBT resin, and a metal such as aluminum and stainless steel.
- the air-permeable container 10 using the above-described lid 1 for a breathable container of the present embodiment (hereinafter also simply referred to as a lid) will be described.
- the air-permeable container 10 of the present embodiment has the air-permeable container lid 1 of the present embodiment as described above on a container body 11 having an internal space S ⁇ b> 1 that accommodates other members. It is attached.
- the lid 1 for the breathable container covers the opening 10a of the container body 11 by attaching the peripheral part of the closing part 2 to the opening peripheral part of the opening 10a of the container body 11 by welding, bonding or the like.
- the air permeable container 10 is configured such that the gas generated in the air permeable container 10 (specifically, the container main body 11) by the gas permeable portion 4 of the lid 1 is outside through the gas permeable path 1 a of the gas permeable portion 4. Can be discharged. Specifically, the internal pressure of the container body 11 rises due to the generation of gas in the container body 11. Along with this, the gas in the container main body 11 flows into the gas permeation path 1a of the lid 1 from the opening of the hole 2c of the closing portion 2.
- the air-permeable container 10 as described above is for accommodating electrodes and the like as members constituting power storage elements such as a secondary battery, an electrolytic capacitor (such as an aluminum electrolytic capacitor), and an electric double layer capacitor. May be used.
- various gases are generated inside the breathable container 10.
- hydrogen gas is generated
- carbon dioxide gas is generated. It will be.
- the air-permeable container lid 1 and the air-permeable container 10 of the present embodiment having the above-described configuration are formed by integrally forming the gas permeable member 41 and the constituent material of the closing portion 2 to form the air-permeable container lid 1. Since it comprises, even if the internal pressure of the container main body 11 rises rapidly, the gas permeable part 4 is hard to be damaged, for example, the gas permeable sheet 3 or the gas permeable member 41 comes off from the air permeable container.
- the holding body 5 of the gas permeable member 41 is comprised from the 1st member 51 and the 2nd member 52 which are several members, it is not limited to this,
- the holding body comprised from one member may be sufficient.
- the method of attaching the gas permeable sheet and the holding body is not particularly limited.
- the gas permeable sheet and the holding body may be attached by integral molding, or after the holder is molded, A transmission sheet may be attached to the holding body.
- the gas permeable member 41 is constituted by the gas permeable sheet 3. Specifically, as shown in FIG. 3, the gas permeable sheet 3 is formed in the hole 2d formed in the central portion of the closed portion 2 and opened on both side surfaces 2a and 2b of the closed portion 2, respectively. It is arranged to close up. More specifically, the closed portion 2 and the gas permeable member 41 are integrated by integral molding so that the peripheral portion of the gas permeable sheet 3 is embedded in the inner peripheral surface of the hole 2d. Yes.
- the gas permeable sheet 3 of this embodiment is a selective permeable sheet.
- the gas permeation path 1 a of the gas permeation section is configured by the hole 2 d and the gas permeation sheet 3.
- the lid 1 for a breathable container of the present embodiment may further include a protective member 7.
- the protection member 7 is extended toward the center of the opening from a cylindrical side wall 7a having both ends open, and from an opening peripheral edge of one end of the side wall 7a.
- a circular gas permeable sheet 7c having a peripheral edge attached to the sheet body attaching portion 7b inside the side wall portion 7a.
- the gas permeable sheet 7c may be the selective permeable sheet or the non-selective permeable sheet.
- the gas permeable sheet 7c is a porous film made of PTFE as described above, It is preferable because the gas permeable sheet 3 formed integrally can be easily protected from dirt and the like.
- the protective member 7 is inserted from at least one of the openings on both sides 2a and 2b (both in the present embodiment) of the closing part 2 into the hole 2d communicating with the opening from the sheet attachment part 7b side and closed. It is attached to part 2. That is, the protective member 7 is attached to the lid 1 so that the gas permeable sheet 7c of the protective member 7 is disposed outside the gas permeable sheet 3 integrated with the closing portion 2 by integral molding.
- the air permeable container lid 1 is attached to the container body to constitute the air permeable container, as in the first embodiment.
- the breathable container of the present embodiment is configured such that the gas of the protective member 7 is formed on both sides of the gas permeable sheet 3 integrated with the closing portion 2, that is, on the inner space side and the outer space side of the container body 11.
- the transmission sheet 7c is arranged. Therefore, for example, the protective member 7 may be configured such that a stored matter contained in the internal space of the container body or a contaminant such as dust from the external space adheres to the gas permeable sheet 3 formed integrally with the closing portion 2. This is prevented by the gas permeable sheet 7c.
- the shape of the protection member 7 of the present embodiment is not particularly limited.
- the protection member 7 has an annular protrusion 7d formed on the outer peripheral surface of the side wall portion 7a. May be.
- the protrusion 7d comes into contact with the inner wall of the hole 2d, so that the protective member 7, the hole 2d, Can be inserted into the hole 2d of the blocking portion 2 in a sealed state.
- the gas permeable portion 4 is constituted by a gas permeable member 41 made of the gas permeable sheet 3.
- a laminated permeable sheet in which a non-selective permeable sheet 3b is laminated on both sides of the selective permeable sheet 3a is used as the gas permeable sheet 3.
- the laminated transmission sheet of this modification is configured by forming an adhesive portion 4a at the peripheral edge of the selective transmission sheet 3a and laminating the non-selective transmission sheet 3b via the adhesion portion 4a.
- the adhesive part can be formed by disposing an adhesive, an adhesive tape, an adhesive resin sheet or the like on the peripheral part of the selective transmission sheet 3a.
- a porous membrane made of PTFE or the like protects the selective permeable sheet 3a from dirt and the like, similarly to the gas permeable sheet 7c attached to the protective member 7. It is preferable because it is easy.
- the gas permeable member 41 of this modification is composed of a laminated permeable sheet in which the non-selective permeable sheet 3b is laminated on both sides of the selective permeable sheet 3a in advance, the protective member as in the second embodiment is used. The contamination of the selective transmission sheet 3a can be prevented without any trouble.
- a third embodiment according to the method for manufacturing a lid for a breathable container will be described.
- the air permeable container lid is manufactured by injecting the gas into the mold and manufacturing the air permeable container lid integrally formed with the gas permeable member and the closing portion.
- cover 1 for air permeable containers of 2nd embodiment is supplied in a metal mold
- the gas permeable sheet is supplied into the mold as an elongated gas permeable sheet continuous body 100.
- the gas permeable sheet continuous body 100 is disposed in a mold so that a space is formed on both sides of a predetermined location. That is, the gas permeable sheet continuous body 100 arrange
- the mold is a mold having an internal space in which the closing portion of the second embodiment can be molded. That is, the inner space has a shape that forms a circular plate-like body, and a core that can form a hole that exposes the gas-permeable sheet from both sides at the center of the portion that becomes the closed portion. It is a mold provided.
- the closing part 2 is integrally formed at a predetermined position of the continuous gas permeable sheet 100. Further, another part having a predetermined interval from the one part of the gas permeable sheet continuous body 100 is similarly placed in the mold and the closing part 2 is integrally formed, and the closing part 2 is integrally formed at a plurality of places.
- the lid continuous body 101 is formed. Then, the gas permeable sheet continuous body 100 is cut
- the gas permeable member in the first embodiment is disposed in the mold.
- the gas permeable member is arranged in the mold so that the gas permeable member 41 and the closing portion 2 are arranged as shown in FIG. Specifically, one end portion of the gas permeable member 41 is flush with the one surface side surface of the closing portion, and the other end portion is a predetermined distance from the other surface side surface of the closing portion 2.
- the gas permeable member 41 is disposed in the mold at a position where it is buried in the depth position (the depth position of the hole 2c in FIG. 2).
- the mold includes a core at a position where a hole corresponding to the hole 2c can be formed in a portion of the molded body that becomes the closed portion 2.
- a material (molding material) constituting the closing portion is injected into the mold as in the third embodiment, and the molding material is cured.
- the lid is manufactured.
- the gas permeable sheet 41 provided with the holding body and the material of the closing portion 2 are integrated by integral molding, the gas permeable sheet is directly formed integrally with the closing portion. It is easier to prevent the gas permeable sheet from being damaged, and the lid can be easily manufactured.
- the manufacturing method of the air-permeable container lid, the air-permeable container, and the air-permeable container lid according to the present invention is not limited to the above-described embodiment, and various methods are possible without departing from the gist of the present invention. It can be changed. Further, the configurations and methods of the plurality of embodiments described above may be arbitrarily adopted and combined (even if the configurations and methods according to one embodiment are applied to the configurations and methods according to other embodiments). Of course, it is of course possible to arbitrarily select configurations, methods, and the like according to various modifications described below and employ them in the configurations, methods, and the like according to the above-described embodiments.
- the selective permeable sheet 3a and the non-selective permeable sheet 3b are used as the gas permeable sheet 3.
- the gas permeable sheet 3 is not limited to this, for example, the selective permeable sheet 3a or Only one or a plurality of the non-selective permeable sheets 3 b may be used as the gas permeable sheet 3.
- the cover body for air permeable containers is provided with the gas permeation
- transmission part may be provided in several places of the obstruction
- a lid for a breathable container attached to a container body having an internal space and an opening communicating with the internal space, the closed portion configured to close the opening;
- a gas permeable portion configured to allow ventilation between the internal space and the external space of the container body, and the gas permeable portion includes a gas permeable member having a gas permeable sheet, and the gas permeable member and the blockage
- the gas permeable member has a holding body for holding the gas permeable sheet
- a lid for a breathable container provided with a gas permeable portion having higher strength can be easily obtained. can get.
- the lid for the breathable container provided with the gas permeable portion having high strength is easier.
- the gas permeable sheet can be protected from contamination and damage.
- the present invention it is possible to easily provide a lid for a breathable container and a breathable container provided with a gas permeable portion having a relatively high strength. Furthermore, the manufacturing method of the air permeable container lid body which can manufacture easily the air permeable container cover body provided with the gas permeation
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Gas Exhaust Devices For Batteries (AREA)
- Laminated Bodies (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Closures For Containers (AREA)
Abstract
Description
斯かる通気性容器では、電極や電解液を収容する容器本体に形成された貫通孔に、気体を透過する気体透過シートが該貫通孔を覆うように取り付けられることで、気体透過部が形成されている。これにより、通気性容器の内側で発生した気体が気体透過部(具体的には、気体透過シート)を透過することで、通気性容器の外側へ排出されるように構成されている(特許文献1及び2参照)。
かかる気体透過部材としては、例えば、保持体に気体を流通させる気体流通孔が形成されており、該気体流通孔に交差するように気体透過シートが保持されているものがある。該気体透過部材が容器本体の貫通孔に挿入されて取り付けられることで、通気性容器の内側で発生した気体が気体流通孔で気体透過シートを透過して、容器の外側へ排出されるように構成される。
かかる気体透過部材は蓋体の貫通孔に挿入して取り付けるため、気体透過シートを容器本体に取り付ける作業が容易にできる。
気体透過部材を貫通孔に強固に取り付け気体透過部の強度を上げるために、接着剤等を用いて気体透過部材を貫通孔に取り付けることが考えられるが、高い強度で接着することは困難である。さらに、接着剤等を用いて気体透過部材を容器本体に取り付ける場合には、貫通孔の内周面や、保持体の外周面に接着剤を塗布する工程が必要となり、製造作業は煩雑になる。
また、比較的強度の高い気体透過部が備えられた通気性容器用蓋体を容易に製造できる通気性容器用蓋体の製造方法を提供することを課題とする。
内部空間と該内部空間に連通する開口とを有する容器本体に取り付けられる通気性容器用蓋体であって、
前記開口を塞ぐように構成される閉塞部と、前記容器本体の内部空間と外部空間とを通気可能に構成される気体透過部とを備え、
前記気体透過部は、気体透過シートを有する気体透過部材から構成され、
前記気体透過部材と前記閉塞部を構成する材料とが一体成形される。
本実施形態に係る通気性容器用蓋体1は、図1及び図2に示すように、内部空間S1と該内部空間S1に連通する開口とを有する容器本体11に取り付けられる通気性容器用蓋体1であって、前記開口を塞ぐように構成される閉塞部2と、前記容器本体11の内部空間S1と外部空間S2とを通気可能に構成される気体透過部4とを備え、前記気体透過部4は、気体透過シート3を有する気体透過部材41から構成され、前記気体透過部材と前記閉塞部2を構成する材料とが一体成形された通気性容器用蓋体1である。
閉塞部2は、取り付けられる容器本体10の開口10aに嵌合可能な形状であり、例えば本実施形態においては、円形の開口10aに合わせて上面視円形状の板状体に形成されている。
中でも、フェノール樹脂が耐熱性、耐湿性、耐薬品性の観点から好ましい。
本実施形態においては、閉塞部2の上面視中央部の一箇所に前記気体透過部4が備えられている。
前記気体透過部4は、容器本体11の内部空間S1と外部空間S2との間で気体が透過可能な気体透過経路1aを備えている。
水素ガスに対する選択性を有する選択性透過シート3aとしては、例えば、芳香族ポリイミド等の樹脂を含むシート材や、水素透過性金属(バナジウム、バナジウム合金、パラジウム合金、ニオブ、ニオブ合金等)の層を含むシート材から構成されたものが挙げられる。水素透過性金属層を含むシート材としては、水素透過性金属層のみからなるシート材(金属箔)や、樹脂シート等の基材層に金属層が蒸着等されてなるシート材等が挙げられる。二酸化炭素を選択的に透過させる選択性透過シート3aとしては、シリコーンゴムからなるシート材、PVA(polyvinyl alcohol)架橋シート材、PEG(polyethylene glycol)架橋シート材等から構成されるものが挙げられる。
本実施形態では、保持体5は、孔5aの一端側に形成される開口(以下、流入口とも記す)5bから流入する気体を他端側に形成される開口(以下、排出口とも記す)5cから排出可能に構成される。
つまり、保持体5は、流入口5b側から排出口5c側へ向かって軸線Lに沿った方向に気体を流通させる流路となる孔5aを備える
ここで、軸線Lとは、保持体5の開口5b、5cの中央部同士を通る仮想線をいう。
第一部材51は、保持体5の排出口5c側の部分を構成し、且つ中央部に孔51aを有する筒状の部材であり、該排出口部5cと反対の端部側には凹部51bが形成されている。
第二部材52は、前記凹部51bに嵌合可能で且つ中央部に孔52aを有する筒状の部材である。
前記第一部材51の凹部51b内には、前記気体透過シート3(具体的には、選択性透過シート3a、および、非選択性透過シート3bの積層シート)が配置され、該気体透過シート3を第一部材51と第二部材52との間で固定するように、第二部材52は、前記凹部51bに嵌合される。
尚、ここで、一体成形とは、金型内に閉塞部を構成する材料と気体透過部材とを入れ、閉塞部を金型内で成形する際に前記気体透過部材と前記閉塞部とを一体化することをいう。
前記気体透過部材41は、閉塞部2の一面側2a(後述する容器本体11に取り付けられた場合に、容器本体11の外側に配置される面側)に、前記保持体5の排出口5cが開口するように配置され、前記保持体5の一方の端部の面は閉塞部2の一面側2aと面一になる。
一方、閉塞部2の他面側2b(後述する容器本体11に取り付けられた場合に、容器本体の内側に配置される面側)には、中央部に開口する孔2cが形成されており、該孔2cは保持体5の流入口5bと連通するように構成されている。
すなわち、閉塞部2の孔2c、気体透過シート3及び保持体5の孔5aによって、本実施形態の通気性容器用蓋体1の気体透過経路1aは構成されている。
本実施形態の通気性容器10は、図1に示すように、他の部材を収容する内部空間S1を備えた容器本体11に、上記のような本実施形態の通気性容器用蓋体1が取り付けられている。
かかる通気性容器10は、蓋体1の前記気体透過部4によって、通気性容器10(具体的には、容器本体11)の内部で発生した気体が気体透過部4の気体透過経路1aを通じて外側へ排出可能となる。具体的には、容器本体11内で気体が発生することによって容器本体11の内圧が上昇する。これに伴って、容器本体11内の気体は、蓋体1の気体透過経路1a内へ、閉塞部2の孔2cの開口から流入する。そして、気体透過経路1aに流入した気体は、排出口5c側へ向かって気体透過経路1a内を流通する際に、各気体透過シート3を透過する。そして、各気体透過シート3を透過した気体は、気体透過経路1aの排出口5cから通気性容器10の外側へ排出される。これにより、容器本体11の内圧が低下することになる。
本実施形態の通気性容器用蓋体1において、気体透過部材41は気体透過シート3から構成されている。
具体的には、図3に示すように、閉塞部2の中央部に形成され、該閉塞部2の両面側2a、2bにそれぞれ開口する孔2dの内部に、気体透過シート3が該孔2dを塞ぐように配置されている。
より具体的には、気体透過シート3の周縁部が、孔2dの内周面に埋め込まれた状態になるように、前記閉塞部2と前記気体透過部材41とが一体成形により一体化されている。
本実施形態の気体透過シート3は、選択性透過シートである。
本実施形態の通気性容器用蓋体1は、前記孔2d及び気体透過シート3によって、気体透過部の気体透過経路1aが構成されている。
保護部材7は、図3に示すように、両端が開口している円筒状の側壁部7aと、該側壁部7aの一方の端部の開口周縁部から開口中心部に向かって延出されているシート体取付部7bと、側壁部7aの内側において前記シート体取付部7bに周縁部が取り付けられた円形状の気体透過シート7cとを備えている。
気体透過シート7cは、前記選択性透過シートであっても、非選択性透過シートであってもよいが、例えば、上記のようなPTFEからなる多孔質膜である場合には、閉塞部2と一体成形されている気体透過シート3を汚れなどから保護しやすいため好ましい。
すなわち、閉塞部2と一体成形により一体化されている気体透過シート3の外側に、保護部材7の気体透過シート7cが配置されるように保護部材7は、蓋体1に取り付けられている。
本実施形態の通気性容器は、閉塞部2と一体成形により一体化されている気体透過シート3の両面側、すなわち、容器本体11の内部空間側と外部空間側とに前記保護部材7の気体透過シート7cが配置されるように構成されている。従って、例えば、容器本体の内部空間に収容された収容物や、外部空間からの埃などの汚染物質が、閉塞部2と一体成形されている気体透過シート3に付着することが前記保護部材7の気体透過シート7cによって防止される。
かかる保護部材7は、前記閉塞部2の前記孔2dにシート体取付部7b側から挿入される際に、孔2dの内壁に前記突起7dが当接することで、保護部材7と、孔2dとがシールされた状態で、閉塞部2の孔2dに挿入することができる。
本変形例の通気性容器用蓋体1において、前記気体透過部4は気体透過シート3からなる気体透過部材41から構成されている。
本変形例において、前記気体透過シート3としては、選択性透過シート3aの両面側に、非選択性透過シート3bを積層された積層透過シートが用いられる。
本変形例の積層透過シートは、選択性透過シート3aの周縁部に接着部4aが形成され、該接着部4aを介して、非選択性透過シート3bが積層されることで構成される。
前記接着部は、接着剤、接着テープ、接着性樹脂シート等を前記選択性透過シート3aの周縁部に配置することで形成することができる。
前記非選択性透過シート3bの材質としては、例えば、前記保護部材7に取り付けられた気体透過シート7cと同様に、PTFEからなる多孔質膜等が、選択性透過シート3aを汚れなどから保護しやすいため好ましい。
次に、通気性容器用蓋体の製造方法にかかる第三実施形態を説明する。
本実施形態の通気性容器用蓋体の製造方法は、前記通気性容器用蓋体を構成する気体透過部材を金型内に配置した状態で、前記金型内に前記閉塞部を構成する材料を注入して型内成形することで、前記気体透過部材と閉塞部とが一体成形された通気性容器用蓋体を製造する通気性容器用蓋体の製造方法である。
まず、第二実施形態の通気性容器用蓋体1の、気体透過部材41である気体透過シートを、金型内に供給する。
このとき、図5に示すように、気体透過シートは長尺状の気体透過シート連続体100として金型内に供給される。
気体透過シート連続体100は、所定の一箇所の両面側に空間が形成されるように金型内に配置される。すなわち、気体透過シート連続体100は、該気体透過シート連続体100を挟んで閉塞部を構成する材料が金型内に注入されるように気体透過シートを配置する。
さらに、気体透過シ-ト連続体100の前記一箇所から所定間隔を有する別の箇所を同様に金型内に配置し閉塞部2を一体成形していき、複数個所に閉塞部2が一体成形された蓋体連続体101が形成される。
その後、閉塞部2が形成されていない箇所において気体透過シート連続体100を切断し、さらに閉塞部2からはみ出している気体透過シートを切除する。
その後、図5Bに示すように、上記第二実施形態で説明したような保護部材7を、閉塞部2の中央部の孔に挿入することで、前記第二実施形態の蓋体を製造する。
本実施形態の蓋体の製造方法によれば、複数の蓋体を製造することが容易にできる。
本実施形態では、第一実施形態の通気性容器用蓋体の製造方法について説明する。
本実施形態の製造方法では、金型内に、第一実施形態での気体透過部材を配置する。
本実施形態では、成形後には図2に示すように気体透過部材41と閉塞部2とが配置されるように、気体透過部材を金型内に配置する。
具体的には、前記気体透過部材41の一方側の端部が閉塞部の一面側表面と面一になるように、且つ、他方側の端部は閉塞部2の他面側表面から所定の深さの位置(図2では孔2cの深さの位置)に埋設されるような位置に、気体透過部材41を金型内に配置する。金型は、孔2cに相当する孔を閉塞部2となる成形体の部分に形成可能な位置に中子を備えている。
この場合、蓋体を製造する際には、金型内に気体透過部材を複数個収容して、閉塞部を構成する材料と一体成形によって一体化することで蓋体を製造することが好ましい。
さらに、比較的強度の高い気体透過部が備えられた通気性容器用蓋体を容易に製造できる通気性容器用蓋体の製造方法を提供することができる。
Claims (5)
- 内部空間と該内部空間に連通する開口とを有する容器本体に取り付けられる通気性容器用蓋体であって、
前記開口を塞ぐように構成される閉塞部と、前記容器本体の内部空間と外部空間とを通気可能に構成される気体透過部とを備え、
前記気体透過部は、気体透過シートを有する気体透過部材から構成され、
前記気体透過部材と前記閉塞部を構成する材料とが一体成形された通気性容器用蓋体。 - 前記気体透過部材は、前記気体透過シートを保持する保持体を有している請求項1に記載の通気性容器用蓋体。
- 前記気体透過シートの少なくとも一方の面側に配置される保護部材をさらに備えた請求項1又は2に記載の通気性容器用蓋体。
- 請求項1乃至3のいずれか一項に記載の通気性容器用蓋体を備えた通気性容器。
- 請求項1乃至3のいずれか一項に記載の通気性容器用蓋体を構成する気体透過部材を金型内に配置した状態で、前記金型内に前記閉塞部を構成する材料を注入して型内成形することで、前記気体透過部材と閉塞部とが一体成形された通気性容器用蓋体を製造する通気性容器用蓋体の製造方法。
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| WO2009001947A1 (ja) | 2007-06-22 | 2008-12-31 | Rubycon Corporation | 電子部品用圧力調節弁及びこれを用いた電子部品 |
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2014
- 2014-03-06 JP JP2014044296A patent/JP2015170470A/ja active Pending
-
2015
- 2015-03-06 US US15/123,377 patent/US20170069890A1/en not_active Abandoned
- 2015-03-06 TW TW104107244A patent/TW201545397A/zh unknown
- 2015-03-06 WO PCT/JP2015/056719 patent/WO2015133623A1/ja not_active Ceased
- 2015-03-06 KR KR1020167026842A patent/KR20160131038A/ko not_active Withdrawn
- 2015-03-06 CN CN201580012091.3A patent/CN106068157A/zh active Pending
- 2015-03-06 EP EP15759092.8A patent/EP3115100A4/en not_active Withdrawn
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| JP2003063549A (ja) * | 2001-06-14 | 2003-03-05 | Tokai Kogyo Co Ltd | 通気可能栓、及びその製造方法 |
| JP2004249653A (ja) * | 2003-02-21 | 2004-09-09 | Tokai Kogyo Co Ltd | 通気シート片を一体的に接合した樹脂成形品の製造方法及びその製造装置 |
| JP2004358746A (ja) * | 2003-06-03 | 2004-12-24 | Tokai Kogyo Co Ltd | インサート射出成形品の製造方法、及びその装置 |
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| JP2009078866A (ja) * | 2007-09-04 | 2009-04-16 | Nitto Denko Corp | 通気部材およびその製造方法 |
| WO2011132247A1 (ja) * | 2010-04-23 | 2011-10-27 | 日東電工株式会社 | 通気部材およびそれを備えた通気筐体 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108352255A (zh) * | 2015-11-17 | 2018-07-31 | 爱普科斯公司 | 具有安全排气口的电解电容器 |
| JP2021077820A (ja) * | 2019-11-13 | 2021-05-20 | 東和化学株式会社 | 通気防水構造体 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3115100A1 (en) | 2017-01-11 |
| KR20160131038A (ko) | 2016-11-15 |
| EP3115100A4 (en) | 2017-11-01 |
| CN106068157A (zh) | 2016-11-02 |
| JP2015170470A (ja) | 2015-09-28 |
| TW201545397A (zh) | 2015-12-01 |
| US20170069890A1 (en) | 2017-03-09 |
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