WO2018157498A1 - P型perc双面太阳能电池及其组件、系统和制备方法 - Google Patents
P型perc双面太阳能电池及其组件、系统和制备方法 Download PDFInfo
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- WO2018157498A1 WO2018157498A1 PCT/CN2017/087361 CN2017087361W WO2018157498A1 WO 2018157498 A1 WO2018157498 A1 WO 2018157498A1 CN 2017087361 W CN2017087361 W CN 2017087361W WO 2018157498 A1 WO2018157498 A1 WO 2018157498A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/30—Coatings
- H10F77/306—Coatings for devices having potential barriers
- H10F77/311—Coatings for devices having potential barriers for photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F10/00—Individual photovoltaic cells, e.g. solar cells
- H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
- H10F10/14—Photovoltaic cells having only PN homojunction potential barriers
- H10F10/148—Double-emitter photovoltaic cells, e.g. bifacial photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/121—The active layers comprising only Group IV materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/129—Passivating
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- H—ELECTRICITY
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- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/137—Batch treatment of the devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/20—Electrodes
- H10F77/206—Electrodes for devices having potential barriers
- H10F77/211—Electrodes for devices having potential barriers for photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/20—Electrodes
- H10F77/206—Electrodes for devices having potential barriers
- H10F77/211—Electrodes for devices having potential barriers for photovoltaic cells
- H10F77/219—Arrangements for electrodes of back-contact photovoltaic cells
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/70—Surface textures, e.g. pyramid structures
- H10F77/707—Surface textures, e.g. pyramid structures of the substrates or of layers on substrates, e.g. textured ITO layer on a glass substrate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to the field of solar cells, and more particularly to a P-type PERC double-sided solar cell, and a method for preparing the P-type PERC double-sided solar cell.
- the solar cell module using the P-type PERC double-sided solar cell adopts the above-mentioned P-type Solar system for PERC double-sided solar cells.
- a crystalline silicon solar cell is a device that effectively absorbs solar radiation energy and converts light energy into electrical energy by using a photovoltaic effect.
- a new hole-electron pair is formed, and the electric field at the PN junction Under the action, the holes flow from the N zone to the P zone, and the electrons flow from the P zone to the N zone, and a current is formed after the circuit is turned on.
- Conventional crystalline silicon solar cells basically use only front passivation technology, depositing a layer of silicon nitride on the front side of the silicon wafer by PECVD to reduce the recombination rate of the minority on the front surface, which can greatly increase the open circuit voltage and short circuit of the crystalline silicon battery. Current, thereby increasing the photoelectric conversion efficiency of the crystalline silicon solar cell. However, since the back side of the silicon wafer is not passivated, the improvement in photoelectric conversion efficiency is still limited.
- the substrate adopts an N-type silicon wafer.
- the carriers generated in the N-type silicon wafer pass through the silicon wafer having a thickness of about 200 ⁇ m, due to the N-type.
- the silicon wafer has a low lifetime and low carrier recombination rate, and some carriers can reach the front pn junction; the front side of the solar cell is the main light-receiving surface, and its conversion efficiency accounts for a high proportion of the entire battery conversion efficiency; The effect is to greatly improve the conversion efficiency of the battery.
- the price of N-type silicon wafer is high, and the process of N-type double-sided battery is complicated; therefore, how to develop high-efficiency and low-cost double-sided solar cells has become a hot spot for enterprises and researchers.
- the present invention combines a PERC high-efficiency battery and a double-sided battery to develop a double-sided PERC solar cell with higher integrated photoelectric conversion efficiency.
- the present invention aims to propose a P-type PERC double-sided solar cell with simple process, low cost, easy promotion, and high photoelectric conversion efficiency.
- the technical problem to be solved by the present invention is to provide a P-type PERC double-sided solar cell with simple structure, low cost, easy promotion, and high photoelectric conversion efficiency.
- the technical problem to be solved by the present invention is also to provide a preparation method of a P-type PERC double-sided solar cell, which has the advantages of simple process, low cost, easy promotion, and high photoelectric conversion efficiency.
- the technical problem to be solved by the present invention is also to provide a P-type PERC double-sided solar cell module, which has a simple structure, low cost, easy promotion, and high photoelectric conversion efficiency.
- the technical problem to be solved by the present invention is also to provide a P-type PERC double-sided solar energy system with simple structure, low cost, easy promotion, and high photoelectric conversion efficiency.
- the present invention provides a P-type PERC double-sided solar cell, which in turn comprises a back silver electrode, a back aluminum gate line, a back passivation layer, a P-type silicon, an N-type emitter, a front silicon nitride film. And positive silver electrodes;
- the laser grooving zone comprises a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units comprising one or more horizontally arranged laser grooving bodies, the back aluminum grid lines and the laser grooving body vertical.
- the laser grooving body is linear
- the laser grooving units are arranged in parallel;
- each laser grooving unit the laser grooving bodies are arranged side by side, and the laser grooving bodies are on the same horizontal plane or are staggered up and down.
- the distance between the laser grooving units is 0.5-50 mm.
- the spacing between the laser grooving bodies is 0.5-50 mm.
- the laser grooving body has a length of 50 to 5000 microns and a width of 10 to 500 microns.
- the number of the back aluminum grid lines is 30-500;
- the width of the back aluminum grid line is 30-500 microns, and the width of the back aluminum grid line is smaller than the length of the laser slotted body.
- the back passivation layer comprises an aluminum oxide layer and a silicon nitride layer, the aluminum oxide layer is connected to the P-type silicon, and the silicon nitride layer is connected to the aluminum oxide layer;
- the thickness of the silicon nitride layer is 20-500 nm
- the aluminum oxide layer has a thickness of 2 to 50 nm.
- the present invention also discloses a method for preparing a P-type PERC double-sided solar cell, comprising:
- laser grooving the back side of the silicon wafer to form a laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units including one or more horizontal direction settings Laser slotted body;
- the method further includes:
- the laser grooving body is linear
- the laser grooving units are arranged in parallel;
- each laser grooving unit the laser grooving bodies are arranged side by side, and the laser grooving bodies are on the same horizontal plane or are staggered up and down;
- the spacing between the laser grooving units is 0.5-50 mm.
- the spacing between the laser grooving bodies is 0.5-50 mm.
- the laser grooving body has a length of 50-5000 microns and a width of 10-500 microns;
- the number of the back aluminum grid lines is 30-500;
- the width of the back aluminum grid line is 30-500 microns, and the width of the back aluminum grid line is smaller than the length of the laser slotted body.
- the present invention also discloses a PERC solar cell module comprising a PERC solar cell and a packaging material, and the PERC solar cell is any of the P-type PERC double-sided solar cells described above.
- the present invention also discloses a PERC solar energy system comprising a PERC solar cell, which is any of the P-type PERC double-sided solar cells described above.
- the laser grooved region is formed by laser grooving on the back passivation layer, and then the aluminum paste is printed in the vertical direction along the laser scribing direction, so that the aluminum paste passes through the slotted region.
- P-type silicon Connected to P-type silicon to obtain a back aluminum gate line.
- the double-sided PERC solar cell can prepare a battery grid structure on the front and back sides of the silicon wafer, and adopts a method different from the conventional printing aluminum paste. Since the width of the aluminum grid is much smaller than the length of the laser grooved area, the aluminum paste and the aluminum paste can be omitted.
- the precise alignment of the laser grooved area simplifies the laser process and printing process, reduces the difficulty of debugging the printing equipment, and is easy to industrialize and produce.
- the laser grooved area outside the aluminum paste coverage area can increase the absorption of sunlight by the back surface of the battery and improve the photoelectric conversion efficiency of the battery. Therefore, the invention has the advantages of simple structure, simple process, low cost, easy promotion, and high photoelectric conversion efficiency.
- Figure 1 is a cross-sectional view showing a P-type PERC double-sided solar cell of the present invention
- FIG. 2 is a schematic view showing the back structure of a P-type PERC double-sided solar cell of the present invention
- FIG. 3 is a schematic view showing an embodiment of a laser grooving zone of a P-type PERC double-sided solar cell according to the present invention
- FIG. 4 is a schematic view of another embodiment of a laser grooving zone of a P-type PERC double-sided solar cell of the present invention.
- the existing single-sided solar cell has an all-aluminum back electric field on the back surface of the battery covering the entire back surface of the silicon wafer.
- the function of the all-aluminum back electric field is to increase the open circuit voltage Voc and the short-circuit current Jsc, forcing the minority carriers away from the surface. The minority carrier recombination rate is reduced, thereby improving battery efficiency as a whole.
- the all-aluminum back electric field is opaque, the back side of the solar cell having an all-aluminum back electric field cannot absorb light energy, and only the front side can absorb light energy, and the integrated photoelectric conversion efficiency of the battery is difficult to be greatly improved.
- the present invention provides a P-type PERC double-sided solar cell, which in turn includes a back silver electrode 1, a back aluminum gate line 2, a back passivation layer 3, a P-type silicon 4, and an N-type emitter. 5.
- the positive silver electrode 7 includes a positive silver electrode main gate 7A and a positive silver electrode sub-gate 7B.
- the back passivation layer 3 includes an aluminum oxide layer 31 and a silicon nitride layer 32.
- the invention improves the existing single-sided PERC solar cell, no longer has an all-aluminum back electric field, but turns it into a plurality of back aluminum grid lines 2, which are opened on the back passivation layer 3 by laser grooving technology.
- the laser grooving area 8 is printed on the parallel-arranged laser grooving area 8 so as to be in local contact with the P-type silicon 4, and the densely-arranged back aluminum grid line 2 can not only serve Increasing the open circuit voltage Voc and the short circuit current Jsc, reducing the minority carrier recombination rate, improving the photoelectric conversion efficiency of the battery, can replace the all-aluminum back electric field of the existing single-sided battery structure, and the back aluminum grid line 2 does not completely cover the silicon On the back side of the film, sunlight can be projected from the back aluminum grid line 2 into the silicon wafer, thereby realizing absorption of light energy on the back side of the silicon wafer and greatly improving the photoelectric conversion efficiency of the battery.
- the laser grooving area 8 includes a plurality of sets of laser grooving units 81 disposed in a horizontal direction, and each set of laser grooving units 81 includes one or more laser grooving bodies 82 disposed in a horizontal direction.
- the back aluminum grid line 2 is perpendicular to the laser slotted body 82.
- the dashed frame shown in Figs. 3 and 4 is a laser grooving unit 81, and each group of laser grooving units 81 includes one or more laser grooving bodies 82 disposed in a horizontal direction.
- the laser grooving unit 81 has various embodiments, including:
- Each group of laser grooving units 81 includes a laser grooving body 82 disposed in a horizontal direction. At this time, the laser grooving unit 81 is a continuous linear grooving area, as shown in FIG. A plurality of laser grooving units 81 are arranged in the vertical direction.
- Each group of laser grooving units 81 includes a plurality of laser grooving bodies 82 disposed in a horizontal direction. At this time, the laser grooving unit 81 is a line segment type non-continuous linear grooving area, as shown in FIG.
- the multiple The laser grooving body 82 may be two, three, four or more, but is not limited thereto.
- a plurality of laser grooving units 81 are arranged in the vertical direction.
- each group of laser grooving units 81 includes a plurality of laser grooving bodies 82 disposed in the horizontal direction, it is divided into the following cases:
- the width, length and shape of the plurality of horizontally arranged laser slotted bodies 82 are the same, and the dimensions are in the order of micrometers, and the length may be 50-5000 micrometers, but is not limited thereto; it should be noted that
- the laser grooving bodies may be on the same horizontal plane, or may be staggered up and down (ie not in the same horizontal plane), and the staggered distribution of the topography depends on the production needs.
- the width, length and shape of the plurality of horizontally arranged laser slotted bodies 82 are the same, and the dimensions are in the order of millimeters, and the length may be 5 to 600 millimeters, but is not limited thereto; it should be noted that
- the laser grooving bodies may be on the same horizontal plane, or may be staggered up and down (ie not in the same horizontal plane), and the staggered distribution of the topography depends on the production needs.
- the plurality of horizontally disposed laser slotted bodies 82 have different widths, lengths, and/or shapes, which can be combined in accordance with production needs. It should be noted that the laser grooving bodies may be on the same horizontal plane, or may be staggered up and down (ie, not in the same horizontal plane), and the staggered distribution of the topography depends on production needs.
- the laser slotted body is linear, which facilitates processing, simplifies the process, and reduces production costs.
- the laser grooving body may also be provided in other shapes, such as curved, curved, wavy, etc., and embodiments thereof are not limited to the embodiments of the present invention.
- the laser grooving units are arranged in parallel.
- the laser grooving bodies are arranged side by side, which can simplify the production process and is suitable for large-scale popularization and application.
- the spacing between the laser grooving units is 0.5-50 mm. In each laser grooving unit, the spacing between the laser grooving bodies is 0.5-50 mm.
- the laser slotted body 82 has a length of 50-5000 microns and a width of 10-500 microns.
- the laser grooving body 82 has a length of 250-1200 microns and a width of 30-80 microns.
- the length, width and spacing of the laser grooving unit and the number and width of the aluminum grid are optimized based on the comprehensive consideration of the contact area of the aluminum grid and the P-type silicon, the opaque area of the aluminum grid, and the full collection of electrons. It is to reduce the shading area of the back aluminum grid as much as possible, while ensuring a good current output, thereby improving the overall photoelectric conversion efficiency of the battery.
- the number of the back aluminum grid lines is 30-500, and the width of the back aluminum grid lines is 30-500 microns.
- the width of the back aluminum grid line is much smaller than the length of the laser slotted body.
- the number of the back aluminum grid lines is 80-220, and the width of the back aluminum grid lines is 50-300 microns.
- the width of the back aluminum grid line is much smaller than the length of the laser slotted body. In the case where the aluminum grid is perpendicular to the laser slotted body, the printing problem of the back aluminum grid line can be greatly facilitated. Without precise alignment, the aluminum grid can be placed in the laser slotted area, which simplifies the laser process and printing process, reduces the difficulty of debugging the printing equipment, and is easy to industrialize and produce.
- the invention forms a laser grooving zone by laser grooving of the back passivation layer, and then printing the aluminum paste in the vertical direction of the laser scribing direction, so that the aluminum paste is connected to the P-type silicon through the slotted region to obtain the back aluminum grid line.
- the PERC double-sided solar cell adopts a battery grid structure on the front and back sides of the silicon wafer, and adopts a method different from the conventional printing aluminum paste, so that precise alignment of the aluminum paste and the laser grooved area is not required, and the process is simple and easy to be industrialized. Large production.
- the aluminum grid is parallel to the laser slotted body.
- the aluminum paste and the laser slotted area need to be accurately aligned.
- the precision and repeatability of the printing equipment are very high, the yield is difficult to control, and the defective products are more, resulting in an average photoelectric conversion efficiency. Decline. With the present invention, the yield can be increased to 99.5%.
- the back passivation layer 3 includes an aluminum oxide layer 31 and a silicon nitride layer 32, the aluminum oxide layer 31 is connected to the P-type silicon 4, and the silicon nitride layer 32 is connected to the aluminum oxide layer 31;
- the silicon nitride layer 32 has a thickness of 20-500 nm
- the aluminum oxide layer 31 has a thickness of 2 to 50 nm.
- the silicon nitride layer 32 has a thickness of 100-200 nm;
- the aluminum oxide layer 31 has a thickness of 5 to 30 nm.
- the present invention also discloses a method for preparing a P-type PERC double-sided solar cell, comprising:
- the laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units comprising one or more horizontally arranged Laser slotted body;
- S106 and S104, S105 can be interchanged, and S106 can be before S104 and S105.
- the method further comprises: polishing the back surface of the silicon wafer.
- the present invention may be provided with a backside polishing step or no backside polishing step.
- the present invention also discloses a PERC solar cell module comprising a PERC solar cell and a packaging material, and the PERC solar cell is any of the P-type PERC double-sided solar cells described above.
- the PERC solar cell module the high-permeability tempered glass, the ethylene-vinyl acetate copolymer EVA, the PERC solar cell, the ethylene-vinyl acetate copolymer EVA, and the highly permeable tempered glass are sequentially connected from top to bottom. composition.
- the present invention also discloses a PERC solar energy system comprising a PERC solar cell, which is any of the P-type PERC double-sided solar cells described above.
- a PERC solar cell As a preferred embodiment of the PERC solar system, a PERC solar cell, a battery pack, a charge and discharge controller inverter, an AC power distribution cabinet, and a solar tracking control system are included.
- the PERC solar system may be provided with a battery pack, a charge and discharge controller inverter, or a battery pack or a charge and discharge controller inverter, and those skilled in the art may set according to actual needs.
- laser grooving the back side of the silicon wafer to form a laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units including one or more horizontal direction settings Laser slotted body having a length of 1000 microns and a width of 40 microns;
- the silicon wafer is sintered at a high temperature to form a back silver electrode and a positive silver electrode.
- laser grooving the back side of the silicon wafer to form a laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units including one or more horizontal direction settings Laser slotted body, the laser slotted body having a length of 500 microns and a width of 50 microns;
- the silicon wafer is sintered at a high temperature to form a back silver electrode and a positive silver electrode.
- laser grooving the back side of the silicon wafer to form a laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units including one or more horizontal direction settings Laser slotted body having a length of 300 microns and a width of 30 microns;
- the silicon wafer is sintered at a high temperature to form a back silver electrode and a positive silver electrode.
- laser grooving the back side of the silicon wafer to form a laser grooving area comprising a plurality of sets of horizontally arranged laser grooving units, each set of laser grooving units including one or more horizontal direction settings Laser slotted body, the laser slotted body having a length of 1200 microns and a width of 200 microns;
- the silicon wafer is sintered at a high temperature to form a back silver electrode and a positive silver electrode.
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Abstract
Description
Claims (10)
- 一种P型PERC双面太阳能电池,其特征在于,依次包括背银电极、背铝栅线、背面钝化层、P型硅、N型发射极、正面氮化硅膜和正银电极;对背面钝化层通过激光开槽形成激光开槽区,所述背铝栅线通过激光开槽区与P型硅相连;所述激光开槽区包括多组水平方向设置的激光开槽单元,每一组激光开槽单元包括一个或多个水平方向设置的激光开槽体,所述背铝栅线与激光开槽体垂直。
- 如权利要求1所述P型PERC双面太阳能电池,其特征在于,所述激光开槽单元之间为平行设置;每一激光开槽单元中,所述激光开槽体为并列设置,所述激光开槽体处于同一水平面上或上下错开。
- 如权利要求1所述P型PERC双面太阳能电池,其特征在于,所述激光开槽单元之间的间距为0.5-50mm;每一激光开槽单元中,所述激光开槽体之间的间距为0.5-50mm;所述激光开槽体的长度为50-5000微米,宽度为10-500微米。
- 如权利要求1所述P型PERC双面太阳能电池,其特征在于,所述背铝栅线的根数为30-500条;所述背铝栅线的宽度为30-500微米,所述背铝栅线的宽度小于所述激光开槽体的长度。
- 如权利要求1所述P型PERC双面太阳能电池,其特征在于,所述背面钝化层包括氧化铝层和氮化硅层,所述氧化铝层与P型硅连接,所述氮化硅层与氧化铝层连接;所述氮化硅层的厚度为20-500nm;所述氧化铝层的厚度为2-50nm。
- 一种如权利要求1-5任一项所述的P型PERC双面太阳能电池的制备方法,其特征在于,包括:(1)在硅片正面和背面形成绒面,所述硅片为P型硅;(2)对硅片进行扩散,形成N型发射极;(3)去除扩散过程形成的正面磷硅玻璃和周边PN结;(4)在硅片背面沉积三氧化二铝膜;(5)在硅片背面沉积氮化硅膜;(6)在硅片正面沉积氮化硅膜;(7)对硅片背面激光开槽,形成激光开槽区,所述激光开槽区包括多组水平方向设置的激光开槽单元,每一组激光开槽单元包括一个或多个水平方向设置的激光开槽体;(8)在所述硅片背面印刷背银主栅电极;(9)在所述硅片背面,沿着激光开槽的垂直方向印刷铝浆,得到背铝栅线,所述背铝栅线与激光开槽体垂直;(10)在所述硅片正面印刷正电极浆料;(11)对硅片进行高温烧结,形成背银电极和正银电极;(12)对硅片进行抗LID退火。
- 如权利要求6所述P型PERC双面太阳能电池的制备方法,其特征在于,步骤(3)和(4)之间,还包括:对硅片背面进行抛光。
- 如权利要求7所述P型PERC双面太阳能电池的制备方法,其特征在于,所述激光开槽体为直线型;所述激光开槽单元之间为平行设置;每一激光开槽单元中,所述激光开槽体为并列设置,所述激光开槽体处于同一水平面上或上下错开;所述激光开槽单元之间的间距为0.5-50mm;每一激光开槽单元中,所述激光开槽体之间的间距为0.5-50mm;所述激光开槽体的长度为50-5000微米,宽度为10-500微米;所述背铝栅线的根数为30-500条;所述背铝栅线的宽度为30-500微米,所述背铝栅线的宽度小于所述激光开槽体的长度。
- 一种PERC太阳能电池组件,其特征在于,包括PERC太阳能电池和封装材料,其特征在于,所述PERC太阳能电池是权利要求1-5任一项所述的P型PERC双面太阳能电池。
- 一种PERC太阳能系统,包括PERC太阳能电池,其特征在于,所述PERC太阳能电池是权利要求1-5任一项所述的P型PERC双面太阳能电池。
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| EP17898860.6A EP3588583A4 (en) | 2017-03-03 | 2017-06-07 | DOUBLE-SIDED P-TYPE PERC SOLAR CELL AND ASSOCIATED MODULE AND SYSTEM, AND METHOD FOR PREPARING THE SAME |
| JP2019525854A JP6741867B2 (ja) | 2017-03-03 | 2017-06-07 | P型perc両面受光型太陽電池及びそのモジュール、システム並びに製造方法 |
| US16/345,735 US20190259887A1 (en) | 2017-03-03 | 2017-06-07 | Bifacial p-type perc solar cell and module, system, and preparation method thereof |
| KR1020197012482A KR102195595B1 (ko) | 2017-03-03 | 2017-06-07 | P형 perc 양면 태양전지 및 그 모듈, 시스템과 제조방법 |
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| CN117199152A (zh) * | 2023-09-11 | 2023-12-08 | 淮安捷泰新能源科技有限公司 | 一种太阳能电池及其制备方法 |
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| CN109904249B (zh) * | 2019-01-03 | 2021-08-31 | 天津爱旭太阳能科技有限公司 | P型perc双面太阳能电池背面图形对位印刷方法、制备方法及电池 |
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Also Published As
| Publication number | Publication date |
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| KR102195595B1 (ko) | 2020-12-29 |
| CN106952972B (zh) | 2019-04-19 |
| CN106952972A (zh) | 2017-07-14 |
| US20190259887A1 (en) | 2019-08-22 |
| KR20190055834A (ko) | 2019-05-23 |
| EP3588583A1 (en) | 2020-01-01 |
| JP2020506528A (ja) | 2020-02-27 |
| JP6741867B2 (ja) | 2020-08-19 |
| EP3588583A4 (en) | 2020-12-09 |
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