WO2019042313A1 - 一种低摩擦系数和低波纹度的金属薄板 - Google Patents
一种低摩擦系数和低波纹度的金属薄板 Download PDFInfo
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- WO2019042313A1 WO2019042313A1 PCT/CN2018/102932 CN2018102932W WO2019042313A1 WO 2019042313 A1 WO2019042313 A1 WO 2019042313A1 CN 2018102932 W CN2018102932 W CN 2018102932W WO 2019042313 A1 WO2019042313 A1 WO 2019042313A1
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- Prior art keywords
- pits
- metal sheet
- low
- waviness
- friction
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/227—Surface roughening or texturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/26—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16S—CONSTRUCTIONAL ELEMENTS IN GENERAL; STRUCTURES BUILT-UP FROM SUCH ELEMENTS, IN GENERAL
- F16S1/00—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16S—CONSTRUCTIONAL ELEMENTS IN GENERAL; STRUCTURES BUILT-UP FROM SUCH ELEMENTS, IN GENERAL
- F16S1/00—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members
- F16S1/04—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members produced by deforming or otherwise working a flat sheet
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16S—CONSTRUCTIONAL ELEMENTS IN GENERAL; STRUCTURES BUILT-UP FROM SUCH ELEMENTS, IN GENERAL
- F16S1/00—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members
- F16S1/04—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members produced by deforming or otherwise working a flat sheet
- F16S1/06—Sheets, panels, or other members of similar proportions; Constructions comprising assemblies of such members produced by deforming or otherwise working a flat sheet by deforming only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2261/00—Product parameters
- B21B2261/14—Roughness
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12993—Surface feature [e.g., rough, mirror]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
Definitions
- the present invention relates to a metal sheet, and more particularly to a metal sheet having a low coefficient of friction and a low waviness.
- the frictional property between the material and the mold significantly affects the metal flow of the material during the forming process, which further affects the stamping forming property of the material.
- the surface roughness of the material can also effectively improve the friction between the material and the mold.
- the principle is material.
- the microstructure of the surface can store lubricating oil, so that an oil film can be maintained at the contact interface between the mold and the material during stamping to improve the lubrication effect. Therefore, in order to obtain a good lubricating effect, it is required that the surface of the material has a relatively reasonable microstructure, which can well store the lubricating oil and ensure a relatively stable oil film during the stamping process.
- the publication number is CN103769431A, and the publication date is May 7, 2014.
- the Chinese patent document entitled "Production Method of Automobile Exterior Panel” discloses a production method of an automobile outer panel.
- the technical solution disclosed in the patent document is mainly for manufacturing a low-wobble hot-dip galvanized automobile outer panel, which adjusts the roughness of the steel sheet in each process by adjusting the roughness of the rolls in different processes, and finally ensures the finished steel plate. Has a certain roughness and a low waviness.
- the technical solution disclosed in the patent document mainly optimizes and improves the matching roller process in the rolling flattening process, and achieves the purpose of improving the surface coating effect of the steel plate, and does not involve specific optimization and improvement of the microscopic surface structure.
- the publication number is CN104884180A, and the publication date is September 2, 2015.
- the Chinese patent entitled "Plate product made of sheet metal, especially steel, the use of the flat product, the roll, and the method for producing the flat product” The literature relates to flat products made of sheet metal, in particular steel, to advantageous uses and to rolls which are particularly suitable for the manufacture of such flat products, and to methods for producing such flat products.
- a metal sheet having a surface texture and a specific texture and a manufacturing process thereof are disclosed, and the topography on the sheet has a double I shape, an H shape, a cross shape, and a C shape.
- the technical problem to be solved by the present invention is to provide a metal foil having a low coefficient of friction and a low waviness which can improve the forming and painting properties of the material.
- a metal sheet having a low friction coefficient and a low waviness the surface of the metal sheet being provided with a plurality of circular or substantially circular micro-pits, each of the pits having a diameter of 30 to 150 ⁇ m and adjacent pits
- the amount of overlap is less than 10%; the ratio of the surface area occupied by the pits per square millimeter of the surface of the metal sheet on which the pit is located is greater than 30%, and the difference in the number of pits in the square of any square millimeter of the surface is less than 20%.
- the surface microstructure is designed as a large number of tiny pits in order to form a "small oil groove" on the surface of the material for storing lubricating oil and improving the stamping forming property of the material; and the overlap between the pits is designed as Less than 10% is to enable the dimples to form "small oil grooves" independent of each other to lock the lubricating oil, and to prevent the lubricating oil from flowing between the dimples to reduce the lubricating effect.
- the shape of the pit is designed to be circular or nearly circular, on the one hand, it can avoid the directional difference of the surface microstructure of the material, on the other hand, it is beneficial to maintain the relative independence between the pit and the pit; the diameter of the pit It is limited to 30-150 ⁇ m because when the pit diameter is less than 30 ⁇ m, the lubricating oil does not easily enter the pit, and the manufacturing difficulty is increased. When the pit diameter is larger than 150 ⁇ m, the surface microstructure is too coarse. It will reduce the adhesion of the paint film, and at the same time, the microstructure of the paint film will not be completely covered by the paint film, resulting in a decrease in paint performance.
- the ratio of the area occupied by the pits per square millimeter is limited to more than 30% because if the proportion of the occupied area is less than 30%, the number of pits is too small, and the pit distribution is too sparse, which may result in the surface of the material.
- the oil storage performance is insufficient and the adhesion between the paint film and the material is lowered.
- the difference in the number of pits per square millimeter is designed to be less than 20% because the difference in the number of pits per unit area is larger, the uniformity of the surface microstructure is worse, the waviness of the surface of the material is increased, and the painted surface is painted. The effect is also worse;
- the one side or both side surfaces of the metal thin plate are provided with the pits.
- the amount of overlap between adjacent pits is less than 5%.
- the amount of overlap between adjacent pits is preferably zero.
- the proportion of the surface area occupied by the pits per square millimeter of the surface of the metal sheet on which the pit is located is greater than 50%.
- the difference in the number of pits in the square of any unit square mm of the surface of the metal sheet on which the pit is located is less than 10%.
- the difference in the number of pits in the square of any unit square mm of the surface of the metal sheet on which the pit is located is less than 5%.
- the metal foil with low friction coefficient and low waviness adopting the above technical solution can effectively reduce the friction coefficient and the waviness by improving the surface microstructure reasonably, thereby improving the forming and painting performance of the material.
- Figure 1 is a view showing the surface microstructure of the metal thin plate in Embodiment 1 of the present invention.
- Figure 2 is a view showing the surface microstructure of the metal thin plate in Embodiment 2 of the present invention.
- Figure 3 is a view showing the surface microstructure of the metal thin plate in Embodiment 3 of the present invention.
- Figure 4 is a view showing the surface microstructure of the metal thin plate in Comparative Example 1 of the present invention.
- Figure 5 is a view showing the surface microstructure of the metal thin plate in Comparative Example 2 of the present invention.
- Figure 6 is a view showing the surface microstructure of the metal thin plate in Comparative Example 3 of the present invention.
- Figure 7 is a view showing the structure of a drawbead tester for measuring the coefficient of friction
- Fig. 7 The meanings of the reference numerals in Fig. 7 are: 1-upper head, 2-drawing arm, 3-lower head, 4-sample.
- the present invention proposes a metal sheet having a low friction coefficient and a low waviness, and the surface microstructure of the metal sheet has the following characteristics:
- the surface microstructure consists of a large number of tiny pits; the overlap between adjacent pits is less than 10%; the shape of the pits is circular or approximately circular, and the diameter is 30-150 ⁇ m; the pits per square millimeter The proportion of occupied area is greater than 30%; the difference in the number of pits in any square mm of the sheet is less than 20%.
- Examples 1-3 are hot-dip galvanized steel sheets having a surface microstructure having the technical features of the present invention
- Comparative Examples 1-3 are hot-dip galvanized steel sheets having ordinary surfaces
- specific surface microstructure parameters of the respective examples and comparative examples are shown in the following table. 1, in which the comparative example is randomly undulating due to its microscopic structure, it is difficult to accurately distinguish the convex and concave pits, so it is difficult to count the pit diameter, the number of pits and the proportion of the pit area, wherein Figures 1-6 correspond to the implementation Surface microstructures of Examples 1-3 and Comparative Examples 1-3.
- Examples 1 to 3 and Comparative Examples 1 to 3 were tested according to the measurement standard ISO 4287:1997.
- the filter was Gaussian filtered, wherein the sampling length of the roughness Ra was 0.8 mm, and the sampling length of the waviness Wa was 40mm, filter interval 0.8 ⁇ 8mm.
- the friction coefficients of Examples 1 to 3 and Comparative Examples 1 to 3 were measured and compared using the drawbead tester shown in Fig. 7.
- Example 1 Example 2
- Example 3 Comparative example 1 Comparative example 2 Comparative example 3
- Roughness 1.02 ⁇ m 1.06 ⁇ m 0.98 ⁇ m 1.03 ⁇ m 1.02 ⁇ m 0.96 ⁇ m Waviness 0.183 ⁇ m 0.193 ⁇ m 0.211 ⁇ m 0.246 ⁇ m 0.235 ⁇ m 0.251 ⁇ m
- Coefficient of friction 0.119 0.112 0.121 0.130 0.127 0.132
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Metal Rolling (AREA)
- Coating With Molten Metal (AREA)
Abstract
Description
| 微观结构 | 凹坑形状 | 凹坑直径 | 凹坑面积占比 | 凹坑数量 | |
| 实施例1 | 散布凹坑 | 圆形 | 约80μm | 60% | 130个/mm 2 |
| 实施例2 | 散布凹坑 | 圆形 | 约100μm | 62% | 110个/mm 2 |
| 实施例3 | 散布凹坑 | 圆形 | 约100μm | 71% | 90个/mm 2 |
| 对比例1 | 随机起伏 | 不规则 | - | - | - |
| 对比例2 | 随机起伏 | 不规则 | - | - | - |
| 对比例3 | 随机起伏 | 不规则 | - | - | - |
| 实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | 对比例3 | |
| 粗糙度 | 1.02μm | 1.06μm | 0.98μm | 1.03μm | 1.02μm | 0.96μm |
| 波纹度 | 0.183μm | 0.193μm | 0.211μm | 0.246μm | 0.235μm | 0.251μm |
| 摩擦系数 | 0.119 | 0.112 | 0.121 | 0.130 | 0.127 | 0.132 |
Claims (7)
- 一种低摩擦系数和低波纹度的金属薄板,其特征在于,该金属薄板的表面布设有多个圆形或大致为圆形的凹坑,单个所述凹坑的直径为30~150μm,相邻凹坑间的重叠量小于10%;凹坑所处的金属薄板表面每平方毫米内凹坑所占据该表面表面积的比例大于30%,并且该表面任意单位平方毫米内的凹坑数量差异小于20%。
- 根据权利要求1所述低摩擦系数和低波纹度的金属薄板,其特征在于,所述金属薄板的单侧或两侧表面布设有所述凹坑。
- 根据权利要求1所述低摩擦系数和低波纹度的金属薄板,其特征在于,相邻凹坑间的重叠量小于5%。
- 根据权利要求1或3所述低摩擦系数和低波纹度的金属薄板,其特征在于,相邻凹坑间的重叠量为0。
- 根据权利要求1所述低摩擦系数和低波纹度的金属薄板,其特征在于,凹坑所处的金属薄板表面每平方毫米内凹坑所占据该表面表面积的比例大于50%。
- 根据权利要求1所述低摩擦系数和低波纹度的金属薄板,其特征在于,凹坑所处的金属薄板表面任意单位平方毫米内的凹坑数量差异小于10%。
- 根据权利要求6所述低摩擦系数和低波纹度的金属薄板,其特征在于,凹坑所处的金属薄板表面任意单位平方毫米内的凹坑数量差异小于5%。
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18850306.4A EP3677352B1 (en) | 2017-08-29 | 2018-08-29 | Metal sheet having low friction coefficient and low waviness |
| US16/635,850 US11559829B2 (en) | 2017-08-29 | 2018-08-29 | Metal sheet having low friction coefficient and low waviness |
| JP2020505155A JP2020528827A (ja) | 2017-08-29 | 2018-08-29 | 低摩擦係数・低うねりの金属薄板 |
| KR1020197036036A KR20200004863A (ko) | 2017-08-29 | 2018-08-29 | 낮은 마찰 계수 및 낮은 파상도를 가지는 금속 시트 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710758710.4 | 2017-08-29 | ||
| CN201710758710.4A CN109424844B (zh) | 2017-08-29 | 2017-08-29 | 一种低摩擦系数和低波纹度的金属薄板 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2019042313A1 true WO2019042313A1 (zh) | 2019-03-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2018/102932 Ceased WO2019042313A1 (zh) | 2017-08-29 | 2018-08-29 | 一种低摩擦系数和低波纹度的金属薄板 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11559829B2 (zh) |
| EP (1) | EP3677352B1 (zh) |
| JP (1) | JP2020528827A (zh) |
| KR (1) | KR20200004863A (zh) |
| CN (1) | CN109424844B (zh) |
| WO (1) | WO2019042313A1 (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111197145B (zh) * | 2018-11-16 | 2021-12-28 | 通用汽车环球科技运作有限责任公司 | 钢合金工件和用于制造压制硬化钢合金部件的方法 |
| CN116543384B (zh) * | 2023-04-07 | 2024-05-31 | 中国人民解放军陆军装甲兵学院 | 预测材料表面滚动角的方法和装置及存储介质和检测系统 |
| JP7816311B2 (ja) * | 2023-08-17 | 2026-02-18 | Jfeスチール株式会社 | 鋼板の表面処理方法、鋼板の製造方法、及びプレス成形品の製造方法 |
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| BE1004324A6 (fr) * | 1989-07-31 | 1992-11-03 | Centre Rech Metallurgique | Tole d'emboutissage en acier, pourvue d'un revetement metallique, et procede de fabrication d'une telle tole. |
| JPH04200902A (ja) * | 1990-11-30 | 1992-07-21 | Kawasaki Steel Corp | 塗膜鮮映性とプレス成形性に優れた金属板およびその製造方法 |
| CA2126458A1 (en) * | 1991-12-25 | 1993-07-08 | Tetsuya Nishiura | Steel sheet excellent in coating sharpness, defect-formation resistance and workability |
| JP2530969B2 (ja) * | 1992-03-25 | 1996-09-04 | 新日本製鐵株式会社 | 塗装鮮映性及びプレス成形性の優れた鋼帯 |
| JP2530968B2 (ja) * | 1992-03-25 | 1996-09-04 | 新日本製鐵株式会社 | 塗装鮮映性及びプレス成形性の優れた鋼帯 |
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| KR101568525B1 (ko) * | 2013-12-24 | 2015-11-11 | 주식회사 포스코 | 가공성이 우수한 아연도금강판 및 그 제조방법 |
| CN105798061B (zh) * | 2016-03-23 | 2018-03-16 | 天津炬坤金属科技有限公司 | 一种0.05~0.1mm超薄精密中宽镜面光马口铁基板冷轧方法 |
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- 2017-08-29 CN CN201710758710.4A patent/CN109424844B/zh active Active
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- 2018-08-29 JP JP2020505155A patent/JP2020528827A/ja active Pending
- 2018-08-29 US US16/635,850 patent/US11559829B2/en active Active
- 2018-08-29 EP EP18850306.4A patent/EP3677352B1/en active Active
- 2018-08-29 KR KR1020197036036A patent/KR20200004863A/ko not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| US20200368798A1 (en) | 2020-11-26 |
| CN109424844A (zh) | 2019-03-05 |
| EP3677352A4 (en) | 2021-06-09 |
| EP3677352A1 (en) | 2020-07-08 |
| JP2020528827A (ja) | 2020-10-01 |
| US11559829B2 (en) | 2023-01-24 |
| CN109424844B (zh) | 2021-10-19 |
| KR20200004863A (ko) | 2020-01-14 |
| EP3677352B1 (en) | 2023-01-25 |
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