WO2020194938A1 - 電源装置と電動車両 - Google Patents
電源装置と電動車両 Download PDFInfo
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- WO2020194938A1 WO2020194938A1 PCT/JP2019/050063 JP2019050063W WO2020194938A1 WO 2020194938 A1 WO2020194938 A1 WO 2020194938A1 JP 2019050063 W JP2019050063 W JP 2019050063W WO 2020194938 A1 WO2020194938 A1 WO 2020194938A1
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- Prior art keywords
- rubber
- power supply
- supply device
- laminated
- sheet
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/658—Means for temperature control structurally associated with the cells by thermal insulation or shielding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
- H01M10/625—Vehicles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/64—Heating or cooling; Temperature control characterised by the shape of the cells
- H01M10/647—Prismatic or flat cells, e.g. pouch cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/209—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for prismatic or rectangular cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/262—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders with fastening means, e.g. locks
- H01M50/264—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders with fastening means, e.g. locks for cells or batteries, e.g. straps, tie rods or peripheral frames
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
- H01M50/291—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by their shape
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
- H01M50/293—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a power supply device in which a large number of battery cells are stacked and an electric vehicle equipped with this power supply device.
- a power supply that stacks a large number of battery cells is a power supply that is mounted on an electric vehicle and supplies power to the motor that runs the vehicle, a power supply that is charged with natural energy such as solar cells or midnight power, and a backup power supply for power outages. Suitable for.
- a separator is sandwiched between the stacked battery cells. The separator insulates the heat conduction between the battery cells and suppresses the induction of thermal runaway of the battery cells. Thermal runaway of a battery cell occurs due to an internal short circuit caused by a short circuit between the positive electrode and the negative electrode inside, or an incorrect handling. When a battery cell undergoes thermal runaway, a large amount of heat is generated.
- the battery cells expand and the separator is pressed with a strong pressure while being charged and discharged, but this state causes the silica airgel to be destroyed and the heat insulating properties to deteriorate.
- the stacked battery cells are fixed in a pressurized state in order to prevent misalignment due to expansion of the battery cells.
- the power supply device arranges a pair of end plates on both end surfaces of a battery block in which a large number of battery cells are stacked, and connects the pair of end plates with a bind bar.
- the bind bar and end plate hold the battery cell in a pressurized state with a considerably strong pressure to prevent malfunction due to relative movement and vibration of the battery cell. Therefore, for example, in a power supply device for stacking battery cells having a laminated surface area of about 100 square centimeters, the end plate is pressed with a strong force of several tons and fixed with a bind bar.
- Separators having a structure that suppresses deterioration of heat insulating properties by being sandwiched between pressurized battery cells have been developed. (See Patent Document 1)
- the separator of Patent Document 1 has a composite layer containing a fiber sheet and silica airgel, and the fiber sheets are folded back and laminated to form a multi-layer structure, which is pressurized to prevent the silica airgel from being destroyed. Since the separator having this structure is folded and laminated, it has a drawback that the whole becomes thick, and further, the internal structure becomes non-uniform between the folded portion and the laminated portion of the fiber sheet, and the pressing surface with the battery cell. There is a drawback that it is difficult to make the pressure difference in the above uniform.
- the separator becomes thick, the battery block in which the battery cells are stacked becomes long and large, and the separator that cannot support the pressing surface of the battery cells by evenly pressing the pressing surface adversely affects the electrodes of the battery cells. Furthermore, since the separator made of a composite layer of fiber sheet and silica airgel cannot absorb the expansion of the battery cell, the pressure of the battery cell rises sharply when the battery cell expands, and an extremely strong force acts on the end plate and bind bar. To do. Therefore, the end plate and the bind bar are required to have an extremely tough material and structure, and the power supply device is heavy and large, and the material cost is high.
- the present invention has been developed for the purpose of eliminating the above drawbacks, and one of the purposes of the present invention is to absorb the expansion of the battery cell with the separator so that the heat insulating property of the separator due to the expansion of the battery cell can be improved. It is an object of the present invention to provide a technique capable of suppressing a decrease and further reducing the expansion of a battery cell and an excessive force acting on an end plate or a bind bar.
- the power supply device includes a battery block 10 in which a plurality of battery cells 1 are laminated in the thickness direction with a separator 2 interposed therebetween, and a pair of end plates arranged on both end surfaces of the battery block 10. 3 and a bind bar 4 which is connected to a pair of end plates 3 and fixes the battery block 10 in a pressurized state via the end plates 3.
- the separator 2 includes a heat insulating sheet 5 made of a fiber sheet and silica airgel, and a rubber-like elastic sheet 6 laminated on the surface of the heat insulating sheet 5. Further, the separator 2 is provided with a laminated region 2A in which the rubber-like elastic sheet 6 is laminated and a non-laminated region 2B in which the rubber-like elastic sheet 6 is not laminated.
- the electric vehicle includes the power supply device 100, a traveling motor 93 to which electric power is supplied from the power supply device 100, a vehicle body 91 including the power supply device 100 and the motor 93, and a motor 93. It is equipped with wheels 97 that are driven by the vehicle and run the vehicle body 91.
- the expansion of the battery cell is absorbed by the separator to prevent the insulation property of the separator from being deteriorated due to the expansion of the battery cell, and the battery cell is further expanded to cause excessive stress on the end plate and the bind bar. It has the characteristic of being able to reduce its action.
- FIG. 1 It is a perspective view of the power supply device which concerns on one Embodiment of this invention. It is a vertical sectional view of the power supply device shown in FIG. It is a horizontal sectional view of the power supply device shown in FIG. It is a perspective view of a separator. It is an enlarged sectional view of the main part of a separator. It is a partially enlarged sectional view which shows another example of a separator. It is a block diagram which shows an example which mounts a power supply device in a hybrid vehicle which runs by an engine and a motor. It is a block diagram which shows the example which mounts the power-source device on the electric vehicle which runs only by a motor.
- the power supply device includes a battery block in which a plurality of battery cells are laminated in the thickness direction with a separator interposed therebetween, and a pair of end plates arranged on both end surfaces of the battery block. It includes a bind bar that is connected to a pair of end plates and fixes the battery block in a pressurized state via the end plates.
- the separator is a rubber-like elastic sheet laminated on the surface of a heat insulating sheet made of a fiber sheet and silica airgel.
- the separator is divided into a laminated region in which the rubber-like elastic sheet is laminated and a non-laminated region in which the rubber-like elastic sheet is not laminated, without laminating the rubber-like elastic sheet on the entire surface of the heat insulating sheet. ..
- the separator laminated between the battery cells is provided with a rubber-like elastic sheet on the surface of the heat insulating sheet, which is thinly deformed when pressed, so that the battery cells expand and become rubber-like. Pressurizing the elastic sheet thins the separator. Therefore, it is possible to prevent the battery cell from expanding and increasing the surface pressure between the battery cell and the separator.
- the heat insulating sheet composed of fiber sheet and silica airgel exhibits excellent heat insulating properties due to the extremely low thermal conductivity of fine inorganic grain silica airgel, but it is pressurized because the fiber gap is filled with silica airgel of inorganic fluid. Even if it is done, the thickness does not change.
- silica airgel is a fine particle composed of a skeleton of silicon dioxide (SiO 2 ) and 90% to 98% of air, and is destroyed when a strong compressive stress is applied to reduce the thermal conductivity.
- the rubber-like elastic sheet laminated on the surface of the heat insulating sheet is thinly deformed by the pressure of the battery cell, so that the compressive stress of the silica airgel that increases due to the expansion of the battery cell is reduced.
- the expanding battery cell pressurizes the heat insulating sheet to prevent the silica airgel from being destroyed, and maintains the excellent heat insulating properties of the heat insulating sheet.
- a separator that maintains excellent thermal insulation properties even when the battery cell is inflated keeps adjacent battery cells in excellent thermal insulation for a long period of time, preventing thermal runaway of the battery cell from being induced next to it. As a result, the safety of the power supply device is guaranteed for a long period of time.
- the rubber-like elastic sheet laminated on the heat insulating sheet is thinly deformed to reduce the internal stress of the heat insulating sheet. There is no need to have a special structure that deforms. Therefore, while using a heat insulating sheet that is not crushed by pressure, it is possible to suppress deterioration of heat insulating properties due to destruction of silica airgel.
- the rubber-like elastic sheet provided on the separator becomes thin due to the expansion of the battery cell, it is possible to suppress the expansion of the battery cell and the increase in pressure. Therefore, it is possible to suppress the expansion of the battery cell and increase the stress of the end plate and the bind bar, and reduce the maximum stress. This is effective in making the end plate and bind bar thinner and lighter.
- the rubber-like elastic sheet is thinly deformed by the expansion of the battery cell, it is possible to suppress the expansion of the battery cell and the relative position shift.
- the relative misalignment of adjacent battery cells causes damage to the bus bar of the metal plate fixed to the electrode terminals of the battery cells and the electrode terminals.
- a power supply device capable of preventing the relative misalignment of the battery cell in which the rubber-like elastic sheet expands can prevent a failure of the connection portion between the electrode terminal and the bus bar due to the expansion of the battery cell.
- the rubber-like elastic sheet is laminated only in the laminated region without laminating the rubber-like elastic sheet on the entire surface of the separator, and the rubber-like elastic sheet is not laminated in the non-laminated region.
- the rubber-like elastic sheet does not adhere to the entire surface of the battery cell, the battery cell expands to the non-laminated region and suppresses the pressure increase between the battery cell and the separator.
- the added value of the pressing force in both the stacked region and the non-stacked region acts on the end plate, but the pressure can be reduced in the non-stacked region while the battery cells are inflated.
- the device can reduce the pressure exerted by the battery block on the end plate to reduce the maximum stress acting on the end plate and busbar. Further, the overall pressing force of the battery cell stressing the separator is also reduced, and there is also a feature that the battery cell can be suppressed from being displaced due to an increase in the pressing force.
- the separator by providing the separator with a non-laminated region, the maximum stress of the end plate and the bind bar at the time of battery cell expansion can be reduced, and in addition, the battery at the boundary between the laminated region and the non-laminated region. Mitigates changes in cell pressure. It is an extremely important characteristic that the battery cell expands to prevent damage to the battery cell from the viewpoint of ensuring high safety in the power supply device.
- the separator provided with the laminated region and the non-laminated region has a step in thickness at the boundary between the laminated region and the non-laminated region.
- This separator strongly pressurizes the surface of the battery cell in the laminated region, the pressure drops in the non-laminated region, and the pressure suddenly changes at the boundary between the laminated region and the non-laminated region.
- This state gives a mechanical load to the electrodes inside the battery.
- the positive and negative electrodes of the battery electrodes are locally damaged by a local mechanical load, causing an internal short circuit.
- An internal short circuit of a battery causes an excessive short-circuit current to cause thermal runaway, and further, when a battery cell undergoes thermal runaway, excessive thermal energy is generated, which impairs safety.
- the rubber-like elastic sheet 6 laminated therein is thinly compressed. It moves from the laminated region 2A toward the non-laminated region 2B. Since the rubber-like elastic sheet 6 has incompressibility that is compressed and the volume hardly changes, when the rubber-like elastic sheet 6 in the laminated region 2A is thinly compressed, it protrudes from the laminated region 2A and heads toward the non-laminated region 2B. And move.
- the rubber-like elastic sheet that moves to the non-laminated region alleviates the change in pressure at the boundary between the laminated region and the non-laminated region.
- a power supply that can expand the battery cell and alleviate the pressure change on the surface of the battery cell at the boundary between the laminated region and the non-laminated region reduces the mechanical load on the electrode of the battery cell and prevents the electrode from being damaged. It realizes a feature that can significantly improve safety by preventing thermal runaway of the battery that occurs when the electrodes are damaged.
- the battery cell is a square battery cell
- the separator has a laminated region at the outer peripheral portion of the heat insulating sheet and a non-laminated region at the center of the heat insulating sheet.
- the battery cell is a square battery cell, and the pressure of the battery cell can be reduced in the non-stacked region, and the battery cell pressurizes the separator to apply a mechanical load to the electrode at the boundary between the outer peripheral portion and the inner peripheral portion. You can reduce the amount you give.
- a non-laminated region can be provided in the center of the square battery cell to reduce the pressure in this region and reduce the stress acting on the end plate and the bus bar.
- rubber-like elastic sheets are laminated on both sides of the heat insulating sheet to absorb the expansion of the battery cell on both sides of the separator, and a thin rubber-like elastic sheet is formed on the surface of the heat insulating sheet. Can be laminated to equalize the pressure on both sides of the battery cell and achieve high safety.
- the power supply device has a structure in which the separator is laminated with a rubber-like elastic sheet only on one side of the heat insulating sheet.
- the expansion of the battery cells laminated on both sides of the separator can be absorbed by the rubber-like elastic sheet laminated on one side of the heat insulating sheet while reducing the manufacturing cost by thinning the separator.
- the rubber-like elastic sheet of the separator can be a non-foamed rubber-like elastic body or a closed-cell foam.
- the rubber-like elastic sheet is a non-foaming rubber-like elastic body or a closed-cell foam, it is excellent in incompressibility that is compressed and the volume hardly changes, so that it is compressed when the battery cell is expanded. Efficiently moves from the laminated region to the non-laminated region, more effectively mitigates the pressure change between the laminated region and the non-laminated region, and prevents thermal runaway due to the mechanical load of the battery cell electrode for safety. There is a feature that can be made even higher.
- the rubber-like elastic sheet is a synthetic rubber sheet.
- the power supply device of the seventh embodiment of the present invention uses synthetic rubber as isoprene rubber, styrene butadiene rubber, butadiene rubber, chloropron rubber, nitrile rubber, horiisobutylene rubber, ethylene propylene rubber, and ethylene vinyl acetate copolymer. Any of rubber, chlorosulfonated polyethylene rubber, acrylic rubber, fluororubber, epichlorohydrin rubber, urethane rubber, silicone rubber, thermoplastic olefin rubber, ethylenepropylene diene rubber, butyl rubber, and polyether rubber.
- the heat-resistant temperature of ethylene-vinyl acetate copolymer rubber of rubber-like elastic sheet is as high as 200 ° C, that of acrylic rubber is as high as 180 ° C, that of fluororubber is as high as 300 ° C, and that of silicone rubber is as high as 280 ° C. it can.
- the thickness of the rubber-like elastic sheet is 0.2 mm or more and 2 mm or less.
- the heat insulating sheet is made thicker than the rubber-like elastic sheet. In this power supply device, the heat insulating property of the separator can be improved by a thick heat insulating sheet, and the induction of thermal runaway of the battery cell can be effectively suppressed.
- the thickness of the heat insulating sheet is 0.5 mm or more and 2 mm or less.
- all the separators laminated between the battery cells are laminated with a rubber-like elastic sheet on the surface of the heat insulating sheet.
- the pressure of all the battery cells can be equalized.
- the power supply device 100 shown in the perspective view of FIG. 1, the vertical sectional view of FIG. 2, and the horizontal sectional view of FIG. 3 includes a battery block 10 in which a plurality of battery cells 1 are laminated in the thickness direction with a separator 2 interposed therebetween.
- the battery cell 1 of the battery block 10 is a square battery cell having a quadrangular outer shape, and a pair of positive and negative electrode terminals 12 are provided on both ends of an upper surface so as to project upward.
- a safety valve (not shown) is provided between the electrode terminals 12. The safety valve opens when the internal pressure of the battery cell 1 rises above a predetermined value to release the gas inside. The safety valve prevents the internal pressure of the battery cell 1 from rising.
- the battery cell 1 is a lithium ion secondary battery.
- the power supply device 100 in which the battery cell 1 is a lithium ion secondary battery has a feature that the charging capacity with respect to the capacity and weight can be increased.
- the battery cell 1 can be any other rechargeable battery such as a non-aqueous electrolyte secondary battery other than the lithium ion secondary battery.
- End plate 3 is a metal plate having an outer shape substantially equal to the outer shape of the battery cell 1 that is not deformed by being pressed by the battery block 10, and bind bars 4 are connected to both side edges.
- the bind bar 4 connects the battery cells 1 in which the end plates 3 are laminated in a pressurized state, and fixes the battery block 10 in the pressurized state at a predetermined pressure.
- the separator 2 is sandwiched between the stacked battery cells 1 to insulate the adjacent battery cells 1, further block heat conduction between the batteries, and further absorb the expansion of the battery cells 1.
- a bus bar (not shown) is fixed to an electrode terminal 12 of an adjacent battery cell 1, and the battery cells 1 are connected in series or in parallel. Since a potential difference is generated in the battery case of the battery cells 1 connected in series, they are insulated by the separator 2 and laminated. The battery cells 1 connected in parallel do not generate a potential difference in the battery case, but are insulated and laminated with a separator 2 in order to prevent the induction of thermal runaway.
- the separator 2 has a rubber-like elastic sheet 6 laminated on the surface of the heat insulating sheet 5.
- the heat insulating sheet 5 is composed of a fiber sheet and silica airgel.
- the heat insulating sheet 5 is filled with silica airgel having an extremely low thermal conductivity in the gaps between the fibers.
- the rubber-like elastic sheet 6 is a sheet that is thinly elastically deformed under pressure. The thickness of the rubber-like elastic sheet 6 elastically changes with pressure to absorb the expansion and contraction of the battery cell 1 and prevent the heat insulating sheet 5 from deteriorating.
- the heat insulating sheet 5 of silica airgel deteriorates its heat insulating properties when the fragile silica airgel is compressed and destroyed.
- the rubber-like elastic sheet 6 reduces the compressive stress of the silica airgel during expansion of the battery cell 1 to prevent destruction, guarantees the excellent heat insulating properties of the heat insulating sheet 5 for a long period of time, and causes thermal runaway of the battery cell 1. And prevent the induction of thermal runaway.
- the heat insulating sheet 5 is composed of a fiber sheet and silica airgel having a nano-sized porous structure.
- the heat insulating sheet 5 is manufactured by impregnating fibers with a gel raw material of silica airgel. After impregnating a fiber sheet with silica airgel, the fibers are laminated, and the gel raw materials are reacted to form a wet gel, and the surface of the wet gel is hydrophobized and dried with hot air.
- the fibers of the fiber sheet are polyethylene terephthalate (PET). However, as the fibers of the fiber sheet, inorganic fibers such as flame-retardant acrylic oxide fibers and glass wool can also be used.
- the fiber sheet of the heat insulating sheet 5 preferably has a fiber diameter of 0.1 to 30 ⁇ m.
- the fiber diameter of the fiber sheet can be made smaller than 30 ⁇ m, the heat conduction by the fibers can be reduced, and the heat insulating characteristics of the heat insulating sheet 5 can be improved.
- Silica airgel is an inorganic fine particle composed of 90% to 98% of air, and has micropores between skeletons formed by clusters of nano-order spheres, and has three-dimensional fine porosity. It has a structure.
- the heat insulating sheet 5 made of a fiber sheet and silica airgel is thin and exhibits excellent heat insulating properties.
- the heat insulating sheet 5 is set to a thickness capable of preventing the induction of thermal runaway of the battery cell 1 in consideration of the energy generated by the battery cell 1 due to thermal runaway.
- the energy generated by thermal runaway of the battery cell 1 increases as the charging capacity of the battery cell 1 increases. Therefore, the thickness of the heat insulating sheet 5 is set to an optimum value in consideration of the charging capacity of the battery cell 1.
- the thickness of the heat insulating sheet 5 is 0.5 mm to 2 mm, and optimally about 1 mm to 1.5 mm.
- the present invention does not specify the thickness of the elastic sheet in the above range, and the thickness of the heat insulating sheet 5 is determined by the heat insulating characteristics of thermal runaway composed of the fiber sheet and silica airgel and the thermal runaway of the battery cell 1. It is set to the optimum value in consideration of the heat insulating properties required to prevent induction.
- the separator 2 has a rubber-like elastic sheet 6 laminated on the surface of the heat insulating sheet 5.
- the thick separator 2 is laminated between the battery cells 1 to enlarge the battery block 10. Since the battery block 10 is required to be miniaturized, the separator 2 is required to be as thin as possible to have heat insulating properties. This is because the power supply device 100 is required to increase the charging capacity with respect to the volume. In the power supply device 100, in order to reduce the size of the battery block 10 and increase the charging capacity, the separator 2 is thinned with a rubber-like elastic sheet 6 and a heat insulating sheet 5 to prevent the induction of thermal runaway of the battery cell 1. That is important.
- the rubber-like elastic sheet 6 is set to, for example, 0.2 mm or more and 2 mm or less, more preferably 0.3 mm to 1 mm or less, and suppresses an increase in compressive stress due to expansion of the battery cell 1. Further, the rubber-like elastic sheet 6 is preferably thinner than the heat insulating sheet 5, while reducing the compressive stress during expansion of the battery cell 1.
- the rubber-like elastic sheet 6 is a non-foamed rubber-like elastic body or a closed-cell foam rubber.
- the rubber-like elastic sheet 6 has a shape at the boundary between the laminated region and the non-laminated region by extruding the rubber compressed in the laminated region into the non-laminated region due to the incompressibility that is compressed and the volume hardly changes. And mitigate changes in pressure.
- a synthetic rubber sheet is suitable for the rubber-like elastic sheet 6.
- Synthetic rubber sheets include isoprene rubber, styrene butadiene rubber, butadiene rubber, chloropron rubber, nitrile rubber, horiisobutylene rubber, ethylene propylene rubber, ethylene vinyl acetate copolymer rubber, chlorosulfonated polyethylene rubber, acrylic rubber, fluororubber, Any one of epichlorohydrin rubber, urethane rubber, silicone rubber, thermoplastic olefin rubber, ethylenepropylene diene rubber, butyl rubber, and polyether rubber can be used alone or in combination of a plurality of synthetic rubber sheets.
- ethylene propylene rubber, ethylene vinyl acetate copolymer rubber, chlorosulfonated polyethylene rubber, acrylic rubber, fluororubber, and silicone rubber have excellent heat insulating properties, so it takes a long time to heat runaway and heat melt. And higher safety can be achieved.
- the rubber-like elastic sheet 6 is made of urethane rubber, it is particularly preferable to use thermoplastic polyurethane rubber or foamed polyurethane rubber.
- the physical properties of the urethane foam rubber are that the density is 150 to 750 kg / m 3 , the thickness is 0.5 to 6.0 mm, and the compression set is 20% or less. Is preferable.
- the compression set referred to here can be obtained by the following method.
- the urethane foam rubber to be measured is compressed by 50% at an ambient temperature of 100 ° C.
- the compressed state is maintained for 22 hours.
- the compressed state is released and the thickness of the urethane foam rubber is measured.
- the compression set is determined by comparing the thickness before and after the test.
- the separator 2 does not have the rubber-like elastic sheet 6 laminated on the entire surface of the heat insulating sheet 5.
- the separator 2 is divided into a laminated region 2A and a non-laminated region 2B, and the rubber-like elastic sheet 6 is laminated only in the laminated region 2A, and the rubber-like elastic sheet 6 is not laminated in the non-laminated region 2B.
- the battery cell 1 is a square battery cell
- the separator 2 is a central portion of the heat insulating sheet 5 with the outer peripheral portion of the heat insulating sheet 5 as the laminated region 2A as shown in FIG. Is the non-stacked region 2B.
- the separator 2 having this structure absorbs the expansion of the central portion of the square battery cell 1 in the non-stacked region 2B.
- the separator 2 can efficiently absorb the expansion of the battery cell 1 by forming the central portion of the square battery cell as a non-stacked area 2B over a wide area.
- the rubber-like elastic sheet 6 provided in the laminated region 2A on the outer peripheral portion of the square battery cell is pressed by the expanded battery cell 1 and compressed thinly.
- the compressed rubber-like elastic sheet 6 is pushed out from the laminated region 2A and moved to the non-laminated region 2B due to the incompressibility of the rubber.
- the rubber-like elastic sheet 6 moved to the non-laminated region 2B becomes thinner as it moves to the inside of the non-laminated region 2B, and relaxes the pressure change at the boundary portion between the laminated region 2A and the non-laminated region 2B.
- the rubber-like elastic sheet 6 that moves to the non-laminated region 2B and gradually becomes thinner also alleviates that the shape of the surface of the battery cell 1 changes stepwise.
- changes in the surface shape and pressure of the battery cell 1 are alleviated to reduce the mechanical load on the electrodes and prevent damage to the electrodes due to the mechanical load. Prevents thermal runaway of batteries and improves safety.
- the rubber-like elastic sheets 6 laminated on both sides of the heat insulating sheet 5 have the same shape, but they do not necessarily have the same shape, and have cell characteristics and reaction force characteristics. Depending on the shape, the shapes may be different from each other.
- the power supply device 100 described above preferably has a structure in which all separators 2 are laminated with rubber-like elastic sheets 6 on both sides of the heat insulating sheet 5, but all separators 2 are necessarily rubber-like elastic on both sides of the heat insulating sheet 5. It is not necessary to have a structure in which the sheets 6 are laminated. As shown in FIG. 6, the separator 2 can have a rubber-like elastic sheet 6 laminated on one side of the heat insulating sheet 5.
- the separators it is not necessary for all the separators to have a laminated structure of a heat insulating sheet and a rubber-like elastic sheet, and a separator having only a heat insulating sheet and a separator having a laminated structure of a heat insulating sheet and a rubber-like elastic sheet are mixed. It can also be provided.
- the rubber-like elastic sheet 6 and the heat insulating sheet 5 are joined via an adhesive layer or an adhesive layer and laminated at a fixed position.
- the rubber-like elastic sheet 6 and the heat insulating sheet 5 may be integrally molded by a method such as two-color molding, and do not necessarily have to be joined via an adhesive layer or an adhesive layer.
- the separator 2 and the battery cell 1 are also joined to each other via an adhesive or an adhesive layer and arranged at a fixed position. However, the separator 2 can also be arranged at a fixed position of a battery holder (not shown) in which the battery cell 1 is arranged at a fixed position in a fitting structure.
- the battery cell 1 is a square battery cell having a charging capacity of 6 Ah to 10 Ah, and the heat insulating sheet 5 of the separator 2 is filled with silica airgel in a fiber sheet to have a thickness of 1 mm.
- the rubber-like elastic sheet 6 laminated on both sides of the heat insulating sheet 5 is used as a urethane rubber sheet having a thickness of 0.5 mm, and a specific battery cell 1 is forced to run away due to heat. Therefore, it is possible to prevent the induction of thermal runaway to the adjacent battery cell 1.
- the above power supply device can be used as a power source for a vehicle that supplies electric power to a motor that runs an electric vehicle.
- an electric vehicle equipped with a power supply device an electric vehicle such as a hybrid vehicle or a plug-in hybrid vehicle that runs on both an engine and a motor, or an electric vehicle that runs only on a motor can be used, and is used as a power source for these vehicles.
- a large number of the above-mentioned power supply devices are connected in series or in parallel, and a large-capacity, high-output power supply device 100 to which a necessary control circuit is added will be described as an example. ..
- FIG. 7 shows an example in which a power supply device is mounted on a hybrid vehicle that runs on both an engine and a motor.
- the vehicle HV equipped with the power supply device shown in this figure includes a vehicle body 91, an engine 96 for traveling the vehicle body 91, a motor 93 for traveling, and wheels driven by these engines 96 and a motor 93 for traveling. It includes 97, a power supply device 100 that supplies electric power to the motor 93, and a generator 94 that charges the battery of the power supply device 100.
- the power supply device 100 is connected to the motor 93 and the generator 94 via the DC / AC inverter 95.
- the vehicle HV runs on both the motor 93 and the engine 96 while charging and discharging the battery of the power supply device 100.
- the motor 93 is driven to drive the vehicle in a region where the engine efficiency is low, for example, when accelerating or traveling at a low speed.
- the motor 93 is driven by being supplied with electric power from the power supply device 100.
- the generator 94 is driven by the engine 96 or by regenerative braking when braking the vehicle to charge the battery of the power supply device 100.
- the vehicle HV may be provided with a charging plug 98 for charging the power supply device 100. By connecting the charging plug 98 to an external power source, the power supply device 100 can be charged.
- FIG. 8 shows an example in which a power supply device is mounted on an electric vehicle traveling only by a motor.
- the vehicle EV equipped with the power supply device shown in this figure supplies electric power to the vehicle body 91, the running motor 93 for running the vehicle body 91, the wheels 97 driven by the motor 93, and the motor 93.
- a power supply device 100 for charging and a generator 94 for charging the battery of the power supply device 100 are provided.
- the power supply device 100 is connected to the motor 93 and the generator 94 via the DC / AC inverter 95.
- the motor 93 is driven by being supplied with electric power from the power supply device 100.
- the generator 94 is driven by the energy used for regenerative braking of the vehicle EV to charge the battery of the power supply device 100. Further, the vehicle EV is provided with a charging plug 98, and the charging plug 98 can be connected to an external power source to charge the power supply device 100.
- the present invention does not specify the use of the power supply device as the power supply of the motor that runs the vehicle.
- the power supply device according to the embodiment can also be used as a power source for a power storage device that charges and stores a battery with electric power generated by solar power generation, wind power generation, or the like.
- the power supply device can also be used as a power source for a power storage device that charges and stores batteries using midnight power at night.
- a power supply device charged with midnight power can be charged with midnight power, which is surplus power of a power plant, and output power in the daytime when the power load is large, so that the peak power in the daytime can be limited to a small value.
- the power supply can also be used as a power source for charging with both solar cell output and midnight power. This power supply device can effectively utilize both the power generated by the solar cell and the midnight power, and can efficiently store electricity while considering the weather and power consumption.
- the above-mentioned power storage devices include backup power supply devices that can be mounted in computer server racks, backup power supply devices for wireless base stations such as mobile phones, power storage power supplies for homes or factories, power supplies for street lights, etc. It can be suitably used for power storage devices combined with solar cells, backup power sources for traffic lights and road traffic indicators, and the like.
- the power supply device can be suitably used as a power source for a large current used for a power source of a motor for driving an electric vehicle such as a hybrid vehicle, a fuel cell vehicle, an electric vehicle, or an electric motorcycle.
- a power supply device for a plug-in hybrid electric vehicle, a hybrid electric vehicle, an electric vehicle, or the like that can switch between an EV driving mode and a HEV driving mode can be mentioned.
- a backup power supply device that can be mounted on a computer server rack, a backup power supply device for wireless base stations such as mobile phones, a power storage device for home use and factories, a power supply for street lights, etc. , Can also be used as appropriate for backup power supplies such as traffic lights.
- 100 ... Power supply device 1 ... Battery cell, 2 ... Separator, 2A ... Laminated area, 2B ... Non-laminated area, 3 ... End plate, 4 ... Bind bar, 5 ... Insulation sheet, 6 ... Rubber elastic sheet, 10 ... Battery Block, 12 ... Electrode terminal, 91 ... Vehicle body, 93 ... Motor, 94 ... Generator, 95 ... DC / AC inverter, 96 ... Engine, 97 ... Wheel, 98 ... Charging plug, HV, EV ... Vehicle.
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Abstract
Description
さらに以下に示す実施形態は、本発明の技術思想の具体例を示すものであって、本発明を以下に限定するものではない。また、以下に記載されている構成部品の寸法、材質、形状、その相対的配置等は、特定的な記載がない限り、本発明の範囲をそれのみに限定する趣旨ではなく、例示することを意図したものである。また、一の実施の形態、実施例において説明する内容は、他の実施の形態、実施例にも適用可能である。また、図面が示す部材の大きさや位置関係等は、説明を明確にするため、誇張していることがある。
ゴム状弾性シートのエチレン酢酸ビニル共重合体ゴムは耐熱温度を200℃に、アクリルゴムは耐熱温度を180℃に、フッ素ゴムは耐熱温度を300℃に、シリコーンゴムは耐熱温度を280℃と高くできる。
以下、さらに具体的な電源装置と電動車両を詳述する。
図1の斜視図と図2の垂直断面図と図3の水平断面図に示す電源装置100は、複数の電池セル1をセパレータ2を挟んで厚さ方向に積層している電池ブロック10と、電池ブロック10の両端面に配置している一対のエンドプレート3と、一対のエンドプレート3を連結してエンドプレート3を介して電池ブロック10を加圧状態に固定しているバインドバー4とを備える。
電池ブロック10の電池セル1は、外形を四角形とする角形電池セルで、上面の両端部に正負一対の電極端子12を上方向に突出して設けている。電極端子12間には安全弁(図示せず)を設けている。安全弁は、電池セル1の内圧が所定値以上に上昇した際に開弁して、内部のガスを放出する。安全弁は、電池セル1の内圧上昇を防止する。
電池セル1は、リチウムイオン二次電池である。電池セル1をリチウムイオン二次電池とする電源装置100は、容量と重量に対する充電容量を大きくできる特長がある。ただし、電池セル1は、リチウムイオン二次電池以外の非水系電解液二次電池等、他の充電できる全ての電池とすることができる。
エンドプレート3は、電池ブロック10に押圧されて変形しない、電池セル1の外形にほぼ等しい外形の金属板で、両側縁にバインドバー4を連結している。バインドバー4は、エンドプレート3が積層している電池セル1を加圧状態で連結して、電池ブロック10を所定の圧力で加圧状態に固定している。
セパレータ2は、積層している電池セル1の間に挟まれて、隣接する電池セル1を絶縁し、さらに電池間における熱伝導を遮断し、さらに、電池セル1の膨張を吸収する。電池ブロック10は、隣接する電池セル1の電極端子12にバスバー(図示せず)を固定して、電池セル1を直列又は並列に接続している。直列に接続される電池セル1は、電池ケースに電位差が発生するので、セパレータ2で絶縁して積層する。並列に接続される電池セル1は、電池ケースに電位差は発生しないが、熱暴走の誘発を防止するために、セパレータ2で断熱して積層する。
断熱シート5は、繊維シートとナノサイズの多孔質構造を有するシリカエアロゲルとからなる。この断熱シート5は、シリカエアロゲルのゲル原料を、繊維に含浸して製造される。シリカエアロゲルを繊維シートに含浸した後、繊維を積層し、ゲル原料を反応させて湿潤ゲルを形成し、さらに湿潤ゲル表面を疎水化、熱風乾燥して製造される。繊維シートの繊維は、ポリエチレンテレフタレート(PET)である。ただ、繊維シートの繊維は、難燃処理を施した酸化アクリル繊維やグラスウールなどの無機繊維も使用できる。
セパレータ2は、図4に示すように、断熱シート5の表面にゴム状弾性シート6を積層している。厚いセパレータ2は、各々の電池セル1の間に積層されて電池ブロック10を大きくする。電池ブロック10は小形化が要求されるので、セパレータ2はできる限り薄くして断熱特性が要求される。電源装置100において、容積に対して充電容量を大きくすることが要求されるからである。電源装置100は、電池ブロック10を小形化して充電容量を大きくするために、セパレータ2には、ゴム状弾性シート6と断熱シート5を薄くして、電池セル1の熱暴走の誘発を阻止することが大切である。このことから、ゴム状弾性シート6は、たとえば0.2mm以上であって2mm以下、さらに好ましくは0.3mm~1mm以下として、電池セル1の膨張による圧縮応力の増加を抑制する。さらに、ゴム状弾性シート6は、好ましくは断熱シート5よりも薄くしながら、電池セル1の膨張時の圧縮応力を低下させる。
図7は、エンジンとモータの両方で走行するハイブリッド自動車に電源装置を搭載する例を示す。この図に示す電源装置を搭載した車両HVは、車両本体91と、この車両本体91を走行させるエンジン96及び走行用のモータ93と、これらのエンジン96及び走行用のモータ93で駆動される車輪97と、モータ93に電力を供給する電源装置100と、電源装置100の電池を充電する発電機94とを備えている。電源装置100は、DC/ACインバータ95を介してモータ93と発電機94に接続している。車両HVは、電源装置100の電池を充放電しながらモータ93とエンジン96の両方で走行する。モータ93は、エンジン効率の悪い領域、例えば加速時や低速走行時に駆動されて車両を走行させる。モータ93は、電源装置100から電力が供給されて駆動する。発電機94は、エンジン96で駆動され、あるいは車両にブレーキをかけるときの回生制動で駆動されて、電源装置100の電池を充電する。なお、車両HVは、図7に示すように、電源装置100を充電するための充電プラグ98を備えてもよい。この充電プラグ98を外部電源と接続することで、電源装置100を充電できる。
また、図8は、モータのみで走行する電気自動車に電源装置を搭載する例を示す。この図に示す電源装置を搭載した車両EVは、車両本体91と、この車両本体91を走行させる走行用のモータ93と、このモータ93で駆動される車輪97と、このモータ93に電力を供給する電源装置100と、この電源装置100の電池を充電する発電機94とを備えている。電源装置100は、DC/ACインバータ95を介してモータ93と発電機94に接続している。モータ93は、電源装置100から電力が供給されて駆動する。発電機94は、車両EVを回生制動する時のエネルギーで駆動されて、電源装置100の電池を充電する。また車両EVは充電プラグ98を備えており、この充電プラグ98を外部電源と接続して電源装置100を充電できる。
Claims (12)
- 複数の電池セルをセパレータを挟んで厚さ方向に積層してなる電池ブロックと、
前記電池ブロックの両端面に配置してなる一対のエンドプレートと、
前記一対のエンドプレートに連結されて、前記エンドプレートを介して電池ブロックを加圧状態に固定してなるバインドバーとを備える電源装置であって、
前記セパレータが、
繊維シートとシリカエアロゲルからなる断熱シートと、
前記断熱シートの表面に積層してなるゴム状弾性シートを備え、
前記セパレータが、
前記ゴム状弾性シートを積層してなる積層領域と、
前記ゴム状弾性シートが積層されない非積層領域とを設けてなることを特徴とする電源装置。 - 請求項1に記載する電源装置であって、
前記電池セルが角形電池セルで、
前記セパレータが、
前記断熱シートの外周部を積層領域として、
前記断熱シートの中央部を非積層領域としてなることを特徴とする電源装置。 - 請求項1又は2に記載する電源装置であって、
前記セパレータが、
前記断熱シートの両面に前記ゴム状弾性シートを積層してなることを特徴とする電源装置。 - 請求項1又は2に記載する電源装置であって、
前記セパレータが、
前記断熱シートの片面のみに前記ゴム状弾性シートを積層してなることを特徴とする電源装置。 - 請求項1ないし4のいずれかに記載する電源装置であって、
前記セパレータの前記ゴム状弾性シートが、
非発泡のゴム状弾性体、又は独立気泡の発泡体であることを特徴とする電源装置。 - 請求項1ないし5のいずれかに記載される電源装置であって、
前記ゴム状弾性シートが、
合成ゴムシートであることを特徴とする電源装置。 - 請求項6に記載する電源装置であって、
前記ゴム状弾性シートの合成ゴムが、
イソプレンゴム、スチレンブタジエンゴム、ブタジエンゴム、クロロプロンゴム、ニトリルゴム、ホリイソブチレンゴム、エチレンプロピレンゴム、エチレン酢酸ビニル共重合体ゴム、クロロスルホン化ポリエチレンゴム、アクリルゴム、フッ素ゴム、エピクロルヒドリンゴム、ウレタンゴム、シリコーンゴム、熱可塑性オレフィンゴム、エチレンプロピレンジエンゴム、ブチルゴム、ポリエーテルゴムの何れかであることを特徴とする電源装置。 - 請求項1ないし7のいずれかに記載する電源装置であって、
前記ゴム状弾性シートの厚さが、
0.2mm以上であって2mm以下であることを特徴とする電源装置。 - 請求項8に記載する電源装置であって、
前記断熱シートが、
前記ゴム状弾性シートよりも厚いことを特徴とする電源装置。 - 請求項1ないし9のいずれかに記載する電源装置であって、
前記断熱シートの厚さが0.5mm以上であって2mm以下であることを特徴とする電源装置。 - 請求項1ないし10のいずれかに記載する電源装置であって、
前記電池セルの間に積層されてなる全ての前記セパレータが、
断熱シートの表面にゴム状弾性シートを積層してなることを特徴とする電源装置。 - 請求項1ないし11のいずれかに記載する電源装置を備える電動車両であって、
前記電源装置と、
該電源装置から電力供給される走行用のモータと、
前記電源装置及び前記モータを搭載してなる車両本体と、
前記モータで駆動されて前記車両本体を走行させる車輪とを備えることを特徴とする電動車両。
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| JP2021508755A JP7491903B2 (ja) | 2019-03-27 | 2019-12-20 | 電源装置と電動車両 |
| US17/439,225 US12476306B2 (en) | 2019-03-27 | 2019-12-20 | Power supply device and electric vehicle |
| CN201980093845.0A CN113614983A (zh) | 2019-03-27 | 2019-12-20 | 电源装置和电动车辆 |
| EP19920802.6A EP3952009A4 (en) | 2019-03-27 | 2019-12-20 | POWER SUPPLY SYSTEM AND ELECTRIC VEHICLE |
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| US12592446B2 (en) | 2020-10-12 | 2026-03-31 | Samsung Sdi Co., Ltd. | Battery pack including heat insulating sheet and friction sheet |
| CN114335847A (zh) * | 2020-10-12 | 2022-04-12 | 三星Sdi株式会社 | 电池包 |
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| GB2615904A (en) * | 2020-12-04 | 2023-08-23 | Rogers Corp | Multilayer sheet for preventing thermal runaway |
| JP2023553272A (ja) * | 2020-12-04 | 2023-12-21 | ロジャーズ・コーポレイション | 熱暴走を防止するための多層シート |
| JP2024505434A (ja) * | 2021-01-15 | 2024-02-06 | ロジャーズ・コーポレイション | 断熱多層シート、製作の方法、及びそれを使用する物品 |
| CN116457992A (zh) * | 2021-04-05 | 2023-07-18 | 株式会社Lg新能源 | 具有改进的绝缘和组装性的包括压缩垫的电池模块、包括该电池模块的电池组和车辆 |
| JP2023554629A (ja) * | 2021-04-05 | 2023-12-28 | エルジー エナジー ソリューション リミテッド | 絶縁性及び組立性向上コンプレッションパッドを備えるバッテリーモジュール、これを含むバッテリーパック及び自動車 |
| KR102792268B1 (ko) | 2021-04-05 | 2025-04-08 | 주식회사 엘지에너지솔루션 | 절연성 및 조립성 향상 컴프레션 패드를 구비하는 배터리 모듈, 이를 포함하는 배터리 팩 및 자동차 |
| WO2022216017A1 (ko) * | 2021-04-05 | 2022-10-13 | 주식회사 엘지에너지솔루션 | 절연성 및 조립성 향상 컴프레션 패드를 구비하는 배터리 모듈, 이를 포함하는 배터리 팩 및 자동차 |
| KR20220138351A (ko) * | 2021-04-05 | 2022-10-12 | 주식회사 엘지에너지솔루션 | 절연성 및 조립성 향상 컴프레션 패드를 구비하는 배터리 모듈, 이를 포함하는 배터리 팩 및 자동차 |
| JP2024534680A (ja) * | 2022-04-29 | 2024-09-20 | 寧徳時代新能源科技股▲分▼有限公司 | 電池及び電力消費機器 |
| JP7739607B2 (ja) | 2022-04-29 | 2025-09-16 | 香港時代新能源科技有限公司 | 電池及び電力消費機器 |
| WO2024195249A1 (ja) * | 2023-03-22 | 2024-09-26 | イビデン株式会社 | 熱伝達抑制シート及びその製造方法、並びに組電池 |
| JP2024166019A (ja) * | 2023-05-18 | 2024-11-28 | 晶科▲儲▼能科技有限公司 | 電池モジュール及び電池パック |
| JP2026502513A (ja) * | 2023-12-11 | 2026-01-23 | エルジー エナジー ソリューション リミテッド | 冷却装置及びそれを含む電池セル積層体 |
| JP7828514B2 (ja) | 2023-12-11 | 2026-03-11 | エルジー エナジー ソリューション リミテッド | 冷却装置及びそれを含む電池セル積層体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7491903B2 (ja) | 2024-05-28 |
| JPWO2020194938A1 (ja) | 2020-10-01 |
| EP3952009A1 (en) | 2022-02-09 |
| EP3952009A4 (en) | 2022-05-18 |
| CN113614983A (zh) | 2021-11-05 |
| US20220166086A1 (en) | 2022-05-26 |
| US12476306B2 (en) | 2025-11-18 |
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