WO2021010456A1 - 構造物保護シート、それを用いた施工方法及びプレキャスト部材、並びに、プレキャスト部材の製造方法 - Google Patents
構造物保護シート、それを用いた施工方法及びプレキャスト部材、並びに、プレキャスト部材の製造方法 Download PDFInfo
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- WO2021010456A1 WO2021010456A1 PCT/JP2020/027758 JP2020027758W WO2021010456A1 WO 2021010456 A1 WO2021010456 A1 WO 2021010456A1 JP 2020027758 W JP2020027758 W JP 2020027758W WO 2021010456 A1 WO2021010456 A1 WO 2021010456A1
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- Prior art keywords
- layer
- protective sheet
- concrete
- polymer cement
- precast member
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/36—Linings or coatings, e.g. removable, absorbent linings, permanent anti-stick coatings; Linings becoming a non-permanent layer of the moulded article
- B28B7/364—Linings or coatings, e.g. removable, absorbent linings, permanent anti-stick coatings; Linings becoming a non-permanent layer of the moulded article of plastic material or rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B19/00—Machines or methods for applying the material to surfaces to form a permanent layer thereon
- B28B19/0092—Machines or methods for applying the material to surfaces to form a permanent layer thereon to webs, sheets or the like, e.g. of paper, cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
- B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/548—No curing step for the last layer
- B05D7/5483—No curing step for any layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/14—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B19/00—Machines or methods for applying the material to surfaces to form a permanent layer thereon
- B28B19/0046—Machines or methods for applying the material to surfaces to form a permanent layer thereon to plastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/63—Macromolecular compounds
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D22/00—Methods or apparatus for repairing or strengthening existing bridges ; Methods or apparatus for dismantling bridges
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F3/00—Sewer pipe-line systems
- E03F3/04—Pipes or fittings specially adapted to sewers
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F3/00—Sewer pipe-line systems
- E03F3/06—Methods of, or installations for, laying sewer pipes
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G23/00—Working measures on existing buildings
- E04G23/02—Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
- E04G23/0203—Arrangements for filling cracks or cavities in building constructions
- E04G23/0214—Arrangements for filling cracks or cavities in building constructions using covering strips
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G23/00—Working measures on existing buildings
- E04G23/02—Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
- E04G23/0218—Increasing or restoring the load-bearing capacity of building construction elements
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/003—Linings or provisions thereon, specially adapted for traffic tunnels, e.g. with built-in cleaning devices
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/04—Lining with building materials
- E21D11/08—Lining with building materials with preformed concrete slabs
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/04—Lining with building materials
- E21D11/10—Lining with building materials with concrete cast in situ; Shuttering also lost shutterings, e.g. made of blocks, of metal plates or other equipment adapted therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2203/00—Other substrates
- B05D2203/30—Other inorganic substrates, e.g. ceramics, silicon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2252/00—Sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
- B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B13/12—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03F—SEWERS; CESSPOOLS
- E03F3/00—Sewer pipe-line systems
- E03F3/06—Methods of, or installations for, laying sewer pipes
- E03F2003/065—Refurbishing of sewer pipes, e.g. by coating, lining
Definitions
- the present invention relates to a structure protective sheet, a construction method and a precast member using the same, and a method for manufacturing a precast member. More specifically, a structure protective sheet that can significantly reduce the construction period when providing a protective layer on the surface of a structure such as concrete and can protect the structure for a long period of time, and construction using the structure protective sheet.
- the present invention relates to a method and a precast member, and a method for manufacturing the precast member.
- Civil engineering structures such as road bridges, tunnels, floodgates and other river management facilities, sewer pipes, and harbor quays will be repaired and reinforced as they age.
- the repair work is carried out by recoating the coating material multiple times after repairing the defective part and the fragile part.
- the reinforcement work is carried out by repeatedly applying a reinforcing coating material to the entire portion to be reinforced.
- the recoating performed in such repair work and reinforcement work is, for example, undercoating, intermediate coating, and topcoating in order on concrete, but usually, intermediate coating and topcoating are performed twice or three times.
- Each coating step cannot be performed continuously in order to dry the coating. For example, a total of 5 layers of undercoat, 1st intermediate coating, 2nd intermediate coating, 1st topcoat, and 2nd topcoat are applied. In that case, it will take at least 5 days.
- it since it is painted outdoors, it may not be sufficiently dried in rainy weather, or the painting work itself may not be possible, depending on the weather. Therefore, it is difficult to shorten the construction period, labor costs are required accordingly, and the construction cost is also high. Further, the quality of the coating film (film thickness, surface roughness, water content, etc.) is affected by the external environment (humidity, temperature, etc.) during the coating process, and as a result, it is difficult to be stable.
- Patent Document 1 proposes a sheet and a method that are simple, low cost, shorten the construction period, and surely prevent deterioration of concrete.
- a concrete repair sheet having an intermediate layer having a resin film and a surface layer made of a cloth material laminated on both sides thereof with an adhesive resin is attached to the concrete surface to be repaired with a construction adhesive.
- a concrete repair method is performed in which a paint is applied to the surface layer on the side opposite to the concrete surface of the attached concrete repair sheet.
- the concrete repair sheet represented by Patent Document 1 uses a resin film as a base material, and a sheet-shaped reinforcing member is provided on the base material via an adhesive layer.
- Patent Document 2 states that it prevents the alkali-aggregate reaction, has excellent followability to cracks in concrete structures, and does not cause swelling of the coating film even when the temperature rises after the coating film is formed.
- a method for protecting a concrete structure using a coating material that makes it possible to prevent the concrete from peeling off has been proposed.
- This technique is a method of forming a base conditioner coating film on the surface of a concrete structure and forming a coating film on the surface of the coating film.
- the base conditioner coating film is formed from a composition containing a cationic (meth) acrylic polymer emulsion and an inorganic hydraulic substance.
- the coating film formed on the surface of the substrate adjusting material coating film is a coating film formed from a composition containing an alkyl (meth) acrylate-based emulsion and an inorganic water-hard substance, and has an elongation rate of 50 to 2000% at 20 ° C.
- the salt-shielding property is 10-2 to 10-4 mg / cm 2 ⁇ day, the water vapor permeability is 5 g / m 2 ⁇ day or more, and the film thickness is 100 to 5000 ⁇ m.
- JP-A-2010-144360 Japanese Unexamined Patent Publication No. 2000-16886
- Conventional concrete repair sheets such as Patent Document 1 have a difference in adhesive strength between a base material and another layer (for example, an adhesive layer or a reinforcing member), a difference in elongation of the base material, the adhesive layer and the reinforcing member, and adhesion.
- a base material and another layer for example, an adhesive layer or a reinforcing member
- adhesion There are problems to be solved, such as the problem of adhesive strength between the agent layer and concrete.
- the base material and the reinforcing member are bonded by an adhesive layer, but when pressure is applied to the concrete repair sheet during or after the construction of the concrete repair sheet, the base material, the adhesive layer and the reinforcing member are reinforced.
- the difference in elongation of the members and the like can cause peeling of the layer interface based on the difference between the adhesive force between the base material and the adhesive layer and the adhesive force between the adhesive layer and the reinforcing member.
- the adhesive layer provided on the concrete repair sheet is softened by heating or the like and bonded to the concrete, but if sufficient adhesive strength cannot be obtained, the concrete repair sheet is peeled off from the concrete surface and used as a repair sheet. May not work.
- the concrete after the concrete repair sheet was applied sometimes swelled over time, but this phenomenon was caused by the presence of the repair sheet, which has low water vapor permeability, and the water vapor inside the concrete lost its escape. Is considered to be.
- the method of forming a coating film by coating on site takes one day for each layer coating, for example, six layers of coating film from the undercoat layer to the topcoat layer, as explained in the background technology column. It takes as long as 6 days to form the above, and there is a problem that the film thickness varies, and the quality and characteristics such as surface roughness and water content are difficult to stabilize.
- the present invention has been made to solve the above problems, and an object of the present invention is to significantly reduce the construction period when providing a protective layer on the surface of a structure such as concrete or a precast member, and to extend the structure for a long period of time. It is an object of the present invention to provide a structure protective sheet that can be protected over a period of time, a construction method and a precast member using the structure protective sheet, and a method for manufacturing a precast member.
- Precast members are concrete products manufactured in advance at factories, etc. for on-site assembly and installation. Precast members are transported to the site by transport vehicles, but especially large precast members are transported by large trailers and installed one after another at the site to form large structures such as road bridges, tunnels, and sewer pipes. Ru.
- the present inventor has researched a concrete protective sheet that can stably protect concrete for a long period of time without depending on a construction method in which a layer is formed on the surface of concrete by a coating means.
- the concrete protective sheet is given performance according to the characteristics of the concrete, specifically, the followability that can follow the cracks and expansions that occur in the concrete, and the deterioration factors such as water and chloride ions in the concrete.
- the present invention has been completed by further providing waterproofness, salt-shielding property, neutralization-preventing property, and water vapor permeability capable of discharging water in concrete as water vapor. And this technical idea can be applied as a structure protection sheet to other structures not for concrete.
- the structure protective sheet according to the present invention includes a polymer cement layer provided on the structure side and a resin layer provided on the polymer cement layer, and has a thickness distribution of ⁇ 100 ⁇ m or less. It is characterized by that.
- the thickness distribution is within the above range, a layer having a small thickness variation can be stably provided on the surface of the structure even if the operator is not a skilled worker.
- the polymer cement layer provided on the structure side is excellent in adhesion to the structure, and the resin layer provided on the polymer cement layer is excellent in waterproofness, salt shielding property, neutralization prevention property, etc. ..
- it does not have components such as a base material, an adhesive layer, and a reinforcing member, the above-mentioned conventional problems based on the difference in adhesive force between each component and the difference in elongation of each component are unlikely to occur.
- the problem of adhesive strength between the adhesive layer and a structure such as concrete is unlikely to occur.
- the structure protection sheet can be mass-produced by reducing the variation in thickness distribution by the coating process and drying process on the production line of the factory, so that the cost can be reduced, the work period at the site can be significantly reduced, and the structure can be mass-produced. Long-term protection can be achieved.
- both the polymer cement layer and the resin layer may be formed as a single layer or as a laminate, respectively.
- each layer is provided in consideration of the overall thickness, imparting function (followability, waterproofness, salt shielding property, neutralization inhibitory property, adhesiveness, water vapor permeability, etc.), production cost, and the like. It is possible to arbitrarily select whether to use a single layer or a laminated layer.
- the polymer cement layer is a layer formed of a resin containing a cement component.
- the term "polymer cement” shall be used regardless of the content ratio of the resin component in the composition.
- the polymer cement layer is a layer having excellent followability and good compatibility, so that the adhesion of the layer itself is excellent. Further, the cement component contained in the polymer cement layer on the structure side acts to enhance the adhesion to the structure such as concrete.
- a release sheet may be provided on one surface of the polymer cement layer and the resin layer.
- a release sheet may be provided, for example, the surface of the structure protection sheet can be protected during transportation to a construction site, and the release sheet is peeled off and bonded at the construction site. Can be done.
- the release sheet is preferably a process paper used in the production process of the structure protection sheet.
- the structure protective sheet according to the present invention is a waterproof sheet having a water vapor transmittance of 10 to 50 g / m 2 ⁇ day.
- the waterproof sheet since the waterproof sheet has a water vapor transmittance within the above range, it is possible to prevent moisture and deterioration factors from entering the structure such as concrete from the outside, and the moisture in the structure is vaporized. Can be transmitted to the outside as.
- the construction method of the structure protection sheet according to the present invention is a construction method using the structure protection sheet according to the present invention, and the structure protection sheet is applied after applying an adhesive on the structure. It is characterized by pasting together.
- a structure protective sheet having a small thickness variation composed of only a layer that does not include a base material or a reinforcing member is used, it can be easily attached to the surface of the structure.
- a layer having a small thickness variation can be stably provided on the surface of the structure even if the worker is not a skilled worker, the construction period can be significantly reduced, and the structure can be protected for a long period of time.
- an undercoat layer is provided between the structure and the adhesive.
- the undercoat layer provided between the structure and the adhesive acts to enhance mutual adhesion, so that the structure protective sheet can stably protect the structure for a long period of time. ..
- the precast member according to the present invention is characterized in that the structure protective sheet according to the present invention is provided on a part or all of the surface of concrete without using an adhesive.
- a protective sheet having a small thickness variation is provided on the surface of concrete without using an adhesive even if the worker is not a skilled worker, so that the cost of the precast member used for a long period of time without any trouble is low. Can be realized.
- the method for manufacturing a precast member according to the present invention is a method for manufacturing a precast member by arranging a structure protective sheet on an inner surface of a formwork and then pouring a concrete forming composition into the formwork.
- the precast member is thick so that the structure protective sheet is provided on a part or all of the surface thereof, and the structure protective sheet includes a polymer cement layer and a resin layer provided on the polymer cement layer. It is characterized in that the cement distribution is within ⁇ 100 ⁇ m.
- a precast member covered with a structure protective sheet can be easily manufactured.
- no undercoat layer or adhesive layer is provided between the concrete and the structure protective sheet, so that the concrete and the polymer cement layer can be separated from each other. Strong adhesion can be achieved.
- the structure protective sheet capable of protecting a structure such as concrete for a long period of time, a construction method and a precast member using the structure protection sheet, and a method for manufacturing a precast member. it can.
- the structure protective sheet is given performance according to the characteristics of the structure so that it can follow the cracks and expansions that occur in the structure and prevent deterioration factors such as water and chloride ions from penetrating the structure.
- the structure protective sheet 1 includes a polymer cement layer 2 provided on the structure 21 side and a resin layer 3 provided on the polymer cement layer 2. It is characterized in that the thickness distribution is within ⁇ 100 ⁇ m, preferably within ⁇ 50 ⁇ m. Both the polymer cement layer 2 and the resin layer 3 may be formed as a single layer or as a laminated layer, respectively.
- this structure protective sheet 1 Since the thickness distribution of this structure protective sheet 1 is within the above range, a layer having a small thickness variation can be stably provided on the surface of the structure 21 even if the worker is not a skilled worker.
- the polymer cement layer 2 provided on the structure side has excellent adhesion to the structure 21, and the resin layer 3 provided on the polymer cement layer 2 has waterproof, salt-shielding, and neutralization-preventing properties. Etc. are excellent. Further, since it does not have components such as a base material, an adhesive layer, and a reinforcing member, problems based on differences in adhesive force between the components and differences in elongation of each component are unlikely to occur. In addition, the problem of adhesive strength between the adhesive layer and a structure such as concrete is unlikely to occur.
- the structure protection sheet 1 can be mass-produced by reducing the variation in thickness distribution by the coating process and the drying process on the production line of the factory, so that the cost can be reduced, the work period at the site can be significantly reduced, and the structure can be mass-produced. Long-term protection can be realized. As a result, the construction period for bonding to the surface of the structure 21 can be significantly reduced, and the structure 21 can be protected for a long period of time.
- the structure 21 is a mating member to which the structure protection sheet 1 according to the present invention is applied.
- Examples of the structure 21 include a structure made of concrete. Concrete is generally obtained by casting and curing a cement composition containing at least a cement-based inorganic substance, an aggregate, an admixture and water. Such concrete is widely used as civil engineering structures such as road bridges, tunnels, river management facilities such as floodgates, sewer pipes, and harbor quays.
- the structure protective sheet 1 to the structure 21 made of concrete, it is possible to follow the cracks and expansions that occur in the concrete, and the deterioration factors such as water and chloride ions do not permeate into the concrete, and the concrete. There is a special advantage that the water inside can be discharged as water vapor.
- the polymer cement layer 2 is a layer arranged on the structure side.
- the polymer cement layer 2 may be, for example, a single layer that is not overcoated as shown in FIG. 1 (A), or may be a laminated layer that is overcoated as shown in FIG. 1 (B).
- Whether to use a single layer or a laminated layer is arbitrarily set in consideration of the overall thickness, imparting function (followability, adhesiveness to a structure, etc.), factory production line, production cost, etc., for example, a production line. If the thickness is short and the single layer does not have a predetermined thickness, two or more layers can be overcoated to form the film. For example, in the case of two layers of overcoating, the second layer is formed after the first layer is dried.
- the polymer cement layer 2 is obtained by applying this paint, which is a paint made of a resin (resin component) containing a cement component.
- the cement component include various cements, limestones containing a component composed of calcium oxide, and viscosities containing silicon dioxide.
- cement is preferable, and examples thereof include Portland cement, alumina cement, early-strength cement, and fly ash cement. Which cement is selected is selected according to the characteristics that the polymer cement layer 2 should have, and is selected in consideration of, for example, the degree of followability to the concrete structure 21 structure.
- Portland cement defined in JIS R5210 can be preferably mentioned.
- the resin component examples include acrylic resin, acrylic urethane resin, acrylic silicone resin, fluororesin, flexible epoxy resin, polybutadiene rubber, and the like. It is preferable that such a resin component is the same as the resin component constituting the resin layer 3 described later from the viewpoint of enhancing the adhesion between the polymer cement layer 2 and the resin layer 3.
- the paint for forming the polymer cement layer 2 is a coating liquid in which a cement component and a resin component are mixed with a solvent.
- the resin component is preferably an emulsion.
- an acrylic emulsion is a polymer fine particle obtained by emulsion polymerization of a monomer such as an acrylic acid ester using an emulsifier.
- Acrylic acid-based polymer emulsion obtained by polymerizing a monomer mixture in water containing a surfactant can be preferably mentioned.
- the content of the acrylic ester or the like constituting the acrylic emulsion is not particularly limited, but is selected from the range of 20 to 100% by mass.
- the surfactant is also blended in an amount as required, and is not particularly limited, but a surfactant to the extent that it becomes an emulsion is blended.
- the polymer cement layer 2 is formed by applying the coating liquid on the release sheet 4 and then drying and removing the solvent (water).
- a mixed composition of a cement component and an acrylic emulsion is used as a coating liquid to form a polymer cement layer 2.
- the resin layer 3 may be formed on the release sheet 4 after the polymer cement layer 2 is formed, but as shown in FIG. 2 (B), the resin layer 3 may be formed.
- the polymer cement layer 2 may be formed after the resin layer 3 is formed on the mold sheet 4.
- the thickness of the polymer cement layer 2 is not particularly limited, but the usage pattern of the structure 21 (river management facilities such as road bridges, tunnels, water gates, sewer pipes, civil engineering structures such as harbor quays, etc.), degree of aging, and shape. It is set arbitrarily by such as.
- the thickness can be, for example, in the range of 0.5 mm to 1.5 mm. As an example, when the thickness is 1 mm, the thickness variation is within ⁇ 100 ⁇ m. Such a thickness of accuracy cannot be achieved by on-site coating, and can be achieved by stable coating on a factory production line. If it is thinner than 1 mm, the thickness variation can be further reduced.
- the polymer cement layer 2 Due to the presence of the cement component, the polymer cement layer 2 is more easily permeable to water vapor than the resin layer 3 described later. Water vapor transmission rate at this time is, for example, 10 ⁇ 50g / m 2 ⁇ about day. Further, the cement component has good compatibility with, for example, the cement component constituting concrete, and can be made to have excellent adhesion to the concrete surface. Further, as shown in FIG. 3, even when the undercoat layer 22 and the adhesive 23 are provided in order on the surface of the structure 21, the polymer cement layer 2 containing the cement component adheres well to the adhesive 23. To do. Further, since the polymer cement layer 2 has stretchability, it can follow the change of concrete even when the structure 21 is cracked or expanded.
- the resin layer 3 is a layer that is arranged on the opposite side of the structure 21 and appears on the surface.
- the resin layer 3 may be, for example, a single layer as shown in FIG. 1 (A) or may be laminated as shown in FIG. 1 (B).
- Whether to use a single layer or a laminated layer takes into consideration the overall thickness, imparting function (waterproofness, salt shielding property, neutralization prevention property, water vapor permeability, etc.), factory production line length, production cost, etc. For example, when the production line is short and a single layer does not have a predetermined thickness, two or more layers can be overcoated to form the film.
- the second layer is applied after the first layer is dried. The second layer is then dried.
- the resin layer 3 is coated with a paint that has flexibility and can follow cracks and cracks generated in concrete and can form a resin layer 3 having excellent waterproofness, salt shielding property, neutralization prevention property and water vapor permeability. Obtained by working.
- the resin constituting the resin layer 3 include acrylic resins, acrylic urethane resins, acrylic silicone resins, fluororesins, flexible epoxy resins, and polybutadiene rubbers that exhibit rubber properties. It is preferable that the resin material is the same as the resin component constituting the polymer cement layer 2 described above. In particular, a resin containing an elastic film-forming component is preferable.
- the acrylic resin exhibiting rubber properties is preferably made of an aqueous emulsion of an acrylic rubber copolymer in that it is excellent in safety and coatability.
- the proportion of the acrylic rubber-based copolymer in the emulsion is, for example, 30 to 70% by mass.
- the acrylic rubber-based copolymer emulsion can be obtained, for example, by emulsion polymerization of a monomer in the presence of a surfactant.
- a surfactant any of anionic, nonionic and cationic surfactants can be used.
- the paint for forming the resin layer 3 is prepared by preparing a mixed coating liquid of a resin composition and a solvent, applying the coating liquid on the release sheet 4, and then drying and removing the solvent.
- the resin layer 3 is formed.
- the solvent may be water or an aqueous solvent, or may be an organic solvent such as xylene / mineral spirit. In the examples described later, an aqueous solvent is used, and the resin layer 3 is made of an acrylic rubber composition. As shown in Examples described later, it is preferable that the resin layer 3 is formed on the release sheet 4 and then the polymer cement layer 2 is formed on the release sheet 4.
- the thickness of the resin layer 3 is arbitrarily set according to the usage pattern of the structure 21 (river management facilities such as road bridges, tunnels, floodgates, civil engineering structures such as sewer pipes and harbor quays), the degree of aging, and the shape. Will be done.
- the thickness is preferably any one within the range of 50 to 150 ⁇ m, and the thickness variation is preferably within ⁇ 50 ⁇ m.
- Such a thickness of accuracy cannot be achieved by on-site coating, and can be stably achieved on the production line of a factory.
- the resin layer 3 has high waterproofness, salt-shielding property, and neutralization-preventing property, but allows water vapor to permeate.
- the water vapor transmittance at this time is preferably, for example, about 10 to 50 g / m 2 ⁇ day.
- the structure protective sheet 1 can be provided with high waterproofness, salt shielding property, neutralization preventing property, and predetermined water vapor permeability.
- the compatibility with the polymer cement layer 2 is good, and the adhesion can be excellent.
- the water vapor permeability was measured in accordance with JIS Z0208 "Humidity Permeability Test Method for Moisture-Proof Packaging Material".
- the produced structure protective sheet 1 may be provided with a release sheet 4 on one surface of the polymer cement layer 2 and the resin layer 3.
- the release sheet 4 can protect the surface of the structure protection sheet 1 when it is transported to a construction site, for example, and the release sheet 4 can be easily peeled off and attached at the construction site.
- the release sheet 4 is preferably a process paper used in the production process of the structure protection sheet 1.
- the material of the process paper used as the release sheet 4 is not particularly limited as long as it is a conventionally known one used in the manufacturing process.
- a laminated paper having an olefin resin layer such as polypropylene or polyethylene can be preferably mentioned.
- the thickness is not particularly limited, but can be any thickness, for example, about 50 to 500 ⁇ m, as long as it is not a thickness that hinders manufacturing, construction, and handling.
- the structure protection sheet 1 described above can protect the structure 21 such as concrete for a long period of time.
- the structure protective sheet 1 is provided with performance according to the characteristics of the structure 21 to follow the cracks and expansions that occur in the structure 21, and the structure 21 is permeated with deterioration factors such as water and chloride ions. It is possible to prevent the structure from being allowed to pass, and to provide a permeability capable of discharging water and deterioration factors in the structure. Since such a structure protective sheet 1 can be manufactured at a factory, it is possible to mass-produce high-quality ones having stable characteristics. As a result, construction can be carried out without relying on the skills of craftsmen, and the construction period can be shortened and labor costs can be reduced.
- the construction method of the structure protection sheet according to the present invention is the construction method using the structure protection sheet 1 according to the present invention, and the adhesive 23 is applied on the structure 21. It is characterized in that the structure protection sheet 1 is attached later. Since this construction method uses a structure protective sheet 1 having a small thickness variation, which is composed of only a layer that does not include a base material or a reinforcing member, the structure protective sheet 1 is easily attached to the surface of the structure 21. be able to.
- the structure protective sheet 1 composed of layers having a small thickness variation can be provided on the structure 21 even if the worker is not a skilled worker, the construction period can be significantly reduced, and the structure 21 can be extended for a long period of time. Can be protected over.
- FIG. 3 is an explanatory view of the construction method of the structure protection sheet 1.
- the undercoat layer 22 is formed on the surface of the structure 21.
- the undercoat layer 22 can be formed by applying a coating liquid obtained by mixing a resin such as an epoxy resin and a solvent to the structure 21 and then volatilizing and drying the solvent in the coating liquid.
- a resin such as an epoxy resin
- a solvent such as an epoxy resin
- the thickness of the undercoat layer 22 is not particularly limited, but can be, for example, in the range of 100 to 150 ⁇ m. Since the undercoat layer 22 provided between the structure 21 and the adhesive 23 acts to enhance mutual adhesion, the structure protective sheet 1 can stably protect the structure 21 for a long period of time. If the structure 21 has cracks or defects, it is preferable to provide the undercoat layer 22 after repairing the cracks or defects.
- the repair is not particularly limited, but usually cement mortar, epoxy resin, or the like is used.
- the adhesive 23 is applied as shown in FIG. 3 (B). As shown in FIG. 3C, the structure protective sheet 1 is attached to the applied adhesive 23 without drying.
- the adhesive 23 include urethane-based adhesives and epoxy-based adhesives. Among them, the adhesive 23 composed of the same type of resin component as the resin component constituting the polymer cement layer 2 of the structure protective sheet 1 is more preferable because the adhesive strength with the polymer cement layer 2 is high.
- the thickness of the adhesive 23 is not particularly limited.
- the adhesive 23 is usually applied to concrete by means such as brush coating or spray coating, and then naturally dried and cured over time.
- FIG. 4 is an explanatory view showing an example in which the structure protection sheet 1 is applied to the cast-in-place construction method.
- the cast-in-place construction method is a construction method in which a formwork 24 is formed at a work site, a concrete composition 21'is poured into the formwork 24, and the concrete composition 21'is left to be hardened to obtain a concrete structure 21.
- the structure protective sheet 1 is attached to the surface of the hardened concrete structure 21, so that the structure 21 is less likely to deteriorate.
- the undercoat layer 22 is applied and dried on the surface of the concrete structure 21, the adhesive 23 is applied on the undercoat layer 22, and then the structure protective sheet 1 is bonded. Then, usually, the adhesive 23 is dried and cured by leaving it to stand naturally to adhere the structure protective sheet 1.
- the structure protection sheet 1 is attached by the same construction method as described above. In this way, the life of the concrete structure 21 can be extended.
- the precast member according to the present invention is a structure protective sheet (hereinafter, also simply referred to as a protective sheet) according to the present invention. That is, as shown in FIG. 5, the precast member 31 according to the present invention is a precast member 31 in which the protective sheet 1 is provided on a part or all of the surface without using an adhesive, and the protective sheet 1 is provided.
- the thickness distribution of the polymer cement layer 2 and the resin layer 3 provided on the polymer cement layer 2 is within ⁇ 100 ⁇ m.
- the polymer cement layer 2 constituting the protective sheet 1 is a layer obtained by applying a resin having a cement component, and the resin layer 3 is obtained by applying a resin having an elastic film forming component. It is a layer.
- the protective sheet 1 having a small thickness variation is provided on the surface of the concrete 21 without using an adhesive even if the precast member 31 is not a skilled worker, the precast member 31 can be used for a long period of time without any trouble. Cost reduction can be realized.
- the layers 2 and 3 constituting the protective sheet 1 are all resin layers 3 having excellent compatibility and excellent followability, the adhesion of the layers themselves is excellent.
- the polymer cement layer 2 provided on the concrete 21 side has excellent adhesion to the concrete 21, and the resin layer 3 provided on the polymer cement layer 2 has excellent waterproofness, salt shielding property, neutralization prevention property, and the like. ing.
- the protective sheet 1 does not have components such as a base material, an adhesive layer, and a reinforcing member, the above-mentioned conventional problem based on the difference in adhesive force between each component and the difference in elongation of each component. Is unlikely to occur. Further, the protective sheet 1 can be mass-produced by reducing the variation in the thickness distribution by the coating process and the drying process on the production line of the factory, so that the cost can be reduced.
- the precast member 31 is provided with a protective sheet 1 on a part or all of the surface of the precast member 31 without using an adhesive.
- the precast member 31 is manufactured by arranging the protective sheet 1 on the inner surface of the mold 24 and then pouring the concrete composition 21'into the mold.
- a protective sheet 1 is provided on a part or all of the surface thereof, and the protective sheet 1 has a polymer cement layer 2 and a resin layer 3 provided on the polymer cement layer 2.
- the provided thickness distribution is within ⁇ 100 ⁇ m, preferably within ⁇ 50 ⁇ m.
- the precast member 31 is made of concrete 21.
- the precast member 31 is generally obtained by casting and curing a cement composition containing at least a cement-based inorganic substance, an aggregate, an admixture, and water.
- Such precast members 31 are widely used as civil engineering concrete for road bridges, tunnels, river management facilities such as water gates, sewer pipes, harbor quays, and the like.
- the protective sheet 1 to the precast member 31, it is possible to follow the cracks and expansions that occur in the concrete 21, and the deterioration factors such as water and chloride ions do not permeate into the concrete 21.
- the water in the concrete can be discharged as water vapor.
- FIG. 6 is an explanatory view of a mold 24 for manufacturing the precast member 31
- FIG. 7 is an explanatory view showing an example of a method of manufacturing the precast member 31.
- the mold 24 is composed of the intended use, size, and shape of the obtained precast member 31.
- the type of the mold 24 is not particularly limited. Usually, a wooden frame is used, but a mold made of another material may be used. Reinforcing members such as reinforcing bars may be provided in the formwork 24, if necessary. Outside the formwork, the formwork itself may be reinforced with a reinforcing member such as a steel material, if necessary.
- a protective sheet 1 is laid on the inner surface of the form 24.
- the protective sheet 1 can be laid on the inner surface of the form 24 by temporarily fixing the protective sheet 1 on the inner surface of the form 24. Further, in the case of the concave formwork 24 as shown in FIG. 6B, since the concrete composition 21'is poured after that, the protective sheet 1 is simply pressed against the inner surface of the formwork 24. It may be.
- the concrete composition 21' is a concrete fluid before hardening and can be easily poured into the formwork.
- the concrete composition 21' may contain a material that imparts various properties (reinforcing material, etc.), if necessary.
- the poured concrete composition 21' is usually naturally dried and hardened. As shown in FIG. 3, the hardened concrete 21 becomes a precast member 31 whose surface is partially or wholly covered with the concrete 21. Such a precast member 31 is protected by the protective sheet 1 for a long period of time, and cracks and expansion do not occur. Further, the concrete 21 is not impregnated with deterioration factors such as water and chloride ions. Further, since the water in the concrete 21 is discharged as water vapor, it does not expand. Since such precast members 31 can be manufactured at a factory or the like, high-quality ones with stable characteristics can be mass-produced. As a result, construction can be carried out without relying on the skills of craftsmen, and the construction period can be shortened and labor costs can be reduced.
- the protective sheet 1 is the same as the above-mentioned structure protective sheet according to the present invention. Such a protective sheet 1 can protect the precast member 31 for a long period of time.
- the protective sheet 1 is provided with performance according to the characteristics of the precast member 31, so that it follows the cracks and expansions that occur in the concrete 21 and prevents deterioration factors such as water and chloride ions from penetrating the concrete 21.
- this manufacturing method it is possible to significantly reduce the construction period when providing the protective layer on the surface of the precast member 31, and to protect the precast member 31 for a long period of time.
- the protective sheet 1 having a small thickness variation is provided on the surface of the concrete 21 without using an adhesive even if it is not a skilled worker, the cost of the precast member 31 that is used for a long period of time without any trouble is reduced. Can be realized.
- Example 1 A release sheet 4 having a thickness of 130 ⁇ m made of PP laminated paper was used. A composition for forming a polymer cement layer was applied onto the release sheet 4 and dried to form a polymer cement layer 2 having a thickness of 1.29 mm composed of a single layer. Then, a composition for forming a resin layer containing an acrylic resin was applied onto the polymer cement layer 2 and dried to form a resin layer 3 having a thickness of 100 ⁇ m composed of a single layer. In this way, the structure protective sheet 1 having a total thickness of 1.39 mm was produced. The structure protective sheet 1 was continuously produced in a factory controlled at about 25 ° C., and was wound into a roll in a manner including the release sheet 4.
- the composition for forming a polymer cement layer is an aqueous acrylic emulsion containing 45 parts by mass of a cement mixture.
- the cement mixture contains at least 70 ⁇ 5 parts by mass of Portland cement, 10 ⁇ 5 parts by mass of silicon dioxide, 2 ⁇ 1 part by mass of aluminum oxide, and 1 to 2 parts by mass of titanium oxide, and the acrylic emulsion is an acrylic acid ester monomer.
- Is emulsified and polymerized using an emulsifier to contain at least 53 ⁇ 2 parts by mass of an acrylic acid-based polymer and 43 ⁇ 2 parts by mass of water.
- the polymer cement layer 2 obtained by applying and drying a composition for forming a polymer cement layer in which these are mixed is a composite layer containing 50% by mass of Portland cement in an acrylic resin.
- the resin layer forming composition is an acrylic silicone-based resin.
- This acrylic silicone resin is an emulsion composition containing 60 parts by mass of acrylic silicone resin, 25 parts by mass of titanium dioxide, 10 parts by mass of ferric oxide, and 5 parts by mass of carbon black.
- Example 2 The composition for forming a polymer cement layer used in Example 1 was applied and dried to form two polymer cement layers 2 having a thickness of 0.65 mm (two layers having a thickness of 1.30 mm). Then, the resin layer forming composition used in Example 1 was applied onto the polymer cement layer 2 and dried to form two resin layers 3 having a thickness of 50 ⁇ m (two layers having a thickness of 100 ⁇ m). The formation of each layer was carried out by a continuous coating and drying device in a factory controlled at about 25 ° C. The structure protective sheet 1 having a total thickness of 1.40 mm used in Example 1 was produced in this way. The structure protective sheet 1 was also continuously produced in the factory, and was wound into a roll in a manner including the release sheet 4.
- Example 1 For Examples 1 and 2, about A4 size (200 mm ⁇ 300 mm) was cut out from the structure protective sheet 1 wound in a roll shape, the thickness of each part was measured at 14 points, and the thickness variation was calculated. In Example 1, the thickness variation was 26 ⁇ m, and in Example 2, the thickness variation was 26 ⁇ m.
- Example 1 the total thickness of the structure protective sheet 1 was changed.
- a structure protective sheet 1 having a total thickness of 0.76 mm was prepared by laminating a polymer cement layer 2 having a thickness of 0.66 mm and a resin layer 3 having a thickness of 100 ⁇ m.
- a structure protective sheet 1 having a total thickness of 1.06 mm was prepared by laminating a polymer cement layer 2 having a thickness of 0.96 mm and a resin layer 3 having a thickness of 100 ⁇ m.
- Example 5 a structure protective sheet 1 having a total thickness of 1.57 mm was prepared by laminating a polymer cement layer 2 having a thickness of 1.47 mm and a resin layer 3 having a thickness of 100 ⁇ m. Other than that, it was the same as in Example 1.
- Example 3 The measurement results in Example 3, the strength is 8.5 N, water vapor transmission rate was 18.2g / m 2 ⁇ day. In Example 4, the intensity was 14.7 N and the water vapor permeability was 13.0 g / m 2 ⁇ day. In Example 5, the intensity was 21.1 N and the water vapor permeability was 10.2 g / m 2 ⁇ day. There was no problem with the strength and water vapor transmission rate at any thickness, and it was usable.
- the coating film which is a laminate of the polymer cement layer 2 and the resin layer 3, was peeled off from the process paper, and the tensile breaking strength was evaluated with a tensile tester (manufactured by Shimadzu Corporation, AGS-J).
- Comparative Example 2 In Comparative Example 1, the work was carried out in a working environment controlled at about 40 ° C. A polymer cement layer 2 having a thickness of 1.18 mm composed of two spray-coated layers and a resin layer 3 having a thickness of 100 ⁇ m consisting of two spray-coated layers are formed, and the total thickness of the structure protective sheet 1 is 1.28 mm. did. Other than that, it was the same as in Comparative Example 1.
- Comparative Example 3 In Comparative Example 3, the work was carried out in a working environment controlled at about 10 ° C. A polymer cement layer 2 having a thickness of 1.29 mm composed of two spray-coated layers and a resin layer 3 having a thickness of 100 ⁇ m consisting of two spray-coated layers are formed, and the total thickness of the structure protective sheet 1 is 1.39 mm. did. Other than that, it was the same as in Comparative Example 1.
- the thickness variation is large, which is considerably larger than the range of ⁇ 100 ⁇ m of the present invention, and the thickness variation is large. It was in the range of 222 ⁇ m ( ⁇ 111 ⁇ m) to 260 ⁇ m ( ⁇ 130 ⁇ m).
- Example 6 Manufacturing of precast members
- the precast member 31 was manufactured by the method shown in FIG. 7 using the mold 24 shown in FIG. 6 (A).
- the protective sheet 1 obtained in Example 1 is placed on the inner surface of the mold 24, and then the concrete composition 21'is poured into the mold. Manufactured.
- a protective sheet 1 is provided on a part or all of the surface thereof.
- Example 7 Using the protective sheet 1 obtained in Example 2, the precast member 31 was manufactured in the same manner as in Example 6.
- the protective sheet 1 is composed of a fluororesin film and an adhesive layer, and the precast member 31 is manufactured by laminating the adhesive layer side on concrete 21.
- Adhesion evaluation The adhesion between the concrete 21 and the protective sheet 1 was evaluated for the precast member 31 formed in Examples 6 and 7 and the precast member 31 formed in Comparative Example 4. Adhesion was determined by a method of peeling off the protective sheet 1 on the concrete 21 in the 180 ° direction. Although it was a qualitative test, in the precast members 31 of Examples 6 and 7, the polymer cement layer 2 was delaminated on the surface of the concrete 21, and the interface between the concrete 21 and the protective sheet 1 was strongly adhered. I understood. On the other hand, the precast member 31 of Comparative Example 4 is peeled off at the interface between the adhesive layer constituting the protective sheet 1 and the concrete 21, and the protective sheet 1 and the concrete 21 are strongly adhered to each other as in Examples 1 and 2. I found that I didn't.
- Structure protection sheet 2 Polymer cement layer 3 Resin layer 4 Release sheet 21 Structure (concrete) 21'Concrete composition (structure forming composition) 22 Undercoat layer 23 Adhesive 24 Formwork 31 Precast member
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Abstract
Description
本発明に係る構造物保護シート1は、図1~図3に示すように、構造物21側に設けられたポリマーセメント層2と、ポリマーセメント層2上に設けられた樹脂層3とを備え、厚さ分布が±100μm以内、好ましくは±50μm以内であることに特徴がある。このポリマーセメント層2と樹脂層3の両層が、それぞれ、単層で形成されてもよいし積層として形成されてもよい。
構造物21は、本発明に係る構造物保護シート1が適用される相手部材である。構造物21としては、コンクリートからなる構造物を挙げることができる。コンクリートは、一般的には、セメント系無機物質と骨材と混和剤と水とを少なくとも含有するセメント組成物を打設し、養生して得られる。こうしたコンクリートは、道路橋、トンネル、水門等河川管理施設、下水道管きょ、港湾岸壁等の土木構造物として広く使用される。本発明ではコンクリートからなる構造物21に構造物保護シート1を適用することで、コンクリートに生じたひび割れや膨張に追従でき、コンクリート内に水や塩化物イオン等の劣化因子を浸透させず、コンクリート中の水分を水蒸気として排出できる、という格別の利点がある。
ポリマーセメント層2は、図3(C)に示すように、構造物側に配置される層である。このポリマーセメント層2は、例えば、図1(A)に示すように重ね塗りしない単層であってもよいし、図1(B)に示すように重ね塗りした積層であってもよい。単層とするか積層とするかは、全体厚さ、付与機能(追従性、構造物への接着性等)、工場の製造ライン、生産コスト等を考慮して任意に設定され、例えば製造ラインが短くて単層では所定の厚さにならない場合は、2層以上重ね塗りして形成することができる。なお、例えば2層の重ね塗りは、1層目の層を乾燥した後に2層目の層を形成する。
樹脂層3は、図3(C)に示すように、構造物21とは反対側に配置されて、表面に現れる層である。この樹脂層3は、例えば、図1(A)に示すように単層であってもよいし、図1(B)に示すように積層であってもよい。単層とするか積層とするかは、全体厚さ、付与機能(防水性、遮塩性、中性化阻止性、水蒸気透過性等)、工場の製造ラインの長さ、生産コスト等を考慮して任意に設定され、例えば製造ラインが短くて単層では所定の厚さにならない場合は、2層以上重ね塗りして形成することができる。なお、重ね塗りは、1層目の層を乾燥した後に2層目の層を塗工する。2層目の層は、その後乾燥される。
本発明に係る構造物保護シートの施工方法は、図3に示すように、上記本発明に係る構造物保護シート1を使用した施工方法であって、構造物21上に接着剤23を塗布した後に構造物保護シート1を貼り合わせる、ことを特徴とする。この施工方法は、基材や補強部材を含まない層だけで構成された厚さバラツキの小さい構造物保護シート1を使用するので、構造物21の表面に構造物保護シート1を容易に貼り合わせることができる。その結果、熟練した作業者でなくても厚さバラツキの小さい層で構成された構造物保護シート1を、構造物21に設けることができ、工期を大幅に削減できるとともに、構造物21を長期にわたって保護することができる。
本発明に係るプレキャスト部材は、本発明に係る構造物保護シート(以下、単に保護シートともいう)が用いられたものである。すなわち、本発明に係るプレキャスト部材31は、図5に示すように、保護シート1が表面の一部又は全部に接着剤を介することなく設けられているプレキャスト部材31であって、保護シート1が、ポリマーセメント層2と該ポリマーセメント層2上に設けられる樹脂層3とを備えた厚さ分布が±100μm以内である、ことを特徴とする。保護シート1を構成するポ リマーセメント層2は、セメント成分を有する樹脂を塗工して得られた層であり、樹脂層3は、弾性膜形成成分を有する樹脂を塗工して得られた層である。
プレキャスト部材31は、図5に示すように、保護シート1が表面の一部又は全部に接着剤を介することなく設けられている。プレキャスト部材31の製造は、図6及び図7に示すように、保護シート1を型枠24の内面に配置した後にその型枠内にコンクリート組成物21’を流し込んで製造される。製造されたプレキャスト部材31は、保護シート1がその表面の一部又は全部に設けられており、保護シート1は、ポリマーセメント層2と、そのポリマーセメント層2上に設けられる樹脂層3とを備えた厚さ分布が±100μm以内、好ましくは±50μm以内である。
保護シート1は、上述した本発明に係る構造物保護シートと同様である。
こうした保護シート1は、プレキャスト部材31を長期にわたって保護することができる。特に、保護シート1にプレキャスト部材31の特性に応じた性能を付与し、コンクリート21に生じたひび割れや膨張に追従させること、コンクリート21に水や塩化物イオン等の劣化因子を浸透させないようにすること、コンクリート中の水分や劣化因子を排出できる透過性を持たせることができる。
PPラミネート紙からなる厚さ130μmの離型シート4を用いた。その離型シート4上に、ポリマーセメント層形成用組成物を塗工し乾燥して単層からなる厚さ1.29mmのポリマーセメント層2を形成した。その後、そのポリマーセメント層2上に、アクリル系樹脂を含む樹脂層形成用組成物を塗工し乾燥して単層からなる厚さ100μmの樹脂層3を形成した。こうして合計厚さ1.39mmの構造物保護シート1を作製した。なお、この構造物保護シート1は、約25℃に管理された工場内で連続生産され、離型シート4を含んだ態様でロール状に巻き取った。
実施例1で用いたポリマーセメント層形成用組成物を塗工し乾燥して厚さが0.65mmのポリマーセメント層2を2層形成した(2層厚さ1.30mm)。その後、そのポリマーセメント層2上に、実施例1で用いた樹脂層形成用組成物を塗工し乾燥して厚さ50μmの樹脂層3を2層形成した(2層厚さ100μm)。各層の形成は、約25℃に管理された工場内の連続塗工乾燥装置で行った。実施例1で用いたこうして合計厚さ1.40mmの構造物保護シート1を作製した。なお、この構造物保護シート1も、工場内で連続生産され、離型シート4を含んだ態様でロール状に巻き取った。
実施例1、2について、ロール状に巻き取った構造物保護シート1から、A4サイズ程度(200mm×300mm)を切り出し、各部で14箇所の厚さを測定し、その厚さバラツキを計算した。実施例1では、厚さバラツキが26μmであり、実施例2も厚さバラツキは26μmであった。
実施例1において、構造物保護シート1の合計厚さを変化させた。実施例3は、厚さ0.66mmのポリマーセメント層2と、厚さ100μmの樹脂層3とを積層した合計厚さ0.76mmの構造物保護シート1を作製した。実施例4は、厚さ0.96mmのポリマーセメント層2と、厚さ100μmの樹脂層3とを積層した合計厚さ1.06mmの構造物保護シート1を作製した。実施例5は、厚さ1.47mmのポリマーセメント層2と、厚さ100μmの樹脂層3とを積層した合計厚さ1.57mmの構造物保護シート1を作製した。それ以外は実施例1と同様とした。
実施例3~5について、強度と水蒸気透過率を測定した。強度は引張試験機(株式会社島津製作所製、AGS-J)で測定した破断強度で評価した。水蒸気透過率(WVTR)は、「透湿度」とも呼ばれ、1m2のフィルム(構造物保護シート1)を24時間で透過する水蒸気の量をグラム数で表すものであり、g/m2・day又はg/m2/dayで表す。水蒸気バリア性を示す指標として用いられている。JIS K 7129に準拠した方法で測定した。
現場でコンクリート上にスプレー塗工する作業を再現した。約25℃程度に管理した作業環境で、コンクリート板上にスプレー塗りでエポキシ樹脂からなる下塗り層22を形成し、工程紙上にスプレー塗り1層からなる厚さ1.47mmのポリマーセメント層2を形成し、その上にスプレー塗り1層からなる厚さ100μmの樹脂層3を形成した。各層は、塗工後の放置時間(常温、12時間)と乾燥(40℃、24時間)の関係で、2日で1層とした。ポリマーセメント層2と樹脂層3との合計厚さは1.57mmであった。乾燥後、工程紙上からポリマーセメント層2と樹脂層3との積層体である塗装膜を剥がし、引張試験機(株式会社島津製作所製、AGS-J)で引張破断強度を評価した。
比較例1において、約40℃程度に管理した作業環境で作業した。スプレー塗り2層からなる厚さ1.18mmのポリマーセメント層2と、スプレー塗り2層からなる厚さ100μmの樹脂層3とを形成し、構造物保護シート1の合計厚さを1.28mmとした。それ以外は比較例1と同様とした。
比較例3において、約10℃程度に管理した作業環境で作業した。スプレー塗り2層からなる厚さ1.29mmのポリマーセメント層2と、スプレー塗り2層からなる厚さ100μmの樹脂層3とを形成し、構造物保護シート1の合計厚さを1.39mmとした。それ以外は比較例1と同様とした。
比較例1~3について、上記実施例3~5と同様の強度と水蒸気透過率を測定した。測定結果は、比較例1では、強度が21.1N、水蒸気透過率が10.2g/m2・dayであった。比較例2では、強度が16.2N、水蒸気透過率が11.3g/m2・dayであった。比較例3では、強度が17.8N、水蒸気透過率が11.4g/m2・dayであった。比較例2は、塗工中の粘度上昇が激しく、使用時間はかなり短いと想定される。比較例3は、塗工乾燥後の表面が白っぽく変色した。比較例1~3のいずれも、現場でコンクリート上にスプレー塗工する作業を再現したものであるので、厚さバラツキは大きく、本発明の範囲である±100μmよりもかなり大きく、厚さバラツキは222μm(±111μm)~260μm(±130μm)の範囲内であった。
(プレキャスト部材の作製)
プレキャスト部材31は、図6(A)に示す型枠24を用い、図7に示す方法で製造した。プレキャスト部材31の製造は、図6及び図7に示すように、実施例1で得られた保護シート1を型枠24の内面に配置した後にその型枠内にコンクリート組成物21’を流し込んで製造した。製造されたプレキャスト部材31は、保護シート1がその表面の一部又は全部に設けられる。
実施例2で得られた保護シート1を用いて、実施例6と同様にしてプレキャスト部材31を製造した。
実施例6、7で用いた保護シート1に代えて、特開2004-36097号公報の第0052~0054段落の保護シート1を用いた。この保護シート1は、フッ素樹脂フィルムと接着剤層とで構成されており、プレキャスト部材31は、接着剤層側をコンクリート21上に貼り合わせて製造した。
実施例6、7で形成したプレキャスト部材31と、比較例4で形成したプレキャスト部材31について、コンクリート21と保護シート1との密着性を評価した。密着性は、コンクリート21上の保護シート1を180°方向に引きはがす方法で行った。定性試験ではあったが、実施例6、7のプレキャスト部材31は、ポリマーセメント層2がコンクリート21表面に残る層間剥離であり、コンクリート21と保護シート1との界面は、強く接着していることがわかった。一方、比較例4のプレキャスト部材31は、保護シート1を構成する接着剤層と、コンクリート21との界面で剥離しており、保護シート1とコンクリート21とは、実施例1、2ほど強く接着していないことがわかった。
2 ポリマーセメント層
3 樹脂層
4 離型シート
21 構造物(コンクリート)
21’ コンクリート組成物(構造物形成組成物)
22 下塗り層
23 接着剤
24 型枠
31 プレキャスト部材
Claims (9)
- 構造物側に設けられたポリマーセメント層と、該ポリマーセメント層上に設けられた樹脂層とを備え、厚さ分布が±100μm以内である、ことを特徴とする構造物保護シート。
- 前記ポリマーセメント層と前記樹脂層の両層が、それぞれ、単層で形成されているか又は積層として形成されている、請求項1に記載の構造物保護シート。
- 前記ポリマーセメント層は、セメント成分を含有する樹脂で形成された層である、請求項1又は2に記載の構造物保護シート。
- 前記ポリマーセメント層と前記樹脂層との一方の面に離型シートを備える、請求項1~3のいずれか1項に記載の構造物保護シート。
- 水蒸気透過率が10~50g/m2・dayの防水シートである、請求項1~4のいずれか1項に記載の構造物保護シート。
- 請求項1~5のいずれか1項に記載の構造物保護シートを使用した施工方法であって、構造物上に接着剤を塗布した後に前記構造物保護シートを貼り合わせる、ことを特徴とする構造物保護シートの施工方法。
- 前記構造物と前記接着剤との間に下塗り層を設ける、請求項6に記載の構造物保護シートの施工方法。
- 請求項1~5のいずれか1項に記載の構造物保護シートが表面の一部又は全部に接着剤を介することなく設けられている、ことを特徴とするプレキャスト部材。
- 構造物保護シートを型枠内面に配置した後に該型枠内にコンクリート形成用組成物を流し込んでプレキャスト部材を製造する方法であって、製造された前記プレキャスト部材は、前記構造物保護シートがその表面の一部又は全部に設けられ、前記構造物保護シートが、ポリマーセメント層と該ポリマーセメント層上に設けられる樹脂層とを備えた厚さ分布が±100μm以内である、ことを特徴とするプレキャスト部材の製造方法。
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| JP2021533107A JP7442527B2 (ja) | 2019-07-17 | 2020-07-17 | 構造物保護シート、それを用いた施工方法及びプレキャスト部材、並びに、プレキャスト部材の製造方法 |
| EP20839600.2A EP4000835A4 (en) | 2019-07-17 | 2020-07-17 | Structure protection sheet, execution method and precast member using structure protection sheet, and method for manufacturing precast member |
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| CN202080050710.9A CN114174059A (zh) | 2019-07-17 | 2020-07-17 | 结构物保护片、使用该结构物保护片的施工方法和预制构件以及预制构件的制造方法 |
| CN202410941435.XA CN118876519A (zh) | 2019-07-17 | 2020-07-17 | 结构物保护片、使用该结构物保护片的施工方法和预制构件以及预制构件的制造方法 |
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| EP4116087A4 (en) * | 2020-03-03 | 2024-03-20 | Keiwa Inc. | Structure protection sheet, concrete block, and method for manufacturing reinforced structure |
| JP2022159063A (ja) * | 2021-03-31 | 2022-10-17 | 恵和株式会社 | 構造物の表面変形の検査方法、構造物の表面変形の検査システム、及び、構造物保護シート |
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| WO2022255145A1 (ja) * | 2021-05-31 | 2022-12-08 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| WO2022255312A1 (ja) * | 2021-05-31 | 2022-12-08 | 恵和株式会社 | 構造物保護シート及び構造物保護シートの施工方法 |
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| JP7799556B2 (ja) | 2021-05-31 | 2026-01-15 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| CN117425760A (zh) * | 2021-05-31 | 2024-01-19 | 惠和株式会社 | 构造物保护片及加强的构造物的制造方法 |
| WO2023286561A1 (ja) * | 2021-07-16 | 2023-01-19 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| JP2023013731A (ja) * | 2021-07-16 | 2023-01-26 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| JP2023018895A (ja) * | 2021-07-28 | 2023-02-09 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| WO2023008097A1 (ja) * | 2021-07-28 | 2023-02-02 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| WO2023058726A1 (ja) * | 2021-10-07 | 2023-04-13 | 恵和株式会社 | 構造物保護シート及び構造物保護シートの施工方法 |
| TWI876214B (zh) * | 2021-10-07 | 2025-03-11 | 日商恵和股份有限公司 | 構造物保護片及構造物保護片的施工方法 |
| WO2023074610A1 (ja) * | 2021-10-28 | 2023-05-04 | 恵和株式会社 | 構造物保護シート及び補強された構造物の製造方法 |
| WO2023181384A1 (ja) * | 2022-03-25 | 2023-09-28 | 恵和株式会社 | コンクリートの柱状物の保護方法 |
| WO2023238803A1 (ja) | 2022-06-06 | 2023-12-14 | 恵和株式会社 | 構造物用シート |
| WO2024024789A1 (ja) | 2022-07-28 | 2024-02-01 | 恵和株式会社 | 構造物用シート |
| WO2024024790A1 (ja) | 2022-07-29 | 2024-02-01 | 恵和株式会社 | 構造物用シート |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2024061725A (ja) | 2024-05-08 |
| SA522431381B1 (ar) | 2024-09-01 |
| IL289779A (en) | 2022-03-01 |
| TW202423644A (zh) | 2024-06-16 |
| AU2020314283A1 (en) | 2022-02-03 |
| TW202110640A (zh) | 2021-03-16 |
| PH12022550103A1 (en) | 2022-11-21 |
| ZA202310849B (en) | 2025-03-26 |
| EP4000835A1 (en) | 2022-05-25 |
| JP7442527B2 (ja) | 2024-03-04 |
| EP4000835A4 (en) | 2023-08-02 |
| CN118876519A (zh) | 2024-11-01 |
| CN114174059A (zh) | 2022-03-11 |
| US20220258378A1 (en) | 2022-08-18 |
| JPWO2021010456A1 (ja) | 2021-01-21 |
| TW202348383A (zh) | 2023-12-16 |
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