WO2021057512A1 - 一种用于陶瓷电热体的复合型材料 - Google Patents

一种用于陶瓷电热体的复合型材料 Download PDF

Info

Publication number
WO2021057512A1
WO2021057512A1 PCT/CN2020/114756 CN2020114756W WO2021057512A1 WO 2021057512 A1 WO2021057512 A1 WO 2021057512A1 CN 2020114756 W CN2020114756 W CN 2020114756W WO 2021057512 A1 WO2021057512 A1 WO 2021057512A1
Authority
WO
WIPO (PCT)
Prior art keywords
oxide
composite material
silicon nitride
molybdenum disilicide
silicon carbide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2020/114756
Other languages
English (en)
French (fr)
Inventor
雷彼得
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Le Mark Ceramic Technology Co Ltd
Original Assignee
Chongqing Le Mark Ceramic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Le Mark Ceramic Technology Co Ltd filed Critical Chongqing Le Mark Ceramic Technology Co Ltd
Priority to US17/761,177 priority Critical patent/US20230354480A1/en
Priority to EP20869722.7A priority patent/EP4036072A4/en
Priority to JP2022518167A priority patent/JP7488890B2/ja
Priority to MX2022003170A priority patent/MX2022003170A/es
Priority to KR1020227011922A priority patent/KR102719978B1/ko
Priority to CA3154927A priority patent/CA3154927C/en
Publication of WO2021057512A1 publication Critical patent/WO2021057512A1/zh
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/148—Silicon, e.g. silicon carbide, magnesium silicide, heating transistors or diodes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • C04B35/58085—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicides
    • C04B35/58092—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicides based on refractory metal silicides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/14—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
    • B28B1/16—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted for producing layered articles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C04B35/575—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by pressure sintering
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • C04B35/584—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • C04B35/584—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride
    • C04B35/593—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride obtained by pressure sintering
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C04B35/645—Pressure sintering
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/02—Details
    • H05B3/06—Heater elements structurally combined with coupling elements or holders
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/141—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/40—Heating elements having the shape of rods or tubes
    • H05B3/42—Heating elements having the shape of rods or tubes non-flexible
    • H05B3/48—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3227—Lanthanum oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3256—Molybdenum oxides, molybdates or oxide forming salts thereof, e.g. cadmium molybdate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3817—Carbides
    • C04B2235/3826—Silicon carbides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3817—Carbides
    • C04B2235/3839—Refractory metal carbides
    • C04B2235/3847—Tungsten carbides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3873—Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3891—Silicides, e.g. molybdenum disilicide, iron silicide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6022—Injection moulding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/027—Heaters specially adapted for glow plug igniters

Definitions

  • the invention relates to a composite material, in particular to a composite material that can be used for ceramic electric heating bodies.
  • the ceramic electric heating body can be used as the electric heating body of the ignition mechanism.
  • the extremely high temperature reached by the ceramic at the moment of electrification can be used for ignition or heating. It can be used in engine ignition, gas stove ignition, water heater ignition, infrared radiation source, oxygen sensor heating, soldering iron tip heating, etc.
  • the electric heating body of ceramic material has the advantages of fast start-up, high temperature resistance, corrosion resistance, high strength and long life.
  • Chinese patent CN100484337C discloses a multilayer circular ceramic heater and its preparation process, and specifically discloses that the resistance layer, insulating layer and conductive layer of the ceramic heater include Si 3 N 4 , Al 2 O 3 , Y 2 O 3 and MoSi 2 four components; Si 3 N 4 functions to form a network structure, Al 2 O 3 and Y 2 O 3 function to adjust the network structure, and MoSi 2 functions to form a conductive heating material.
  • the ceramic electric heating body prepared by the above-mentioned components has a fast reaction speed, a high temperature, a time period for reaching a desired temperature, a long service life, a high yield of the manufacturing process, and a low manufacturing cost.
  • the composite materials prepared by the preparation materials in the above patents still have the following problems in some applications: high temperature coefficient of resistance and large inrush current directly lead to an increase in the cost of the power supply. Due to the rapid change of current/resistance, the use of The algorithm is complicated in power control.
  • the purpose of the present invention is to provide a composite material with a small impulse current, and at the same time reduce the application cost of a ceramic electric heating body prepared by using the material.
  • the present invention is achieved as follows: a composite material for ceramic electric heating bodies, characterized in that: the preparation components of the composite material include silicon nitride, molybdenum disilicide, silicon carbide, yttrium oxide, oxide Aluminum and lanthanum oxide.
  • the preparation components of the composite material include silicon nitride, molybdenum disilicide, silicon carbide, yttrium oxide, oxide Aluminum and lanthanum oxide.
  • silicon nitride, molybdenum disilicide and silicon carbide are the main functional materials, and aluminum oxide, yttrium oxide and lanthanum oxide are auxiliary materials.
  • the composite material prepared by using the above-mentioned material parts is suitable as the heating layer of the ceramic electric heating body.
  • the composite material prepared by using the above-mentioned material parts is suitable as the insulating layer of the ceramic electric heating body.
  • the composite material prepared by using the above-mentioned material parts is suitable as the conductive layer of the ceramic electric heating body.
  • the main functional material further includes tungsten carbide.
  • the auxiliary material further includes ytterbium oxide.
  • a ceramic electric heating body is prepared by using the above-mentioned composite material.
  • the impulse current is small when the temperature coefficient of resistance TCR is large, and the impulse current is small when the temperature coefficient of resistance TCR is small.
  • the cost of the supporting power supply and control components can be greatly reduced. It effectively solves the problems of high cost and difficult control of the original ceramic structural material body in the actual application of supporting control electronic components, and reaches the similar performance index of the international ceramic material structural body.
  • the use of the material of the present invention can use a 60W power supply, which reduces the requirement for power supply capacity.
  • silicon nitride, molybdenum disilicide and silicon carbide are the main functional materials, providing high-temperature performance, heating performance, electrical conductivity, etc. after the composite material is prepared into a ceramic heater.
  • Alumina, yttrium oxide and lanthanum oxide are auxiliary materials, which mainly help composite materials to help ceramic sintering, improve room temperature, high temperature strength, and high temperature oxidation resistance when preparing ceramic electric heating bodies.
  • the composite material in this embodiment can be used to prepare ceramic electric heating bodies.
  • the ceramic electric heating bodies in this embodiment are mostly ceramic electric heating bodies, including but not limited to heating layers, insulating layers, and conductive layers.
  • the main functional material further includes tungsten carbide (WC).
  • the auxiliary material further includes ytterbium oxide (Yb2O3).
  • a ceramic electric heating body is prepared by using the above-mentioned composite material.
  • the ceramic electric heating body in this embodiment has a multilayer structure from the inside and the outside, with at least two or more layers.
  • the inner layer structure is a resistive layer
  • the outer layer structure is a conductive layer.
  • the inner layer structure is a resistance layer
  • the middle layer structure is an insulating layer
  • the outer layer structure is a conductive layer.
  • the multilayer ceramic electric heating body in this embodiment is manufactured by grouting to prevent manufacturing, and includes the following steps:
  • Step 1 Prepare mixed slurry: silicon nitride, silicon carbide, molybdenum disilicide, yttrium oxide, lanthanum oxide, and aluminum oxide powder, add water according to the weight ratio, mix and stir evenly, and put it into a container.
  • different mixed slurries are prepared and equipped in different containers for standby.
  • Step 2 Grouting: Put the grouting molds with open ends on the grouting machine, and then pour the mixed ceramic slurry into the grouting machine to start grouting. According to the number of layers of the ceramic electric heating body, grouting is carried out in stages, and then the grouting is carried out sequentially from the outer layer to the inner layer.
  • Step 3 Sintering: Take out the copper grouting mold of the ceramic green body that has been dried and lose water, put it into the sintering mold, and finally put the sintering mold containing the green ceramic body into the sintering furnace for sintering at a temperature of 1400°C and a pressure Sintering at 2000-5000Kpa for 7-12 hours.
  • Step 4 Take the sintered ceramic material body out of the sintering mold, perform external trimming, and perform electrode assembly.
  • the impulse current is small when the temperature coefficient of resistance TCR is large, and the impulse current is small when the temperature coefficient of resistance TCR is small.
  • the cost of the supporting power supply and control components can be greatly reduced. It effectively solves the problems of high cost and difficult control of the original ceramic structural material body in the actual application of supporting control electronic components, and reaches the similar performance index of the international ceramic material structural body.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Resistance Heating (AREA)
  • Ceramic Products (AREA)

Abstract

一种用于陶瓷电热体的复合型材料，复合型材料的制备成分包括氮化硅、二硅化钼、碳化硅、氧化钇、氧化铝和氧化镧。该复合型材料，可使得陶瓷电热体的冲击电流小。

Description

一种用于陶瓷电热体的复合型材料 技术领域
本发明涉及一种复合型材料，尤其涉及可用于陶瓷电热体的复合型材料。
背景技术
陶瓷电热体作为一种导体材料，可将其作为点火机构的电热体使用，通过陶瓷在通电瞬间达到的极高温度，进行点火或加热。可应用在发动机点火、燃气灶点火、热水器点火、红外辐射源、氧传感器加热、烙铁头加热等等领域。陶瓷材料的电热体具有启动快、耐高温、耐腐蚀、强度高寿命长等优势。
在中国专利CN100484337C中公开了一种多层圆形陶瓷电热体及其制备工艺，并具体公开了陶瓷电热体的电阻层、绝缘层及导电层的组成成分包含Si 3N 4、Al 2O 3、Y 2O 3、MoSi 2四种成分；Si 3N 4作用为形成网状组织结构，Al 2O 3及Y 2O 3作用为调节网状组织，MoSi 2作用为形成导电发热材料。
通过上述成分制备的陶瓷电热体反应速度快、温度高、达到预期温度的时间段，使用寿命长，制作工艺的成品率高，制造成本低。
但是上述专利中的制备材料所制备的复合型材料，在一些应用中依然存在以下问题：电阻温度系数大，冲击电流大，直接导致供电电源的成本增加，因电流/电阻变化速度快，在采用功率控制时算法复杂。
发明内容
本发明的目的在于提供一种冲击电流小的复合型材料，同时降低使用该材料制备的陶瓷电热体的应用成本。
为了实现上述目的，本发明是这样实现的：一种用于陶瓷电热体的复合型材料，其特征在于：复合型材料的制备成分包括氮化硅、二硅化钼、碳化硅、氧化钇、氧化铝和氧化镧。其中氮化硅、二硅化钼和碳化硅为主功能性材料，氧化铝、氧化钇和氧化镧为辅助性材料。
为进一步降低冲击电流，所述复合型材料的成分按以下比例制备：氮化硅、碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(200-900)：(50-900)：(500-2800)：(40-100)：(10-90)：(5-80)。
进一步的，复合型材料按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(300-800)：(400-900)：(800-2800)：(40-100)：(30-90)：(5-80)。采用上述材料份数制备而成的复合型材料适合作为陶瓷电热体的发热层。
进一步的，复合型材料按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(400-900)：(50-200)：(500-800)：(40-90)：(30-80)：(5-60)。采用上述材料份数制备而成的复合型材料适合作为陶瓷电热体的绝缘层。
进一步的，复合型材料按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼、氧化钇：氧化镧：氧化铝＝(200-700)：(100-700)：(600-1500)：(40-80)：(10-70)：(5-50)。采用上述材料份数制备而成的复合型材料适合作为陶瓷电热体的导电层。
优选的，所述主功能性材料还包括碳化钨。
优选的，所述辅助性材料还包括氧化镱。
一种陶瓷电热体，采用上述所述的复合型材料制备而成。
有益效果：
采用本发明的复合型材料及陶瓷电热体，具有以下优势：
1.达到不同的电阻温度系数TCR，实现了负温度系数到正温度系数的任意转换，既能实现TCR＝-500，也可达到TCR＝5000,同时保证了原有陶瓷材料的多种性能优势，如启动快、耐高温、耐腐蚀、高强度等。
2、冲击电流小：同时做到了电阻温度系数TCR大时冲击电流小，且电阻温度系数TCR小时冲击电流也小。对于负或低的TCR，因为启动电流的降低，可以极大降低配套使用的电源及控制元件的成本。有效解决了原有的陶瓷结构材料体在实际应用配套控制电子元件成本高、控制困难的问题，达到国际陶瓷材料结构体类同性能指标。如以前采用为100W电源通过本发明的材料的使用可采用60W的电源，降低电源容量的要求。
具体实施方式
下面将通过附图中所示的实施例来介绍本发明，但本发明并不局限于所介绍的实施方式，任何在本实施例基本精神上的改进或替代，仍属于本发明权利要求 所要求保护的范围：
实施例：一种的复合型材料，其制备成分包括氮化硅(Si3N4)、二硅化钼(MOSi2)、碳化硅(SiC)、氧化钇(Y2O3)、氧化铝(Al2O3)和氧化镧(La2O3)。其中氮化硅、二硅化钼和碳化硅为主功能性材料，提供复合型材料制备成陶瓷电热体后的高温性能、发热性能、导电性能等。氧化铝、氧化钇和氧化镧为辅助性材料，主要帮助复合材料在制备陶瓷电热体时帮助陶瓷烧结、提高室温、高温强度、耐高温氧化能力等。
其中，所述复合型材料的成分按以下比例制备：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(200-900)：(50-900)：(500-2800)：(40-100)：(10-90)：(5-80)；可选择但不限于不同的比例份数进行制备：
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：50：500：40：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：400：500：40：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：50：1000：40：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：50：500：80：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：50：500：40：50：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：50：500：40：10：50；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝500：50：500：40：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝400：800：500：55：70：76；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝600：700：1200：70：30：20；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝800：70：2100： 67：60：35；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝900：900：2800：100：90：80。
其中，本实施例中的复合型材料可用来制备陶瓷电热体，本实施例中的陶瓷电热体为多成陶瓷电热体，包括但不限于发热层、绝缘层和导电层等。
对于发热层，可采用按以下材料份数制备的复合型材料：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(300-800)：(400-900)：(800-2800)：(40-100)：(30-90)：(5-80)。
可选择但不限于不同的比例份数进行制备：
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝300：400：800：40：30：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝400：800：1800：50：60：20；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝600：700：2000：80：70：70；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝700：4、500：1200：60：70：70；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝800：900：2800：100：90：80。
对于绝缘层，可采用按以下材料份数制备的复合型材料：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(400-900)：(50-200)：(500-800)：(40-90)：(30-80)：(5-60)。
可选择但不限于不同的比例份数进行制备：
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝400：50：500：40：30：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝500：100：600：60：70：35；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝700：150：700：50：40：30；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝800：90：650：70：40：50；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝900：200：800：90：80：60。
对于导电层，可采用按以下材料份数制备的复合型材料：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(200-700)：(100-700)：(600-1500)：(40-80)：(10-70)：(5-50)。
可选择但不限于不同的比例份数进行制备：
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝200：100：600：40：10：5；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝400：300：800：60：30：15；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝600：500：1000：70：50：30；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝500：600：1300：50：60：45；
如氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝700：700：1500：80：70：50。
作为本实施例中的另一实施方式，所述主功能性材料还包括碳化钨(WC)。
作为本实施例中的另一实施方式，所述辅助性材料还包括氧化镱(Yb2O3)。
一种陶瓷电热体，采用上述所述的复合型材料制备而成。
其中，本实施例中的陶瓷电热体为由内之外的多层层状结构，至少具有两层以上，当为两层时内层结构为电阻层，外层结构为导电层。当为三层结构时，内层结构为电阻层，中间层结构为绝缘层，外层结构为导电层。
其中，本实施例中的多层陶瓷电热体采用注浆防止制造，并包括以下步骤：
步骤1：制备混合浆料：氮化硅、碳化硅、二硅化钼、氧化钇、氧化镧、氧化铝粉末，按照重量配比加水混合搅拌均匀，装入容器内。其中，根据多层陶瓷电热体的不同层调配不同的混合浆料，装备在不同的容器中备用。
作为本实施例中的一种实施方式，以上材料成分的总和重量：水重＝1：(1-4)。
步骤2：注浆成型：将两端开口的注浆模放入注浆机上，再将混合好的陶瓷浆料注入注浆机内开始注浆成型。按照陶瓷电热体的层数分次注浆，才用由外层至内层的方式依次注浆。
步骤3：烧结：将干燥已失水的陶瓷胚体铜注浆模取出，放入烧结模内，最后将装有陶瓷生胚体的烧结模放入烧结炉内烧结，在温度1400℃、压力2000-5000Kpa下烧结7-12个小时。
步骤4：将烧结完后的陶瓷材料体从烧结模中取出，进行外部修整，并进行电极装配。
采用本实施例的复合型材料制造的陶瓷电热体，达到不同的电阻温度系数TCR，实现了负温度系数到正温度系数的任意转换，既能实现TCR＝-500，也可达到TCR＝5000,同时保证了原有陶瓷材料的多种性能优势，如启动快、耐高温、耐腐蚀、高强度等。
冲击电流小：同时做到了电阻温度系数TCR大时冲击电流小，且电阻温度系数TCR小时冲击电流也小。对于负或低的TCR，因为启动电流的降低，可以极大降低配套使用的电源及控制元件的成本。有效解决了原有的陶瓷结构材料体在实际应用配套控制电子元件成本高、控制困难的问题，达到国际陶瓷材料结构体类同性能指标。

Claims (9)

  1. 一种用于陶瓷电热体的复合型材料，其特征在于：复合型材料的制备成分包括氮化硅、二硅化钼、碳化硅、氧化钇、氧化铝和氧化镧。
  2. 如权利要求1所述的复合型材料，其特征在于：所述复合型材料的成分按以下比例制备：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(200-900)：(50-900)：(500-2800)：(40-100)：(10-90)：(5-80)。
  3. 如权利要求2所述的复合型材料，其特征在于：按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(300-800)：(400-900)：(800-2800)：(40-100)：(30-90)：(5-80)。
  4. 如权利要求2所述的复合型材料，其特征在于：按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(400-900)：(50-200)：(500-800)：(40-90)：(30-80)：(5-60)。
  5. 如权利要求2所述的复合型材料，其特征在于：按以下材料份数制备而成：氮化硅：碳化硅：二硅化钼：氧化钇：氧化镧：氧化铝＝(200-700)：(100-700)：(600-1500)：(40-80)：(10-70)：(5-50)。
  6. 如权利要求1、2、3、4或5所述的复合型材料，其特征在于：所述主功能性材料还包括碳化钨。
  7. 如权利要求1、2、3、4或5所述的复合型材料，其特征在于：所述辅助性材料还包括氧化镱。
  8. 如权利要求6所述的复合型材料，其特征在于：所述辅助性材料还包括氧化镱。
  9. 一种陶瓷电热体，其特征在于：采用上述任一项权利要求所述复合型材料制造而成。
PCT/CN2020/114756 2019-09-25 2020-09-11 一种用于陶瓷电热体的复合型材料 Ceased WO2021057512A1 (zh)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US17/761,177 US20230354480A1 (en) 2019-09-25 2020-09-11 Composite material for ceramic electric heating element
EP20869722.7A EP4036072A4 (en) 2019-09-25 2020-09-11 COMPOSITE MATERIAL FOR A CERAMIC ELECTRIC RADIATOR
JP2022518167A JP7488890B2 (ja) 2019-09-25 2020-09-11 セラミック電気発熱体用複合材料
MX2022003170A MX2022003170A (es) 2019-09-25 2020-09-11 Material compuesto para elemento de calefaccion electrica ceramica.
KR1020227011922A KR102719978B1 (ko) 2019-09-25 2020-09-11 세라믹 전기발열체용 복합재료
CA3154927A CA3154927C (en) 2019-09-25 2020-09-11 COMPOSITE-TYPE MATERIAL FOR CERAMIC ELECTRIC HEATING ELEMENTS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201910912107.6 2019-09-25
CN201910912107.6A CN110590371A (zh) 2019-09-25 2019-09-25 一种用于陶瓷电热体的复合型材料

Publications (1)

Publication Number Publication Date
WO2021057512A1 true WO2021057512A1 (zh) 2021-04-01

Family

ID=68863287

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/114756 Ceased WO2021057512A1 (zh) 2019-09-25 2020-09-11 一种用于陶瓷电热体的复合型材料

Country Status (8)

Country Link
US (1) US20230354480A1 (zh)
EP (1) EP4036072A4 (zh)
JP (1) JP7488890B2 (zh)
KR (1) KR102719978B1 (zh)
CN (1) CN110590371A (zh)
CA (1) CA3154927C (zh)
MX (1) MX2022003170A (zh)
WO (1) WO2021057512A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2024537281A (ja) * 2022-03-30 2024-10-10 チョンチン リ－マーク テクノロジー カンパニー リミテッド オールセラミック発熱体

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110590371A (zh) * 2019-09-25 2019-12-20 重庆利迈陶瓷技术有限公司 一种用于陶瓷电热体的复合型材料
CN116730724B (zh) * 2023-05-05 2024-11-01 衡阳凯新特种材料科技有限公司 一种用于陶瓷探针的碳化硅复合陶瓷材料及其制备方法
CN118026701A (zh) * 2024-01-31 2024-05-14 浙江上硅聚力特材科技有限公司 一种氮化硅基陶瓷电发热体制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100484337C (zh) 2004-08-21 2009-04-29 雷彼得 多层圆形陶瓷陶瓷电热体及制备工艺
CN101455118A (zh) * 2006-05-18 2009-06-10 日本特殊陶业株式会社 陶瓷加热器和电热塞
CN104860681A (zh) * 2014-02-26 2015-08-26 东莞市国研电热材料有限公司 一种叠层式陶瓷加热体及其制备工艺
JP2019021501A (ja) * 2017-07-18 2019-02-07 日本特殊陶業株式会社 セラミックヒータ、及びグロープラグ
CN109526079A (zh) * 2018-12-18 2019-03-26 重庆利迈陶瓷技术有限公司 一种大电压陶瓷电热体
CN110536491A (zh) * 2019-09-25 2019-12-03 重庆利迈陶瓷技术有限公司 一种两层结构的陶瓷电热体及电烙铁
CN110590371A (zh) * 2019-09-25 2019-12-20 重庆利迈陶瓷技术有限公司 一种用于陶瓷电热体的复合型材料

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5085804A (en) * 1984-11-08 1992-02-04 Norton Company Refractory electrical device
CA1240710A (en) * 1984-11-08 1988-08-16 Malcolm E. Washburn Refractory composition and products resulting therefrom
JP3600658B2 (ja) * 1995-02-02 2004-12-15 株式会社デンソー セラミックヒータ及びその製造方法
JP3785696B2 (ja) * 1996-09-11 2006-06-14 株式会社デンソー グロープラグ
US5786565A (en) * 1997-01-27 1998-07-28 Saint-Gobain/Norton Industrial Ceramics Corporation Match head ceramic igniter and method of using same
US6797220B2 (en) * 2000-12-04 2004-09-28 Advanced Ceramics Research, Inc. Methods for preparation of three-dimensional bodies
CN1596557A (zh) * 2001-11-30 2005-03-16 揖斐电株式会社 陶瓷加热器
DE102006027958A1 (de) * 2006-06-14 2007-12-20 Schott Ag Optokeramiken, daraus hergestellte optische Elemente sowie Abbildungsoptiken
DE102006062371A1 (de) * 2006-12-20 2008-06-26 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Elektrisch leitender Keramikkompositwerkstoff
US8901467B2 (en) * 2010-12-09 2014-12-02 Surface Igniter Llc Multi-layer ceramic heater and/or igniter and method for making the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100484337C (zh) 2004-08-21 2009-04-29 雷彼得 多层圆形陶瓷陶瓷电热体及制备工艺
CN101455118A (zh) * 2006-05-18 2009-06-10 日本特殊陶业株式会社 陶瓷加热器和电热塞
CN104860681A (zh) * 2014-02-26 2015-08-26 东莞市国研电热材料有限公司 一种叠层式陶瓷加热体及其制备工艺
JP2019021501A (ja) * 2017-07-18 2019-02-07 日本特殊陶業株式会社 セラミックヒータ、及びグロープラグ
CN109526079A (zh) * 2018-12-18 2019-03-26 重庆利迈陶瓷技术有限公司 一种大电压陶瓷电热体
CN110536491A (zh) * 2019-09-25 2019-12-03 重庆利迈陶瓷技术有限公司 一种两层结构的陶瓷电热体及电烙铁
CN110590371A (zh) * 2019-09-25 2019-12-20 重庆利迈陶瓷技术有限公司 一种用于陶瓷电热体的复合型材料

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP4036072A4

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2024537281A (ja) * 2022-03-30 2024-10-10 チョンチン リ－マーク テクノロジー カンパニー リミテッド オールセラミック発熱体
EP4503847A4 (en) * 2022-03-30 2026-03-18 Chongqing Le Mark Tech Co Ltd HEATING ELEMENT MADE ENTIRELY OF CERAMIC

Also Published As

Publication number Publication date
CA3154927A1 (en) 2021-04-01
US20230354480A1 (en) 2023-11-02
KR102719978B1 (ko) 2024-10-18
JP7488890B2 (ja) 2024-05-22
CA3154927C (en) 2025-04-08
EP4036072A1 (en) 2022-08-03
CN110590371A (zh) 2019-12-20
JP2022550290A (ja) 2022-12-01
MX2022003170A (es) 2022-05-25
EP4036072A4 (en) 2023-10-18
KR20220061205A (ko) 2022-05-12

Similar Documents

Publication Publication Date Title
WO2021057512A1 (zh) 一种用于陶瓷电热体的复合型材料
CN108530109B (zh) 一种碳/碳复合材料表面1500~1700℃抗氧化涂层及制备方法
CN109400164B (zh) 一种max相/氮化物陶瓷层状梯度复合材料及其快速制备方法和应用
CN111116228A (zh) 一种抗烧蚀ZrC-HfC/SiC双层复相陶瓷涂层的制备方法
WO2021057507A1 (zh) 一种两层结构的陶瓷电热体及电烙铁
CN106587629A (zh) 硼化物改性玻璃陶瓷基复合高温抗氧化涂层及其制备方法
CN106376107A (zh) 大功率氮化硅陶瓷加热片及其内软外硬的制作方法
CN112279653B (zh) 一种具有裂纹愈合能力的陶瓷材料及其制备方法
CN104844199B (zh) 注浆法制备氧化锆-硼化锆双层复合陶瓷发热体的工艺
US4556780A (en) Ceramic heater
CN110903074A (zh) 一种碳化硅基体表面高温抗氧化涂层及其制备方法
CN104844250B (zh) 一种耐高温多孔夹层透波材料及其制备方法
CN115849958B (zh) 一种陶瓷基复合材料的热防护涂层及其制备方法和应用
CN104829227B (zh) 一种氧化锆‑硼化锆双层复合陶瓷发热体及其制备方法
CN101182212B (zh) 硼化物-氧化物复相陶瓷及其制备方法
CN107324807A (zh) 一种低压高能SiC半导体电嘴材料的制备方法
CN110453104B (zh) 一种钛基SiC-Ti混杂梯度材料及其制备方法
CN109678560B (zh) 一种在基体材料上形成的高温抗烧蚀涂层及其制备方法和应用
JP2537606B2 (ja) セラミツクヒ−タ
CN120443178B (zh) 一种钽钨合金抗氧化涂层及其制备工艺
CN102875179B (zh) 一种电池用异质陶瓷材料的封接方法
CN103288456A (zh) 一种无金属离子添加的高纯硅氮氧陶瓷的低温制备方法
US20250044043A1 (en) Latent heat storage unit
CN107734721A (zh) 一种液相热煤炉用陶瓷加热圈
CN118234069A (zh) 发热体、制备发热体的方法及发热装置

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20869722

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: MX/A/2022/003170

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 3154927

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2022518167

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20227011922

Country of ref document: KR

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2020869722

Country of ref document: EP

Effective date: 20220425

WWG Wipo information: grant in national office

Ref document number: MX/A/2022/003170

Country of ref document: MX