WO2021154603A1 - Single photon avalanche diode device - Google Patents

Single photon avalanche diode device Download PDF

Info

Publication number
WO2021154603A1
WO2021154603A1 PCT/US2021/014647 US2021014647W WO2021154603A1 WO 2021154603 A1 WO2021154603 A1 WO 2021154603A1 US 2021014647 W US2021014647 W US 2021014647W WO 2021154603 A1 WO2021154603 A1 WO 2021154603A1
Authority
WO
WIPO (PCT)
Prior art keywords
implanted
region
type
pixel elements
type material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2021/014647
Other languages
French (fr)
Inventor
Ching-Ying Lu
Yangsen KANG
Shuang Li
Kai ZANG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adaps Photonics Inc
Original Assignee
Adaps Photonics Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adaps Photonics Inc filed Critical Adaps Photonics Inc
Priority to CN202180011174.6A priority Critical patent/CN115176346B/en
Priority to JP2022554744A priority patent/JP7319743B2/en
Priority to EP21748257.9A priority patent/EP4097771A4/en
Publication of WO2021154603A1 publication Critical patent/WO2021154603A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F30/00Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors
    • H10F30/20Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors
    • H10F30/21Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation
    • H10F30/22Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes
    • H10F30/225Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes the potential barrier working in avalanche mode, e.g. avalanche photodiodes
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • C30B25/18Epitaxial-layer growth characterised by the substrate
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04NPICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N25/00Circuitry of solid-state image sensors [SSIS]; Control thereof
    • H04N25/70SSIS architectures; Circuits associated therewith
    • H04N25/76Addressed sensors, e.g. MOS or CMOS sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/10Integrated devices
    • H10F39/12Image sensors
    • H10F39/199Back-illuminated image sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/807Pixel isolation structures
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/809Constructional details of image sensors of hybrid image sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/811Interconnections
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/95Circuit arrangements
    • H10F77/953Circuit arrangements for devices having potential barriers
    • H10F77/959Circuit arrangements for devices having potential barriers for devices working in avalanche mode
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/806Optical elements or arrangements associated with the image sensors
    • H10F39/8067Reflectors

Definitions

  • the present invention relates generally to sensing devices. More particularly, the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices.
  • CMOS complementary metal oxide semiconductor
  • the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
  • a photodiode is a p-n junction or PIN structure. When a photon of sufficient energy strikes the diode, it creates an electron-hole pair. This mechanism is also known as the inner photoelectric effect. If the absorption occurs in the junction's depletion region, or one diffusion length away from it, these carriers are swept from the junction by the built-in electric field of the depletion region. Thus holes move toward the anode, and electrons toward the cathode, and a photocurrent is produced. The total current through the photodiode is the sum of the dark current (current that is generated in the absence of light) and the photocurrent, so the dark current must be minimized to maximize the sensitivity of the device. See, Photodiode, Wikipedia.
  • avalanche photodiode Another example of a photo diode is called an "avalanche photodiode.”
  • the avalanche photodiodes are photodiodes with structure optimized for operating with high reverse bias, approaching the reverse breakdown voltage. This allows each photo-generated carrier to be multiplied by avalanche breakdown, resulting in internal gain within the photodiode, which increases the effective responsivity of the device.
  • Many limitations exist with these convention photodiodes These devices are difficult to manufacture. These devices also have poor signal to noise ratios for sensitive applications. Additionally, such photodiodes are often not capable of being integrated with complex integrated circuit devices. Power consumption is also high, thereby limiting the applications for these devices.
  • the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices.
  • CMOS complementary metal oxide semiconductor
  • the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
  • the present invention provides a single photon avalanche diode device.
  • the device has a logic substrate comprising an upper surface.
  • the logic substrate comprises a semiconductor substrate with logic circuitry, such as those made using CMOS technology.
  • the device has a sensor substrate bonded to an upper surface of the logic substrate.
  • the sensor substrate comprises a plurality of pixel elements spatially disposed to form an array structure.
  • each of the pixel elements has a passivation material, an epitaxially grown silicon material, an implanted p-type material configured in a first portion of the epitaxially grown material, an implanted n-type material configured in a second portion of the epitaxially grown material, and a junction region configured from the implanted p-type material and the implanted n-type material.
  • Each pixel element has a deep trench region bordering the pixel element.
  • the trench region comprises a fill material, a surrounding charge material, and a surrounding insulating material.
  • the device also has a first contact region coupled to the implanted p-type material and a second contact region coupled to the implanted n-type material.
  • the single photon avalanche photodiode in operation works by biasing the device above a breakdown voltage of the device.
  • an avalanche region which is a region where the electric field is above the avalanche breakdown threshold
  • both electrons and holes have a probability of breaking a silicon covalent bond to free another electron-hole pair in a process.
  • the process results in a multiplication of electron-hole pairs with a gain typically larger than 10 5 -10 6 . Therefore, a single photon detected and generating a photo-generated electron-hole pair causes a large signal pulse. Further details of the present operation can be found throughout the present specification and more particularly below.
  • the present technique provides an easy to use process that relies upon conventional technology.
  • the method provides higher device yields in dies per wafer with the integrated approach.
  • the method provides a process and system that are compatible with conventional process technology without substantial modifications to conventional equipment and processes.
  • the invention provides for an improved CMOS integrated circuit device and related methods for a variety of uses. Depending upon the embodiment, one or more of these benefits may be achieved.
  • Figure 1 is a simplified cross-sectional view diagram of a device according to an embodiment of the present invention.
  • Figure 2 is a top-view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 3 is a more detailed cross-sectional view diagram of a device according to an embodiment of the present invention.
  • Figure 4 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 5 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 6 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 7 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 8 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 9 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • Figure 10 is a simplified cross-sectional view diagram of a sensor device of Figure 9 according to an alternative embodiment of the present invention.
  • the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices.
  • CMOS complementary metal oxide semiconductor
  • the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
  • FIG. 1 is a simplified cross-sectional view diagram of a device according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, a single photon avalanche diode device 100 is provided. The device has a semiconductor substrate 101 comprising an upper surface.
  • the semiconductor substrate is a wafer having logic circuits, and related cells.
  • the semiconductor substrate can be called a logic substrate.
  • the substrate can be a complementary metal oxide silicon (CMOS) substrate, a blank or unpatterned substrate, a patterned, hybrid substrate, among others.
  • CMOS complementary metal oxide silicon
  • the semiconductor substrate has a plurality of CMOS cells for logic circuitry, and can also include a plurality of memory cells, interface cells, and other circuit elements.
  • the substrate has a bonding point 103 and logic circuits 105, which can be configured as an output, quenching, recharge circuit, among others.
  • CMOS complementary metal oxide silicon
  • the device has a sensor substrate and bonding region 107 bonded to an upper surface of the sensor substrate at the bonding point or plane.
  • the term sensor substrate is a semiconductor substrate having one or more sensing elements thereon.
  • the upper surface has been planarized.
  • the sensor substrate comprises a plurality of pixel elements 109 spatially disposed to form an array structure.
  • the array structure is N by M, where N is 1 and greater and M is 1 and greater.
  • N ranges from 1 to 10 or 1000 or millions or billions and M is 1 to 10 or millions or billions, among other variations.
  • each of the pixel elements has a size ranging from 1 micron to about 100 microns, although there can be other variations. As shown, two side view diagrams of pixel elements are shown.
  • each of the pixel elements has a passivation material.
  • the passivation material (which can be formed as layers) includes an oxide material, a high-K dielectric material, a nitride material, or a polyimide material, combinations thereof, and the like.
  • each of the pixel elements is formed on an epitaxially grown silicon material.
  • the epitaxially grown silicon material can be formed using an epitaxial reactor using silicon based precursor gases. As shown, a thickness of epitaxial material is made of a suitable thickness and is grown using a high temperature growth technique, among others.
  • the epitaxial material is a monocrystalline silicon material, which is substantially defect free.
  • the device has passivation material 111.
  • each of the pixel elements has an implanted p-type material 113 configured in a first portion of the epitaxially grown material, an implanted n-type material 115 configured in a second portion of the epitaxially grown material, and a junction region configured from the implanted p-type material and the implanted n-type material.
  • the implanted p- type material comprises a boron material having a concentration density of 1E15 atoms/cm 3 to 1E18 atoms/cm 3 .
  • the implanted n-type material comprises a phosphorous entity or an arsenic entity having a concentration density of 1E17 atoms/cm 3 to 1E19 atoms/cm 3 .
  • the implanted p-type material and the implanted n-type material are configured within a vicinity of the semiconductor substrate of the pixel element or near the bonding region, as shown.
  • each pixel element has a deep trench region 117 bordering the pixel element.
  • the trench region comprises a fill material, a surrounding charge material, and a surrounding insulating material 119.
  • the fill material comprises a metal material, a semiconductor material, or an insulating material.
  • the fill material is a metal material to prevent cross-talk, although the fill material can also be an insulating material, such as oxide material.
  • the surrounding charge material is a high K dielectric material.
  • the surrounding insulating material includes an oxide or a nitride material, among others.
  • the charge material configured at a deep trench isolation structure has a negative charge.
  • high k dielectric material such as AI 2 O 3 deposited by atomic layer deposition techniques forms negative fixed charge at an Si02/AI203 interface region.
  • the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Additionally, spatially excluding the deep trench isolation sidewall interface from the depletion region greatly reduces chances for the interface defects to drift to the avalanche region. Accordingly, noise or the dark count rate can be greatly reduced.
  • the device also has a first contact region 121 coupled to the implanted p- type material and a second contact region coupled to the implanted n-type material on the opposite side of the sensor substrate.
  • the contacts are configured as an anode and a cathode for each of the pixel elements.
  • the device has a bottom metal reflector, as shown.
  • the metal reflector can be made of an aluminum material, a metal/oxide material, or a semiconductor material.
  • the bottom reflector is configured to reflect light back into an active region of the epitaxial material or active region.
  • FIG. 2 is a top-view diagram of a device according to an alternative embodiment of the present invention.
  • This diagram is merely an example, which should not unduly limit the scope of the claims herein.
  • such device includes integrated circuit elements to replace certain elements from the logic substrate, which is described herein.
  • each pixel element 200 has a surrounding trench region, and inner active region, which is made of epitaxial material.
  • each pixel element has the p-type implanted region 201 within the n-type implanted region 203, as shown.
  • Each of the pixel elements is configured as a square, but can also be configured in other shapes, such as a circle, a rectangle, oval, or other variations.
  • each pixel region is coupled to an integrated high voltage transistor 207, and has a quenching resistor 205, as shown.
  • Each of the transistor and resistor circuit elements are monolithically integrated with the sensor substrate and pixel elements.
  • FIG. 3 is a more detailed cross-sectional view diagram of a device according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein.
  • the device has the surrounding trench region 300, which is configured from a deep trench isolation.
  • the deep trench isolation is configured from an etching process.
  • the trench region comprises a fill material, a surrounding charge material 305, 307, and a surrounding insulating material 301 303.
  • the surrounding insulating material includes an oxide or a nitride material, among others.
  • the charge material configured at a deep trench isolation structure has a negative charge.
  • high k dielectric material such as AI2O3 deposited by atomic layer deposition techniques forms negative fixed charge at an S1O2/AI2O3 interface region.
  • the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Such configuration reduces a dark count rate, leading to efficiencies with the device.
  • the trench is filled with a conductive material, such as metal, to prevent cross-talk or other limitations leading to problems.
  • the conductive material can also be biased at the same bias as the anode or more negative bias in reference to the anode depending upon the embodiment.
  • the device has a low doped epitaxial silicon region 311 coupled to a higher doped avalanche region.
  • p+ type material 309 provides for lateral conduction and a low contact resistance.
  • an n type material 315 configured within the epitaxial material.
  • the device also has a p type material 313 overlying the n type material.
  • the device also has contact region 317 coupled to the p type material and an overlying passivation material 319.
  • FIG 4 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • the device can include a shallow trench isolation 401, 403 below the deep trench isolation (which was referred to as the surrounding trench region).
  • the shallow trench isolation can include an oxide material as a filler.
  • FIG. 5 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • the device can include a micro lens 501 configured overlying the surface of the substrate.
  • the micro lens is configured to focus incoming light onto active regions of the epitaxial material.
  • the micro lens can be monolithically integrated or made of an optical material that is mechanically attached to the passivation layer.
  • Figure 6 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • the device has an anti- reflective material 601 overlying a backside of the device.
  • the anti-reflective layer can be any optical material, such as an oxide, a nitride, or metal oxides, or other suitable materials, or combinations thereof, or the like.
  • the anti-reflective coating reduces light refraction at the backside surface, which allows more light to travel into an active device region.
  • FIG. 7 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • the device has nanostructures 701. That is each of the pixel elements comprises a plurality of nano-structures configured within a vicinity of an interface to the upper surface to facilitate trapping of a photon coming in contact with the nano-structure.
  • the nano-structures can be made on the sensor substrate.
  • the nano-structures are made using one or more of the following processes.
  • nano-structures are formed using a periodic pattern (or can also be unpatterned in other examples) made by using a dry etching or selective wet etching of a silicon bearing material.
  • dry etching of silicon bearing material causes formation of rectangular, or circular, or hexagonal shapes, or other shapes, of holes or openings.
  • the period of the nano-structures can be in the range of 650-850nm, and a diameter of the nano-holes or openings can be in the range of 400-600nm, although there can be other variations.
  • the depth of nano structures can be in the range of 300-450 nm, but can be others.
  • the nano holes are oxidized and filled with an oxide fill material.
  • nano structures can also be made by a selective wet etching process.
  • selective wet etching creates an inverse pyramid of holes or openings as shown.
  • the period of the inverse pyramid can be in the range of 700-900nm, among others.
  • the depth of the inverse pyramid depends on the period of the pyramid because of a fixed angle of pyramid resulted from crystal direction. After wet etching, the pyramids are also oxidized and filled with oxide fill material. Further details of the present nanostructure configuration can be found throughout the present specification.
  • FIG. 8 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • each of the pixel elements comprises a plurality of nano-structures 801 configured overlying the aperture region to facilitate trapping of a photon coming in contact with the nano-structure.
  • the nano-structure is configured from a silicon material. As shown, nanostructures 701 are configured within a vicinity of the interface region, and nanostructures 801 are configured within a vicinity of the aperture region.
  • FIG. 9 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
  • the device can also be configured as an inverted structure.
  • the implanted p-type material 901 and the implanted n-type 903 material are configured within a vicinity of an aperture region of the pixel element.
  • the device also has epitaxial material 905 defined within a pixel element surrounded by a trench region. As shown, each trench region has a fill material 907, a dielectric material, and a charge layer (collectively reference numeral 909).
  • the device has an overlying passivation material 911, which can be a silicon dioxide, silicon nitride, or combinations thereof.
  • An upper contact region 913 is coupled to the n-type material, as shown.
  • the device also has a lower contact region coupled to bonding point 915 and p-type material.
  • the device has a bottom metal reflector, as shown.
  • the metal reflector can be made of an aluminum material, a metal/oxide material, or a semiconductor material.
  • the bottom reflector is configured to reflect light back into an active region of the epitaxial material or active region.
  • the device has a logic substrate 919, which is a semiconductor substrate configured with logic circuitry.
  • the substrate can be a complementary metal oxide silicon (CMOS) substrate, a blank or unpatterned substrate, a patterned, hybrid substrate, among others.
  • the semiconductor substrate has a plurality of CMOS cells for logic circuitry, and can also include a plurality of memory cells, interface cells, and other circuit elements.
  • the substrate has a bonding region 917 and logic circuits 921, which can be configured as an output, quenching, recharge circuit, among others.
  • CMOS complementary metal oxide silicon
  • FIG 10 is a simplified cross-sectional view diagram of a sensor device of Figure 9 according to an alternative embodiment of the present invention.
  • the device can also be configured as an inverted structure.
  • the implanted p-type material 1009 and the implanted n-type 1007 material are configured within a vicinity of an aperture region of the pixel element.
  • the device also has epitaxial material 1003 defined within a pixel element surrounded by a trench region. As shown, each trench region has a fill material 1010, a dielectric material, and a charge layer 1015 1017, and a thin layer of dielectric material 1011 1013.
  • the device has an overlying passivation material 1005, which can be a silicon dioxide, silicon nitride, or combinations thereof.
  • An upper contact region 1019 is coupled to the n-type material, as shown.
  • the device has a p+ type region 1001, as shown.
  • the device also has a lower contact region coupled to bonding point.
  • the charge material configured at a deep trench isolation structure has a negative charge.
  • high k dielectric material such as AI2O3 deposited by atomic layer deposition techniques forms negative fixed charge at an Si02/AI203 interface region.
  • the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Additionally, spatially excluding the deep trench isolation sidewall interface from the depletion region greatly reduces chances for the interface defects to drift to the avalanche region. Accordingly, noise or the dark count rate can be greatly reduced.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Multimedia (AREA)
  • Signal Processing (AREA)
  • Solid State Image Pick-Up Elements (AREA)
  • Light Receiving Elements (AREA)

Abstract

The present invention provides a single photon avalanche diode device. The device has a logic substrate comprising an upper surface. The device has a sensor substrate bonded to an upper surface of the logic substrate. In an example, the sensor substrate comprises a plurality of pixel elements spatially disposed to form an array structure. In an example, each of the pixel elements has a passivation material, an epitaxially grown silicon material, an implanted p-type material configured in a first portion of the epitaxially grown material, an implanted n-type material configured in a second portion of the epitaxially grown material, and a junction region configured from the implanted p-type material and the implanted n-type material.

Description

SINGLE PHOTON AVALANCHE DIODE DEVICE
BACKGROUND OF INVENTION
[0001] The present invention relates generally to sensing devices. More particularly, the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices. Merely by way of example, the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
[0002] Research and development in integrated microelectronics have continued to produce astounding progress with sensor devices. Many examples of photo diodes exist. For example, a photodiode is a p-n junction or PIN structure. When a photon of sufficient energy strikes the diode, it creates an electron-hole pair. This mechanism is also known as the inner photoelectric effect. If the absorption occurs in the junction's depletion region, or one diffusion length away from it, these carriers are swept from the junction by the built-in electric field of the depletion region. Thus holes move toward the anode, and electrons toward the cathode, and a photocurrent is produced. The total current through the photodiode is the sum of the dark current (current that is generated in the absence of light) and the photocurrent, so the dark current must be minimized to maximize the sensitivity of the device. See, Photodiode, Wikipedia.
[0003] Another example of a photo diode is called an "avalanche photodiode." The avalanche photodiodes are photodiodes with structure optimized for operating with high reverse bias, approaching the reverse breakdown voltage. This allows each photo-generated carrier to be multiplied by avalanche breakdown, resulting in internal gain within the photodiode, which increases the effective responsivity of the device. [0004] Although highly successful, many limitations exist with these convention photodiodes. These devices are difficult to manufacture. These devices also have poor signal to noise ratios for sensitive applications. Additionally, such photodiodes are often not capable of being integrated with complex integrated circuit devices. Power consumption is also high, thereby limiting the applications for these devices. These and other limitations of conventional photo didoes may be further described throughout the present specification and more particularly below.
[0005] From the above, it is seen that techniques for improving sensing devices are highly desired.
SUMMARY
[0006] According to the present invention, techniques related generally to sensing devices are provided. More particularly, the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices. Merely by way of example, the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
[0007] In an example, the present invention provides a single photon avalanche diode device. The device has a logic substrate comprising an upper surface. In an example, the logic substrate comprises a semiconductor substrate with logic circuitry, such as those made using CMOS technology. The device has a sensor substrate bonded to an upper surface of the logic substrate. In an example, the sensor substrate comprises a plurality of pixel elements spatially disposed to form an array structure. In an example, each of the pixel elements has a passivation material, an epitaxially grown silicon material, an implanted p-type material configured in a first portion of the epitaxially grown material, an implanted n-type material configured in a second portion of the epitaxially grown material, and a junction region configured from the implanted p-type material and the implanted n-type material. Each pixel element has a deep trench region bordering the pixel element. In an example, the trench region comprises a fill material, a surrounding charge material, and a surrounding insulating material. The device also has a first contact region coupled to the implanted p-type material and a second contact region coupled to the implanted n-type material.
[0008] In an example, the single photon avalanche photodiode in operation works by biasing the device above a breakdown voltage of the device. When a photo-generated electron-hole pair reaches an avalanche region (which is a region where the electric field is above the avalanche breakdown threshold), both electrons and holes have a probability of breaking a silicon covalent bond to free another electron-hole pair in a process. The process results in a multiplication of electron-hole pairs with a gain typically larger than 105-106. Therefore, a single photon detected and generating a photo-generated electron-hole pair causes a large signal pulse. Further details of the present operation can be found throughout the present specification and more particularly below.
[0009] Many benefits are achieved by way of the present invention over conventional techniques. For example, the present technique provides an easy to use process that relies upon conventional technology. In some embodiments, the method provides higher device yields in dies per wafer with the integrated approach. Additionally, the method provides a process and system that are compatible with conventional process technology without substantial modifications to conventional equipment and processes. Preferably, the invention provides for an improved CMOS integrated circuit device and related methods for a variety of uses. Depending upon the embodiment, one or more of these benefits may be achieved. These and other benefits will be described in more throughout the present specification and more particularly below. [0010] Various additional objects, features and advantages of the present invention can be more fully appreciated with reference to the detailed description and accompanying drawings that follow.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] Figure 1 is a simplified cross-sectional view diagram of a device according to an embodiment of the present invention.
[0012] Figure 2 is a top-view diagram of a device according to an alternative embodiment of the present invention.
[0013] Figure 3 is a more detailed cross-sectional view diagram of a device according to an embodiment of the present invention.
[0014] Figure 4 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0015] Figure 5 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0016] Figure 6 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0017] Figure 7 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0018] Figure 8 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0019] Figure 9 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention.
[0020] Figure 10 is a simplified cross-sectional view diagram of a sensor device of Figure 9 according to an alternative embodiment of the present invention.
DETAILED DESCRIPTION OF THE SPECIFIC EMBODIMENTS [0021] According to the present invention, techniques related generally to sensing devices are provided. More particularly, the present invention provides a method and device for sensing light using a photo diode technique, and in particular a single photon avalanche diode technique in combination with one or more complementary metal oxide semiconductor (CMOS) devices. Merely by way of example, the device can be used sensor applications, time of flight applications, LiDAR applications, among others. But it will be recognized that the invention has a much broader range of applicability.
[0022] Figure 1 is a simplified cross-sectional view diagram of a device according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, a single photon avalanche diode device 100 is provided. The device has a semiconductor substrate 101 comprising an upper surface.
As shown, the semiconductor substrate is a wafer having logic circuits, and related cells. In an example, the semiconductor substrate can be called a logic substrate. In an example, the substrate can be a complementary metal oxide silicon (CMOS) substrate, a blank or unpatterned substrate, a patterned, hybrid substrate, among others. In an example, the semiconductor substrate has a plurality of CMOS cells for logic circuitry, and can also include a plurality of memory cells, interface cells, and other circuit elements. As shown, the substrate has a bonding point 103 and logic circuits 105, which can be configured as an output, quenching, recharge circuit, among others. Of course, there can be other variations, modifications, and alternatives.
[0023] In an example, the device has a sensor substrate and bonding region 107 bonded to an upper surface of the sensor substrate at the bonding point or plane. In an example, the term sensor substrate is a semiconductor substrate having one or more sensing elements thereon.
In an example, the upper surface has been planarized. In an example, the sensor substrate comprises a plurality of pixel elements 109 spatially disposed to form an array structure. In an example, the array structure is N by M, where N is 1 and greater and M is 1 and greater. In an example, N ranges from 1 to 10 or 1000 or millions or billions and M is 1 to 10 or millions or billions, among other variations. In an example, each of the pixel elements has a size ranging from 1 micron to about 100 microns, although there can be other variations. As shown, two side view diagrams of pixel elements are shown.
[0024] In an example, each of the pixel elements has a passivation material. In an example, the passivation material (which can be formed as layers) includes an oxide material, a high-K dielectric material, a nitride material, or a polyimide material, combinations thereof, and the like. In an example, each of the pixel elements is formed on an epitaxially grown silicon material. The epitaxially grown silicon material can be formed using an epitaxial reactor using silicon based precursor gases. As shown, a thickness of epitaxial material is made of a suitable thickness and is grown using a high temperature growth technique, among others. In an example, the epitaxial material is a monocrystalline silicon material, which is substantially defect free. In an example, the device has passivation material 111.
As shown, each of the pixel elements has an implanted p-type material 113 configured in a first portion of the epitaxially grown material, an implanted n-type material 115 configured in a second portion of the epitaxially grown material, and a junction region configured from the implanted p-type material and the implanted n-type material. In an example, the implanted p- type material comprises a boron material having a concentration density of 1E15 atoms/cm3 to 1E18 atoms/cm3. In an example, the implanted n-type material comprises a phosphorous entity or an arsenic entity having a concentration density of 1E17 atoms/cm3 to 1E19 atoms/cm3. Of course, there can be other variations, modifications, and alternatives. As shown, the implanted p-type material and the implanted n-type material are configured within a vicinity of the semiconductor substrate of the pixel element or near the bonding region, as shown.
[0025] As shown, each pixel element has a deep trench region 117 bordering the pixel element. In an example, the trench region comprises a fill material, a surrounding charge material, and a surrounding insulating material 119. In an example, the fill material comprises a metal material, a semiconductor material, or an insulating material. In a preferred example, the fill material is a metal material to prevent cross-talk, although the fill material can also be an insulating material, such as oxide material. In an example, the surrounding charge material is a high K dielectric material. In an example, the surrounding insulating material includes an oxide or a nitride material, among others.
[0026] In an example, the charge material configured at a deep trench isolation structure has a negative charge. In an example, high k dielectric material, such as AI2O3 deposited by atomic layer deposition techniques forms negative fixed charge at an Si02/AI203 interface region. In an example, the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Additionally, spatially excluding the deep trench isolation sidewall interface from the depletion region greatly reduces chances for the interface defects to drift to the avalanche region. Accordingly, noise or the dark count rate can be greatly reduced.
[0027] In an example, the device also has a first contact region 121 coupled to the implanted p- type material and a second contact region coupled to the implanted n-type material on the opposite side of the sensor substrate. In an example, the contacts are configured as an anode and a cathode for each of the pixel elements.
[0028] In an example, the device has a bottom metal reflector, as shown. In an example, the metal reflector can be made of an aluminum material, a metal/oxide material, or a semiconductor material. In an example, the bottom reflector is configured to reflect light back into an active region of the epitaxial material or active region.
[0029] Figure 2 is a top-view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. In an example, such device includes integrated circuit elements to replace certain elements from the logic substrate, which is described herein. As shown, each pixel element 200 has a surrounding trench region, and inner active region, which is made of epitaxial material. In an example, each pixel element has the p-type implanted region 201 within the n-type implanted region 203, as shown. Each of the pixel elements is configured as a square, but can also be configured in other shapes, such as a circle, a rectangle, oval, or other variations. Om am example, each pixel region is coupled to an integrated high voltage transistor 207, and has a quenching resistor 205, as shown. Each of the transistor and resistor circuit elements are monolithically integrated with the sensor substrate and pixel elements.
[0030] Figure 3 is a more detailed cross-sectional view diagram of a device according to an embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device has the surrounding trench region 300, which is configured from a deep trench isolation. The deep trench isolation is configured from an etching process.
[0031] In an example, the trench region comprises a fill material, a surrounding charge material 305, 307, and a surrounding insulating material 301 303. In an example, the surrounding insulating material includes an oxide or a nitride material, among others.
[0032] In an example, the charge material configured at a deep trench isolation structure has a negative charge. In an example, high k dielectric material, such as AI2O3 deposited by atomic layer deposition techniques forms negative fixed charge at an S1O2/AI2O3 interface region. In an example, the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Such configuration reduces a dark count rate, leading to efficiencies with the device. In an example, as shown, the trench is filled with a conductive material, such as metal, to prevent cross-talk or other limitations leading to problems. In an example, the conductive material can also be biased at the same bias as the anode or more negative bias in reference to the anode depending upon the embodiment.
[0033] As shown, the device has a low doped epitaxial silicon region 311 coupled to a higher doped avalanche region. As shown, p+ type material 309 provides for lateral conduction and a low contact resistance. Also shown is an n type material 315 configured within the epitaxial material. The device also has a p type material 313 overlying the n type material.
[0034] In an example, the device also has contact region 317 coupled to the p type material and an overlying passivation material 319.
[0035] Figure 4 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device can include a shallow trench isolation 401, 403 below the deep trench isolation (which was referred to as the surrounding trench region). In an example, the shallow trench isolation can include an oxide material as a filler.
[0036] Figure 5 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device can include a micro lens 501 configured overlying the surface of the substrate. In an example, the micro lens is configured to focus incoming light onto active regions of the epitaxial material. In an example, the micro lens can be monolithically integrated or made of an optical material that is mechanically attached to the passivation layer. Of course, there can be other variations, modifications, and alternatives.
[0037] Figure 6 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. In an example, the device has an anti- reflective material 601 overlying a backside of the device. In an example, the anti-reflective layer can be any optical material, such as an oxide, a nitride, or metal oxides, or other suitable materials, or combinations thereof, or the like. In an example, the anti-reflective coating reduces light refraction at the backside surface, which allows more light to travel into an active device region.
[0038] Figure 7 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device has nanostructures 701. That is each of the pixel elements comprises a plurality of nano-structures configured within a vicinity of an interface to the upper surface to facilitate trapping of a photon coming in contact with the nano-structure. In an example, the nano-structures can be made on the sensor substrate. In an example, the nano-structures are made using one or more of the following processes.
[0039] In an example, light trapping works by coupling incoming photons into a lateral waveguide mode that increases absorption length. In an example, as shown, nano-structures are formed using a periodic pattern (or can also be unpatterned in other examples) made by using a dry etching or selective wet etching of a silicon bearing material. In an example, dry etching of silicon bearing material causes formation of rectangular, or circular, or hexagonal shapes, or other shapes, of holes or openings. In an example, for silicon, the period of the nano-structures can be in the range of 650-850nm, and a diameter of the nano-holes or openings can be in the range of 400-600nm, although there can be other variations. In an example, to be compatible with CMOS STI (shallow trench isolation) processes, the depth of nano structures can be in the range of 300-450 nm, but can be others. After dry etching, the nano holes are oxidized and filled with an oxide fill material.
[0040] In an example, nano structures can also be made by a selective wet etching process. In an example, selective wet etching creates an inverse pyramid of holes or openings as shown.
In an example, the period of the inverse pyramid can be in the range of 700-900nm, among others. In an example, the depth of the inverse pyramid depends on the period of the pyramid because of a fixed angle of pyramid resulted from crystal direction. After wet etching, the pyramids are also oxidized and filled with oxide fill material. Further details of the present nanostructure configuration can be found throughout the present specification.
[0041] Figure 8 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. In an example, each of the pixel elements comprises a plurality of nano-structures 801 configured overlying the aperture region to facilitate trapping of a photon coming in contact with the nano-structure. In an example, the nano-structure is configured from a silicon material. As shown, nanostructures 701 are configured within a vicinity of the interface region, and nanostructures 801 are configured within a vicinity of the aperture region.
[0042] Figure 9 is a simplified cross-sectional view diagram of a device according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device can also be configured as an inverted structure. In an example, the implanted p-type material 901 and the implanted n-type 903 material are configured within a vicinity of an aperture region of the pixel element. The device also has epitaxial material 905 defined within a pixel element surrounded by a trench region. As shown, each trench region has a fill material 907, a dielectric material, and a charge layer (collectively reference numeral 909). The device has an overlying passivation material 911, which can be a silicon dioxide, silicon nitride, or combinations thereof. An upper contact region 913 is coupled to the n-type material, as shown. The device also has a lower contact region coupled to bonding point 915 and p-type material.
[0043] In an example, the device has a bottom metal reflector, as shown. In an example, the metal reflector can be made of an aluminum material, a metal/oxide material, or a semiconductor material. In an example, the bottom reflector is configured to reflect light back into an active region of the epitaxial material or active region. In an example, the device has a logic substrate 919, which is a semiconductor substrate configured with logic circuitry. In an example, the substrate can be a complementary metal oxide silicon (CMOS) substrate, a blank or unpatterned substrate, a patterned, hybrid substrate, among others. In an example, the semiconductor substrate has a plurality of CMOS cells for logic circuitry, and can also include a plurality of memory cells, interface cells, and other circuit elements. As shown, the substrate has a bonding region 917 and logic circuits 921, which can be configured as an output, quenching, recharge circuit, among others. Of course, there can be other variations, modifications, and alternatives.
[0044] Figure 10 is a simplified cross-sectional view diagram of a sensor device of Figure 9 according to an alternative embodiment of the present invention. This diagram is merely an example, which should not unduly limit the scope of the claims herein. As shown, the device can also be configured as an inverted structure. In an example, the implanted p-type material 1009 and the implanted n-type 1007 material are configured within a vicinity of an aperture region of the pixel element. The device also has epitaxial material 1003 defined within a pixel element surrounded by a trench region. As shown, each trench region has a fill material 1010, a dielectric material, and a charge layer 1015 1017, and a thin layer of dielectric material 1011 1013. The device has an overlying passivation material 1005, which can be a silicon dioxide, silicon nitride, or combinations thereof. An upper contact region 1019 is coupled to the n-type material, as shown. The device has a p+ type region 1001, as shown. The device also has a lower contact region coupled to bonding point.
[0045] In an example, the charge material configured at a deep trench isolation structure has a negative charge. In an example, high k dielectric material, such as AI2O3 deposited by atomic layer deposition techniques forms negative fixed charge at an Si02/AI203 interface region. In an example, the negative fixed charge creates a positive flat band voltage shift, which causes semiconductor material near the deep trench isolation sidewall in accumulation mode rather than in a depletion mode. Additionally, spatially excluding the deep trench isolation sidewall interface from the depletion region greatly reduces chances for the interface defects to drift to the avalanche region. Accordingly, noise or the dark count rate can be greatly reduced.
[0046] These diagrams are merely examples, which should not unduly limit the scope of the claims herein. In light of the present invention disclosure, one of ordinary skill in the art would recognize many other variations, modifications, and alternatives. For example, various steps outlined above may be added, removed, modified, rearranged, repeated, and/or overlapped, as contemplated within the scope of the invention. It is also understood that the examples and embodiments described herein are for illustrative purposes only and that various modifications or changes in light thereof will be suggested to persons skilled in the art and are to be included within the spirit and purview of this process and scope of the appended claims.

Claims

1. A single photon avalanche diode device comprising: a logic substrate comprising an upper surface; a sensor substrate bonded to the upper surface of the logic substrate, the sensor substrate comprising a plurality of pixel elements spatially disposed to form an array structure, each of the pixel elements comprising: a passivation material; an epitaxially grown p-type silicon material; an implanted p-type material configured in a first portion of the epitaxially grown material; and an implanted n-type material configured in a second portion of the epitaxially grown material; a junction region configured from the implanted p-type material and the implanted n- type material; and a deep trench region bordering the pixel element, the trench region comprising a fill material, a surrounding charge material, and a surrounding insulating material; a first contact region on a first side of the sensor substrate coupled to the implanted p-type material; a second contact region on a second side of the sensor substrate coupled to the implanted n-type material; and whereupon the charge material is configured with a negative charge to cause a plurality of holes within a vicinity of the surrounding charge material.
2. The device of claim 1 wherein each of the pixel elements comprises an anti-reflective material overlying the passivation material.
3. The device of claim 1 wherein each of the pixel elements having a size ranging from 1 micron to about 100 microns.
4. The device of claim 1 wherein the passivation material comprises an oxide material, a high-K dielectric material, a nitride material, or a polyimide material.
5. The device of claim 1 wherein the implanted p-type material comprises a boron material having a concentration density of 1E15 atoms/cm3 to 1E18 atoms/cm3.
6. The device of claim 1 wherein the implanted n-type material comprises a phosphorous entity or an arsenic entity having a concentration density of 1E17 atoms/cm3 to 1E19 atoms/cm3.
7. The device of claim 1 wherein the array structure is N by M, where N is 1 and greater and M is 1 and greater.
8. The device of claim 1 wherein the fill material comprises a metal material, a semiconductor material, or an insulating material.
9. The device of claim 1 wherein the implanted p-type material and the implanted n-type material are configured within a vicinity of the logic substrate of the pixel element.
10. The device of claim 1 wherein the logic substrate comprises a plurality of CMOS cells.
11. The device of claim 1 wherein each of the pixel elements comprises a plurality of nano structures configured overlying the aperture region to facilitate trapping of a photon coming in contact with the nano-structure, the nano-structure being configured from a silicon material.
12. The device of claim 1 wherein each of the pixel elements comprises a plurality of nano structures configured within a vicinity of an interface to the upper surface to facilitate trapping of a photon coming in contact with the nano-structure.
13. The device of claim 1 wherein each of the pixel elements comprises a reflective material configured on an opposite side of the aperture region to facilitate reflecting a photon from a underlying region to the junction region.
14. A single photon avalanche diode device comprising: a logic substrate comprising an upper surface; a sensor substrate bonded to an upper surface of the logic substrate, the sensor substrate comprising a plurality of pixel elements spatially disposed to form an array structure, each of the pixel elements comprising: an epitaxially grown p-type silicon material; an implanted n-type material configured in a first portion of the epitaxially grown material; an implanted p-type material overlying the n-type material and configured in a second portion of the epitaxially grown material; a junction region configured from the implanted p-type material and the implanted n-type material; and a deep trench region bordering the pixel element, the trench region comprising a trench opening, a surrounding insulating material, a surrounding charge material, and a fill material; and a first contact region on a back side of the sensor substrate coupled to the implanted n-type material; and a second contact region on a front side of the sensor substrate coupled to the implanted p-type material. whereupon the charge material is configured with a negative fixed charge to cause a plurality of holes within a vicinity of the surrounding charge material.
15. The device of claim 14 wherein each of the pixel elements comprises an anti-reflective material overlying the passivation material.
16. The device of claim 14 wherein each of the pixel elements having a size ranging from 1 micron to about 100 microns.
17. The device of claim 14 wherein the passivation material comprises an oxide material, a high-K dielectric material, a nitride material, or a polyimide material.
18. The device of claim 14 wherein the implanted p-type material comprises a boron material having a concentration density of 1E15 atoms/cm3 to 1E18 atoms/cm3.
19. The device of claim 14 wherein the implanted n-type material comprises a phosphorous entity or an arsenic entity having a concentration density of 1E17 atoms/cm3 to 1E19 atoms/cm3.
20. The device of claim 14 wherein the array structure is N by M, where N is i and greater and M is 1 and greater.
21. The device of claim 14 wherein the fill material comprises a metal material, a semiconductor material, or an insulating material.
22. The device of claim 14 wherein the implanted p-type material and the implanted n-type material are configured within a vicinity of an aperture region of the pixel element.
23. The device of claim 14 wherein the semiconductor substrate comprises a plurality of CMOS cells.
24. The device of claim 14 wherein each of the pixel elements comprises a plurality of nano structures configured overlying the aperture region to facilitate trapping of a photon coming in contact with the nano-structure, the nano-structure being configured from a silicon material.
25. The device of claim 14 wherein each of the pixel elements comprises a plurality of nano structures configured within a vicinity of an interface to the upper surface to facilitate trapping of a photon coming in contact with the nano-structure.
26. The device of claim 14 wherein each of the pixel elements comprises a reflective material configured on an opposite side of the aperture region to facilitate reflecting a photon from a backside region to the junction region.
PCT/US2021/014647 2020-01-28 2021-01-22 Single photon avalanche diode device Ceased WO2021154603A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202180011174.6A CN115176346B (en) 2020-01-28 2021-01-22 Single photon avalanche diode device
JP2022554744A JP7319743B2 (en) 2020-01-28 2021-01-22 Single-photon avalanche diode device
EP21748257.9A EP4097771A4 (en) 2020-01-28 2021-01-22 SINGLE PHOTON AVALANCHE DIODE DEVICE

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/775,101 2020-01-28
US16/775,101 US11508867B2 (en) 2020-01-28 2020-01-28 Single photon avalanche diode device

Publications (1)

Publication Number Publication Date
WO2021154603A1 true WO2021154603A1 (en) 2021-08-05

Family

ID=76970448

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2021/014647 Ceased WO2021154603A1 (en) 2020-01-28 2021-01-22 Single photon avalanche diode device

Country Status (5)

Country Link
US (2) US11508867B2 (en)
EP (1) EP4097771A4 (en)
JP (1) JP7319743B2 (en)
CN (1) CN115176346B (en)
WO (1) WO2021154603A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7635034B2 (en) * 2021-03-22 2025-02-25 キヤノン株式会社 Photoelectric conversion device, photoelectric conversion system, and mobile body
US12183754B2 (en) * 2021-08-24 2024-12-31 Globalfoundries Singapore Pte. Ltd. Single-photon avalanche diodes with deep trench isolation
JP7799488B2 (en) * 2022-01-01 2026-01-15 キヤノン株式会社 Photoelectric conversion device, photoelectric conversion system, and equipment
CN116072762A (en) * 2022-12-30 2023-05-05 深圳市灵明光子科技有限公司 A kind of SPAD device and manufacturing method thereof
CN117525093B (en) * 2023-11-13 2024-07-19 成都燧石蓉创光电技术有限公司 Detection device with MOS trench isolation region and forming method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150054111A1 (en) * 2013-08-23 2015-02-26 Kabushiki Kaisha Toyota Chuo Kenkyusho Single photon avalanche diode
KR20170132467A (en) * 2016-05-24 2017-12-04 주식회사 우리로 single photon avalanche diode and method of manufacturing the same
US20190006399A1 (en) 2016-10-18 2019-01-03 Sony Semiconductor Solutions Corporation Photodetector
WO2019018846A2 (en) 2017-07-21 2019-01-24 W&Wsens, Devices Inc. Microstructure enhanced absorption photosensitive devices
US10204950B1 (en) 2017-09-29 2019-02-12 Taiwan Semiconductor Manufacturing Company Ltd. SPAD image sensor and associated fabricating method
US20190097075A1 (en) * 2017-09-22 2019-03-28 Stmicroelectronics (Research & Development) Limited Deep trench isolation (dti) bounded single photon avalanche diode (spad) on a silicon on insulator (soi) substrate
EP3462497A1 (en) 2017-03-22 2019-04-03 Sony Semiconductor Solutions Corporation Imaging device and signal processing device
EP3553824A1 (en) 2017-11-15 2019-10-16 Sony Semiconductor Solutions Corporation Photodetection element and method for manufacturing same

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057892A (en) * 1990-09-14 1991-10-15 Xsirius Photonics, Inc. Light responsive avalanche diode
US7659564B2 (en) * 2006-02-14 2010-02-09 International Business Machines Corporation CMOS imager photodiode with enhanced capacitance
IT1392366B1 (en) 2008-12-17 2012-02-28 St Microelectronics Rousset OPERATING PHOTODIODO IN GEIGER MODE WITH INTEGRATED AND CONTROLLABLE SUPPRESSION RESISTOR, PHOTODIUM RING AND RELATIVE PROCESS OF PROCESSING
US8786043B2 (en) * 2012-05-05 2014-07-22 SiFotonics Technologies Co, Ltd. High performance GeSi avalanche photodiode operating beyond Ge bandgap limits
US20140167200A1 (en) 2012-12-19 2014-06-19 Agency For Science, Technology And Research Photodetector and method for forming the same
JP5925711B2 (en) 2013-02-20 2016-05-25 浜松ホトニクス株式会社 Detector, PET apparatus and X-ray CT apparatus
EP2816601B1 (en) 2013-06-20 2017-03-01 IMEC vzw Improvements in or relating to pinned photodiodes for use in image sensors
JP2015084392A (en) 2013-10-25 2015-04-30 浜松ホトニクス株式会社 Photo-detector
US9466631B2 (en) 2014-05-13 2016-10-11 Stmicroelectronics S.R.L. Solid state photomultipliers array of enhanced fill factor and simplified packaging
FR3041817B1 (en) 2015-09-30 2017-10-13 Commissariat Energie Atomique PHOTODIODE OF SPAD TYPE
FR3042310B1 (en) * 2015-10-12 2018-10-12 Commissariat A L'energie Atomique Et Aux Energies Alternatives MANUFACTURE OF A MULTISPECTRAL PHOTODIOD MATRIX IN CDHGTE BY CADMIUM DIFFUSION
JP2018019040A (en) 2016-07-29 2018-02-01 キヤノン株式会社 Photodetection device and photodetection system
US10497818B2 (en) * 2016-07-29 2019-12-03 Canon Kabushiki Kaisha Photodetection device and photodetection system
US10658419B2 (en) 2016-09-23 2020-05-19 Apple Inc. Stacked backside illuminated SPAD array
US11101311B2 (en) * 2018-06-22 2021-08-24 Ningbo Semiconductor International Corporation Photodetector and fabrication method, and imaging sensor
CN109509764A (en) * 2018-12-12 2019-03-22 上海华力集成电路制造有限公司 Cmos image sensor and its manufacturing method
KR102662233B1 (en) * 2019-02-28 2024-05-02 삼성전자주식회사 Image sensor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150054111A1 (en) * 2013-08-23 2015-02-26 Kabushiki Kaisha Toyota Chuo Kenkyusho Single photon avalanche diode
KR20170132467A (en) * 2016-05-24 2017-12-04 주식회사 우리로 single photon avalanche diode and method of manufacturing the same
US20190006399A1 (en) 2016-10-18 2019-01-03 Sony Semiconductor Solutions Corporation Photodetector
EP3462497A1 (en) 2017-03-22 2019-04-03 Sony Semiconductor Solutions Corporation Imaging device and signal processing device
WO2019018846A2 (en) 2017-07-21 2019-01-24 W&Wsens, Devices Inc. Microstructure enhanced absorption photosensitive devices
US20190097075A1 (en) * 2017-09-22 2019-03-28 Stmicroelectronics (Research & Development) Limited Deep trench isolation (dti) bounded single photon avalanche diode (spad) on a silicon on insulator (soi) substrate
US10204950B1 (en) 2017-09-29 2019-02-12 Taiwan Semiconductor Manufacturing Company Ltd. SPAD image sensor and associated fabricating method
EP3553824A1 (en) 2017-11-15 2019-10-16 Sony Semiconductor Solutions Corporation Photodetection element and method for manufacturing same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP4097771A4

Also Published As

Publication number Publication date
EP4097771A1 (en) 2022-12-07
US20220367743A1 (en) 2022-11-17
JP2023502183A (en) 2023-01-20
US20210234057A1 (en) 2021-07-29
US11508867B2 (en) 2022-11-22
US11742449B2 (en) 2023-08-29
CN115176346A (en) 2022-10-11
EP4097771A4 (en) 2024-02-21
JP7319743B2 (en) 2023-08-02
CN115176346B (en) 2023-07-28

Similar Documents

Publication Publication Date Title
US11742449B2 (en) Single photon avalanche diode device
TWI639243B (en) Device and related method for enhancing electromagnetic radiation detection
US12094903B2 (en) Microstructure enhanced absorption photosensitive devices
CN113921646B (en) Single-photon detector, manufacturing method thereof and single-photon detector array
US7022544B2 (en) High speed photodiode with a barrier layer for blocking or eliminating slow photonic carriers and method for forming same
CN111133590A (en) Microstructure-enhanced absorption photosensitive devices
US11830954B2 (en) Microstructure enhanced absorption photosensitive devices
CN113707751B (en) Single photon avalanche photoelectric detector and preparation method thereof
EP4059055A1 (en) Microstructure enhanced absorption photosensitive devices
CN114551412A (en) Crosstalk-free indium gallium arsenic Geiger mode focal plane detection chip structure and manufacturing method thereof
CN115188854B (en) Photoelectric detector and method for preparing the same
CN113707750B (en) Waveguide-coupled avalanche photodetector and preparation method thereof
KR102423371B1 (en) Integrated circuit photodetector
US8227882B2 (en) Light-sensitive component with increased blue sensitivity, method for the production thereof, and operating method
US11967664B2 (en) Photodiodes with serpentine shaped electrical junction
CN115377241B (en) Planar avalanche photoelectric detection array chip of monolithic photoelectric integration on SOI and preparation method thereof
TWI889383B (en) Optical apparatus
KR100653236B1 (en) Embedded Silicon Germanium Junction Solar Cell
CN121358039A (en) Single-photon avalanche diode integrating III-V compound transistors with silicon heterostructure and its fabrication method
CN119497434A (en) Back-incident avalanche photodetector and preparation method thereof
CN120282551A (en) Single photon avalanche diode, preparation method thereof and photoelectric detector
CN118448482A (en) Single photon avalanche detector structure and manufacturing method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21748257

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2022554744

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2021748257

Country of ref document: EP

Effective date: 20220829