WO2022017402A1 - 一种芯片转移方法、电子设备 - Google Patents
一种芯片转移方法、电子设备 Download PDFInfo
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- WO2022017402A1 WO2022017402A1 PCT/CN2021/107476 CN2021107476W WO2022017402A1 WO 2022017402 A1 WO2022017402 A1 WO 2022017402A1 CN 2021107476 W CN2021107476 W CN 2021107476W WO 2022017402 A1 WO2022017402 A1 WO 2022017402A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/70—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping
- H10P72/74—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
- G09F9/33—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements being semiconductor devices, e.g. diodes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H29/00—Integrated devices, or assemblies of multiple devices, comprising at least one light-emitting semiconductor element covered by group H10H20/00
- H10H29/01—Manufacture or treatment
- H10H29/02—Manufacture or treatment using pick-and-place processes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W90/00—Package configurations
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/01—Manufacture or treatment
- H10H20/036—Manufacture or treatment of packages
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/70—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping
- H10P72/74—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support
- H10P72/7428—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support used to support diced chips prior to mounting
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/70—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping
- H10P72/74—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support
- H10P72/7434—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support used in a transfer process involving at least two transfer steps, i.e. including an intermediate handle substrate
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/70—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping
- H10P72/74—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof for supporting or gripping using temporarily an auxiliary support
- H10P72/744—Details of chemical or physical process used for separating the auxiliary support from a device or a wafer
Definitions
- the present application relates to the technical field of micro light-emitting diode displays, and in particular, to a chip transfer method and electronic equipment.
- micro LED light emitting diode
- the micro LED technology forms micron-scale micro LEDs on a donor substrate, such as a wafer. Then, the micro LEDs on the above-mentioned donor substrate are transferred to a receptor substrate, such as a circuit board, and arranged in an array. Each micro LED can be driven to light up individually as a pixel, so that the display screen can present a picture with higher detail and higher contrast.
- Micro LED inherits the characteristics of high efficiency, high brightness, high reliability and fast response time of LED, and has the characteristics of self-illumination, which has the advantages of energy saving, simple structure, small size and thin shape.
- OLED organic light emitting diode
- micro LED displays are easier and more accurate to debug colors, have longer luminous life and higher brightness, and have better material stability and life. Long, no image burn-in and other advantages.
- massively parallel pick and place technology can be used to pick up micro LEDs on the donor substrate in batches through the transfer head and transfer them to the substrate. Since the transfer head needs to move repeatedly between the donor substrate and the donor substrate, it takes a certain amount of time to pick and place the micro LEDs during each movement. Therefore, when making a display screen with higher resolution, the production efficiency is too low due to the huge number of micro LEDs to be transferred, which is insufficient to support the expectations of the market and production cost.
- the present application provides a chip transfer method and electronic device for improving the problem of low efficiency of mass transfer micro LED technology.
- a chip transfer method for transferring a chip in a motherboard to a substrate.
- the method includes: first, providing a scaling layer.
- the stretchable layer may include a plurality of first fibers and a plurality of second fibers, and a laminated first cloth layer and a second cloth layer.
- the first fibers and the second fibers intersect between the first cloth layer and the second cloth layer, and there are multiple intersection points between the first fibers and the second fibers.
- a first distance H1 is controlled between two adjacent intersection points, and a second distance H2 is controlled between the first cloth layer and the second cloth layer.
- the first cloth layer in the stretchable layer is close to the chip, and the second cloth layer is far away from the chip. Then, the plurality of chips are separated, and the separated plurality of chips are connected to the first fiber and the second fiber, respectively. Next, the plurality of chips pasted with the stretchable layer are respectively arranged in a plurality of preset positions of the substrate. Finally, the first and second fibers are removed.
- the stretchable layer can be pasted with each chip in the motherboard.
- the first distance H1 can be the same as the distance between two chips on the motherboard.
- the plurality of chips on the stretchable layer can be arranged on each preset position on the substrate.
- the first and second fibers are then removed to complete the mass transfer of the chip.
- the chip transfer method provided by the present application only the stretchable layer needs to be pasted with a plurality of chips on the motherboard. Then, the chip on the stretchable layer is arranged on the substrate. In this way, most or even all chips on the same motherboard can be transferred to the substrate at one time. Therefore, in the process of chip transfer, there is no need for the transfer head to go back and forth between the mother board and the substrate, so as to improve the efficiency of mass transfer of chips.
- providing the stretchable layer includes crossing a plurality of first warp threads and a plurality of first weft threads to form a first cloth layer.
- the spacing between two adjacent first warp threads is the same as the first spacing H1
- the spacing between two adjacent first weft threads is the same as the first spacing H1.
- a plurality of second warp threads and a plurality of second weft threads are intersected to form a second fabric layer.
- the interval between two adjacent second warp threads is the same as the first interval H1
- the interval between two adjacent second weft threads is the same as the first interval H1.
- the vertical projection of the second warp thread on the first cloth layer is located between two adjacent first warp threads, and the vertical projection of the second weft thread on the first cloth layer is located between two adjacent second weft threads.
- the positions of the crossed first weft threads and the first warp threads in the first fabric layer and the crossed second weft threads and the second warp threads in the second fabric layer in the stretchable layer can be controlled, so that the first The spacing H1 can be the same as the spacing between two chips of the motherboard.
- the first fibers intersect the first and second warp threads, and the second fibers intersect the first and second weft threads. In this way, both the first fibers and the second fibers can be made to cross the first cloth layer and the second cloth layer.
- the above-mentioned attaching the stretchable layer to the chip includes: aligning and attaching an intersection point to a chip in the motherboard. Since the position of the intersection can be controlled, the chips on the motherboard can be pasted as required.
- aligning and pasting an intersection point with a chip in the motherboard includes: on the first cloth layer, coating an adhesive layer at the intersection point. Then, the side surface of the stretchable layer coated with the adhesive layer is pasted on the motherboard, so that the vertical projection of a cross point on the motherboard overlaps with one chip in the motherboard. In this way, an adhesive layer can be formed on the first cloth layer, and the stretchable layer can be pasted on the mother board through the adhesive layer.
- aligning and pasting a cross point with a chip in the motherboard includes dispensing glue on the motherboard to form a plurality of adhesive layers, and a vertical projection of one adhesive layer on the motherboard overlaps with a chip in the motherboard. Then, the surface of the side where the first fabric layer is located is pasted on the mother board through a plurality of adhesive layer arrays, so that the vertical projection of a cross point on the mother board overlaps with one adhesive layer.
- An adhesive layer array is formed by dispensing glue at the position of each chip on the motherboard, and the stretchable layer is pasted on the motherboard through the adhesive layer array.
- aligning and pasting an intersection point with a chip in the motherboard includes: coating a colloidal material layer on the motherboard, and patterning the colloidal material layer, so that a plurality of adhesive layers are formed on the motherboard, one The vertical projection of the adhesive layer on the motherboard overlaps with a chip in the motherboard. Then, the side surface on which the first fabric layer is located is pasted on the mother board through an adhesive layer, so that the vertical projection of a cross point on the mother board overlaps with an adhesive layer. In this way, multiple adhesive layers on the mother board can be formed in the same mask exposure process, thus improving the efficiency of the manufacturing process.
- the motherboard includes a substrate for carrying chips.
- Attaching the stretchable layer to the chip includes attaching the stretchable layer to the side surface of the substrate away from the chip. In this way, the surface of the side where the first electrode and the second electrode are located in the chip can be prevented from contacting the adhesive layer, thereby affecting the performance of the chip.
- the chip includes a first electrode and a second electrode.
- Disposing the plurality of chips on the stretchable layer on the plurality of preset positions of the substrate includes: adopting a flip-chip process, at the preset positions, the first electrode and the second electrode of a chip are close to the substrate, and are welded on the substrate.
- the above flip-chip process enables the first electrodes and the second electrodes of the chip to be directly welded on the substrate, thereby improving the efficiency of transmitting electrical signals to the first electrodes and the second electrodes.
- the method further includes: stretching the first fiber and the second fiber, so that the first fiber and the second fiber are drawn together.
- there is a welding distance Hb between two adjacent preset positions on the substrate, and H3 Hb. In this way, all chips on the stretch layer can be transferred to the substrate.
- the spacing between two adjacent first warp threads is the same as the first spacing H1, and the spacing between two adjacent first weft threads is the same as the first spacing H1, including: setting the periphery of the motherboard A plurality of first positioning posts; a first positioning post is arranged between every two adjacent first warp threads, and is in contact with two adjacent first warp threads.
- a plurality of second positioning posts are provided around the motherboard.
- a second positioning column is arranged between every two adjacent first weft threads, and is in contact with two adjacent first weft threads.
- the direction of the first geometric length L1 of the first positioning column is perpendicular to the two adjacent first warp lines; the direction of the second geometric length L2 of the second positioning column is perpendicular to the two adjacent first weft lines.
- the first positioning post is arranged between two adjacent first warp threads and is in contact with two adjacent first warp threads, by setting the first geometric length L1 of the first positioning post, the The purpose of controlling the distance between two adjacent first warp threads to be the same as the first distance H1 can be achieved.
- the second geometric length L2 of the second positioning column the purpose of controlling the distance between two adjacent first wefts to be the same as the first distance H1 can be achieved.
- the direction of the second geometric length L2 of the second positioning column is perpendicular to the two adjacent first wefts, respectively.
- stretching the first fiber and the second fiber, and controlling the first fiber and the second fiber to have a third distance H3 between two adjacent cores on the first fiber and the second fiber includes: stretching the first fiber and the second fiber.
- the direction of the first geometric width B1 of the first positioning column is perpendicular to the two adjacent second fibers respectively; the direction of the second geometric width B2 of the second positioning column is perpendicular to the two adjacent first fibers respectively.
- the first positioning column is originally arranged between two adjacent first warp threads, and the first warp threads and the stretched second fibers are arranged in the same direction. Therefore, after the first warp thread is removed, each of the first positioning posts turned 90° can be disposed between every two adjacent second fibers and contact with two adjacent second fibers.
- the second positioning column is originally arranged between two adjacent first weft threads, and the first weft threads and the stretched first fibers are arranged in the same direction.
- each of the above-mentioned second positioning posts turned by 90° can be disposed between two adjacent first fibers and in contact with two adjacent first fibers. Based on this, through the first positioning column, the first distance H1 between two adjacent first warp threads can be controlled, and the third distance H3 between two adjacent second fibers can also be controlled. The first spacing H1 between two adjacent first wefts can be controlled through the second positioning column, and the third spacing H3 between two adjacent first fibers can also be controlled. In this way, there is no need to separately increase the positioning columns when positioning the first fibers and the second fibers, thereby reducing the number of positioning columns and simplifying the positioning process.
- the first fibers and the second fibers are drawn from a wave shape to a straight shape.
- the third distance H3 between two adjacent chips on the first fiber and the second fiber may be approximately the same as twice the second distance H2.
- the third distance H3 between the two adjacent chips on the first fiber and the second fiber can be made to be the same as the two adjacent preset positions on the substrate.
- the welding pitch Hb between them is the same or approximately the same.
- the motherboard includes a substrate for carrying chips, and the substrate has a plurality of first alignment marks.
- the method further includes overlapping the position of a first warp thread or a first weft thread in the stretchable layer with at least one first alignment mark. In this way, by aligning the stretchable layer with the motherboard, it is ensured that a vertical projection of an intersection point on the motherboard is located at the position of a chip on the motherboard.
- the substrate has at least one second alignment mark.
- the above-mentioned method further includes disposing the plurality of chips on the stretchable layer before the plurality of preset positions of the substrate.
- a chip on the first fiber and the second fiber is controlled to overlap with a second alignment mark. Therefore, it can be ensured that each chip has a one-to-one correspondence with a preset position of the substrate.
- the materials of the first warp threads and the first weft threads, and the second warp threads and the second weft threads include the first material.
- the material of the first fiber and the second fiber includes the second material.
- the first material and the second material are different.
- At least removing the part of the first cloth layer located between two adjacent intersections includes: putting the stretchable layer with the chips pasted into the first solvent for dissolving the first material.
- the first warp threads and the first weft threads, and the materials of the second warp threads and the second weft threads composed of the first material can be dissolved, while the first warp threads and the second weft threads composed of the second material can be dissolved.
- the fibers and the second fibers may be insoluble in the first solvent described above.
- removing at least the part of the first cloth layer located between two adjacent intersections includes: using a laser to pair the first warp, the part between the two adjacent intersections, and the first weft , the part between two adjacent intersections is cut.
- the required lines can be selectively cut by setting the wavelength band of the laser.
- the above method further includes: removing the second warp and the second weft, so that the first cloth layer and the second weft can be separated.
- the second fabric layer is removed.
- separating the plurality of chips includes cutting the motherboard to separate the plurality of chips.
- the above-mentioned motherboard may be a wafer, so that a plurality of chips are formed on the substrate of the wafer at one time through the wafer preparation method.
- removing the first fibers and the second fibers includes: using a laser stripping process to separate the adhesive layer from the chip, and extracting the first fibers and the second fibers.
- the adhesive layer is irradiated with a laser to release its viscosity, so that the first fiber and the second fiber are only placed on the top of the chip and not attached to the chip, and then the first fiber and the second fiber are removed to remove the first fiber and the second fiber.
- the purpose of the first fiber and the second fiber is used to remove the first fiber and the second fiber.
- an electronic device including a display screen, and the display screen is prepared by any one of the above-mentioned chip transfer methods.
- the electronic device has the same technical effect as the chip transfer method provided by the foregoing embodiments, and details are not described herein again.
- FIG. 1a is a schematic structural diagram of an electronic device provided by an embodiment of the application.
- Fig. 1b is a schematic diagram of an explosion structure of the electronic device shown in Fig. 1a;
- Fig. 1c is a schematic diagram of an arrangement of micro LED chips in the display screen in Fig. 1b;
- FIG. 1d is a schematic structural diagram of the pixel driving circuit provided on the substrate in FIG. 1c;
- Fig. 2a is a schematic structural diagram of the micro LED chip in Fig. 1c;
- Fig. 2b is a schematic structural diagram of a motherboard having the micro LED chip shown in Fig. 2a;
- 3a is a schematic diagram of a chip transfer method provided by an embodiment of the present application.
- FIG. 3b is a schematic diagram of another chip transfer method provided by an embodiment of the present application.
- FIG. 4 is a flowchart of a chip transfer method provided by an embodiment of the present application.
- FIG. 5a is a schematic structural diagram of a telescopic layer provided by an embodiment of the present application.
- FIG. 5b is a schematic structural diagram of another telescopic layer provided by an embodiment of the present application.
- FIG. 6a is a schematic diagram of locating a telescopic layer according to an embodiment of the present application.
- FIG. 6b is a schematic structural diagram of the first positioning column in FIG. 6a;
- Fig. 6c is another structural schematic diagram of the first positioning column in Fig. 6a;
- FIG. 7 is a schematic diagram of pasting a stretchable layer and a motherboard according to an embodiment of the present application.
- FIG. 8 is a schematic diagram of aligning the telescopic layer and the motherboard according to an embodiment of the present application.
- FIG. 9a is a schematic diagram of forming an adhesive layer on the telescopic layer according to an embodiment of the present application.
- Fig. 9b is another schematic diagram of pasting the stretchable layer and the motherboard according to the embodiment of the application.
- Fig. 9c is another schematic diagram of pasting the stretchable layer and the motherboard according to the embodiment of the present application.
- FIG. 10a is a schematic diagram of forming an adhesive layer in a motherboard where a chip is located according to an embodiment of the present application
- FIG. 10b is another schematic diagram of forming an adhesive layer in a motherboard where a chip is located according to an embodiment of the present application;
- 11a is a schematic diagram of forming a colloidal material layer on a motherboard according to an embodiment of the present application.
- Fig. 11b is a schematic diagram of patterning the colloidal material layer shown in Fig. 11a;
- FIG. 11c is another schematic diagram of pasting the stretchable layer and the motherboard according to the embodiment of the present application.
- 12a is a schematic diagram of forming a colloidal material layer on a motherboard according to an embodiment of the present application
- Fig. 12b is a schematic diagram of patterning the colloidal material layer shown in Fig. 12a;
- Fig. 12c is another schematic diagram of pasting the stretchable layer and the motherboard according to the embodiment of the present application.
- FIG. 13 is a schematic diagram of cutting a mother board pasted with a telescopic layer according to an embodiment of the application
- Figure 14a is a schematic structural diagram after cutting the part of the first cloth layer in Figure 13;
- Fig. 14b is a schematic structural diagram after the second cloth layer in Fig. 14a is removed;
- Fig. 15 is another structural schematic diagram after the second cloth layer in Fig. 14a is removed;
- FIG. 16 is a schematic structural diagram of the first fiber and the second fiber shown in FIG. 15 after drawing;
- 17a is a schematic diagram of flipping the first positioning column according to an embodiment of the present application.
- Fig. 17b is a schematic diagram of positioning the second fiber by using the first positioning column shown in Fig. 17a;
- FIG. 18 is a schematic diagram of the positioning of the first fiber and the second fiber after drawing provided by an embodiment of the present application.
- 19 is a schematic structural diagram of welding the chips on the stretched first fibers and the second fibers to a substrate;
- 20 is a schematic diagram of aligning the first fiber and the second fiber after drawing with the substrate
- 21 is a schematic diagram of a flip-chip structure provided by an embodiment of the present application.
- FIG. 22 is a schematic structural diagram after removing the adhesive layer in FIG. 20;
- FIG. 23 is a schematic view of the structure after removing the first fibers and the second fibers in FIG. 22 .
- azimuth terms such as “upper”, “lower”, “horizontal”, and “longitudinal” may include, but are not limited to, definitions relative to the schematic placement of components in the drawings. It should be understood that, These directional terms may be relative concepts, and they are used for relative description and clarification, which may vary accordingly depending on the orientation in which the components are placed in the figures.
- connection should be understood in a broad sense.
- connection may be a fixed connection, a detachable connection, or an integrated body; it may be directly connected, or Can be indirectly connected through an intermediary.
- electrical connection may be a direct electrical connection, or an indirect electrical connection achieved through an intermediate medium.
- the embodiment of the present application provides a chip transfer method, which can be used to manufacture an electronic device with a display function.
- the electronic device can be applied to various communication systems or communication protocols, such as: global system of mobile communication (GSM), code division multiple access (CDMA) system, wideband code division multiple access ( Wideband code division multiple access wireless, WCDMA), general packet radio service (general packet radio service, GPRS), long term evolution (long term evolution, LTE) and so on.
- the electronic device may include a mobile phone (mobile phone), a tablet computer (pad), a TV, a smart wearable product (for example, a smart watch, a smart bracelet), a virtual reality (VR) terminal device, an augmented reality (AR) ) terminal equipment and other electronic products with display function.
- the embodiments of the present application do not specifically limit the specific form of the above-mentioned electronic device. For the convenience of description, the following description is made by taking the electronic device 01 as a mobile phone as shown in FIG. 1a as an example.
- the electronic device 01 mainly includes a micro (micro) LED display panel (display panel, DP) 10 as shown in FIG. 1a, and a middle frame 11 and a housing 12 as shown in FIG. 1b.
- the micro LED display screen 10 and the housing 12 are respectively located on both sides of the middle frame 11 and are connected to the middle frame 11 , and the middle frame 11 can be used to carry the micro LED display screen 10 .
- the electronic device 01 may further include a printed circuit board (PCB) and a battery 13 disposed on the side surface of the middle frame 11 facing the housing 12 .
- the housing 12 is connected with the middle frame 11 to form an accommodating cavity for accommodating the above-mentioned electronic devices such as PCB and battery. Therefore, it is possible to prevent water vapor and dust from outside from invading into the accommodating cavity, thereby affecting the performance of the above-mentioned electronic device.
- the above-mentioned micro LED display screen 10 has an active display area (AA).
- the AA area is used for displaying images, and the area around the AA area is used for setting the driving circuit.
- the AA area is provided with a plurality of micro (micro) LED chips 101 (hereinafter referred to as: micro LED chips) as shown in FIG. 1c.
- micro LED chips 101 can be used as a pixel of the micro LED display Driven to emit light individually.
- a plurality of adjacent micro LED chips for emitting light of three primary colors such as the red-emitting micro-LED chip 101_R, the green-emitting micro-LED chip 101_G, and the blue-emitting micro-LED chip 101_B can constitute one pixel unit 102 .
- the red light-emitting micro LED chip 101_R can be used as a red pixel
- the green light-emitting micro LED chip 101_G can be used as a green pixel
- the blue light-emitting micro LED chip 101_B can be used as a blue pixel.
- the above-mentioned pixel unit 102 can be used as a repeating unit of pixel arrangement.
- the pixel arrangement of the micro LED display screen 10 is the red pixel (micro LED chip 101_R), the green pixel (micro LED chip 101_G) and the blue pixel (micro LED chip 101_G) in the same pixel unit 102.
- the LED chips 101_B) are located in the same row and have the same area as an example.
- the arrangement of red, green, and blue primary color pixels can be determined according to requirements, which is not limited in this application.
- the arrangement of the pixels of the above-mentioned micro LED display screen 10 may also be a Pentile pixel arrangement (also referred to as a P arrangement), an RGB-Delta pixel arrangement (also referred to as a P arrangement) with unequal areas of red pixels, blue pixels and green pixels. It can be called D arrangement) and so on.
- the micro LED display screen 10 further includes a substrate 20 as shown in FIG. 1c.
- the substrate 20 includes pixel driving circuits 201 arranged in an array as shown in FIG. 1d. Therefore, the above-mentioned substrate 20 may also be referred to as an array substrate.
- the pixel driving circuit 201 may include a plurality of transistors T and at least one capacitor C. 1d, the pixel driving circuit 201 is a 2T1C structure, that is, including two transistors, such as thin film transistors (thin film transistors, TFT), such as T1 and T2, and a capacitor C as an example for description.
- TFT thin film transistors
- a pixel driving circuit 201 can be connected with the first electrode 110 of a micro LED chip 101 as shown in FIG. 2a, such as the anode (anode, a) in FIG. 1d, and the second electrode 120, such as the cathode ( cathode, c) electrical connection.
- the pixel driving circuit 201 can individually apply voltage to the first electrode 110 and the second electrode 120 of each micro LED chip 101, and control the flow through the light emitting layer 130 in the micro LED chip 101 (as shown in FIG. 2a ). ) current. Therefore, the number of photons excited in the light-emitting layer 130 can be controlled, so as to achieve the purpose of controlling the light-emitting brightness of the micro LED chip 101 .
- the manufacturing process of the micro LED chip 101 may be, as shown in FIG. 2b , the epitaxial layer 140 (including the above-mentioned light-emitting layer 130) as shown in FIG. 2a is fabricated on the motherboard 21, such as the substrate 100 of a wafer (wafer). . Next, the first electrode 110 and the second electrode 120 are formed on the above-mentioned epitaxial layer 140 . Then, the motherboard 21 can be cut to obtain a plurality of micro LED chips 101, so as to separate the plurality of LED chips 101.
- the present application does not limit the material of the above-mentioned substrate 100, which may be sapphire, glass, silicon wafer, organic matter, or the like.
- the motherboard 21 may be a carrier board for carrying a plurality of chips 101 .
- the plurality of micro LED chips 101 on the carrier board need to be separated, the plurality of micro LED chips 101 can be separated from the carrier board, so that the carrier board does not need to be cut.
- the following descriptions are all exemplified by taking the motherboard 21 as a wafer as an example.
- the cut micro LED chip 101 can be transferred to the above-mentioned substrate 20 having the pixel driving circuit 201, and the first electrode 110 and the second electrode 120 of the micro LED chip 101 can be connected with the pixel
- the drive circuit 201 is electrically connected.
- the motherboard 21 can be used as a substrate for providing the micro LED chips 101, and the above-mentioned array substrate with the pixel driving circuit 201 can be used as a substrate for receiving the micro LED chips 101. substrate 20 .
- the materials of the light emitting layers 130 of the multiple micro LED chips 101 in the same motherboard 21 are the same, so the light emitted by the multiple micro LED chips 101 in the same motherboard 21 is also the same .
- the motherboard 21_R with the red-emitting micro LED chip 101_R and the motherboard 21_G with the green-emitting micro LED chip 101_G may be respectively fabricated .
- the motherboard 21_B on which the blue light-emitting micro LED chip 101_B is made is separately separated.
- the plurality of micro LED chips 101_R, the plurality of micro LED chips 101_G, and the plurality of micro LED chips 101_B are sequentially transferred to the same substrate 20 .
- the motherboard 21 on which the blue-emitting micro LED chips 101_B are made may be separated and transferred to the substrate 20 .
- a micro LED chip 101_B is selected, and a first phosphor layer (not shown in the figure) is coated on its light-emitting surface, and the first phosphor layer can be excited by blue light. glows red.
- another micro LED chip 101_B is selected, and a second phosphor layer (not shown in the figure) is coated on the light-emitting surface thereof, and the second phosphor layer can emit green light under the excitation of blue light.
- the phosphor layer is no longer coated on the surface of the other micro LED chip 101_B, so that it still emits blue light, thereby realizing the display of three primary colors.
- the motherboard 21 on which the micro LED chips 101 for emitting ultraviolet light are made can be separated and transferred to the substrate 20 .
- different fluorescent layers are respectively coated on the light-emitting surfaces of the three micro LED chips 101 in the same pixel unit 102 on the substrate 20, so that the different fluorescent layers can emit red light respectively under the excitation of the above-mentioned ultraviolet light , green light and blue light, thus realizing three primary color display.
- the initial spacing Ha between two adjacent micro LED chips 101 in the motherboard 21 refers to the preset distance between the centers of the two adjacent micro LED chips 101 in the motherboard 21.
- the initial distance Ha between two adjacent micro LED chips 101 in the above-mentioned motherboard 21 may also be, in the motherboard 21 The distance between a point within a certain range of the center of one micro LED chip 101 and a point within a certain range of the center of another micro LED chip 101 adjacent to the micro LED chip 101 .
- the welding distance Hb between two adjacent preset positions on the substrate 20 refers to the preset distance between the respective centers of the two adjacent micro LED chips 101 after the micro LED chip 101 is expected to be welded on the substrate 20 . distance.
- the welding distance Hb between the above-mentioned two adjacent preset positions can also be, after the micro LED chip 101 is expected to be welded on the substrate 20, the distance between one micro LED chip 101 The distance from a point within a certain range of its center to a point within a certain range of its center in another micro LED chip 101 adjacent to the micro LED chip 101 .
- the following embodiments of the present application are taken as an example in which the distance between any two adjacent micro LED chips is the above-mentioned initial distance Ha along the horizontal or vertical direction in the motherboard 21, and the horizontal or vertical direction on the substrate 20 is used as an example.
- the spacing between any adjacent preset positions is described by the above-mentioned welding spacing Hb as an example.
- the chip transfer method for batch transferring the micro LED chips 101 in the motherboard 21 to the substrate 20 provided by the embodiment of the present application will be described in detail below. As shown in FIG. 4 , the chip transfer method includes S101 to S105 .
- the stretchable layer 30 may include a plurality of first fibers 301 and a plurality of second fibers 302 , and a first cloth layer 31 and a second cloth layer 32 that are laminated.
- the first fibers 301 extending in the first direction X and the second fibers 302 extending in the second direction Y intersect between the first fabric layer 31 and the second fabric layer 32, the first fibers 301 and the second fibers 302 There are multiple intersections 300 therebetween.
- the first direction X and the second direction Y intersect, for example, they may be arranged vertically.
- the first direction X and the second direction Y may constitute an XOY plane
- the first cloth layer 31 may be parallel to the XOY plane
- the second cloth layer 32 may be parallel to the XOY plane.
- the stacking of the first fabric layer 31 and the second fabric layer 32 means that, along the Z direction perpendicular to the XOY plane, the first fabric layer 31 may be located below the second fabric layer 32, or the first fabric layer 31 may be located above the second cloth layer 32 .
- FIG. 5 a is an example for illustrating that the first cloth layer 31 is located below the second cloth layer 32 .
- the fact that the first fibers 301 and the second fibers 302 intersect between the first fabric layer 31 and the second fabric layer 32 means that the first fibers 301 are between the first fabric layer 31 and the second fabric layer 32 along the Extending in the first direction X (ie transverse direction), the second fibers 302 extend along the second direction Y (longitudinal direction) between the first cloth layer 31 and the second cloth layer 32 . Since the first direction X and the second direction Y intersect, for example, they may be arranged vertically. Therefore, one laterally extending first fiber 301 will intersect with a plurality of longitudinally extending second fibers 302 .
- a longitudinally extending second fiber 302 will intersect a plurality of transversely extending first fibers 301 .
- the first fibers 301 and the second fibers 302 may cross between the first cloth layer 31 and the second cloth layer 32 horizontally and vertically.
- any two first fibers 301 may be parallel to each other, and any two second fibers 302 may be parallel to each other.
- first distance H1 between two adjacent intersections 300
- second distance H2 between the first cloth layer 31 and the second cloth layer 32
- the size of the above-mentioned first spacing H1 can be set according to the position of the micro LED chips 101 to be transferred. .
- two adjacent intersections 300 refer to two adjacent intersections 300 in a horizontal direction or a vertical position.
- first direction X ie lateral direction
- second direction Y ie, longitudinal direction
- the above S101 may specifically include: first, as shown in FIG. 5b , cross a plurality of first warp threads 312 and a plurality of first weft threads 311 to form a first cloth layer 31 .
- the distance between two adjacent first warp threads 312 is the same as the first distance H1
- the distance between two adjacent first weft threads 311 is the same as the first distance H1.
- any two first weft threads 311 may be parallel to each other, for example, as shown in FIG.
- any two first warp threads 312 are parallel to each other, for example, any one of the first warp threads 312 may be parallel to the second direction Y, that is, arranged longitudinally.
- the intersection of the plurality of first warp threads 312 and the plurality of first weft threads 311 means that one horizontally arranged first weft thread 311 will intersect with a plurality of longitudinally arranged first warp threads 312 .
- one longitudinally arranged first warp 312 will cross a plurality of transversely arranged first wefts 311 .
- the second cloth layer 32 is formed by intersecting a plurality of second warp threads 322 and a plurality of second weft threads 321 .
- the distance between two adjacent second warp threads 322 is the same as the first distance H1
- the distance between two adjacent second weft threads 321 is the same as the first distance H1.
- the vertical projection of the second warp thread 322 on the first cloth layer 31 is located between two adjacent first warp threads 312, and the vertical projection of the second weft thread 321 on the first cloth layer 31 is located between two adjacent first cloth layers 31. Between the two wefts 321.
- any two second wefts 321 may be parallel to each other.
- any second weft 321 may be parallel to the first direction X, that is, arranged laterally.
- Any two second meridians 322 are parallel to each other, for example, any one of the second meridians 322 may be parallel to the second direction Y, that is, arranged longitudinally.
- the intersection of the plurality of second warp threads 322 and the plurality of second weft threads 321 means that one horizontally arranged second weft thread 321 crosses a plurality of longitudinally arranged second warp threads 322 .
- one longitudinally arranged second warp 322 will cross a plurality of transversely arranged second wefts 321 .
- the first cloth layer 31 may be parallel to the XOY plane as shown in FIG. 5b.
- the above-mentioned vertical projection of the second warp 322 on the first fabric layer 31 refers to the projection of the second warp 322 on the first fabric layer 31 along the Z direction perpendicular to the XOY plane.
- the vertical projection of the second weft 321 on the first cloth layer 31 refers to the projection of the second weft 321 on the first cloth layer 31 along the Z direction perpendicular to the XOY plane.
- the following "vertical projection" method can be obtained in the same way, and will not be repeated one by one.
- first fibers 301 cross the first warp 312 located below and the second warp 322 located above along the first direction X.
- second fibers 302 cross the first weft 311 located below and the second weft 321 located above in the second direction Y. In this way, the first fibers 301 and the second fibers 302 can be crossed horizontally and vertically between the first cloth layer 31 and the second cloth layer 32 .
- the second distance H2 in FIG. 5b is the distance between the second warp 322 in the second fabric layer 32 and the vertical projection of the second warp 322 on the first fabric layer 31 (represented by thin dotted lines) spacing representation.
- the representations of the second distance H2 in the following drawings are the same, and will not be repeated one by one.
- first fibers 301 and the second fibers 302 cross vertically and horizontally between the first fabric layer 31 and the second fabric layer 32 means that the first fibers 301 and the second fibers 302 not only cross horizontally and vertically, but also The first fibers 301 and the second fibers 302 also intersect with the first cloth layer 31 and the second cloth layer 32 described above.
- the method for controlling the distance between two adjacent first warp threads 312 and the distance between two adjacent first weft threads 311 may be as shown in FIG.
- a plurality of first positioning posts 41 are disposed around the board 21 , and one first positioning post 41 is disposed between every two adjacent first meridians 312 and is in contact with two adjacent first meridians 312 .
- a plurality of second positioning pillars 42 are arranged around the motherboard 21 , and one second positioning pillar 42 is arranged between every two adjacent first weft threads 311 and is in phase with two adjacent first weft threads 311 . get in touch with.
- the direction of the second geometric length L2 of the second positioning column 42 is perpendicular to the two adjacent first wefts 311 respectively.
- a clamping member (not shown in the figure) can be used to control the distance between the two adjacent first warp threads 312.
- the manipulator clamps both ends of each of the first warp threads 312 and the first weft threads 311 to prevent the first warp threads 312 and the first weft threads 311 from being in a loose state.
- the second distance H2 (as shown in FIG. 5 b ) between the first cloth layer 31 and the second cloth layer 32 can also be adjusted by moving the manipulator.
- the above description is given by taking an example that the cross-sections of the first positioning column 41 and the second positioning column 42 (parallel to the motherboard 21 ) are rectangular.
- the first positioning column 41 may be a rectangular parallelepiped.
- the cross-sectional dimensions of the first positioning column 41 and the second positioning column 42 may also be circular.
- the first positioning column 41 may be a cylinder.
- the first geometric length L1 of the first positioning post 41 refers to the distance between opposite sides of the first positioning post 41 along a direction perpendicular to the first meridian 312, such as the first direction X, .
- the second geometric length L2 of the second positioning column 42 refers to the distance between two opposite sides of the second positioning column 42 along a direction perpendicular to the first weft 311 , eg, the second direction Y.
- the above description is based on an example that the distance between any two adjacent micro LED chips 101 in the motherboard 21 is the above-mentioned first distance H1 (as shown in FIG. 7 ).
- the spacing between two adjacent micro LED chips 101 in the motherboard 21 may also be different.
- the first geometric length L1 of the first positioning column 41 and the second geometric length L2 of the second positioning column 42 can be set according to the spacing requirements, so as to meet the requirements of the difference between the two adjacent micro LED chips 101. spacing requirements.
- the first cloth layer 31 can be close to the micro LED chip 101, and the second cloth layer 32 can be far away from the micro LED chip 101.
- the positions of the first cloth layer 31 and the second cloth layer 32 may be interchanged. The following descriptions are given by taking the example that the first fabric layer 31 is closer to the micro LED chip 101 .
- an intersection 300 of the first fiber 301 and the second fiber 302 in the stretchable layer 30 is aligned and pasted with a micro LED chip 101 in the motherboard 21 , so that the plurality of intersections 300 in the stretchable layer 30 and the plurality of micro LED chips 101 in the motherboard 21 are pasted one by one.
- the alignment of an intersection 300 and a micro LED chip 101 in the motherboard 21 means that after the stretchable layer 30 and the micro LED chip 101 are pasted, the vertical projection of an intersection 300 on the motherboard 21 is the same as the micro LED chip 101 . At least a portion of the LED chips 101 overlap.
- the vertical projection of an intersection 300 on the motherboard 21 may overlap the center of a micro LED chip 101 , or the vertical projection of an intersection 300 on the motherboard 21 may overlap with the center perimeter of a micro LED chip 101 Partially overlapping.
- the vertical projection of a cross point 300 on the motherboard 21 may completely overlap with a micro LED chip 101 . Therefore, when S102 is executed, a cross point 300 can be accurately pasted with the position of a micro LED chip 101 in the motherboard 21 .
- FIG. 8 is an example of setting one first alignment mark 51 at four corner positions around the substrate 100 as an example.
- the material of the first alignment mark 51 may be a metal material, which is formed by a photolithography process (including processes such as masking, exposure, development, and etching).
- a camera such as a charge coupled device (charge coupled device, CCD) may be used to acquire the positions of the first alignment mark 51 and the stretchable layer 30 .
- the processor (not shown in the figure) can use the aforementioned manipulator to control the position of a first warp 312 or a first weft 311 on the edge of the telescopic layer 30 according to the acquisition result of the CCD, so that it can be connected with at least one first pair of The positions of the position markers 51 are overlapped, so as to achieve the purpose of aligning the stretchable layer 30 with the motherboard 21 .
- the leftmost first meridian 312 in FIG. 8 overlaps with the positions of the upper and lower first alignment marks 51 on the left side of the substrate 100 .
- the rightmost first meridian 312 overlaps with the positions of the upper and lower first alignment marks 51 on the right side of the substrate 100 .
- the stretchable layer 30 and the The alignment accuracy of the motherboard 21 may not be lower than 0.5 ⁇ m. That is, the alignment accuracy between the stretchable layer 30 and the motherboard 21 is not lower than 5% of the size of a single side of the micro LED chip 101 .
- the above S102 may include, as shown in FIG. 9a , first, at least on the first cloth layer 31 , coating the adhesive layer 60 at the intersection 300 of the first fiber 301 and the second fiber 302 . Then, as shown in FIG. 9 b , the side surface of the stretchable layer 30 coated with the adhesive layer 60 is pasted on the motherboard 21 so that the vertical projection of a cross point 300 on the motherboard 21 is the same as that of a micro in the motherboard 21 .
- the LED chips 101 overlap.
- the first embodiment may be, as shown in FIG. 9b, a cross point 300 in the stretchable layer 30 is separated from the micro LED chip 101 (the micro LED chip 101) through the adhesive layer 60 and the substrate 100 in the motherboard 21.
- One side surface A1 located below the substrate 100 is pasted. In this way, the surface of the side where the first electrode 110 and the second electrode 120 are located in the micro LED chip 101 can be prevented from contacting the adhesive layer 60, thereby affecting the performance of the micro LED chip 101.
- the micro LED chip 101 is located on the surface A2 of the substrate 100 , the surface A2 is disposed opposite to the surface A1 , and the surface A1 of the substrate 100 faces the stretchable layer 30 .
- the vertical projection of an intersection 300 on the substrate 100 overlaps with the vertical projection of a micro LED chip 101 on the substrate 100 , thereby ensuring that an intersection 300 is aligned with a micro LED chip 101 in the motherboard 21 paste.
- the second embodiment may be, as shown in FIG. 9c , a cross point 300 in the stretchable layer 30 passes through the adhesive layer 60 and the micro LED chip 101 (the micro LED chip 101 is located above the substrate 100 and is represented by a solid line).
- the side surface away from the substrate 100 is pasted.
- the surface A2 of the substrate 100 faces the stretchable layer 30, and the first fibers 301 and the second fibers 302 and the micro LED chip 101 are all located on the side where the surface A2 of the substrate 100 is located.
- the vertical projection of an intersection 300 on the substrate 100 can still overlap with the vertical projection of a micro LED chip 101 on the substrate 100 by an intersection 300 .
- the above S102 may include, as shown in FIG. 10a , firstly, dispensing glue on the motherboard 21 to form a plurality of glue layers 60 .
- the vertical projection of one adhesive layer 60 on the motherboard 21 overlaps with a micro LED chip 101 in the motherboard 21, that is, the vertical projection of one adhesive layer 60 on the substrate 100 overlaps with a micro LED chip 101 on the substrate Vertical projections on 100 overlap.
- a plurality of adhesive layers 60 can be formed through a dispensing process. of dispensing arrays.
- the micro LED chip 101 is located on the surface A2 of the substrate 100 , and the surface A1 of the substrate 100 faces the adhesive layer 60 .
- the side surface of the stretchable layer 30 where the first fabric layer 31 is located is pasted on the motherboard 21 through the above-mentioned adhesive layer 60 , so as to make a vertical projection of an intersection 300 on the motherboard 21 Overlap with a glue layer 60 .
- the vertical projection of an adhesive layer 60 on the motherboard 21 overlaps with a micro LED chip 101 in the motherboard 21, so it can be ensured that a cross point 300 is pasted in alignment with a micro LED chip 101 through an adhesive layer 60 .
- FIG. 9 b the side surface of the stretchable layer 30 where the first fabric layer 31 is located is pasted on the motherboard 21 through the above-mentioned adhesive layer 60 , so as to make a vertical projection of an intersection 300 on the motherboard 21 Overlap with a glue layer 60 .
- the vertical projection of an adhesive layer 60 on the motherboard 21 overlaps with a micro LED chip 101 in the motherboard 21, so it can be ensured that a cross point 300 is pasted in alignment with a micro LED chip 101 through an adhesive layer 60 .
- the adhesive layer 60 may be formed on the side surface of the micro LED chip 101 (the micro LED chip 101 is located above the substrate 100 and represented by a solid line) away from the substrate 100 through a dispensing process. At this time, the surface A2 of the substrate 100 faces the adhesive layer 60 .
- the side surface of the stretchable layer 30 where the first fabric layer 31 is located is pasted on the motherboard 21 through the above-mentioned adhesive layer 60 , and a cross point 300 is connected to a micro LED in the motherboard 21 .
- the chip 101 is adhered to the phase.
- the first fibers 301 and the second fibers 302 and the micro LED chip 101 are all located on the side where the surface A2 of the substrate 100 is located.
- the above S102 may include, as shown in FIG. 11 a , coating a colloidal material layer 61 on the motherboard 21 .
- a colloidal material layer 61 may be coated on the side surface A1 of the substrate 100 away from the micro LED chip 101 (the micro LED chip 101 is indicated by a dotted line below the substrate 100).
- the colloidal material layer 61 may cover the surface A1 of the substrate 100, so the surface A1 is not shown in FIG. 11a.
- the micro LED chip 101 is located on the surface A2 of the substrate 100.
- a mask exposure process can be used to pattern the colloidal material layer 61 , so that a plurality of adhesive layers 60 as shown in FIG.
- the side surface of the stretchable layer 30 where the first fabric layer 31 is located is pasted on the motherboard 21 through the above-mentioned adhesive layer 60 , so that an intersection 300 and a micro LED in the motherboard 21 are The chip 101 is pasted in alignment. At this time, an intersection 300 is pasted to the side surface A1 of the substrate 100 away from the micro LED chip 101 through the above-mentioned adhesive layer 60 .
- a colloidal material layer 61 may be coated on the side surface of the micro LED chip 101 away from the substrate 100.
- the colloidal material layer 61 can cover the micro LED chip 101 and the substrate 100 .
- a mask exposure process can be used to pattern the colloidal material layer 61, so that the adhesive layer 60 as shown in FIG. 12b is formed at the position of each micro LED chip 101 in the motherboard 21.
- the side surface of the stretchable layer 30 where the first fabric layer 31 is located is pasted on the motherboard 21 through the above-mentioned adhesive layer 60 , so that an intersection 300 is connected to the substrate 100 of the motherboard 21 .
- the previous micro LED chip 101 is pasted in position.
- the first fibers 301 and the second fibers 302 and the micro LED chip 101 are all located on the side where the surface A2 of the substrate 100 is located.
- An intersection 300 is pasted with the surface of the side of the micro LED chip 101 away from the substrate 100 through the above-mentioned adhesive layer 60 .
- the glue layer 60 can be UV glue.
- the UV glue can undergo a cross-linking reaction under the irradiation of a specific UV band to complete the curing. Wherein, the higher the curing degree, the stronger the adhesive layer 60 is.
- the above-mentioned adhesive layer 60 may be formed by mixing at least one of acrylate or epoxy acrylate with a photoinitiator. In this case, when the adhesive layer 60 is irradiated with UV light with a wavelength of 345 nm, 365 nm, 385 nm or 405 nm, the adhesive layer 60 can undergo a cross-linking reaction to achieve curing.
- UV curing treatment it is also possible to selectively perform UV curing treatment on specific positions of the adhesive layer 60 , so that the viscosity of the specific positions is higher, and the viscosity of other positions is lower.
- a cross point 300 is pasted with the position of a micro LED chip 101 in the motherboard 21. Therefore, UV curing can be performed on a position of the adhesive layer 60 corresponding to one intersection 300 , thereby enhancing the adhesiveness of the adhesive layer 60 in this part.
- the viscosity of the rest of the adhesive layer 60 is relatively weak, which facilitates the removal of the adhesive layer 60 in the subsequent process.
- the above description is given by taking the example of pasting the side surface of the stretchable layer 30 where the first fabric layer 31 is located and the location of a micro LED chip 101 in the motherboard 21 as an example.
- the side surface where the second fabric layer 32 is located can also be pasted with the location of a micro LED chip 101 in the motherboard 21 .
- the pasting process is the same as the above, and will not be repeated here. .
- a laser cutting process may be used to cut the substrate 100 of the motherboard 21, Thereby, the plurality of micro LED chips 101 are separated.
- the above-mentioned motherboard 21 is a carrier board for carrying the micro LED chips 101
- the plurality of micro LED chips 101 may be removed from the carrier board in the process of performing the above S103. break away.
- the above S103 may specifically include, as shown in FIG. 14a , firstly using a laser to align the part of the first warp 312 between two adjacent intersections 300 and the first weft 311 The portion located between the intersections of two adjacent first fibers 301 and second fibers 302 is cut.
- a laser may be used to focus the part of the first warp 312 between two adjacent intersections 300 and the part of the first weft 311 between two adjacent intersections 300, so that the part is Under the action of the laser, it can be cut, but the rest of the stretchable layer 30 will not be cut.
- the material of the first cloth layer 31 may be different from the materials of the first fibers 301 and the second fibers 302 .
- the material of the first cloth layer 31 can absorb the energy emitted by the laser, so that sublimation or melting occurs under the action of the energy, so that the first warp 312 in the first cloth layer 31 is located between two adjacent intersections 300 , and the portion of the first weft 311 located between two adjacent intersections 300 is cut off.
- the materials of the first fiber 301 and the second fiber 302 can transmit the above-mentioned laser light and avoid absorbing the energy of the laser light, so that the first fiber 301 and the second fiber 302 will not be cut under the laser irradiation.
- the second fabric layer 32 is not pasted with the adhesive layer 60, the second warp threads 322 and the second weft threads 321 can be directly extracted to form the structure shown in FIG. 14b, in which the first fibers 301 remain in FIG. 14b. , the second fibers 302 and some materials in the first cloth layer 31 . At this time, the second cloth layer 32 can be completely removed.
- the materials of the first warp threads 312 and the first weft threads 311 and the second warp threads 322 and the second weft threads 321 may include the first material.
- the material of the first fibers 301 and the second fibers 302 may include the second material. The first material and the second material are different.
- the above S103 may specifically include placing the stretchable layer 30 pasted with the micro LED chip 101 into the first solvent for dissolving the first material.
- the first warp threads 312 and the first weft threads 311, and the materials of the second warp threads 322 and the second weft threads 321, which are composed of the first material can be dissolved, and the second material
- the constituted first fibers 301 and second fibers 302 may be insoluble in the above-mentioned first solvent.
- the structure shown in FIG. 15 can be formed, and the first fiber 301 and the second fiber 302 are left in FIG. 15 .
- the first cloth layer 31 and the second cloth layer 32 can be completely or almost completely removed.
- the configuration of the first material, the second material, and the first solvent will be described below.
- the first material that constitutes the first warp threads 312 and the first weft threads 311 and the materials of the second warp threads 322 and the second weft threads 321 can be cotton
- the second material that constitutes the first fibers 301 and the second fibers 302 can be wool
- the first solvent may be sulfuric acid having a concentration of 75% and a temperature of 24°C. In this way, cotton can be dissolved in the first solvent, but wool cannot be dissolved in the first solvent, so that the first cloth layer 31 and the second cloth layer 32 can be removed, and the first fibers 301 and the second fibers 302 can be retained. Purpose.
- the first material constituting the first warp threads 312 and the first weft threads 311 and the materials of the second warp threads 322 and the second weft threads 321 can be acetate fibers, and the first fibers 301 and the second fibers 302 are constituted
- the second material can be polyester.
- the first solvent may be glacial acetic acid at a temperature of 24°C. In this way, the acetate fiber can be dissolved in the first solvent, but the polyester cannot be dissolved in the first solvent, so that the first cloth layer 31 and the second cloth layer 32 can be removed, and the first fibers 301 and the second fibers can be retained.
- the first material constituting the first warp threads 312 and the first weft threads 311, and the materials of the second warp threads 322 and the second weft threads 321 may be cotton
- the first material constituting the first fibers 301 and the second fibers 302 may be cotton.
- the second material can be acrylic.
- the first solvent may be fruit acid having a concentration of 75% and a temperature of 24°C. In this way, cotton fibers can be dissolved in the first solvent, while acrylic fibers cannot be dissolved in the first solvent, so that the first cloth layer 31 and the second cloth layer 32 can be removed, and the first fibers 301 and 302 can be retained. the goal of.
- the first warp threads 312 and the first weft threads 311, and the second warp threads 322 and the second weft threads 321 may be It is prone to fracture under tension.
- the first warp threads 312 and the first weft threads 311, as well as the second warp threads 322 and the second weft threads 321 will be broken, so as to remove the first cloth layer 31 located in the opposite direction.
- the purpose of the portion between adjacent two intersections 300 is prone to fracture under tension.
- the first fibers 301 and the second fibers 302 change from a wave shape to a straight shape.
- the third distance H3 between the two adjacent micro LED chips 101 on the first fiber 301 and the second fiber 302 can be approximately 2 times the second distance H3
- the spacing H2 is the same. In this way, after the first fibers 301 and the second fibers 302 are stretched, the third distance H3 between the two adjacent micro LED chips 101 on the first fibers 301 and the second fibers 302 can be consistent with the substrate 20 .
- the welding spacing Hb between the two upper adjacent preset positions 70 is the same or approximately the same.
- the first fiber 301 and the second fiber 302 are stretched between two adjacent micro LED chips 101
- the distances along the horizontal direction (the first direction X) and the vertical direction (the second direction Y) are the above-mentioned third distance H3 as an example, and the distance between any adjacent preset positions on the substrate 20 along the horizontal direction or the vertical direction is the above-mentioned distance.
- the welding pitch Hb will be explained as an example.
- the above-mentioned preset position 70 may not be a mark that actually exists on the substrate 20 and can be recognized by human eyes.
- the above-mentioned preset position 70 may be a preset position stored inside the chip welding device and used for welding the micro LED chip 101 as required. This position can be obtained by the alignment mark on the CCD acquisition substrate 20 .
- performing the stretching of the first fibers 301 and the second fibers 302 may specifically include, firstly stretching the first fibers 301 and the second fibers 302 by the above-mentioned manipulator, so as to expand the adjacent two fibers. spacing between the micro LED chips 101 . Then, the plurality of first positioning posts 41 are turned over by 90° as shown in FIG. 17a. It can be seen from the above that the first positioning column 41 is originally disposed between two adjacent first warp threads 312 , and the first warp threads 312 and the stretched second fibers 302 are both disposed along the second direction Y.
- each of the first positioning posts 41 turned 90° can be arranged between every two adjacent second fibers 302, as shown in FIG.
- the two fibers 302 are in contact.
- the first positioning column 41 is disposed between two adjacent second fibers 302 and is in contact with the two adjacent second fibers 302, the first geometric width B1 of the first positioning column 41 is set by setting the first positioning column 41. , the purpose of controlling the distance between two adjacent second fibers 302 to be the same as the third distance H3 can be achieved.
- the above-mentioned plurality of second positioning columns 42 are turned over by 90°. It can be seen from the above that, as shown in FIG. 6a , the second positioning column 42 is originally arranged between two adjacent first weft threads 311 , and the first weft threads 311 and the stretched first fibers 301 are both arranged along the first direction X . Therefore, after the first weft 311 is removed, as shown in FIG. 18 , each of the second positioning posts 42 flipped by 90° can be disposed between two adjacent first fibers 301 and adjacent to two adjacent first fibers 301 contacts.
- the first geometric width B1 of the first positioning column 41 refers to the distance between opposite sides of the first positioning column 41 along a direction perpendicular to the second fibers 302 , eg, the first direction X.
- the second geometric width B2 of the second positioning column 42 refers to the distance between two opposite sides of the second positioning column 42 along a direction perpendicular to the first fibers 301 , eg, the second direction Y.
- the above description is given by taking an example that the distance between any two adjacent micro LED chips 101 that are soldered on the substrate 20 is the same as the above-mentioned third distance H3 (as shown in FIG. 19 ). In other embodiments of the present application, the distances between two adjacent micro LED chips 101 soldered on the substrate 20 may also be different.
- the first geometrical width B1 of the first positioning column 41 and the second geometrical width B2 of the second positioning column 42 can be set according to the spacing requirements, so as to meet the requirements of different adjacent micro LED chips 101 spacing requirements.
- the first distance H1 between two adjacent first warp threads 312 can be controlled, and the third distance between two adjacent second fibers 302 can also be controlled.
- H3 controls.
- the first spacing H1 between two adjacent first weft threads 311 can be controlled through the second positioning column 42
- the third spacing H3 between two adjacent first fibers 301 can also be controlled. In this way, there is no need to separately increase the positioning columns when positioning the first fibers 301 and the second fibers 302 , thereby reducing the number of positioning columns and simplifying the positioning process.
- the micro LED chip 101 and the preset position 70 ( As shown in Figure 16) for alignment.
- the micro LED chip 101 and the preset position 70 ( As shown in Figure 16) for alignment.
- at least one second alignment mark 52 may be fabricated on the substrate 20 .
- the manufacturing method of the second alignment mark 52 is the same as the manufacturing method of the first alignment mark 51 , and details are not described herein again.
- the second alignment mark 52 and the positions of the micro LED chips 101 on the first fiber 301 and the second fiber 302 can be acquired by using a CCD.
- the processor (not shown in the figure) can use the above-mentioned manipulator to control the position of a micro LED chip 101 on the first fiber 301 and the second fiber 302 to overlap with the position of a second alignment mark 52 according to the acquisition result of the CCD, Thereby, the purpose of aligning the micro LED chip 101 with the preset position 70 of the substrate 20 is achieved.
- the first fibers 301 and the second fibers 302 can be pasted on the surface A1 of the substrate 100 , and the micro LED chip 101 is disposed on the surface A2 of the substrate 100 , the surface A1 and the surface A2 are set opposite to each other.
- a flip-chip process can be used to solder a micro LED chip 101 to a preset position 70 (as shown in FIG. 16 ) on the substrate 20 .
- the first electrode 110 and the second electrode 120 of the micro LED chip 101 are disposed close to the substrate 20, so that they can be directly soldered on the substrate 20 and connected with the pixel driving circuit 201 on the substrate 20 (as shown in FIG. 1d ). shown) electrical connection. In this way, the transmission efficiency of the circuit on the substrate 20 for providing electrical signals to the first electrode 110 and the second electrode 120 of the micro LED chip 101 can be improved.
- the technology for packaging the micro LED chip 101 using the above flip-chip process is also different.
- the technology for packaging the micro LED chip 101 using the above flip-chip process may be referred to as a chip on board (COB) technology.
- COB chip on board
- the technology of encapsulating the micro LED chip 101 using the flip-chip process may be referred to as chip on glass (COG) technology.
- the substrate 20 when the substrate for carrying the above-mentioned pixel driving circuit 201 is a plastic substrate, the technology of using the above-mentioned flip-chip micro LED chip 101 for packaging can be referred to as a chip on plastic substrate packaging technology (chip on plastic, COP).
- chip on plastic, COP chip on plastic
- the first fibers 301 and the second fibers 302 and the micro LED chip 101 are all located on the side where the surface A2 of the substrate 100 is located.
- the first electrode 110 and the second electrode 120 of the micro LED chip 101 are disposed away from the substrate 20, and a via hole (not shown in the figure) can be formed on the micro LED chip 101 through the epitaxial layer 140, so that the An electrode 110 and a second electrode 120 are soldered on the substrate 20 through different via holes.
- a laser lift off (LLO) process may be used first to irradiate the adhesive layer 60 to release the adhesiveness of the adhesive layer 60 so that the adhesive layer 60 is separated from the micro LED chip 101 .
- LLO laser lift off
- the first fiber 301 and the second fiber 302 are only placed above the micro LED chip 101 and are not pasted with the micro LED chip 101 .
- the first fibers 301 and the second fibers 302 are extracted to achieve the purpose of removing the first fibers 301 and the second fibers 302 .
- the substrate 20 ie, the micro LED panel
- the substrate 20 ie, the micro LED panel
- the micro LED chips 101 are welded as shown in FIG. 23 can be cleaned, thereby completing the mass transfer process of the micro LED chips 101 .
- the stretchable layer 30 before stretching can be pasted with each micro LED chip 101 in the motherboard 21 .
- both the second warp threads 322 and the second weft threads 321 in the second fabric layer 32 and the first fabric layer 31 have the above-mentioned second distance H2 . Since the first fibers 301 intersect with the second warp threads 322 and the second fibers 302 intersect with the second weft threads 321 , the first fibers 301 and the second fibers 302 in the stretchable layer 30 before stretching can be wavy.
- the first weft threads 311 and the first warp threads 312 in the first fabric layer 31 and the second weft threads 321 and the second warp threads 322 in the second fabric layer 32 can be aligned with each other.
- the first distance H1 between two adjacent intersection points of the first fiber 301 and the second fiber 302 crossing the first cloth layer 31 and the second cloth layer 32 is controlled. Therefore, the first spacing H1 can be the same as the initial spacing Ha between two adjacent micro LED chips 101 in the motherboard 21 .
- an intersection 300 is pasted with the position of one micro LED chip 101 in the motherboard 21.
- the substrate of the mother board 21 can be cut, and the above-mentioned first cloth layer 31 and second cloth layer 32 can be removed.
- the first fibers 301 and the second fibers 302 in the stretchable layer 30 are stretched to increase the space between the two adjacent micro LED chips 101 on the first fibers 301 and the second fibers 302
- the distance between two adjacent micro LED chips 101 is changed from the original first distance H1 to the third distance H3.
- the third distance H3 is the same as the welding distance Hb between two adjacent preset positions 70 on the substrate 20 .
- the micro LED chips 101 located on the stretched first fibers 301 and the second fibers 302 can be welded to each of the preset positions 70 on the substrate 20 one by one. Then, the above-mentioned first fibers 301 and second fibers 302 are removed, and the formed micro LED chips 101 are cleaned to complete the mass transfer of the micro LED chips 101 .
- the transfer head does not need to go back and forth between the mother board 21 serving as the donor substrate and the substrate 20, so as to achieve the purpose of improving the mass transfer efficiency of chips.
- the micro LED chip in the motherboard is pasted before the film is not stretched, and then the micro LED chip is bound after stretching the film. on the circuit board.
- the deformation amount of the film is determined by the material constituting the film, and the film is composed of the same material, the deformation amount of the film before and after stretching is basically the same. Therefore, the displacement of the micro LED chip at any position on the film is basically the same before and after the film is stretched.
- the first distance H1 between any two adjacent intersection points of the first fibers 301 and the second fibers 302, and the first fibers 301 and the second fibers 302 can be adjusted according to requirements.
- the arched height before unstretching ie the second distance H2 between the first cloth layer 31 and the second cloth layer 32
- the application range is wider.
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Abstract
Description
Claims (23)
- 一种芯片转移方法,用于将芯片从母板转移至基板,其特征在于,所述方法包括:提供伸缩层;所述伸缩层包括多条第一纤维和多条第二纤维,以及层叠设置的第一布料层和第二布料层;所述第一纤维和所述第二纤维交叉于所述第一布料层和所述第二布料层之间,所述第一纤维与所述第二纤维之间具有多个交叉点,其中,相邻两个所述交叉点之间具有第一间距H1,所述第一布料层和所述第二布料层之间具有第二间距H2;将所述伸缩层与所述芯片粘贴,所述第一布料层靠近所述芯片,所述第二布料层远离所述芯片;分离多个所述芯片,分离的多个所述芯片分别与所述第一纤维和所述第二纤维相连接;将与所述伸缩层粘贴的多个所述芯片分别设置于所述基板的多个预设位置;去除所述第一纤维和所述第二纤维。
- 根据权利要求1所述的芯片转移方法,其特征在于,所述提供伸缩层包括:将多条第一经线和多条第一纬线交叉形成所述第一布料层,其中,相邻两条所述第一经线之间的间距与所述第一间距H1相同,相邻两条所述第一纬线之间的间距与所述第一间距H1相同;将多条第二经线和多条第二纬线交叉形成所述第二布料层,其中,相邻两条所述第二经线之间的间距与所述第一间距H1相同,相邻两条所述第二纬线之间的间距与所述第一间距H1相同,所述第二经线在所述第一布料层上的垂直投影位于相邻两条所述第一经线之间,所述第二纬线在所述第一布料层上的垂直投影位于相邻两条所述第二纬线之间。
- 根据权利要求2所述的芯片转移方法,其特征在于,所述第一纤维与所述第一经线和所述第二经线交叉;所述第二纤维与所述第一纬线和所述第二纬线交叉。
- 根据权利要求2或3所述的芯片转移方法,其特征在于,所述将所述伸缩层与所述芯片粘贴包括:将一个所述交叉点与所述母板中的一个所述芯片对位粘贴。
- 根据权利要求4所述的芯片转移方法,其特征在于,所述母板中相邻两个所述芯片之间具有初始间距Ha,Ha=H1。
- 根据权利要求4或5所述的芯片转移方法,其特征在于,所述将一个所述交叉点与所述母板中的一个所述芯片对位粘贴包括:在所述第一布料层上,所述交叉点处涂覆胶层;将所述伸缩层涂覆有胶层的一侧表面粘贴于所述母板上,使得一个所述交叉点在所述母板上的垂直投影与所述母板中的一个芯片重叠。
- 根据权利要求4或5所述的芯片转移方法,其特征在于,所述将一个所述交叉点与所述母板中的一个所述芯片对位粘贴包括:在所述母板上点胶形成多个胶层,一个所述胶层在所述母板上的垂直投影与所述母板中一个芯片重叠;将所述第一布料层所在的一侧表面通过多个所述胶层粘贴于所述母板上,使得一个所述交叉点在所述母板上的垂直投影与一个所述胶层重叠。
- 根据权利要求4或5所述的芯片转移方法,其特征在于,所述将一个所述交叉点与所述母板中的一个所述芯片对位粘贴包括:在所述母板上涂覆胶体材料层,并对所述胶体材料层进行图案化,使得所述母板上形成多个胶层,一个所述胶层在所述母板上的垂直投影与所述母板中一个芯片重叠;将所述第一布料层所在的一侧表面通过所述胶层粘贴于所述母板上,使得一个所述交叉点在所述母板上的垂直投影与一个所述胶层重叠。
- 根据权利要求4-8任一项所述的芯片转移方法,其特征在于,所述母板包括用于承载所述芯片的衬底;所述将所述伸缩层与所述芯片粘贴包括:将所述伸缩层粘贴于所述衬底远离所述芯片的一侧表面上。
- 根据权利要求9所述的芯片转移方法,其特征在于,所述芯片包括第一电极和第二电极;所述将所述伸缩层上的多个芯片分别设置于所述基板的多个预设位置包括:采用倒装工艺,在所述预设位置,将一个所述芯片的第一电极和第二电极靠近所述基板,并焊接于所述基板上。
- 根据权利要求2-10任一项所述的芯片转移方法,其特征在于,所述分离多个所述芯片之后,将所述伸缩层上的多个芯片分别设置于所述基板的多个预设位置之前,所述方法还包括:将所述第一纤维和所述第二纤维拉伸,使所述第一纤维和所述第二纤维上相邻两个芯片之间具有第三间距H3;其中,所述基板上相邻两个预设位置之间具有焊接间距Hb,H3=Hb。
- 根据权利要求2-11任一项所述的芯片转移方法,其特征在于,所述相邻两条所述第一经线之间的间距与所述第一间距H1相同,相邻两条所述第一纬线之间的间距与所述第一间距H1相同包括:在所述母板的周边设置多个第一定位柱;将一个所述第一定位柱设置于每相邻两条所述第一经线之间,且与相邻两条所述第一经线相接触;所述第一定位柱具有第一几何长度L1;L1=H1;在所述母板的周边设置多个第二定位柱;将一个所述第二定位柱设置于每相邻两条所述第一纬线之间,且与相邻两条所述第一纬线相接触;所述第二定位柱具有第二几何长度L2;L2=H1;其中,所述第一定位柱的第一几何长度L1的方向与相邻两条所述第一经线分别垂直;所述第二定位柱的第二几何长度L2的方向与相邻两条所述第一纬线分别垂直。
- 根据权利要求12所述的芯片转移方法,其特征在于,所述将所述第一纤维和所述第二纤维拉伸,控制所述第一纤维和所述第二纤维上相邻两个芯片之间具有第三间距H3包括:对所述第一纤维和所述第二纤维进行拉伸;将多个所述第一定位柱翻转90°,并将一个所述第一定位柱设置于每相邻两条所述第二纤维之间,且与相邻两条所述第二纤维相接触;所述第一定位柱具有第一几何宽度B1;B1=H3;将多个所述第二定位柱翻转90°,并将一个所述第二定位柱设置于每相邻两条所述第一纤维之间,且与相邻两条所述第一纤维相接触;所述第二定位柱具有第二几何宽度B2;B2=H3;其中,所述第一定位柱的第一几何宽度B1的方向与相邻两条所述第二纤维分别垂直;所述第二定位柱的第二几何宽度B2的方向与相邻两条所述第一纤维分别垂直。
- 根据权利要求11所述的芯片转移方法,其特征在于,所述第二间距H2和所述焊接间距Hb之间满足:H2=Hb/2。
- 根据权利要求2或3所述的芯片转移方法,其特征在于,所述母板包括用于承载所述芯片的衬底,所述衬底上具有多个第一对位标;所述将所述伸缩层与所述芯片粘贴之前,所述方法还包括:将所述伸缩层中的一条所述第一经线或者一条所述第一纬线与至少一个所述第一对位标重叠。
- 根据权利要求2或3所述的芯片转移方法,其特征在于,所述基板上具有至少一个第二对位标;所述将所述伸缩层上的多个芯片分别设置于所述基板的多个预设位置之前,所述方法还包括:控制所述第一纤维和所述第二纤维上的一个所述芯片与一个所述第二对位标重叠。
- 根据权利要求11所述的芯片转移方法,其特征在于,所述分离多个所述芯片之后,将所述第一纤维和所述第二纤维拉伸之前,所述方法还包括:去除所述第一布料层中,位于相邻两个所述交叉点之间的部分。
- 根据权利要求17所述的芯片转移方法,其特征在于,所述第一经线和所述第一纬线,以及所述第二经线和所述第二纬线的材料包括第一材料;所述第一纤维和所述第二纤维的材料包括第二材料;所述第一材料和所述第二材料不同;所述去除所述第一布料层中,位于相邻两个所述交叉点之间的部分包括:将粘贴有所述芯片的伸缩层放入用于溶解所述第一材料的第一溶剂中。
- 根据权利要求17所述的芯片转移方法,其特征在于,所述去除所述第一布料层中,位于相邻两个所述交叉点之间的部分包括:采用激光对所述第一经线中,位于相邻两个所述交叉点之间的部分,以及所述第一纬线中,位于相邻两个所述交叉点之间的部分进行切割。
- 根据权利要求19所述的芯片转移方法,其特征在于,所述分离多个所述芯片之后,将所述第一纤维和所述第二纤维拉伸之前,所述方法还包括:去除所述第二经线和所述第二纬线。
- 根据权利要求1所述的芯片转移方法,其特征在于,所述分离多个所述芯片包括对所述母板进行切割,以将多个所述芯片分离。
- 根据权利要求6-8任一项所述的芯片转移方法,其特征在于,所述去除所述第一纤维和所述第二纤维包括:采用激光剥离工艺,将所述胶层与所述芯片分离,并抽去所述第一纤维和所述第二纤维。
- 一种电子设备,其特征在于,包括显示屏,所述显示屏采用如权利要求1-22任一项所述的芯片转移方法制备。
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| US18/006,066 US12512360B2 (en) | 2020-07-24 | 2021-07-20 | Chip transfer method and electronic device |
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2021
- 2021-07-20 US US18/006,066 patent/US12512360B2/en active Active
- 2021-07-20 WO PCT/CN2021/107476 patent/WO2022017402A1/zh not_active Ceased
- 2021-07-20 EP EP21845429.6A patent/EP4181180B1/en active Active
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115909899A (zh) * | 2022-11-21 | 2023-04-04 | 福州京东方光电科技有限公司 | 显示面板、电路板及显示装置 |
| CN116612699A (zh) * | 2023-07-17 | 2023-08-18 | 惠科股份有限公司 | 灯板、显示装置和灯板的组装方法 |
| CN116612699B (zh) * | 2023-07-17 | 2023-11-21 | 惠科股份有限公司 | 灯板、显示装置和灯板的组装方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112038280A (zh) | 2020-12-04 |
| CN112038280B (zh) | 2022-07-29 |
| EP4181180A4 (en) | 2024-01-17 |
| EP4181180A1 (en) | 2023-05-17 |
| EP4181180B1 (en) | 2025-11-26 |
| US20230352334A1 (en) | 2023-11-02 |
| US12512360B2 (en) | 2025-12-30 |
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