WO2023034455A1 - Cathode-ray tube ultraviolet light source - Google Patents
Cathode-ray tube ultraviolet light source Download PDFInfo
- Publication number
- WO2023034455A1 WO2023034455A1 PCT/US2022/042265 US2022042265W WO2023034455A1 WO 2023034455 A1 WO2023034455 A1 WO 2023034455A1 US 2022042265 W US2022042265 W US 2022042265W WO 2023034455 A1 WO2023034455 A1 WO 2023034455A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- light source
- cathode
- ultraviolet light
- glass envelope
- target
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J63/00—Cathode-ray or electron-stream lamps
- H01J63/06—Lamps with luminescent screen excited by the ray or stream
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/025—Associated optical elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2893/00—Discharge tubes and lamps
- H01J2893/0031—Tubes with material luminescing under electron bombardment
Definitions
- UV light is a form of electromagnetic radiation with wavelengths from about 10 nanometers (nm) to 400 nm. UV light has a shorter wavelength than visible light, but longer than X-rays. Short wave ultraviolet light damages DNA and sterilizes surfaces with which it comes into contact. For humans, suntan and sunburn are familiar effects of exposure of the skin to UV light, along with increased risk of skin cancer.
- UVC light there are no natural sources of UV light below about 280 nm due to atmospheric absorption. This includes the UVC spectrum of 190 nm to 280 nm, which can be used for disinfection because UVC light is strongly absorbed by nucleic acids which can damage DNA and RNA.
- a UVC light source with a wavelength from 190-230 nm is effective at sterilizing surfaces without posing a danger to humans in the vicinity. Below 190 nm a UV light would produce significant amounts of ozone, which have been known to have deleterious effects on humans.
- UV light with a wavelength ⁇ 280 nm has a limited range of transmission and is also efficiently scattered by aerosols and molecules in air. Because of these factors, light with a wavelength ⁇ 280 nm may also be used for non-line of sight (NLOS) covert communication systems.
- NLOS non-line of sight
- Low pressure mercury vapor lamps have been used to produce UVC light for sterilization. Such lamps are energy efficient and cost effective but suffer from their use of mercury, which is an environmental hazard and can be toxic to humans. There has been a movement away from the use of low pressure mercury vapor lamps in recent years due to environmental and health concerns.
- Light Emitting Diodes have also been used to produce UVC light. While they do not include mercury or other heavy metals, they are not very efficient and are relative low capacity compared to other UVC light technologies.
- Pulsed Xenon lamps produce a wide spectrum of UV light but are relatively expensive compared to other technologies. Since the spectrum of UV is so wide, the output of the lamps need to be filtered to attenuate wavelengths outside of the 190-230 nm range.
- a cathode-ray ultraviolet light source includes: an elongated glass envelope having a first end and second end, the glass envelope defining an evacuated volume; an electron gun positioned within the evacuated volume proximate to the first end and being capable of developing an electron beam; a target disposed within the evacuated volume between the first and second end of the glass envelope, the target comprising a phosphor material covered with a reflective metal film; and an electron beam focusing and deflecting mechanism disposed within the evacuated volume between the electron gun and the target to direct the electron beam towards the reflective metal film of the target.
- a method for operating a cathode-ray tube ultraviolet light source includes directing an electron beam to reflective metal film covering a phosphor in an evacuated glass envelope and emitting ultraviolet light from the phosphor the glass envelope.
- the electron beam is focused and steered across the reflective metal film in a pattern.
- UVC light can be produced in an efficient, cost-effective manner without the use of dangerous and environmentally unfriendly heavy metals such as mercury.
- Figure 1 is an illustration of a first example cathode-ray ultraviolet light source
- Figure 2 is an illustration of a second example cathode-ray ultraviolet light source
- Figure 3 is a perspective view of a beam shaper
- Figure 4 is an end view a beam shaper
- Figure 5 is a first diagram illustrating an ideal and actual radiant intensity graph for illuminating the walls of a square room
- Figure 6 is a second diagram illustrating an ideal and actual radiant intensity graph for illuminating the walls of a square room
- Figure 7 is an illustration of a third example cathode-ray ultraviolet light source
- Figure 8 is an illustration of a fourth example cathode-fay ultraviolet light source
- Figure 9 is an illustration of a fifth example cathode-ray ultraviolet light source
- Figure 10 is an illustration of a sixth example cathode-ray ultraviolet light source.
- FIG. 11 illustrates a spectral tuning method for a cathode-ray tube ultraviolet light source using a plurality of phosphors.
- Fig. 1 is an illustration of a first example cathode-ray ultraviolet light source 10 including an elongated glass envelope 12 having a first end 14 and a second end 16 and defining an evacuated volume 18.
- An electron gun 20 is positioned within the evacuated volume 18 near the first end 14 and is capable of developing an electron beam 22.
- a target 24 is disposed within the evacuated volume 18 between the first end 14 and the second end 16 of the glass envelope 12.
- An electron beam focusing and deflecting mechanism 25 is used to focus the electron beam 22 and to steer the beam across the surface of the target 24.
- a target 24 is disposed within the evacuated volume 18 proximate the second end 16 of the glass envelope 12.
- the target 24 includes a phosphor material 26 covered with a reflective metal film 28.
- the electron beam 22 impinges upon the reflective metal film 28, it penetrates the film and causes the phosphor material 26 to emit ultraviolet (UV) light from the second end 16 of the glass envelope 12 with relatively little internal loss due to the reflective film 28.
- UV ultraviolet
- Fig. 2 is an illustration of a second example cathode-ray ultraviolet light source 10’ which is similar to the first example of Fig. 1 with the exception of the target 24’ configuration and location, where like reference numerals refer to like components, portions or elements.
- the target 24’ is provided upon one or more side portions 30 of the glass envelope 12.
- the targets 24’ include phosphor materials 26’ covered with reflective metal films 28’. When the electron beam 22 impinges upon the reflective metal films 28’ under the influence of the deflecting mechanism 25, it penetrates the film to cause the phosphor material 26’ to emit UV light from the side portions 30 of the glass envelope 12 with relatively little internal loss due to the reflective film 28’.
- Fig. 3 is a perspective view and Figure 4 is an end view of a beam shaper 32 for the light source 10' of Fig. 2, where like reference numerals refer to like components, portions or elements.
- the beam shaper 32 is substantially cylindrical in shape and includes cylindrical opening 34 in an end plate 36 that is receptive to the glass envelope 12 of light source 10’.
- the end plate 36 supports a number of radial fins 38 and has an alignment slot 35.
- Ultraviolet light emitted by the light source 10’ is shaped by the fins 38 to provide a desired distribution of UV light into the ambient environment
- the alignment Slot 35 ensures a fixed position and orientation of the beam shaper 32 with respect to the light source 10’ inserted into opening 34 to provide consistent emission patterns for the UV light.
- Fig. 5 is a diagram 39 illustrating an ideal radiant intensity graph 41 and an actual radiant intensity graph 43 of an example light source for illuminating the walls of a square room.
- the ideal radiant intensity is show in dotted lines while the actual radiant energy is shown in dashed lines.
- Fig. 6 is a second diagram 45 illustrating an ideal radiant intensity graph 47 and an actual radiant intensity graph 49 of the example light source for illuminating the walls of a square room. Again, the ideal radiant intensity is show in dotted lines while the actual radiant energy is shown in dashed lines.
- FIG. 7 is an illustration of a third example cathode-ray ultraviolet light source 10” which has a glass envelope 12” with an enlarged second end 16” , where like reference numerals refer to like components, portions or elements.
- the target 24 includes, as in the previous embodiments, a target 24” having a phosphor material covered by a reflective metal film.
- This example further includes an external reflector 40 to help direct the UV light emanating from second end 16” of the light source;
- a combination of beam steering, variable focus and intensity control allows the beam angle to be controlled between about 5 degrees and 120+ degrees.
- Fig, 8 is an illustration of a fourth example cathode-ray ultraviolet light source 10''' which has a target 24''' covering the internal side and end portions of a glass envelope 12''' , where like reference numerals refer to like components, portions or elements.
- the target 24''' includes, as in the previous embodiments, a target 24''' having a phosphor material covered by a reflective metal film.
- This example further includes an external reflector 42 to help direct the UV light emanating from the light source.
- a combination of beam steering, variable focus and intensity control allows the beam angle to be controlled between about 5 degrees and 120+ degrees.
- FIG. 9 is an illustration of a fifth example cathode-ray ultraviolet light source
- a target 24'''' is suspended within the evacuated volume 18 of the glass envelope by a UV light diffusion body 44.
- the target 24'''' includes, as in the previous embodiments, a phosphor material covered by a reflective metal film and has a concave configuration with the metal film facing the electron beam 22. Ultraviolet light emitted from the phosphor of the target 24'''' is diffused by the light diffusion body 24 to provide nearly 360° of light emission coverage.
- Fig. 10 is an illustration of a sixth example cathode-ray ultraviolet light source 10''''' which is essentially the same as the example of Fig. 9 wife the exception feat fee light diffusion body 44 has been omitted, where like reference numerals refer to like components, portions or elements.
- fee target 24'''' directs UV light in a somewhat conical fashion from fee second end 16” ” of the light source.
- Figure 11 illustrates a spectral tuning method for a cathode-ray tube ultraviolet light source using a plurality of phosphors.
- four different phosphors are laid out in a 2x2 grid 46 and comprise a Material A, Material B, Material C and Material D.
- a “spirograph” type pattern 48 A over Material A produces an emission spectra 50A.
- a spirograph type pattern 48B over Material C and Material D produces a different emission spectra SOB.
- the emission wavelength of a light source 10 is determined by the phosphor material being irradiated.
- AIN is a material that can emit UVC light at 210 nm.
- AlGaN can emit at different (longer) wavelengths.
- the amount of gallium will determine the emission wavelength which will increase with the amount of gallium added to the alloy.
- dopants can be added to AIN or AlGaN to change their emission wavelengths.
- hexagonal boron nitride will emit UVC light in the range of 210-220 nm.
- a phosphor material that emits in the wavelength range of about 450 nm to about 650 nm may be incorporated with a phosphor material that emits in the wavelength range of about 190 nm to about 280 nm in order to provide a visual indication that the device is operating.
- a preferred wavelength range for safety is 190-230 nm, for certain applications this range may be extended up to about 280 nm.
- some wavelengths ⁇ 280 nm may be optimal, although special precautions are recommended outside of the optimal 190-230 nm range.
- Preferred electron beam energy is 6,000 to 34,000 V.
- Beam current can range from 1 ⁇ A to 5 mA.
- Suitable spot sizes for certain applications is in the range of 0.1 to 1.0 mm in diameter. For some applications, a maximum spot size of up to about 5 mm in diameter may be desirable.
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
- Discharge Lamps And Accessories Thereof (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2022339611A AU2022339611A1 (en) | 2021-08-31 | 2022-08-31 | Cathode-ray tube ultraviolet light source |
| EP22865529.6A EP4396856A4 (en) | 2021-08-31 | 2022-08-31 | CATHODUM TUB WITH ULTRAVIOLET LIGHT SOURCE |
| US18/688,346 US12542268B2 (en) | 2021-08-31 | 2022-08-31 | Cathode-ray tube ultraviolet light source |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202163239196P | 2021-08-31 | 2021-08-31 | |
| US63/239,196 | 2021-08-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023034455A1 true WO2023034455A1 (en) | 2023-03-09 |
Family
ID=85411602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2022/042265 Ceased WO2023034455A1 (en) | 2021-08-31 | 2022-08-31 | Cathode-ray tube ultraviolet light source |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US12542268B2 (en) |
| EP (1) | EP4396856A4 (en) |
| AU (1) | AU2022339611A1 (en) |
| WO (1) | WO2023034455A1 (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3519742A (en) * | 1964-02-25 | 1970-07-07 | Ncr Co | Photochromic display using cathode ray tube |
| US3891886A (en) * | 1969-03-28 | 1975-06-24 | Rca Corp | Cathode ray tube having a luminescent screen including a two component white-emitting phosphoric mixture |
| US5644193A (en) * | 1993-12-17 | 1997-07-01 | Kabushiki Kaisha Toshiba | Phosphor, cathode-ray tube, fluorescent lamp and radiation intensifying screen |
| US20040140432A1 (en) * | 2002-10-10 | 2004-07-22 | Applied Materials, Inc. | Generating electrons with an activated photocathode |
| US20050110386A1 (en) * | 2003-11-03 | 2005-05-26 | Tiberi Michael D. | Laser cathode ray tube |
| US7315114B2 (en) * | 2004-02-17 | 2008-01-01 | Hitachi Displays, Ltd. | Display apparatus provided with a light-emitting glass face panel having an inner surface coated with a phosphor layer |
| US7828459B2 (en) * | 2004-09-29 | 2010-11-09 | Abl Ip Holding Llc | Lighting system using semiconductor coupled with a reflector have a reflective surface with a phosphor material |
| US8282243B2 (en) * | 2010-05-19 | 2012-10-09 | Panasonic Corporation | LED lamp and lighting device |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0529090B1 (en) * | 1991-03-06 | 1996-11-27 | Miyota Kabushiki Kaisha | Cathode luminescence device |
| US6614161B1 (en) * | 1993-07-20 | 2003-09-02 | University Of Georgia Research Foundation, Inc. | Resonant microcavity display |
| US5473396A (en) * | 1993-09-08 | 1995-12-05 | Matsushita Electric Industrial Co., Ltd. | Display apparatus and method of making the same |
| US20050110384A1 (en) | 2003-11-24 | 2005-05-26 | Peterson Charles M. | Lighting elements and methods |
| US8294367B2 (en) * | 2007-02-05 | 2012-10-23 | Vu1 Corporation | System and apparatus for cathodoluminescent lighting |
| US7834553B2 (en) * | 2007-02-05 | 2010-11-16 | Vu1 Corporation | System and apparatus for cathodoluminescent lighting |
| US8217346B2 (en) * | 2008-06-03 | 2012-07-10 | National University Corporation Shizuoka University | Optical microscope |
| JP5833325B2 (en) * | 2011-03-23 | 2015-12-16 | スタンレー電気株式会社 | Deep ultraviolet light source |
| MX387882B (en) * | 2015-12-04 | 2025-03-19 | Luxbright Ab | AN ELECTRON GUIDE AND RECEPTION ELEMENT. |
-
2022
- 2022-08-31 EP EP22865529.6A patent/EP4396856A4/en active Pending
- 2022-08-31 AU AU2022339611A patent/AU2022339611A1/en active Pending
- 2022-08-31 WO PCT/US2022/042265 patent/WO2023034455A1/en not_active Ceased
- 2022-08-31 US US18/688,346 patent/US12542268B2/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3519742A (en) * | 1964-02-25 | 1970-07-07 | Ncr Co | Photochromic display using cathode ray tube |
| US3891886A (en) * | 1969-03-28 | 1975-06-24 | Rca Corp | Cathode ray tube having a luminescent screen including a two component white-emitting phosphoric mixture |
| US5644193A (en) * | 1993-12-17 | 1997-07-01 | Kabushiki Kaisha Toshiba | Phosphor, cathode-ray tube, fluorescent lamp and radiation intensifying screen |
| US20040140432A1 (en) * | 2002-10-10 | 2004-07-22 | Applied Materials, Inc. | Generating electrons with an activated photocathode |
| US20050110386A1 (en) * | 2003-11-03 | 2005-05-26 | Tiberi Michael D. | Laser cathode ray tube |
| US7315114B2 (en) * | 2004-02-17 | 2008-01-01 | Hitachi Displays, Ltd. | Display apparatus provided with a light-emitting glass face panel having an inner surface coated with a phosphor layer |
| US7828459B2 (en) * | 2004-09-29 | 2010-11-09 | Abl Ip Holding Llc | Lighting system using semiconductor coupled with a reflector have a reflective surface with a phosphor material |
| US8282243B2 (en) * | 2010-05-19 | 2012-10-09 | Panasonic Corporation | LED lamp and lighting device |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP4396856A4 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US12542268B2 (en) | 2026-02-03 |
| EP4396856A4 (en) | 2025-11-12 |
| US20240363326A1 (en) | 2024-10-31 |
| EP4396856A1 (en) | 2024-07-10 |
| AU2022339611A1 (en) | 2024-04-18 |
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