WO2023063625A1 - 배터리 진단 장치, 배터리 팩, 전기 차량, 및 배터리 진단 방법 - Google Patents
배터리 진단 장치, 배터리 팩, 전기 차량, 및 배터리 진단 방법 Download PDFInfo
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- WO2023063625A1 WO2023063625A1 PCT/KR2022/014494 KR2022014494W WO2023063625A1 WO 2023063625 A1 WO2023063625 A1 WO 2023063625A1 KR 2022014494 W KR2022014494 W KR 2022014494W WO 2023063625 A1 WO2023063625 A1 WO 2023063625A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/3644—Constructional arrangements
- G01R31/3648—Constructional arrangements comprising digital calculation means, e.g. for performing an algorithm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L3/00—Electric devices on electrically-propelled vehicles for safety purposes; Monitoring operating variables, e.g. speed, deceleration or energy consumption
- B60L3/0023—Detecting, eliminating, remedying or compensating for drive train abnormalities, e.g. failures within the drive train
- B60L3/0046—Detecting, eliminating, remedying or compensating for drive train abnormalities, e.g. failures within the drive train relating to electric energy storage systems, e.g. batteries or capacitors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
- B60L58/10—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling batteries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
- B60L58/10—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling batteries
- B60L58/18—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling batteries of two or more battery modules
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R19/00—Arrangements for measuring currents or voltages or for indicating presence or sign thereof
- G01R19/10—Measuring sum, difference or ratio
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R19/00—Arrangements for measuring currents or voltages or for indicating presence or sign thereof
- G01R19/165—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values
- G01R19/16528—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values using digital techniques or performing arithmetic operations
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R19/00—Arrangements for measuring currents or voltages or for indicating presence or sign thereof
- G01R19/165—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values
- G01R19/16533—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application
- G01R19/16538—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application in AC or DC supplies
- G01R19/16542—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application in AC or DC supplies for batteries
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/367—Software therefor, e.g. for battery testing using modelling or look-up tables
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/382—Arrangements for monitoring battery or accumulator variables, e.g. SoC
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/392—Determining battery ageing or deterioration, e.g. state of health
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/396—Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/50—Testing of electric apparatus, lines, cables or components for short-circuits, continuity, leakage current or incorrect line connections
- G01R31/52—Testing for short-circuits, leakage current or ground faults
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L2240/00—Control parameters of input or output; Target parameters
- B60L2240/40—Drive Train control parameters
- B60L2240/54—Drive Train control parameters related to batteries
- B60L2240/547—Voltage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
- B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
- B60L58/10—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling batteries
- B60L58/16—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling batteries responding to battery ageing, e.g. to the number of charging cycles or the state of health [SoH]
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/382—Arrangements for monitoring battery or accumulator variables, e.g. SoC
- G01R31/3835—Arrangements for monitoring battery or accumulator variables, e.g. SoC involving only voltage measurements
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a technique for diagnosing micro-shorts of each battery cell from voltage behavior of a plurality of battery cells during idle.
- a battery system eg, a battery pack
- a series connection of a plurality of battery cells is widely used.
- micro short circuit also referred to as an internal short circuit or micro short circuit
- a micro short circuit is a representative type of defect condition that directly or indirectly affects fire.
- a micro short circuit is caused by a side reaction (eg, precipitation of lithium metal) in the battery cell and/or penetration of foreign substances into the battery cell.
- Conventional micro short circuit detection mainly adopts a method of comparing the internal resistance of a battery cell continuously monitored during charging and discharging with a reference value.
- the estimation of the internal resistance basically requires not only the voltage for each battery cell but also the detected value of the current, and the internal resistance is highly dependent on various internal and external conditions, resulting in poor accuracy.
- the present invention has been made to solve the above problems, monitoring the trend of voltage behavior during idle of a plurality of battery cells according to repetition of idle events, and detecting a minute short circuit having a strong correlation with the voltage behavior. It aims to provide an apparatus and method.
- An apparatus for diagnosing a battery includes a battery monitor configured to detect a voltage of each of a plurality of battery cells included in a battery module; and a latest value of a first voltage deviation indicating a difference between the voltage behavior of each battery cell and the average voltage behavior of the plurality of battery cells over a relaxation time from the start of an idle event in which the battery module switches from charging to idle. and control circuitry configured to determine. When the total number of occurrences of the idle event is equal to or greater than the reference number, the control circuit applies a smoothing algorithm to the latest value of the first voltage deviation for each battery cell, thereby corresponding to the latest value of the first voltage deviation. and determine an up-to-date value of the second voltage deviation.
- the control circuit is configured to determine, for each battery cell, a latest value of a third voltage deviation representing a difference between a latest value of the first voltage deviation and a latest value of the second voltage deviation.
- the control circuit is configured to determine, for each battery cell, a latest value of a fourth voltage deviation representing a difference between a latest value of the third voltage deviation and a previous value of the third voltage deviation.
- the control circuit is configured to determine, for each battery cell, a latest value of a threshold deviation using a scatter plot of a time series of the fourth voltage deviation having a predetermined size.
- the control circuit is configured to, for each battery cell, compare the latest value of the third voltage deviation with the latest value of the threshold deviation to determine whether or not the battery cell has a micro-short circuit.
- the voltage behavior of each battery cell may represent an average of voltages of the corresponding battery cell sequentially detected a predetermined number of times over a relaxation time from the start of the idle event.
- the smoothing algorithm may be a moving average filter.
- the reference number of times may be greater than or equal to the size of the moving average filter.
- the scatter plot may be a standard deviation.
- the control circuit may be configured to determine, for each battery cell, an up-to-date value of the threshold deviation by multiplying the scatter plot by a predetermined margin constant.
- the control circuit for each battery cell, when the latest value of the third voltage deviation is less than or equal to the latest value of the threshold deviation, increases an abnormality factor associated with the battery cell by a first value, and increases the abnormality factor associated with the corresponding battery cell.
- the factor may be configured to determine that a minute short circuit exists in the corresponding battery cell.
- the control circuit may be configured to reduce an abnormality factor associated with a corresponding battery cell by a second value when the latest value of the third voltage deviation is greater than the latest value of the threshold deviation for each battery cell.
- a battery pack according to another aspect of the present invention includes the battery diagnosis device.
- An electric vehicle includes the battery pack.
- a battery diagnosis method relates to a voltage behavior of each battery cell from the start of an idle event in which a battery module including a plurality of battery cells is switched from charging to idle to a relaxation time, and the plurality of battery cells. and determining a latest value of the first voltage deviation representing a difference between the average voltage behavior of the battery cells.
- the battery diagnosis method may correspond to the latest value of the first voltage deviation by applying a smoothing algorithm to the latest value of the first voltage deviation for each battery cell when the total number of occurrences of the idle event is equal to or greater than the reference number.
- the voltage behavior of each battery cell may represent an average of voltages of the corresponding battery cell sequentially detected a predetermined number of times over a relaxation time from the start of the idle event.
- the smoothing algorithm may be a moving average filter.
- the reference number of times may be greater than or equal to the size of the moving average filter.
- the scatter plot may be a standard deviation.
- the latest value of the critical deviation may be equal to a product of the scatter plot and a predetermined margin constant.
- a minute short circuit having a strong correlation with the voltage behavior may be detected by monitoring a trend of voltage behavior of a plurality of battery cells during idle according to repetition of an idle event. Accordingly, it is possible to take appropriate protective measures to prevent dangerous issues such as explosion or ignition of a battery cell due to a minute short circuit.
- FIG. 1 is a diagram showing the configuration of an electric vehicle according to the present invention by way of example.
- FIG. 2 is a diagram referenced to describe an exemplary equivalent circuit of a battery cell.
- FIG. 3 is a diagram referenced to describe a change in voltage of a battery cell over time during rest.
- FIG. 4 is a graph illustratively illustrating a change over time in a voltage behavior of a battery cell according to repetition of an idle event.
- 5 is a graph exemplarily illustrating a change over time in a first voltage deviation of a battery cell according to repetition of an idle event.
- FIG. 6 is a graph illustratively illustrating a change over time in a second voltage deviation of a battery cell according to repetition of an idle event.
- FIG. 7 is a graph exemplarily illustrating a change over time in a third voltage deviation of a battery cell according to repetition of an idle event.
- FIG. 8 is a graph exemplarily illustrating a change over time in a fourth voltage deviation of a battery cell according to repetition of an idle event.
- FIG. 9 is a graph illustratively illustrating a change over time in a threshold deviation for determining minute shorts of a battery cell according to repetition of an idle event.
- 10 and 11 are flowcharts referenced to illustratively describe a method for diagnosing a battery according to an embodiment of the present invention.
- FIG. 1 is a diagram showing the configuration of an electric vehicle according to the present invention by way of example.
- an electric vehicle 1 includes a vehicle controller 2 , a battery pack 10 , and an electric load 30 .
- the charging/discharging terminals P+ and P- of the battery pack 10 may be electrically coupled to the charger 40 through a charging cable or the like.
- the charger 40 may be included in the electric vehicle 1 or may be provided in a charging station outside the electric vehicle 1 .
- the vehicle controller 2 (eg, Electronic Control Unit (ECU)) transmits a key-on signal to a battery diagnosis in response to a start button (not shown) provided in the electric vehicle 1 being switched to the ON-position by the user. configured to transmit to device 100 .
- the vehicle controller 2 is configured to transmit a key-off signal to the battery diagnosis device 100 in response to the start button being switched to the OFF-position by the user.
- the charger 40 may communicate with the vehicle controller 2 to supply charging power through the charging/discharging terminals P+ and P- of the battery pack 10 .
- the battery pack 10 includes a battery module 11 , a relay 20 and a battery diagnostic device 100 .
- the battery module 11 includes a series connected body of a plurality of battery cells (B 1 to B N , where N is a natural number equal to or greater than 2). That is, within the battery module 11, a plurality of battery cells B 1 to B N may be connected in series to each other.
- the plurality of battery cells B 1 to B N may be manufactured to have the same electrochemical specifications. For example, as long as it is capable of repeatedly charging and discharging, such as a lithium ion cell, the type of the plurality of battery cells B 1 to B N is not particularly limited.
- a symbol 'B j '(j is a natural number less than or equal to N) is assigned to indicate a battery cell.
- the relay 20 is electrically connected in series to the battery module 11 through a power path connecting the battery module 11 and the electric load 30 .
- the relay 20 is illustrated as being connected between the positive terminal of the battery module 11 and the charge/discharge terminal P+.
- the relay 20 is turned on and off in response to a switching signal from the battery diagnosis device 100 and/or the vehicle controller 2 .
- the relay 20 may be a mechanical contactor that is turned on and off by the magnetic force of a coil or a semiconductor switch such as a metal oxide semiconductor field effect transistor (MOSFET).
- MOSFET metal oxide semiconductor field effect transistor
- the electric load 30 includes an inverter 31 and an electric motor 32 .
- the inverter 31 is provided to convert direct current from the battery module 11 included in the battery pack 10 into alternating current in response to a command from the battery diagnosis device 100 or the vehicle controller 2.
- the electric motor 32 is driven using AC power from the inverter 31 .
- As the electric motor 32 a three-phase AC motor can be used, for example.
- a state in which the relay 20 is turned on and the battery module 11 is being charged/discharged may be referred to as a 'cycle state (or load state)'.
- the battery module 11 When the relay 20 is switched from on to off, the battery module 11 is in a 'idle state (or no-load state, calendar state)' in a cycle state, and the voltage of the battery cell B j in the dormant state may be referred to as 'relaxation voltage (or rest voltage, no-load voltage)'.
- the relaxation voltage after a sufficient time has elapsed since the battery cell B j is switched from charging or discharging to resting may converge to an open circuit voltage (OCV).
- OCV open circuit voltage
- the battery diagnosis apparatus 100 includes a battery monitor 110 and a control circuit 120 .
- the battery diagnosis apparatus 100 may further include a communication circuit 130 .
- the battery diagnosis device 100 includes a battery monitor 110 , a control circuit 120 and a communication circuit 130 .
- the battery monitor 110 includes a voltage detector 112 .
- the battery monitor 110 may further include a current detector 114 .
- the voltage detector 112 is connected to the positive terminal and the negative terminal of each of the plurality of battery cells (B 1 to B N ) included in the battery module 11, and the voltage across both ends of the battery cell (B j ) (' may be referred to as 'cell voltage') and generate a voltage signal representing the detected cell voltage.
- the current detector 114 is serially connected to the battery module 11 through a current path between the battery module 11 and the inverter 30 .
- the current detector 114 may be implemented with one or a combination of two or more known current detection elements such as a shunt resistor, a Hall effect element, and the like. As shown in FIG. 1 , when a plurality of battery cells B 1 to B N are connected in series, the same charge/discharge current flows through the plurality of battery cells B 1 to B N .
- the current detector 114 may output a current signal representing the direction and magnitude of the charge/discharge current to the control circuit 120 based on the voltage across the shunt resistor according to Ohm's law.
- Control circuit 120 may be operatively coupled to relay 20 , battery monitor 110 , and communication circuit 130 .
- relay 20 When two components are operably coupled, it means that the two components are directly or indirectly connected so that signals can be transmitted and received in one direction or both directions.
- the control circuit 120 may be referred to as a 'battery controller', and in terms of hardware, ASICs (application specific integrated circuits), DSPs (digital signal processors), DSPDs (digital signal processing devices), PLDs (programmable logic devices), FPGAs It may be implemented using at least one of (field programmable gate arrays), microprocessors, and electrical units for performing other functions.
- ASICs application specific integrated circuits
- DSPs digital signal processors
- DSPDs digital signal processing devices
- PLDs programmable logic devices
- FPGAs field programmable gate arrays
- microprocessors and electrical units for performing other functions.
- the control circuit 120 may collect a voltage signal and/or a current signal from the battery monitor 110 .
- the control circuit 120 may convert and record the analog signal collected from the battery monitor 110 into a digital value using an analog to digital converter (ADC) provided therein.
- ADC analog to digital converter
- the battery monitor 110 may transmit a result of converting an analog signal into a digital value by itself to the control circuit 120 .
- the memory 121 may be, for example, a flash memory type, a hard disk type, a solid state disk type (SSD type), a silicon disk drive type (SDD type), or a multimedia card micro type. micro type), random access memory (RAM), static random access memory (SRAM), read-only memory (ROM), electrically erasable programmable read-only memory (EEPROM), programmable read-only memory (PROM) At least one type of storage medium may be included.
- the memory 121 may store data and programs required for arithmetic operations by the control circuit 120 .
- the memory 121 may store data representing a result of an arithmetic operation performed by the control circuit 120 .
- the memory 121 may store pre-given functions, logics, and algorithms to be used to detect minute short circuits of the battery cell B j .
- the memory 121 may be integrated into the control circuit 120 .
- the control circuit 120 may turn on the relay 20 in response to a key-on signal from the vehicle controller 2 .
- the control circuit 120 may turn off the relay 20 in response to a key-off signal from the vehicle controller 2 .
- the key-on signal is a signal requesting a transition from the dormant state to the cycle state.
- the key-off signal is a signal requesting a transition from the dormant state to the cycle state.
- the vehicle controller 2 may be in charge of on/off control of the relay 20 instead of the control circuit 120 .
- the communication circuit 130 is configured to support wired communication or wireless communication between the control circuit 120 and the vehicle controller 2 .
- Wired communication may be, for example, contoller area network (CAN) communication
- wireless communication may be, for example, ZigBee or Bluetooth communication.
- the type of communication protocol is not particularly limited.
- the communication circuit 130 may include an output device (eg, a display, a speaker) that provides information received from the control circuit 120 and/or the vehicle controller 2 in a form recognizable by a user (driver). .
- a normal battery cell refers to a battery cell without a micro short circuit
- an ideal battery cell refers to a battery cell with a micro short circuit.
- a normal battery cell may be equivalent as a series circuit of a DC voltage source (V DC ), an internal resistance (R 0 ), and an RC pair (R 1 , C).
- V DC DC voltage source
- R 0 internal resistance
- R 1 RC pair
- an ideal battery cell may be equivalent to having an additional resistance (R ISC ) connected between both ends (+, -) of a series circuit corresponding to a normal battery cell.
- the additional resistance (R ISC ) acts as a path for the leakage current (I ISC ).
- the voltage of the DC voltage source (V DC ) is the OCV of the battery cell (B j ), and the cell voltage of the battery cell (B j ) is the DC voltage source (V DC ), the internal resistance component (R 0 ) and the RC pair ( R 1 , C) is the total voltage of the series circuit.
- the charge/discharge current is zero (OA) and the voltage of the RC pair (R 1 , C) is zero (0 V)
- the relaxation voltage and OCV are the same.
- a decrease in the resistance value of the resistor R ISC means that micro-shorts intensify, and as the micro-shorts intensify, the amount of power consumed as leakage current I ISC may increase.
- the voltage increase amount of the abnormal battery cell may be smaller than that of the normal battery cell.
- the voltage drop of the abnormal battery cell may be greater than that of the normal battery cell.
- energy stored in an abnormal battery cell may be consumed as a leakage current (I ISC ) even during an idle state in which a charge/discharge current is zero. Therefore, during idle, the voltage of the abnormal battery cell is lower than that of the normal battery cell, and the voltage decrease rate of the abnormal battery cell is faster than that of the normal battery cell.
- I ISC leakage current
- FIG. 3 is a diagram referenced for explaining the change over time in the voltage of a battery cell during idle
- FIG. 4 is a graph showing the change over time in the voltage behavior of a battery cell according to repetition of an idle event
- 5 is a graph showing a change over time in a first voltage deviation of a battery cell according to repetition of an idle event. 4 and 5, the horizontal axis represents the event number x representing the order of occurrence of idle events.
- the vertical axis of FIG. 4 represents the voltage behavior (average voltage over relaxation time) of the battery cell B j for each idle event, and the vertical axis of FIG. 5 represents the first voltage deviation of the battery cell B j for each idle event.
- FIG. 3 illustrates a voltage behavior of one battery cell (B j ) among a plurality of battery cells (B 1 to B N ) during rest.
- Time point t A is the start point of a specific pause event.
- a dormant event is when the battery module 11 is switched from charging to dormant.
- the cell voltage of the battery cell (B j ) continues to rise until the starting point in time t A , drops momentarily at the starting point in time t A when the charging current becomes zero, and then converges toward OCV.
- Time point t B is a time point after a predetermined relaxation time ( ⁇ t) has elapsed from start time point t A.
- the voltage behavior of the battery cell B j represents the average of the voltages of the battery cell B j sequentially detected a predetermined number of times over the relaxation time ⁇ t from time point t A to time point t B .
- the relaxation time ⁇ t may be a predetermined multiple of the time interval for detecting the voltage of the battery cell B j .
- the relaxation time ⁇ t is 60 seconds
- the voltage of the battery cell B j may be sequentially detected a total of 600 times at intervals of 0.1 seconds. Accordingly, the voltage behavior of each of the plurality of battery cells B 1 to B N with respect to the idle period from the time point t A to the time point t B may be determined. Equation 1 below is an example of a function used to calculate the voltage behavior of the battery cell B j among the plurality of battery cells B 1 to B N .
- Equation 1 S is the total number of voltage detections during the relaxation time ( ⁇ t) (e.g., 600), and V j [i][x] is the battery cell at the ith detection timing during rest by the rest event of event number x.
- the voltage of (B j ), V j_AV [x], is the average of the voltages of the battery cell (B j ) detected S times during the relaxation time ( ⁇ t) by the rest event of event number x.
- the control circuit 120 monitors the voltage behavior of the battery cell B j during idle whenever an idle event occurs (ie, whenever the event number x increases by 1). Accordingly, as shown in FIG. 4 , changes over time in a plurality of voltage behaviors (V 1_AV [x] to V N_AV [x]) of the plurality of battery cells B 1 to B N according to repetition of the idle event. A time series representing is recorded in the memory 121.
- the control circuit 120 determines the latest value of the first voltage deviation of the battery cell B j whenever an idle event occurs.
- the first voltage deviation of the battery cell B j represents a difference between the voltage behavior of the battery cell B j and the average voltage behavior of the plurality of battery cells B 1 to B N . Equation 2 below is an example of a function used to calculate the first voltage deviation of the battery cell B j .
- V M [x] is the average voltage behavior of a plurality of battery cells (B 1 to B N ) corresponding to the dormant event of event number x
- V j_D1 [x] is the dormant event of event number x This is the first voltage deviation of the battery cell B j . That is, whenever the event number x increases by one, V 1_D1 [x] to V N_D1 [x] associated with the plurality of battery cells B 1 to B N may be calculated. Accordingly, as shown in FIG.
- FIGS. 6 to 9 processes additionally performed by the control circuit 120 for micro-short detection will be described with reference to FIGS. 6 to 9 .
- the processes related to FIGS. 6 to 9 may be performed when a condition in which the total number of occurrences of idle events (ie, the event number x of recently generated idle events) is equal to or greater than the reference number is satisfied.
- the graphs shown in FIGS. 6 to 9 are related to a single curve (related to the battery cell above) marked with a thick solid line among a plurality of first voltage deviation curves shown in FIG. will be.
- FIG. 6 is a graph exemplarily illustrating a change over time in a second voltage deviation of a battery cell according to repetition of an idle event
- FIG. 7 is an example of a change over time in a third voltage deviation of a battery cell according to repetition of an idle event
- FIG. 8 is a graph exemplarily showing a change over time in a fourth voltage deviation of a battery cell according to repetition of a dormant event
- FIG. It is a graph showing the change over time of the critical deviation as an example.
- FIGS. 6 to 9 For convenience of description, only a single curve representing a change over time of the second voltage deviation associated with the first voltage deviation of the ideal battery cell is shown in FIGS. 6 to 9 .
- the control circuit 120 applies a smoothing algorithm to the latest value of the first voltage deviation of the battery cell B j to the battery cell corresponding to the latest value of the first voltage deviation ( The latest value of the second voltage deviation of B j ) may be determined.
- a moving average filter is an example of a smoothing algorithm. Equation 3 below is an example of a moving average filter used to calculate the second voltage deviation of the battery cell B j .
- W (a natural number greater than or equal to 2) is the size of the moving average filter
- V j_D2 [x] is the second voltage deviation of the battery cell (B j ) corresponding to the idle event of event number x
- V j_D2 [x -1] is the second voltage deviation of the battery cell B j corresponding to the idle event of event number x-1.
- the latest value of the second voltage deviation of the battery cell B j is the first voltage deviations (V j_D1 [x-W+1] to V j_D1 [ x-1]) may be used to indicate a result of correcting the latest value (V j_D1 [x]) of the first voltage deviation corresponding to the current pause event.
- V 1_D2 [x] to V N_D2 [x] associated with the plurality of battery cells B 1 to B N may be newly calculated. Accordingly, a time series showing changes over time in the plurality of second voltage deviations (V 1_D2 [x] to V N_D2 [x]) of the plurality of battery cells B 1 to B N according to the repetition of the dormant event (ie, Relationship data between the event number and the second voltage deviation) is recorded in the memory 121 .
- the smoothing algorithm may be replaced with an algorithm other than Equation 3 (eg, a double exponential smoothing filter).
- the control circuit 120 determines the latest value of the third voltage deviation representing the difference between the latest value of the first voltage deviation and the latest value of the second voltage deviation. Equation 4 below illustrates the relationship between the first voltage deviation, the second voltage deviation, and the third voltage deviation.
- V j_D3 [x] is the third voltage deviation of the battery cell B j corresponding to the idle event of event number x.
- the third voltage deviation of the battery cell (B j ) represents a deepening trend of minute short circuits in the battery cell (B j ).
- V 1_D3 [x] to V N_D3 [x] associated with the plurality of battery cells B 1 to B N may be calculated.
- a time series showing changes over time in the plurality of third voltage deviations V 1_D3 [x] to V N_D3 [x] of the plurality of battery cells B 1 to B N according to the repetition of the dormant event ie, Relationship data between the event number and the third voltage deviation
- the dormant event ie, Relationship data between the event number and the third voltage deviation
- the control circuit 120 determines the latest value of the fourth voltage deviation representing the difference between the latest value of the third voltage deviation and the previous value of the third voltage deviation.
- the fourth voltage deviation of the battery cell (B j ) represents the variability of the deepening trend of the minute short circuit of the battery cell (B j ). Equation 5 below illustrates the relationship between the third voltage deviation and the fourth voltage deviation.
- V j_D4 [x] is the fourth voltage deviation of the battery cell B j corresponding to the idle event of event number x.
- V j_D3 [x] is the latest value of the third voltage deviation
- V j_D3 [x-1] is the previous value of the third voltage deviation.
- a time series showing changes over time in the plurality of fourth voltage deviations V 1_D4 [x] to V N_D4 [x] of the plurality of battery cells B 1 to B N according to the repetition of the dormant event ie, Relationship data between the event number and the fourth voltage deviation
- the dormant event ie, Relationship data between the event number and the fourth voltage deviation
- the control circuit 120 uses a scatter plot of a time series of a fourth voltage deviation having a predetermined size (which is a natural number greater than or equal to 2) with respect to the battery cell B j to determine the latest value of the threshold deviation.
- Decide. Equation 6 below is an example of a function used to calculate the standard deviation as a scatter plot of the time series of the fourth voltage deviation of the battery cell B j .
- Equation 6 ⁇ j [x] is the standard deviation of the time series (size y) of the fourth voltage deviation of the battery cell B j , and V j_D4_AV is the average of the time series (size y) of the fourth voltage deviation.
- ⁇ j [x] corresponds to the dormant event of event number x.
- the control circuit 120 sets the latest value V j_Th [x] of the threshold deviation used for detecting a minute short of the battery cell B j to be equal to the value obtained by multiplying ⁇ j [x], which is a scatter plot, by a predetermined margin constant.
- V j_Th [x] ⁇ j [x] ⁇ Q.
- Q is a margin constant. Accordingly, whenever the event number x increases by 1, V 1_Th [x] to V N_Th [x] associated with the plurality of battery cells B 1 to B N may be calculated. Accordingly , a time series (that is , event number Relationship data between y and the threshold deviation) is recorded in the memory 121 .
- the curve of FIG. 9 illustrates a time series of threshold deviations associated with an ideal battery cell (refer to the bold line in FIG. 5 ) when y and Q are 100 and -15, respectively.
- the control circuit 120 increases an anomaly factor indicating a minor short circuit symptom of the battery cell B j , when V j_D3 [x] ⁇ V j_Th [x], Otherwise, the anomaly factor can be reduced.
- the ideal factor may be increased by a first value (eg, 10) from the previous value or by a first ratio (eg, 10%) of the previous value.
- the ideal factor may be decreased by a second value (eg, 1) from the previous value or by a second ratio (eg, 2%) of the previous value.
- the control circuit 120 may determine that a minute short circuit exists in the battery cell B j in response to an abnormality factor associated with the battery cell B j being greater than or equal to a threshold value (eg, 100).
- the control circuit 120 in response to the condition of V j_D3 [x] > V j_Th [x] being continuously satisfied while the event number x increases by a predetermined value (eg, 10), the battery cell B j
- An abnormality factor related to may be reset to an initial value (eg, 0).
- the initial value is the lower limit value of the ideal factor.
- FIGS. 10 and 11 are flowcharts referenced to illustratively describe a method for diagnosing a battery according to an embodiment of the present invention.
- the method of FIGS. 10 and 11 may be initiated whenever an idle event occurs in which the battery module 11 is switched from charging to idle. For reference, a value greater than the previous event number by 1 may be assigned to the event number x of the newly generated idle event.
- step S1010 the control circuit 120, for each of the plurality of battery cells B 1 to B N , from the start of the idle event to the relaxation time ⁇ t, the battery
- the latest value of the first voltage deviation representing the difference between the voltage behavior (V j_AV [x]) of the cell (B j ) and the average voltage behavior (V M [x]) of the plurality of battery cells (B 1 to B N ) ( V j_D1 [x]) is determined (see Equations 1 and 2).
- V j_D1 [x] may be written to the memory 121 .
- step S1020 the control circuit 120 determines whether the total number of occurrences of idle events is greater than or equal to a reference number. If the value of step S1020 is "yes", it proceeds to step S1030.
- the total number of occurrences may indicate a maximum value among event numbers assigned to idle events that have occurred up to now.
- step S1030 the control circuit 120 applies a smoothing algorithm to the latest value of the first voltage deviation (V j_AV [x]) for each of the plurality of battery cells (B 1 to B N ) to obtain the first voltage.
- the latest value of the second voltage deviation (V j_D2 [x]) corresponding to the latest value of the deviation (V j_D1 [x]) is determined (see Equation 3).
- the latest value of the second voltage deviation (V j_D2 [x]) is a weighted average of the latest value of the first voltage deviation (V j_D1 [x]) and the previous value of the second voltage deviation (V j_D2 [x-1]) can be V j_D2 [x] may be written to the memory 121 .
- step S1040 the control circuit 120 performs the latest value of the first voltage deviation (V j_D1 [x]) and the latest value of the second voltage deviation (V for each of the plurality of battery cells B 1 to B N ).
- the latest value (V j_D3 [x]) of the third voltage deviation representing the difference between j_D2 [x]) is determined (see Equation 4).
- V j_D3 [x] may be written to the memory 121 .
- step S1050 the control circuit 120, for each of the plurality of battery cells B 1 to B N , the latest value of the third voltage deviation (V j_D3 [x]) and the previous value of the third voltage deviation (V The latest value (V j_D4 [x]) representing the difference between j_D3 [x-1]) of the fourth voltage deviation is determined (see Equation 5).
- V j_D4 [x] may be written to the memory 121 .
- step S1060 the control circuit 120 performs a time series (V j_D4 [x-y+1] ⁇ ) of a fourth voltage deviation having a predetermined size (y) for each of the plurality of battery cells (B 1 ⁇ B N ).
- the latest value (V j_Th [x]) of the threshold deviation is determined using the scatter plot (eg, standard deviation ⁇ j [x]) of V j_D4 [x] (see Equation 6).
- step S1070 the control circuit 120 sets the latest value of the third voltage deviation (V j_D3 [x]) to the latest value of the threshold deviation (V j_Th [x] for each of the plurality of battery cells B 1 to B N ). x]), it is determined whether the condition of V j_D3 [x] ⁇ V j_Th [x] is satisfied. V j_D3 [x] ⁇ V j_Th [x] indicates that the battery cell (B j ) has a slight short circuit symptom. If the value of step S1070 is "yes”, the process proceeds to step S1082. When the value of step S1070 is "no", it may proceed to step S1084.
- step S1082 the control circuit 120 determines the ideal factor associated with the battery cell B j for which the condition of V j_D3 [x] ⁇ V j_Th [ x ] is satisfied among the plurality of battery cells B 1 to B N . is increased by the first value.
- step S1084 the control circuit 120, among the plurality of battery cells B 1 to B N , has an error associated with the battery cell B j for which the condition of V j_D3 [x] ⁇ V j_Th [x] is not satisfied. Decrease the factor by a second value.
- step S1086 the control circuit 120 determines whether the abnormality factor associated with the battery cell B j for which the condition of V j_D3 [x] ⁇ V j_Th [x] is satisfied is greater than or equal to a threshold value. If the value of step S1084 is "YES”, it indicates that it has been detected that a minute short circuit exists in the battery cell B j . If the value of step S1084 is “yes”, it may proceed to step S1090.
- the control circuit 120 executes at least one protection operation.
- the protection operation may include generating a diagnostic message notifying the identification number and/or location of the battery cell B j associated with an abnormality factor equal to or greater than a threshold value.
- the diagnostic message may be transmitted to the vehicle controller 2 and/or the vehicle user via the communication circuit 130 .
- the protection operation may include off control of the relay 20 .
- the embodiments of the present invention described above are not implemented only through devices and methods, and may be implemented through a program that realizes functions corresponding to the configuration of the embodiments of the present invention or a recording medium on which the program is recorded. Implementation can be easily implemented by an expert in the technical field to which the present invention belongs based on the description of the above-described embodiment.
- control circuit 130 communication circuit
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Abstract
Description
Claims (14)
- 배터리 모듈에 포함된 복수의 배터리 셀 각각의 전압을 검출하도록 구성되는 배터리 모니터; 및상기 배터리 모듈이 충전으로부터 휴지로 전환되는 휴지 이벤트의 시작 시점부터 이완 시간에 걸친, 각 배터리 셀의 전압 거동과 상기 복수의 배터리 셀의 평균 전압 거동 간의 차이를 나타내는 제1 전압 편차의 최신값을 결정하도록 구성되는 제어 회로를 포함하고,상기 제어 회로는, 상기 휴지 이벤트의 총 발생 횟수가 기준 횟수 이상인 경우, 각 배터리 셀에 대해,상기 제1 전압 편차의 최신값에 평활화 알고리즘을 적용하여, 상기 제1 전압 편차의 최신값에 대응하는 제2 전압 편차의 최신값을 결정하고,상기 제1 전압 편차의 최신값과 상기 제2 전압 편차의 최신값 간의 차이를 나타내는 제3 전압 편차의 최신값을 결정하고,상기 제3 전압 편차의 최신값과 상기 제3 전압 편차의 이전값 간의 차이를 나타내는 제4 전압 편차의 최신값을 결정하고,소정 사이즈를 가지는 상기 제4 전압 편차의 시계열의 산포도를 이용하여, 임계 편차의 최신값을 결정하고,상기 제3 전압 편차의 최신값을 상기 임계 편차의 최신값과 비교하여, 해당 배터리 셀의 미소 단락 유무를 판정하도록 구성되는 배터리 진단 장치.
- 제1항에 있어서,각 배터리 셀의 전압 거동은,상기 휴지 이벤트의 시작 시점부터 이완 시간에 걸쳐 소정 횟수 순차 검출된 해당 배터리 셀의 전압의 평균을 나타내는 배터리 진단 장치.
- 제1항에 있어서,상기 평활화 알고리즘은, 이동 평균 필터이고,상기 기준 횟수는, 상기 이동 평균 필터의 사이즈 이상인 배터리 진단 장치.
- 제1항에 있어서,상기 산포도는, 표준 편차인 배터리 진단 장치.
- 제1항에 있어서,상기 제어 회로는, 각 배터리 셀에 대해,상기 산포도에 소정의 마진 상수를 곱하여, 상기 임계 편차의 최신값을 결정하도록 구성되는 배터리 진단 장치.
- 제1항에 있어서,상기 제어 회로는, 각 배터리 셀에 대해,상기 제3 전압 편차의 최신값이 상기 임계 편차의 최신값 이하인 경우, 해당 배터리 셀에 연관된 이상 팩터를 제1 값만큼 증가시키고,해당 배터리 셀에 연관된 이상 팩터가 임계치에 도달한 경우, 해당 배터리 셀에 미소 단락이 존재하는 것으로 판정하도록 구성되는 배터리 진단 장치.
- 제6항에 있어서,상기 제어 회로는, 각 배터리 셀에 대해,상기 제3 전압 편차의 최신값이 상기 임계 편차의 최신값 초과인 경우, 해당 배터리 셀에 연관된 이상 팩터를 제2 값만큼 감소시키도록 구성되는 배터리 진단 장치.
- 제1항 내지 제7항 중 어느 한 항에 따른 상기 배터리 진단 장치를 포함하는 배터리 팩.
- 제8항에 따른 상기 배터리 팩을 포함하는 전기 차량.
- 복수의 배터리 셀을 포함하는 배터리 모듈이 충전으로부터 휴지로 전환되는 휴지 이벤트의 시작 시점부터 이완 시간에 걸친, 각 배터리 셀의 전압 거동과 상기 복수의 배터리 셀의 평균 전압 거동 간의 차이를 나타내는 제1 전압 편차의 최신값을 결정하는 단계를 포함하고,상기 휴지 이벤트의 총 발생 횟수가 기준 횟수 이상인 경우, 각 배터리 셀에 대해,상기 제1 전압 편차의 최신값에 평활화 알고리즘을 적용하여, 상기 제1 전압 편차의 최신값에 대응하는 제2 전압 편차의 최신값을 결정하는 단계;상기 제3 전압 편차의 최신값과 상기 제3 전압 편차의 이전값 간의 차이를 나타내는 제4 전압 편차의 최신값을 결정하는 단계;소정 사이즈를 가지는 상기 제4 전압 편차의 시계열의 산포도를 이용하여, 임계 편차의 최신값을 결정하는 단계; 및상기 제3 전압 편차의 최신값을 상기 임계 편차의 최신값과 비교하여, 해당 배터리 셀의 미소 단락 유무를 판정하는 단계를 더 포함하는 배터리 진단 방법.
- 제10항에 있어서,각 배터리 셀의 전압 거동은,상기 휴지 이벤트의 시작 시점부터 이완 시간에 걸쳐 소정 횟수 순차 검출된 해당 배터리 셀의 전압의 평균을 나타내는 배터리 진단 방법.
- 제10항에 있어서,상기 평활화 알고리즘은, 이동 평균 필터이고,상기 기준 횟수는, 상기 이동 평균 필터의 사이즈 이상인 배터리 진단 방법.
- 제10항에 있어서,상기 산포도는, 표준 편차인 배터리 진단 방법.
- 제10항에 있어서,상기 임계 편차의 최신값은, 상기 산포도와 소정의 마진 상수의 곱과 동일한 배터리 진단 방법.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL22881254.1T PL4293370T3 (pl) | 2021-10-13 | 2022-09-27 | Urządzenie do diagnozowania akumulatorów, pakiet akumulatorowy, pojazd elektryczny oraz sposób diagnozowania akumulatorów |
| JP2023545869A JP7508711B2 (ja) | 2021-10-13 | 2022-09-27 | バッテリー診断装置、バッテリーパック、電気車両、及びバッテリー診断方法 |
| US18/277,239 US12613289B2 (en) | 2021-10-13 | 2022-09-27 | Battery diagnosis apparatus, battery pack, electric vehicle, and battery diagnosis method |
| CN202280017352.0A CN117015715A (zh) | 2021-10-13 | 2022-09-27 | 电池诊断装置、电池组、电动车辆和电池诊断方法 |
| ES22881254T ES3043889T3 (en) | 2021-10-13 | 2022-09-27 | Battery diagnosis apparatus, battery pack, electric vehicle, and battery diagnosis method |
| EP22881254.1A EP4293370B1 (en) | 2021-10-13 | 2022-09-27 | Battery diagnosis apparatus, battery pack, electric vehicle, and battery diagnosis method |
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| KR10-2021-0136165 | 2021-10-13 | ||
| KR1020210136165A KR20230052763A (ko) | 2021-10-13 | 2021-10-13 | 배터리 진단 장치, 배터리 팩, 전기 차량, 및 배터리 진단 방법 |
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| US (1) | US12613289B2 (ko) |
| EP (1) | EP4293370B1 (ko) |
| JP (1) | JP7508711B2 (ko) |
| KR (1) | KR20230052763A (ko) |
| CN (1) | CN117015715A (ko) |
| ES (1) | ES3043889T3 (ko) |
| HU (1) | HUE073396T2 (ko) |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN117207837A (zh) * | 2023-10-07 | 2023-12-12 | 嘉丰盛精密电子科技(孝感)有限公司 | 一种新能源汽车电池包负载均衡调度方法及系统 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111856316B (zh) * | 2019-04-02 | 2021-10-26 | 华为技术有限公司 | 检测电池组内短路的方法及相关装置、电动车 |
| CN115461634B (zh) * | 2020-11-27 | 2025-10-28 | 株式会社Lg新能源 | 电池诊断装置、电池诊断方法、电池组及车辆 |
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| Publication number | Publication date |
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| EP4293370B1 (en) | 2025-09-17 |
| JP2024505902A (ja) | 2024-02-08 |
| US20240230784A9 (en) | 2024-07-11 |
| KR20230052763A (ko) | 2023-04-20 |
| EP4293370A4 (en) | 2024-10-23 |
| HUE073396T2 (hu) | 2026-01-28 |
| US20240133972A1 (en) | 2024-04-25 |
| ES3043889T3 (en) | 2025-11-26 |
| US12613289B2 (en) | 2026-04-28 |
| EP4293370A1 (en) | 2023-12-20 |
| PL4293370T3 (pl) | 2025-11-24 |
| CN117015715A (zh) | 2023-11-07 |
| JP7508711B2 (ja) | 2024-07-01 |
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