WO2023219420A1 - 로터리 킬른 - Google Patents
로터리 킬른 Download PDFInfo
- Publication number
- WO2023219420A1 WO2023219420A1 PCT/KR2023/006363 KR2023006363W WO2023219420A1 WO 2023219420 A1 WO2023219420 A1 WO 2023219420A1 KR 2023006363 W KR2023006363 W KR 2023006363W WO 2023219420 A1 WO2023219420 A1 WO 2023219420A1
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- WO
- WIPO (PCT)
- Prior art keywords
- rotating tube
- temperature
- stirring
- tube
- rotary kiln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K1/00—Details of thermometers not specially adapted for particular types of thermometer
- G01K1/14—Supports; Fastening devices; Arrangements for mounting thermometers in particular locations
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/42—Arrangement of controlling, monitoring, alarm or like devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/08—Rotary-drum furnaces, i.e. horizontal or slightly inclined externally heated
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/22—Rotary drums; Supports therefor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/32—Arrangement of devices for charging
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/33—Arrangement of devices for discharging
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D19/00—Arrangements of controlling devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
- F27D21/0014—Devices for monitoring temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
- F27D21/04—Arrangement of indicators or alarms
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K1/00—Details of thermometers not specially adapted for particular types of thermometer
- G01K1/16—Special arrangements for conducting heat from the object to the sensitive element
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K13/00—Thermometers specially adapted for specific purposes
- G01K13/04—Thermometers specially adapted for specific purposes for measuring temperature of moving solid bodies
- G01K13/08—Thermometers specially adapted for specific purposes for measuring temperature of moving solid bodies in rotary movement
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K7/00—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
- G01K7/02—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using thermoelectric elements, e.g. thermocouples
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D19/00—Arrangements of controlling devices
- F27D2019/0028—Regulation
Definitions
- the present invention relates to a rotary kiln that can directly measure the temperature of a tube assembly and the temperature of raw material powder that is heated and rotated by the tube assembly.
- secondary batteries refer to batteries that can be charged and discharged, unlike primary batteries that cannot be recharged. These secondary batteries are widely used in the field of high-tech electronic devices such as phones, laptop computers, and camcorders.
- lithium secondary batteries which have high energy density and voltage, long cycle life, and low self-discharge rate, have been commercialized and are widely used.
- the lithium secondary battery uses lithium transition metal oxide as a cathode active material.
- the cathode active materials include lithium cobalt oxide with a high operating voltage and excellent capacity characteristics, lithium nickel oxide with a high reversible capacity of about 200 mAh/g and easy to implement large-capacity batteries, and lithium nickel with some of the nickel replaced with cobalt.
- Cobalt oxide, lithium nickel cobalt metal oxide in which part of nickel is replaced with manganese, cobalt or aluminum, lithium manganese-based oxide with excellent thermal stability and low cost, and lithium iron phosphate with excellent stability are used.
- the above-described positive electrode active material is manufactured by mixing a precursor for producing a positive electrode active material and a lithium raw material, then putting it in a heating device and firing it at a high temperature.
- a rotary kiln may be used as the heating device.
- the rotary kiln accommodates a precursor for producing a positive electrode active material and lithium raw material (hereinafter referred to as raw material powder), and rotates and mixes them in the horizontal direction.
- the rotary kiln is provided on the outside of the rotating tube and heats the rotating tube to mix the raw material. It includes a heating element that heats and reacts the powder, a supply member that supplies raw material powder to the rotating tube, and a recovery member that recovers the raw material powder discharged from the rotating tube.
- the heating element heats the rotating tube and heats the raw material powder through the heated rotating tube.
- accurate heat management was difficult because the heating temperature of the rotating tube and the heating temperature of the raw material powder were unknown, and in particular, there was no way to check whether the raw material powder was heated to a uniform temperature. As a result, there was a problem in that uniform quality control of raw material powder was difficult.
- the present invention can directly measure the temperature of the tube assembly and the temperature of the raw material powder that is rotated and heated by the tube assembly, and thus more accurate and precise heat management is possible during the firing process, and as a result, the temperature of the raw material powder is heated.
- the task is to provide a rotary kiln capable of quality control.
- the rotary kiln for firing raw material powder of the present invention includes a tube assembly provided with a rotating tube that rotates and heats the raw material powder while rotating in a horizontally arranged state; and a temperature measuring unit provided on the rotating tube, wherein the temperature measuring unit includes: a first temperature sensor; a first fixing member fixing the first temperature sensor to the rotating tube; And it may include an insulator provided between the first fixing member and the rotating tube and blocking heat from the rotating tube from being conducted to the first temperature sensor.
- the first temperature sensor is provided inside the rotating tube and can measure the temperature of the raw material powder.
- the first temperature sensor may measure temperature distribution in a radial direction around the inner circumference of the rotating tube.
- the first fixing member may be provided to surround the first temperature sensor.
- the first temperature sensor is provided in plural pieces, and the first fixing member includes: a pair of horizontal portions disposed inside the rotating tube and extending in the longitudinal direction of the rotating tube; and a vertical rod whose both ends are respectively fixed to a pair of horizontal parts and where a plurality of first temperature sensors are installed at predetermined intervals in a radial direction around the inner circumference of the rotating tube.
- the temperature measuring unit may further include a first coupling member that secures the first fixing member to the rotating tube.
- the first coupling member includes: a first coupling piece provided inside the rotating tube and coupled to the front end of the first fixing member; a second coupling piece provided as an outer part provided outside the rotating tube, and an inner part provided between the first fixing member and the insulator and having a tip fastened to the first coupling piece; And a pressure piece disposed between the first coupling piece and the second coupling piece, and deformed when the first coupling piece and the second coupling piece are coupled, may include a pressure piece that presses the first fixing member.
- the rotary kiln further includes an auxiliary temperature measuring unit that directly measures the temperature of the rotating tube, and the auxiliary temperature measuring unit is inserted into the outer surface of the rotating tube without penetrating into the interior of the tube assembly and rotates.
- a second temperature sensor that measures the temperature of the tube; And it may include a second fixing member for fixing the second temperature sensor to the rotating tube.
- the rotary kiln includes a receiving unit that receives the temperature measured by the temperature measuring unit and the temperature measured by the auxiliary temperature measuring unit; And it may further include an inspection unit that generates a defective signal when the temperature of the temperature measuring unit and the temperature of the auxiliary temperature measuring unit received by the receiving unit are less than or greater than a preset input value.
- the rotary kiln when a defective signal is generated by the inspection unit, controls the heating temperature of the rotating tube to adjust the temperature of the temperature measurement unit and the temperature of the auxiliary temperature measurement unit to be within a preset input value. It may further include a control unit. .
- the plurality of first temperature sensors are disposed in a radial direction around the inner circumference of the rotating tube and can sense the temperature distribution by measuring the temperature of the raw material powder introduced into the rotating tube and the temperature of a space without the raw material powder.
- the temperature measuring unit further includes a detection member that detects the filling amount of the raw material powder introduced into the rotating tube through the temperature distribution in the radial direction around the inner circumference of the rotating tube detected by a plurality of first temperature sensors, and the detection The member detects the first temperature sensor that senses the temperature of the raw material powder in a state where a plurality of first temperature sensors are located in the radial direction of the rotating tube, and inputs the input filling amount data corresponding to the number of detected first temperature sensors. You can select and calculate the raw material powder filling amount.
- the rotary kiln further includes a stirring assembly for stirring the raw material powder rotated by the rotating tube, wherein the stirring assembly includes a stirring part for stirring the raw material powder rotated by the rotating tube; and a coupling part that couples the stirring part to one end of the rotating tube, wherein the coupling part is supported on one end of the rotating tube, a ring-shaped support piece to which the stirring part is coupled, and the supporting piece rotates. It may include a fixing means that is detachably coupled to one end of the tube.
- the stirring unit includes one or more stirring pieces for stirring the raw material powder, and the stirring pieces include two or more rotating bodies provided at predetermined intervals; And it may include a stirring rod that connects the corresponding rotating bodies and stirs the raw material powder rotated by the rotating tube.
- the rotating body may have a diameter smaller than the diameter of the inner peripheral surface of the rotating tube so that it is not supported on the inner peripheral surface of the rotating tube.
- the stirring part may further include an auxiliary stirring rod that connects the corresponding stirring pieces and agitates the raw material powder located between the corresponding stirring pieces.
- the rotating tube may be prepared as a composite metal (clad metal) integrated by fusing dissimilar metals.
- the heterogeneous metal material may be prepared from a metallic material and a non-ferrous metal material.
- the heterogeneous metal includes an internal metal material located inside the rotating tube and an external metal material located outside the rotating tube, and the internal metal material may have a thinner thickness than the external metal material.
- the rotating tube is formed with an inlet through which raw material powder is introduced and an outlet through which the raw material powder is discharged, and the inner metal material may be provided so that its thickness gradually increases from the inlet to the outlet of the rotating tube. .
- the rotary kiln according to the first embodiment of the present invention includes a temperature measuring unit provided in a rotating tube, wherein the temperature measuring unit includes a first temperature sensor and a first fixing member, wherein the first temperature sensor It has the characteristic of directly measuring temperature. Due to these characteristics, the temperature of the raw material powder can be accurately measured, and thus quality control of the raw material powder can be easily performed.
- a rotary kiln includes a temperature measuring unit provided on a rotating tube, wherein the temperature measuring unit includes a first temperature sensor and a first fixing member, wherein the first temperature sensor is located on the rotating tube. It is characterized by measuring the temperature distribution in the radial direction around the inner circumference. Due to these features, the temperature distribution can be accurately sensed by measuring the temperature of the raw material powder put into the rotating tube and the temperature of the space without the raw material powder.
- FIG. 1 is a perspective view showing a rotary kiln according to a first embodiment of the present invention.
- Figure 2 is a cross-sectional view showing a rotary kiln according to a first embodiment of the present invention.
- Figure 3 is a cross-sectional view showing the temperature measuring part of the rotary kiln according to the first embodiment of the present invention.
- Figure 4 is a partial enlarged view of Figure 3.
- Figure 5 is a view showing a display portion of a rotary kiln according to a first embodiment of the present invention.
- Figure 6 is a cross-sectional view showing the insulator of a rotary kiln according to the first embodiment of the present invention.
- Figure 7 is a cross-sectional view showing a rotary kiln according to a second embodiment of the present invention.
- Figure 8 is a side cross-sectional view schematically showing a rotary kiln according to a second embodiment of the present invention.
- Figure 9 is a cross-sectional view showing a tube assembly and a temperature measuring unit of a rotary kiln according to a second embodiment of the present invention.
- Figure 10 is a partial cross-sectional perspective view of Figure 9.
- Figure 11 is a front view showing a connection piece according to a second embodiment of the present invention.
- Figure 12 is a front view showing a fixing piece according to a second embodiment of the present invention.
- Figure 13 is a flowchart showing a method for detecting the filling amount of a rotary kiln according to a second embodiment of the present invention.
- Figure 14 is a process diagram showing a method for detecting the filling amount of a rotary kiln in the second embodiment of the present invention.
- Figure 15 is a cross-sectional view showing another embodiment of the rotary kiln according to the second embodiment of the present invention.
- Figure 16 is a cross-sectional view showing a rotary kiln according to a third embodiment of the present invention.
- Figure 17 is a partial cross-sectional view showing the combined structure of the stirring assembly and the tube assembly in the rotary kiln according to the third embodiment of the present invention.
- Figure 18 is a perspective view showing the stirring assembly of a rotary kiln according to a third embodiment of the present invention.
- Figure 19 is an assembly diagram showing the stirring assembly of the rotary kiln according to the third embodiment of the present invention.
- Figure 20 is a perspective view showing a first example of a stirring unit included in the stirring assembly.
- Figure 21 is a perspective view showing a second example of a stirring unit included in the stirring assembly.
- Figure 22 is a perspective view showing a third example of a stirring unit included in the stirring assembly.
- Figure 23 is an enlarged cross-sectional view showing the combined state of the tube assembly and the stirring assembly.
- Figure 24 is a cross-sectional view showing another embodiment of the rotary kiln according to the third embodiment of the present invention.
- Figure 25 is a cross-sectional view taken along line A-A in Figure 24.
- Figure 26 is a cross-sectional view taken along line B-B in Figure 25.
- Figure 27 is a perspective view showing a rotating tube of a rotary kiln according to a fourth embodiment of the present invention.
- Figure 28 is a cross-sectional view of Figure 27.
- Figure 29 is a process chart showing the fusion process in the rotating tube manufacturing method.
- Figure 30 is a process chart showing the bending process in the rotating tube manufacturing method.
- 31 is a process diagram showing another embodiment of the bending process in the rotating tube manufacturing method.
- Figure 32 is a cross-sectional view showing another embodiment of the rotary kiln according to the fourth embodiment of the present invention.
- Figure 33 is a cross-sectional view showing another embodiment of the rotary kiln according to the fourth embodiment of the present invention.
- Figure 1 is a perspective view showing a rotary kiln according to a first embodiment of the present invention
- Figure 2 is a cross-sectional view showing a rotary kiln according to a first embodiment of the present invention
- Figure 3 is a perspective view showing a rotary kiln according to a first embodiment of the present invention.
- FIG. 4 is a partial enlarged view of FIG. 3
- FIG. 5 is a drawing showing the display unit of the rotary kiln according to the first embodiment of the present invention.
- the rotary kiln according to the first embodiment of the present invention is for calcining raw material powder, and includes a tube assembly 100, a supply assembly 10, and a recovery assembly 20. Includes.
- the raw material powder may be a mixture of a precursor for producing a positive electrode active material and a lithium raw material.
- the tube assembly 100 has a structure that mixes and heats raw material powder while rotating in a horizontally arranged state. That is, the tube assembly 100 includes a rotating tube 110 that mixes the raw material powder 1 while rotating the raw material powder 1 in a horizontally arranged state, and a heating element 120 that heats the rotating tube 110. ) includes. Meanwhile, the rotating tube 110 may have a double structure including an external metal material and an internal metal material.
- the rotating tube 110 is heated to a set temperature by the heating element 120, and the heated rotating tube 110 rotates to mix and heat the supplied raw material powder 1. do.
- the tube assembly 100 includes a support member that supports rotation in the horizontal direction.
- the support member is provided with a rotating gear that surrounds the outer peripheral surface of the tube assembly 100, and a support gear that engages with both sides of the bottom of the rotating gear to support the rotating gear and rotate by the rotating gear. Includes support.
- the tube assembly 100 includes a rotating member that rotates the tube assembly in the horizontal direction.
- the rotating member includes a driving gear coupled to surround the outer peripheral surface of the tube assembly 100, and a driving motor engaged with the driving gear and rotating the tube assembly 100 in the horizontal direction through the driving gear.
- the heating element 120 is provided in a heating body that surrounds the outer surface of the rotating tube 110 and a heating body corresponding to the rotating tube 110, and heats the rotating tube 110. Includes media.
- the heating medium may be any one of an electric heating element, SIC, Mo-Si, or gas burner. Additionally, the outer surface of the heating body may be made of a heat-resistant material to prevent the heat source of the heating medium from being discharged outside.
- the supply assembly 10 has a structure for supplying raw material powder to the rotating tube 110. That is, the supply assembly 10 is an input member that is inserted into one end of the rotating tube 110 (the left end of the rotating tube 110 as seen in FIG. 2) and feeds raw material powder into the inside of the rotating tube 110, It includes a chamber that collects gas and water vapor generated when heating the raw material powder supplied inside the rotating tube 110, and a protective member that seals between the rotating tube 110 and the chamber.
- the recovery assembly 20 has a structure to recover the raw material powder discharged from the rotating tube 110. That is, the recovery assembly 20 includes a recovery member into which the other end of the rotation tube 110 (the right end of the rotation tube 110 when viewed in FIG. 2) is inserted so as to be freely rotatable. The recovery member recovers the raw powder discharged from the rotating tube 110 and then moves it to a set location and stores it.
- the rotary kiln according to the first embodiment of the present invention includes a temperature measuring unit 200 provided in the rotating tube, as shown in FIGS. 3 and 4.
- the temperature measuring unit 200 has a structure that can directly measure the temperature of the rotating tube 110 included in the tube assembly 100 and the temperature of the raw material powder that is heated while rotating by the tube assembly 100. have Accordingly, the temperature of the rotating tube 110 and the temperature of the raw material powder can be accurately measured, and as a result, the quality of the raw material powder can be easily managed.
- the temperature measuring unit 200 has a structure that can directly measure the temperature of the raw material powder that is rotated and heated by the rotating tube 110. That is, the temperature measuring unit 200 includes a first fixing member 210, a first temperature sensor 220, and a first coupling member 230.
- the first fixing member 210 is used to secure and protect the first temperature sensor 220 to the rotating tube 110. That is, the first fixing member 210 has a cylindrical shape and is inserted from the outside to the inside of the rotation tube 110, and has a structure in which the tip is located inside the rotation tube 110. Accordingly, the first fixing member 210 comes into direct contact with the raw material powder supplied to the rotating tube 110, and as a result, the temperature rises to the temperature corresponding to the raw material powder.
- the first fixing member 210 may be made of a metal material so that the heat source of the raw powder can be quickly conducted.
- the first fixing member 210 may be made of the same material as the rotating tube 110.
- the first fixing member 210 may be made of nickel material. Accordingly, the first fixing member 210 can be quickly raised to the temperature of the raw material powder, and the ease of manufacturing can be improved.
- the tip of the first fixing member 210 (that is, the tip of the first fixing member located inside the rotating tube) may be provided in a hemispherical shape. This can greatly reduce the friction between the first fixing member 210 and the raw material powder, and greatly improve the contact area between the first fixing member 210 and the raw material powder. In addition, damage to the first fixing member 210 can be prevented.
- the first fixing member 210 may be provided in a cone shape.
- the first temperature sensor 220 is built into the tip of the first fixing member 210 and detects the temperature of the raw material powder by measuring the temperature of the first fixing member 210.
- the first temperature sensor 220 may be provided as a thermocouple.
- a thermocouple is a device made of two types of metals to measure a wide range of temperatures using the Seebeck effect. In other words, when two types of metals are combined in a thermocouple, if the temperatures at both ends of the joint are different, current flows between the two metals. With this current, the temperature difference between the two contact points can be known.
- the first coupling member 230 is coupled to the distal end of the first fixing member 210 and has a structure for fixing the first fixing member 210 to the rotating tube 110.
- the first coupling member 230 is provided on the inside of the rotating tube 110, and the first coupling piece 231 is coupled to the front end of the first fixing member 210 and is provided on the outside of the rotating tube 110. and a second coupling piece 232, the tip of which is fastened to the first coupling piece 231 through between the first fixing member 210 and the rotating tube 110, and the first coupling piece 231 and the second coupling piece 232. It includes a pressure piece 233 that is disposed between the coupling pieces 232 and is deformed when the first and second coupling pieces 231 and 232 are fastened to press and secure the first fixing member 210.
- the second coupling piece 232 is provided between the outer portion 2321 provided on the outside of the rotating tube 110, the first fixing member 210, and the insulator, and its tip is fastened to the first coupling piece. It is provided with an inner part (2322).
- first coupling piece 231 and the second coupling piece 232 have a nut shape so that the first fixing member 210 can penetrate therethrough.
- the first coupling member 230 can fix the first fixing member 210 while the pressing piece 233 is deformed,
- the pressing piece 233 is restored and the first fixing member 210 can be unfastened.
- the first coupling piece 231 may be welded to the inner peripheral surface of the rotating tube 110 for loosening and sealing.
- the first coupling member 230 releases the fastening of the first coupling piece 231 and the second coupling piece 232, and then protrudes the first fixing member 210 further into the inside of the rotating tube 110. It can be moved to the outside of the rotating tube 110. Accordingly, the position of the temperature measuring unit 200 coupled to the rotating tube 110 can be adjusted. Accordingly, the position of the temperature measuring unit 200 coupled to the rotating tube 110 can be easily adjusted according to the amount of raw material powder input into the rotating tube 110, and as a result, the temperature of the raw material powder can be measured more accurately. there is. In addition, compatibility and non-processing time can be shortened.
- the temperature measuring unit 200 having this structure can directly measure the temperature of the raw material powder introduced into the rotating tube 110, and as a result, the accurate temperature of the raw material powder can be obtained.
- the temperature measuring unit 200 can stably protect and secure the first temperature sensor 220 by including the first fixing member 210 and the first coupling member 230.
- an auxiliary temperature measuring unit 300 that directly measures the temperature of the rotating tube 110 may be further included.
- the auxiliary temperature measuring unit 300 has a structure that can accurately measure the temperature of the rotating tube 110. That is, the auxiliary temperature measuring unit 300 includes a second fixing member 310, a second temperature sensor 320, and a second coupling member 330.
- the second fixing member 310 is used to protect the second temperature sensor 320 from the rotating tube 110. That is, the second fixing member 310 is inserted from the outside to the inside of the rotation tube 110, but the tip is provided so that it does not penetrate into the inside of the tube assembly 100, and rotates while contacting the rotation tube 110. The temperature rises to the temperature corresponding to that of the tube 110.
- the second fixing member 310 may be made of the same material as the first fixing member 210, thereby reducing manufacturing costs.
- the second temperature sensor 320 is built into the distal end of the second fixing member 310 and detects the temperature of the rotating tube 110 by measuring the temperature of the second fixing member 310. Meanwhile, the second temperature sensor 320 may be provided as the same sensor as the first temperature sensor 220.
- the second coupling member 330 is coupled to the distal end of the second fixing member 310 and fixes the second fixing member 310 to the rotating tube 110. That is, the second coupling member can secure the second fixing member 310 to the rotary tube 110 by inserting the second fixing member 310 inside and coupling the outer side to the rotary tube 110. . Meanwhile, the second coupling member 330 may be welded to the rotating tube 110 for sealing and fixing force.
- the auxiliary temperature measuring unit 300 having this structure can directly measure the temperature of the rotating tube 110, and as a result, the accurate temperature of the rotating tube 110 can be obtained.
- the auxiliary temperature measuring unit 300 can stably protect and secure the second temperature sensor 320 by including a second fixing member 310 and a second coupling member 330.
- a plurality of temperature measuring units 200 and auxiliary temperature measuring units 300 may be provided at set intervals in the longitudinal direction of the rotating tube 110. Accordingly, the temperature of the raw material powder and the rotating tube 110 can be directly measured at set intervals of the rotating tube 110, and as a result, the ease of quality control can be improved.
- the rotary kiln according to the first embodiment of the present invention can accurately measure the temperature of the raw material powder and the rotating tube 110 by including the temperature measuring unit 200 and the auxiliary temperature measuring unit 300, and thus the raw material powder
- the temperature of the powder can be effectively managed, and as a result, the quality of the raw powder can be easily managed.
- the rotary kiln according to the first embodiment of the present invention may further include a receiving unit 400, an inspection unit 500, a control unit 600, and a display unit 700 for temperature management.
- FIG. 5 is a diagram illustrating a display unit 700 that displays a state in which temperature is managed by the receiver 400, inspection unit 500, and control unit 600 of the rotary kiln according to the first embodiment of the present invention.
- the receiving unit 400 is provided at one end of the rotating tube 110, and measures the temperature of the raw material powder measured by the temperature measuring unit 200 and the rotating tube 110 measured by the auxiliary temperature measuring unit 300. receives each temperature.
- a temperature measurement assembly is configured including a temperature measurement unit and an auxiliary temperature measurement unit.
- a plurality of temperature measuring assemblies are provided in the longitudinal direction of the rotating tube 110, and the receiving unit 400 measures the temperature of the raw material powder measured by the plurality of temperature measuring assemblies and the rotating tube ( 110) temperature is received respectively.
- the inspection unit 500 maintains a normal signal if the temperature of the raw material powder and the temperature of the rotating tube 110 received by the receiver 400 are within the set input value, and generates a defective signal if it is less than or greater than the set input value. generates
- the inspection unit 500 generates a defective signal at the corresponding location when any one of the temperatures of the plurality of raw material powders and the temperature of the rotating tube 110 is less than or greater than the set input value.
- control unit 600 adjusts the heating temperature of the rotating tube 110 so that the heating temperature of the raw material powder and the heating temperature of the rotating tube 110 are within the set value. do.
- the control unit 600 adjusts the temperature of the rotating tube 110 by increasing or lowering the temperature of the heating element 120 disposed in the longitudinal direction of the rotating tube 110, and adjusts the temperature of the rotating tube 110. As the raw material powder is heated by the rotating tube 110, the temperature of the raw material powder can be adjusted.
- the second display window 720 shown in FIG. 5 displays the current temperature of the heating element 120 and the corrected temperature of the heating element 120 controlled by the control unit 600.
- the display unit 700 includes a first display window 710 and a second display window 720.
- the first display window 710 displays the temperature (P) of the raw powder received by the receiver 400 and the temperature (T) of the rotating tube 110.
- the second display window 720 displays the current temperature (F) of the heating element 120 that heats the rotating tube 110 and the corrected temperature (R) of the heating element 120 controlled by the control unit 600.
- the display unit 700 can display the current temperature status of the rotary kiln in real time, and as a result, the operator can easily check for defects. In particular, the exact location of the defect can be confirmed.
- Figure 6 is a cross-sectional view showing the insulator of a rotary kiln according to the first embodiment of the present invention.
- the rotary kiln according to the first embodiment of the present invention includes an insulator 240 with thermal insulation between the temperature measuring unit 200 and the rotating tube 110, as shown in FIG. 6. .
- the insulator 240 has a structure that blocks the conduction of heat between the temperature measuring unit 200 and the rotating tube 110.
- the insulator 240 is provided between the first fixing member of the temperature measuring unit 200 and the rotating tube 110. More precisely, the insulator 240 may be provided in a form that surrounds the outer peripheral surface of the first fixing member in contact with the rotating tube 110. Additionally, the insulator 240 may be provided in the hole and surface of the rotating tube through which the temperature measuring unit 200 penetrates or is in contact with.
- the insulator 240 can block heat conduction between the temperature measuring unit 200 and the rotating tube 110, and as a result, the temperature measuring unit 200 can block the heat conduction of the raw material powder by the insulator 240. Temperature can be measured accurately.
- the insulator 240 may be made of glass fiber.
- the rotating tube 110 is heated through the heating element 120 of the tube assembly 100 to raise it to the set temperature. At the same time, the rotating tube 110 is rotated.
- the raw material powder is supplied to the rotating tube 110 through the supply assembly 10. Then, the raw material powder is rotated by the rotating tube 110 and simultaneously heated and fired.
- the temperature measuring unit directly measures the temperature of the raw material powder and the temperature of the rotating tube 110, and the measured temperature of the raw material powder and the temperature of the rotating tube 110 are displayed in real time on the first display window 710 of the display unit 700. It is displayed as Of course, the current temperature of the heating element 120 is displayed in real time on the second display window 720 of the display unit 700.
- the inspection unit 500 outputs a defective signal if the temperature of the raw material powder and the temperature of the rotating tube 110 received by the receiver 400 are less than or greater than the set input value. This can be displayed through the first display window 710 of the display unit 700.
- the control unit 600 adjusts the current temperature of the heating element 120 so that the temperature of the raw material powder and the temperature of the rotating tube 110 are within the set input value. do. At this time, the adjusted temperature of the heating element 120 is displayed on the second display window 720 of the display unit 700.
- the temperature measurement assembly can uniformly maintain the temperature of the raw material powder mixed and heated by the rotating tube, and as a result, quality can be effectively managed.
- Figure 7 is a cross-sectional view showing a rotary kiln according to a second embodiment of the present invention
- Figure 8 is a side cross-sectional view schematically showing a rotary kiln according to a second embodiment of the present invention
- Figure 9 is a second embodiment of the present invention.
- FIG. 10 is a partial cross-sectional perspective view of FIG. 9
- FIG. 11 is a front view showing a connection piece according to a second embodiment of the present invention
- FIG. 12 is a view showing the present invention. This is a front view showing the fixing piece according to the second embodiment.
- the rotary kiln according to the second embodiment of the present invention is for calcining raw material powder, and includes a tube assembly 100 and a supply assembly 10 for supplying the raw material powder 1 to the tube assembly. ), and a recovery assembly 20 that recovers the raw material powder 1 discharged from the tube assembly.
- the rotary kiln according to the second embodiment of the present invention measures the temperature distribution in the radial direction around the inner circumference of the rotating tube, as shown in FIG. It further includes a temperature measuring unit 200' that detects the filling amount.
- the raw material powder 1 may be a mixture of a precursor for producing a positive electrode active material and a lithium raw material.
- the tube assembly 100 is for rotating and simultaneously heating the raw material powder 1, and includes a rotating tube 110 and a heating element 120.
- the tube assembly 100 further includes a stirring member 111 that is provided inside the rotating tube 110 and agitates the raw material powder 1 introduced into the rotating tube 110.
- the stirring member 111 includes a screw stirring piece 111a formed along the inner peripheral surface of the rotating tube 110, and a straight stirring piece 111b formed along the longitudinal direction of the rotating tube 110.
- the rotating tube includes a stirring member.
- the supply assembly 10 has a structure for supplying the raw material powder 1 to the rotating tube 110.
- the recovery assembly 20 has a structure to recover the raw material powder 1 discharged from the rotating tube 110.
- the rotary kiln according to the second embodiment of the present invention includes a temperature measuring unit 200' for accurately detecting the filling amount of the raw material powder 1 introduced into the rotating tube 110.
- the temperature measuring unit 200' includes a plurality of first temperature sensors 220' that detect the temperature distribution in the radial direction around the inner circumference of the rotating tube 110, and a plurality of first temperature sensors 220' is disposed in the radial direction around the inner circumference of the rotating tube 110 and detects the temperature distribution by measuring the temperature of the raw material powder 1 introduced into the rotating tube 110 and the temperature of the space without the raw material powder 1. .
- the plurality of first temperature sensors 220' can detect the filling amount of the raw material powder 1 introduced into the rotating tube 110 through the temperature distribution in the radial direction around the inner circumference of the rotating tube 110.
- the plurality of first temperature sensors 220' are composed of a temperature assembly, and a plurality of temperature assemblies may be provided in the longitudinal direction of the rotating tube 110. Accordingly, the filling amount of the raw material powder 1 introduced into the entire rotating tube 110 can be accurately detected.
- the first temperature sensor 220' may be provided as a thermocouple that detects the temperature of the raw material powder 1.
- thermocouples include platinum-platinum rhodium thermocouples, chromel-alumel thermocouples, iron-constantan thermocouples, and copper-constantan thermocouples.
- the plurality of first temperature sensors 220' can detect the height at which the raw material powder 1 is filled by detecting the temperature distribution in the radial direction around the inner circumference of the rotating tube 110.
- the temperature measuring unit 200' includes a first fixing member 210' that fixes a plurality of first temperature sensors 220' arranged in a radial direction around the inner circumference of the rotating tube 110.
- the first fixing member 210' is for fixing a plurality of first temperature sensors 220', and has a pair of horizontal parts 211 and a vertical Includes rod 222.
- the pair of horizontal parts 211 have the same structure, are disposed correspondingly inside the rotating tube 110, and are provided to extend in the longitudinal direction of the rotating tube 110.
- the horizontal portion 211 is provided with a plurality of horizontal rods 2211 and one or more connection pieces 2212 connecting the plurality of horizontal rods 2211 in the longitudinal direction, so that the horizontal portion 2212 is horizontal corresponding to the length of the rotating tube 110. Part 211 can be easily assembled.
- the pair of horizontal parts 211 can connect the corresponding horizontal bars 2211 in the longitudinal direction by inserting the corresponding horizontal bars 2211 into sockets provided at both ends of the connecting piece 2212.
- the vertical rod 222 is for arranging a plurality of first temperature sensors 220' in the radial direction of the inner circumference of the rotary tube 110, and is disposed in the radial direction of the inner circumference of the rotary tube 110, and is disposed on both sides.
- the ends are each fixed to a pair of horizontal parts 211, and a plurality of first temperature sensors 220' are arranged at set intervals along the longitudinal direction. That is, the plurality of first temperature sensors 220' are arranged in the radial direction around the inner circumference of the rotating tube 110 by the vertical rod 222.
- the vertical rod 222 is fixed at one end while being coupled to the inner socket 2212a of the connecting piece 2212 provided on one horizontal portion 211, and the other end is connected to the other one. It is coupled to the outer socket 2212b of the connecting piece 2212 provided on the horizontal portion 211. Accordingly, the coupling between the vertical bar 222 and the horizontal portion 211 can be improved.
- the vertical rod 222 may be provided with a fixing piece 2221 for fixing the plurality of first temperature sensors 220' so that they do not move, as shown in FIG. 12.
- the fixing piece 2221 may be provided as a metal band wound around the outer circumferential surface of the first temperature sensor 220' disposed on the vertical rod 222 and fixing the first temperature sensor 220'.
- the metal band can easily fix the first temperature sensor 220' to the vertical rod 222, or can be easily separated. The result is ease of maintenance.
- the first fixing member 210' may further include an auxiliary vertical rod 223 provided between the outer peripheral surface of the connecting piece 2212 and the inner peripheral surface of the rotating tube 110.
- the auxiliary vertical bar 223 is located on the same vertical line as the vertical bar 222.
- a first temperature sensor 220' that detects the raw material powder 1 between the outer peripheral surface of the connecting piece 2212 and the inner peripheral surface of the rotating tube 110 may be further disposed on the auxiliary vertical rod 223. Accordingly, the temperature of the raw material powder 1 filled on the outer peripheral surface of the connecting piece 2212 and the inner peripheral surface of the rotating tube 110 can be measured.
- the auxiliary vertical rod 223 may be provided with a fixing piece 2221 that fixes the first temperature sensor 220' so that it does not move.
- the fixing piece 2221 may be provided as a metal band wound around the outer peripheral surface of the first temperature sensor 220' disposed on the auxiliary vertical rod 223 and fixing the first temperature sensor 220'.
- the first fixing member 210' may further include a bracket 225 that couples and fixes the pair of horizontal parts 211 to the stirring member 111 provided in the rotating tube 110.
- One end of the bracket 225 is bolted to the stirring member 111, and the horizontal bar 2211 of the horizontal portion 211 is fitted to the other end. Accordingly, the first fixing member 210' can be stably fixed inside the rotating tube 110.
- an insulator 240 is included between the first fixing member 210' and the rotating tube 110. That is, the insulator 240 is provided between the first fixing member and the rotating tube and blocks heat from the rotating tube from being conducted to the first fixing member.
- the first fixing member 210' can fix the plurality of first temperature sensors 220' to be stably disposed in the radial direction of the inner circumference of the rotating tube 110.
- the temperature measuring unit 200' may further include a detection member 250.
- the detection member 250 detects the raw material powder (1) introduced into the rotating tube 110 through the temperature distribution in the radial direction around the inner circumference of the rotating tube 110 detected by the plurality of first temperature sensors 220'. Detect the filling amount.
- the detection member 250 detects the temperature of the raw material powder 1 in a state where a plurality of first temperature sensors 220' are located in the radial direction of the rotating tube 110.
- the sensor 220' is detected, and the input filling amount data corresponding to the number of detected first temperature sensors 220' is selected to calculate the filling amount of the raw material powder 1.
- the input filling amount data is the filling amount calculated by the operator according to the diameter of the rotating tube 110 and the position of the first temperature sensor 220'.
- the detection member 250 calculates the filling amount of the raw material powder 1 of the entire rotating tube 110 by integrating the filling amount calculated from the plurality of temperature assemblies arranged in the longitudinal direction of the rotating tube 110.
- the temperature detected by the first temperature sensors 220' Nos. 1 to 3 is 450°
- the temperature detected by the first temperature sensors 220' Nos. 4 to 5 is 300°.
- the member 250 calculates the filling amount by selecting 10% of the filling amount corresponding to the three first temperature sensors 220' among the input filling amount data.
- the temperature measuring unit 200' may further include a control member 260.
- the control member 260 adjusts the amount of the raw powder 1 introduced into the rotating tube 110 when the filling amount of the powder raw material detected by the detection member 250 is less than or greater than the preset powder raw material filling amount. Control.
- the control member 260 controls the supply assembly 10 to increase the input amount of the raw powder 1.
- the supply assembly 10 is controlled to reduce the input amount of the raw powder 1. In this way, the amount of raw material powder 1 filled in the rotating tube 110 can be kept constant.
- Figure 15 is a cross-sectional view showing another embodiment of the rotary kiln according to the first embodiment of the present invention.
- the vertical rod 222 is provided with a fixing piece 2221 for fixing a plurality of first temperature sensors 220', and the fixing piece 2221 is configured to hold the first temperature sensor 220'.
- (220') is provided with a coupling groove formed in the vertical bar 222 so that it is inserted and coupled.
- the fixing force of the fixing piece 2221 can be increased, thereby preventing the plurality of first temperature sensors disposed on the vertical rod 222 from moving when the rotating tube 110 rotates.
- the rotary kiln according to the second embodiment of the present invention can detect the temperature distribution in the radial direction around the inner circumference of the rotating tube 110 by including a temperature measuring unit 200', and accordingly, the rotating tube 110
- the filling amount of the raw material powder 1 can be accurately detected in real time, and as a result, the filling amount of the raw material powder 1 filled in the rotating tube 110 can be controlled to be constant.
- FIG. 13 is a flowchart showing a method for detecting the filling amount of a rotary kiln according to a second embodiment of the present invention
- FIG. 14 is a process chart showing a method for detecting the filling amount of a rotary kiln in a second embodiment of the present invention.
- the method for detecting the filling amount of a rotary kiln is to (a) rotate the raw material powder (1) introduced through the rotating tube (110) disposed in the horizontal direction, and rotate the rotating tube ( Heating the rotating raw powder (1) by 110); and (b) detecting the temperature distribution in the radial direction of the inner circumference of the rotating tube 110 using a plurality of first temperature sensors 220' provided in the temperature measuring unit 200'.
- the filling amount detection method of the rotary kiln according to the second embodiment of the present invention uses a tube assembly 100, a temperature measuring unit 200', a supply assembly 10, and a recovery assembly 20, and the tube assembly (100), the temperature measuring unit 200', the supply assembly 10, and the recovery assembly 20 have been described in detail previously, so their detailed description will be omitted.
- step (a) the rotating tube 110 of the tube assembly 100 is rotated in the horizontal direction, and then the rotating tube 110 is heated to a set temperature through the heating element 120 of the tube assembly 100.
- the raw material powder 1 is introduced into the rotating tube 110 using the supply assembly 10. Then, the raw material powder 1 is heated while rotating by the heated rotating tube 110, and is mixed while being stirred by the stirring member 111 provided inside the rotating tube 110.
- Step (b) includes a process of detecting the temperature distribution in the radial direction around the inner circumference of the rotating tube 110 using a plurality of first temperature sensors 220' provided in the temperature measuring unit 200'. That is, the plurality of first temperature sensors 220' are disposed in the radial direction around the inner circumference of the rotating tube 110 and measure the temperature of the raw material powder 1 introduced into the rotating tube 110 and the space without the raw material powder 1. The temperature distribution is detected through temperature measurement.
- five first temperature sensors 220' are disposed in the radial direction of the inner circumference of the rotating tube 110. That is, from the bottom, the first temperature sensors 220' numbered 1, 2, and 3 are placed in contact with the raw material powder 1, and the first temperature sensors 220' numbered 4 and 5 are placed in contact with the raw material powder 1. placed in space. Accordingly, the five first temperature sensors 220' measure the temperature of the raw material powder 1 introduced into the rotating tube 110 (first temperature sensors 1, 2, and 3 shown in the table of FIG. 14) and the raw material powder ( 1) The temperature of the empty space (first temperature sensors 4 and 5 listed in the table of FIG. 14) is measured, and the temperature distribution is sensed accordingly.
- step (b) the raw material powder filled in the rotating tube 110 is measured through the temperature distribution detected by the plurality of first temperature sensors 220' using the detection member 250 of the temperature measuring unit 200'. It includes the process of calculating the filling amount in (1). That is, the detection member 250 detects the first temperature sensor 220' that senses the temperature of the raw material powder 1 in a state located in the radial direction of the rotating tube 110, and the detected first temperature sensor 220 Calculate the filling amount of the raw material powder (1) by selecting the input filling amount data corresponding to the number of ').
- the detection member 250 contains input filling amount data corresponding to three first temperature sensors 220', which are numbered 1, 2, and 3 first temperature sensors 220'.
- 10% which is the filling amount of raw material powder (1).
- the filling amount data entered here is calculated by the operator and then entered.
- step (b) further includes a process of adjusting the amount of raw material powder 1 fed into the rotating tube 110 using the control member 260 of the temperature measuring unit 200'. That is, if the filling amount of the powder raw material calculated by the detection member 250 is less than or greater than the preset powder raw material filling amount, the control member 260 adjusts the amount of the raw powder 1 fed into the rotating tube 110. Control as much as possible.
- the method for detecting the filling amount of the rotary kiln according to the first embodiment of the present invention can detect the filling amount of the raw material powder 1 filled in the rotating tube 110 in real time, and the input amount of the raw material powder 1 It can be adjusted.
- Figure 16 is a cross-sectional view showing a rotary kiln according to a third embodiment of the present invention
- Figure 17 is a partial cross-sectional view showing the coupling structure of the stirring assembly and the tube assembly in the rotary kiln according to the third embodiment of the present invention
- Figure 18 is a perspective view showing the stirring assembly of the rotary kiln according to the third embodiment of the present invention
- Figure 19 is an assembly view showing the stirring assembly of the rotary kiln according to the third embodiment of the present invention
- Figure 20 is included in the stirring assembly.
- Figure 21 is a perspective view showing a first example of the stirring part included in the stirring assembly
- Figure 21 is a perspective view showing a second example of the stirring part included in the stirring assembly
- Figure 22 is a perspective view showing a third example of the stirring part included in the stirring assembly
- Figure 23 is a tube assembly and This is an enlarged cross-sectional view showing the combined state of the stirring assembly.
- the rotary kiln according to the third embodiment of the present invention is for calcining raw material powder, and includes a tube assembly 100 including a rotating tube 110 and a heating element 120, and a supply assembly. (10), and a recovery assembly (20).
- the tube assembly 100 has a structure that mixes raw material powder while rotating in a horizontally arranged state. That is, the tube assembly 100 includes a rotating tube 110, and the rotating tube has a double structure including an external metal material and an internal metal material provided inside the external metal material.
- the supply assembly 10 has a structure for supplying raw material powder to the tube assembly.
- the recovery assembly 20 has a structure to recover the raw material powder discharged from the tube assembly 100.
- the rotary kiln according to the third embodiment of the present invention includes a stirring assembly 50 for stirring raw material powder rotated by the rotating tube 110 of the tube assembly 100.
- the stirring assembly 50 may be detachably provided inside the rotating tube 110.
- the stirring assembly 50 may be coupled to the rotating tube 110 without moving, or may be disconnected to be separated from the rotating tube 110. Accordingly, the stirring assembly 50 with various sizes, shapes, and lengths can be replaced according to changes in the structure of the facility, and as a result, work efficiency and non-operation time can be greatly reduced.
- the stirring assembly is used to stir the raw material powder rotated by the tube assembly to spread heat well or to stir it so that it is evenly mixed.
- the stirring assembly 50 includes a stirring unit 510 provided inside the rotating tube and stirring the raw material powder rotated by the rotating tube, and the stirring unit 510 ) and includes a coupling portion 520 that is connected to and detachably coupled to one end of the rotating tube 110 (the right end of the rotating tube as seen in FIG. 17).
- the stirring unit 510 includes one or more stirring pieces 511 for stirring the raw material powder. And the stirring piece 511 connects two or more rotating bodies 5111 spaced apart from each other and the corresponding rotating bodies 5111, and stirs the raw material powder rotated by the rotating tube 110. Includes rod 5112.
- the rotating body 5111 has the same ring shape as the inner peripheral surface of the rotating tube and has a smaller size than the inner peripheral surface of the rotating tube. That is, as shown in FIG. 17, when the coupling portion 520 is coupled to the rotating tube, the rotating body 5111 is placed in a suspended state inside the rotating tube. Accordingly, the outer peripheral surface of the rotating body 5111 and the inner peripheral surface of the rotating tube 110 can be spaced at the same interval, and as a result, the stirring bar 5112 and the rotating tube 110 can be maintained at a constant interval, Uniform stirring can be maintained. In particular, contact between the rotating body 5111 and the rotating tube 110 can be prevented.
- the stirring rod 5112 has a bar shape and connects the corresponding rotating bodies 5111 to each other. That is, the corresponding rotating bodies 5111 can be connected by coupling both ends of the stirring rod 5112 to the corresponding rotating bodies 5111, respectively.
- two or more stirring bars 5112 are provided, and the two or more stirring bars 5112 are arranged at equal intervals along the edge of the rotating body 5111.
- the stirring rod 5112 and the rotating body 5111 may be coupled by a coupling means 5113 or may be provided to be separable.
- the coupling means 5113 may be provided as a bolt. That is, by tightening the bolt, the stirring rod 5112 and the rotating body 5111 can be combined, and by loosening the bolt, the stirring rod 5112 and the rotating body 5111 can be separated. As a result, maintenance is easy and the stirring unit 510 can be assembled in various shapes.
- the stirring unit 510 may be assembled by connecting two rotating bodies 5111 and two short stirring rods 5112. That is, the stirring unit 510 whose length in the left and right directions is reduced as seen in FIG. 20 can be assembled. This can be applied by assembling the stirring part 510 to a small length when the space inside the rotating tube 110 is not large.
- the stirring unit 510 can be assembled by connecting two rotating bodies 5111 and two long stirring rods 5112. In other words, it is possible to assemble the stirring unit 510 whose length in the left and right directions is increased when viewed in FIG. 21. This can greatly reduce the number of stirring units 510 disposed inside the rotating tube 110.
- the stirring unit 510 can be assembled by connecting two rotating bodies 5111 and four stirring rods 5112. When the stirring unit 510 assembled in this way is applied to the rotating tube 110, the stirring property of the raw material powder can be greatly improved.
- the coupling unit 520 is for coupling the stirring unit 510 to the rotating tube.
- the coupling unit 520 can detachably couple the stirring unit 510 to the rotating tube 110 to increase efficiency. .
- the coupling portion 520 is a ring-shaped support piece 521 that is supported on one end of the rotation tube 110 and to which the stirring portion 510 is coupled, and the support piece 521 is connected to the rotation tube 110.
- the fixing means 522 that can be coupled to or separated from one end of the.
- the rotating body 5111 disposed on the outermost side of the stirring unit 510 is fixed to the coupling unit 520, thereby fixing the stirring unit 510 and the coupling unit 520.
- the fixing means 522 may be provided as a fixing bolt that penetrates the support piece 521 and is fastened to one end of the rotating tube 110.
- the coupling part 520 can fix the support piece 521 to the rotating tube 110 by tightening the fixing bolt, and as a result, the stirring part 510 fixed to the coupling part 520 can be connected to the rotating tube 110. It can be fixed so that it does not move inside the . Meanwhile, by loosening the fixing bolt, the support piece 521 can be separated from the rotating tube 110, and as a result, the stirring unit 510 along with the coupling portion 520 can be separated from the inside of the rotating tube 110. there is.
- the stirring assembly having this structure can be fixed to the rotating tube 110 or separated.
- the stirring assembly can be used by combining various specifications of the stirring assembly with the rotating tube 110 to suit structural changes in the equipment. As a result, it facilitates structural changes and significantly reduces downtime.
- the stirring part 510 connects the corresponding stirring pieces 511 and mixes the raw material powder located between the corresponding stirring pieces 511. It may further include an auxiliary stirring rod 512 for stirring.
- auxiliary stirring rod 512 for stirring.
- the auxiliary stirring rod 512 can connect two or more, preferably three or more stirring parts 510 in the longitudinal direction, thereby improving usability.
- the auxiliary stirring rod 512 may be coupled by a coupling means 5113 or may be provided to be detachable.
- the coupling means 5113 may be provided as a bolt. That is, by tightening or loosening the bolt, the auxiliary stirring rod 512 may be coupled to the stirring unit 510 or the auxiliary stirring rod 512 may be separated from the stirring unit 510.
- the auxiliary stirring bar 512 when viewed from one end of the rotating tube 110, the auxiliary stirring bar 512 may be arranged to be offset from the stirring bar 5112. That is, as seen in FIG. 17, if the stirring rod 5112 is connected to the upper and lower portions of the rotating body 5111, the auxiliary stirring rod may be connected to the left and right sides of the rotating body 5111, respectively. Accordingly, the strength of the stirring assembly can be increased, and the stirring performance can be improved by creating a time difference when stirring the raw material powder.
- the stirring bar 5112 and the auxiliary stirring bar 512 may have the same thickness, and thus can be used interchangeably.
- the stirring bar 5112 and the auxiliary stirring bar 512 may have the same length.
- the auxiliary stirring bar 512 may be used instead of the stirring bar 5112, and the stirring bar 5112 may be used instead of the auxiliary stirring bar 512.
- the rotary kiln according to the third embodiment of the present invention includes a stirring assembly detachably coupled to the inside of the rotating tube 110, so that the stirring assembly provided in the rotating tube 110 can be easily replaced when process conditions change. This makes it possible to easily change the structure of the facility, and as a result, non-operation time can be greatly reduced.
- FIG. 24 is a cross-sectional view showing another embodiment of the rotary kiln according to the third embodiment of the present invention
- FIG. 25 is a cross-sectional view taken along line A-A in FIG. 24
- FIG. 26 is a cross-sectional view taken along line B-B in FIG. 25.
- the stirring unit 510 includes a fixing piece 513, and the fixing piece 513 is provided with two or more stirring pieces 511. , the stirring piece 511 disposed on the outermost side based on the support piece 521 is fixed to the inner peripheral surface of the rotating tube 110. Accordingly, it is possible to prevent the stirring unit 510 from moving when the rotating tube 110 rotates.
- the fixing piece 513 fixes the stirring piece 511, which is located in a cantilever shape inside the rotating tube 110, to the inner circumferential surface of the rotating tube 110, and accordingly, when the rotating tube 110 rotates, the stirring assembly The flow phenomenon can be prevented, and as a result, the raw material powder can be stirred stably.
- the fixing piece 513 is disposed in at least two places between the stirring piece 511 and the inner peripheral surface of the rotating tube 110 and fixes the stirring piece 511 to the inner peripheral surface of the rotating tube 110.
- the fixing piece 513 may be disposed between the stirring piece 511 disposed on the outermost side with respect to the support piece 521 and the inner peripheral surface of the rotating tube 110.
- the fixing piece 513 is coupled to the stirring piece 511 disposed on the outermost side with respect to the support piece 521, and the other end may be supported on the inner peripheral surface of the rotating tube 110. . That is, the fixing piece 513 may be provided integrally with the correction unit. Accordingly, convenience of use can be improved.
- the fixing piece 513 can be integrated by being coupled to the stirring piece 511 through a bolt or adhesive.
- the fixing piece 513 is coupled through a bolt 513a as shown in FIG. 12, it can be easily replaced when the fixing piece 513 is damaged, and as a result, ease of maintenance can be improved.
- the fixing piece is made of a metal material, the fixing piece can be coupled to the stirring piece through welding.
- the rotary kiln according to the fourth embodiment of the present invention is characterized by including a rotating tube made of composite metal.
- the rotating tube is made of a composite metal in which dissimilar metals are fused and integrated, and thus the bonding properties of dissimilar metals can be greatly improved.
- the thickness of the metal located on the inside or the metal located on the outside can be effectively adjusted and applied. For example, the thickness of the metal located inside the rotating tube can be minimized.
- Figure 27 is a perspective view showing a tube assembly of a rotary kiln according to a fourth embodiment of the present invention
- Figure 28 is a cross-sectional view of Figure 27.
- the rotary kiln according to the fourth embodiment of the present invention includes a tube assembly 100 provided with a rotating tube 110 and a heating element 120.
- the rotating tube 110 has a structure that mixes raw material powder while rotating in a horizontally arranged state. That is, the rotating tube 110 has a double structure including an external metal material 1111 and an internal metal material 1112 provided inside the external metal material 1111.
- the rotating tube 110 may have a structure made of composite metal (clad metal) integrated by fusing dissimilar metal materials.
- the conventional rotating tube has a structure in which two metal tubes are fitted and coupled.
- the rotating tube 110 of the present invention has a structure made of composite metal (clad metal) integrated by fusing dissimilar metal materials, and as a result, the bonding force can be greatly increased.
- the rotating tube 110 of the present invention is manufactured by placing two metal materials in the shape of a plate, fusing them to manufacture a composite metal, and bending the composite metal into a tube shape.
- the rotating tube 110 includes an internal metal material 1112 located on the inside and an external metal material 1111 located on the outside, and the internal metal material 1112 and the external metal material 1111 are fused by fusion. It may be a structure made of an integrated composite metal (clad metal).
- composite metals are made by fusing dissimilar metals together by soldering or hot pressing, and thus the bondability and durability of the fused dissimilar metals can be improved.
- composite metals are not plated or coated, but are fused by pressing metals (non-ferrous metals), they can penetrate while destroying the mutual structures and stabilize the structures themselves, and as a result, the bonding between metals is greatly increased. You can.
- the rotary kiln according to the fourth embodiment of the present invention can increase bonding properties by including a rotating tube 110 made of clad metal integrated by fusing dissimilar metal materials.
- the different metals used to manufacture the rotating tube 110 may be made of metallic materials and non-ferrous metal materials.
- the external metal material may be made of a non-ferrous metal material.
- the internal metal material 1112 located inside the rotating tube 110 is made of nickel (Ni), and the external metal material 1111 located outside the rotating tube 110 is made of stainless steel. It can be prepared from materials.
- the rotating tube 110 includes an internal metal material 1112 made of nickel and an external metal material 1111 made of stainless steel, thereby preventing contamination of the raw material powder and increasing the strength of the rotating tube. .
- the internal metal material may have a thinner thickness than the external metal material.
- the internal metal material is the part that comes into contact with the raw material powder, and its role is to prevent contamination of the raw material powder, so costs can be reduced by minimizing the thickness.
- the external metal material rotates in contact with the rotating member and the support member, it is formed to be thicker than the internal metal material to prevent wear and damage.
- the internal metal material 1112 may have a thickness of 1 to 3 mm.
- the internal metal material 1112 has a thickness of 1 mm or less, deformation and damage of the internal metal material may occur when the internal metal material and the external metal material are compressed.
- the internal metal material 1112 has a thickness of 3 mm or more, a large amount of nickel (Ni) material may be used unnecessarily, resulting in a significant increase in cost. Accordingly, the internal metal material 1112 can be set to a thickness of 1 to 3 mm to prevent problems and increased costs.
- the rotary kiln according to the fourth embodiment of the present invention can improve bondability and manufacturing efficiency by including a rotating tube 110 made of clad metal integrated by fusing dissimilar metal materials.
- Figure 29 is a process chart showing a fusion process
- Figure 30 is a process chart showing a bending process
- Figure 31 is a process chart showing another example of the bending process.
- the rotating tube manufacturing method includes a fusion process, a bending process, and a sealing process.
- the fusion process fuses dissimilar metal materials with hot pressure to manufacture an integrated composite metal plate.
- a metal material (112A) and a non-ferrous metal material (111A) are prepared as different types of metal materials.
- the metal material 112A may be made of a nickel material
- the non-ferrous metal material 111A may be made of a stainless steel material.
- the metal material 112A and the non-ferrous metal material 111A prepared in this way are compressed using a rolling roller 30.
- the composite metal plate 2 can be manufactured by fusing the metal material 112A and the non-ferrous metal material 111A. Meanwhile, when the metal material 112A and the non-ferrous metal material 111A are fused, their mutual tissues are destroyed and penetrate into them, thereby stabilizing the tissues themselves.
- the internal metal material of the rotating tube 110 has a thinner thickness than the external metal material.
- the internal metal material has a thickness of 1 to 3 mm.
- the bending process bends the composite metal plate 2 to manufacture a cylindrical rotating tube 110. At this time, it is bent so that the metal material is located on the inside and the non-ferrous metal material is located on the outside. That is, referring to FIG. 28, the inner metal material 1112 located on the inside of the rotating tube is made of nickel (Ni), and the outer metal material 1111, which is a non-ferrous metal material located on the outside of the rotating tube, is made of stainless steel. It is made of (Stainless steel) material.
- the composite metal plate 2 is bent into a coil shape (spiral) through a trimming equipment 40 to manufacture an unfinished rotating tube 110A.
- the unfinished rotating tube (110A) is cut to the set size.
- the composite metal plate 2 is bent into an O shape using a press (not shown) to manufacture an unfinished rotating tube 110A.
- the portion where the ends of the unfinished rotating tube (110A) are in contact with each other or the corresponding portion is sealed using welding or the like. Then, the finished rotary tube 110 as shown in FIG. 28 can be manufactured.
- the finished rotating tube 110 is made of composite metal (clad metal) in which dissimilar metal materials are integrated, and as a result, bonding properties can be improved and the thickness of the internal metal material can be minimized.
- Figure 32 is a cross-sectional view showing another embodiment of the rotary kiln according to the fourth embodiment of the present invention.
- the rotary kiln according to the fourth embodiment of the present invention includes a rotating tube 110, and the rotating tube 110 is a composite metal (clad metal) in which different types of metal materials are integrated. It is prepared as follows. And the heterogeneous metal material is prepared as an internal metal material 1112 and an external metal material 1111.
- the rotating tube 110 is formed with an inlet portion through which the raw material powder is introduced, and an outlet portion through which the raw material powder is discharged.
- the density and weight increase as the heat treatment temperature increases.
- the density and weight of the raw material powder located in the discharge portion increases compared to the raw material powder located in the inlet portion, and as a result, the internal metal material 1112 provided in the discharge portion of the rotating tube 110 is deformed, worn, and damaged.
- the internal metal material undergoes greater deformation, wear, and damage at the outlet part of the rotating tube than at the inlet part.
- the internal metal material 1112 is moved from the inlet part of the rotating tube 110 (the left end of the rotating tube as seen in FIG. 32) to the discharge part (the right side of the rotating tube as seen in FIG. 32).
- the thickness may be gradually increased toward the end. That is, the thickness ( ⁇ ) of the internal metal material 1112 located at the discharge part of the rotating tube can be set to be greater than the thickness ( ⁇ ) of the internal metal material 1112 located at the inlet part of the rotating tube 110.
- Figure 33 is a cross-sectional view showing another embodiment of the rotary kiln according to the fourth embodiment of the present invention.
- the inner metal material 1112 increases in thickness from the inlet part of the rotating tube 110 (left end of the rotating tube as seen in FIG. 22) to the discharge part (right end of the rotating tube as seen in FIG. 22). It can be arranged to increase gradually. That is, the thickness ( ⁇ ) of the internal metal material 1112 located at the discharge part of the rotating tube 110 can be made larger than the thickness ( ⁇ ) of the internal metal material 1112 located at the inlet part of the rotating tube 110. there is.
- the external metal material 1111 extends from the discharge part of the rotary tube 110 (the right end of the rotary tube as seen in FIG. 33) to the inlet part of the rotary tube 110 (the left end of the rotary tube as seen in FIG. 33). ), the thickness can be gradually increased. That is, the thickness (A) of the external metal material located at the inlet of the rotating tube may be greater than the thickness (B) of the external metal material located at the outlet of the rotating tube.
- the thickness of A is set to 4 mmm and the thickness of B is set to 3 mm
- the thickness of ⁇ is set to 1 mm and the thickness of ⁇ is set to 2 mm.
- the rotating tube 110 made of composite metal is manufactured by fusing the external metal material and the internal metal material set in this way. Then, the thickness of the inlet part of the rotating tube becomes 5mm and the thickness of the outlet part becomes 5mm.
- the thickness of the inlet and discharge portions of the rotating tube can be made the same while the thickness of the internal metal material located in the discharge portion can be increased.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Description
Claims (20)
- 수평방향으로 배치된 상태로 회전하면서 원료 분말을 회전시키고 가열하는 회전튜브가 마련된 튜브 조립체; 및상기 회전튜브에 구비된 온도측정부를 포함하며,상기 온도측정부는,제1 온도센서;상기 제1 온도센서를 상기 회전튜브에 고정하는 제1 고정부재; 및상기 제1 고정부재와 상기 회전튜브 사이에 구비되고, 상기 회전튜브의 열이 상기 제1 온도센서로 전도되지 않도록 차단하는 단열체를 포함하는 로터리 킬른.
- 청구항 1에 있어서,상기 제1 온도센서는, 상기 회전튜브의 내부에 구비되고 상기 원료 분말의 온도를 측정하는 로터리 킬른.
- 청구항 1에 있어서,상기 제1 온도센서는, 상기 회전튜브의 내둘레 반경 방향에 대한 온도 분포를 측정하는 로터리킬른.
- 청구항 2에 있어서,상기 제1 고정부재는, 상기 제1 온도센서를 감싸는 형태로 구비되는 로터리 킬른.
- 청구항 3에 있어서,상기 제1 온도센서는, 복수개로 마련되고,상기 제1 고정부재는,상기 회전튜브의 내부에 배치되고, 상기 회전튜브의 길이방향으로 연장되는 한 쌍의 수평부; 및양쪽 단부가 한 쌍의 수평부에 각각 고정되고, 상기 회전튜브의 내둘레 반경 방향으로 복수개의 제1 온도센서가 기 설정된 간격으로 설치되는 수직봉을 포함하는 로터리 킬른.
- 청구항 2에 있어서,상기 온도측정부는,상기 제1 고정부재를 상기 회전튜브에 고정하는 제1 결합부재를 더 포함하는 로터리 킬른.
- 청구항 6에 있어서,상기 제1 결합부재는,상기 회전튜브의 내측에 구비되고, 상기 제1 고정부재의 선단부에 결합되는 제1 결합편;상기 회전튜브의 외측에 구비되는 외측부와, 상기 제1 고정부재와 상기 단열체 사이에 구비되고 선단이 상기 제1 결합편에 체결되는 내측부로 마련된 제2 결합편; 및상기 제1 결합편과 제2 결합편 사이에 배치되고, 제1 결합편 및 제2 결합편 체결시 변형되면서 상기 제1 고정부재를 가압하는 가압편을 포함하는 로터리 킬른.
- 청구항 1에 있어서,상기 로터리 킬른은,상기 회전튜브의 온도를 직접 측정하는 보조 온도측정부를 더 포함하고,상기 보조 온도측정부는,상기 회전튜브의 외면에 삽입되되, 상기 튜브 조립체의 내부로 관통되지 않게 삽입되면서 상기 회전튜브의 온도를 측정하는 제2 온도센서; 및상기 제2 온도센서를 상기 회전튜브에 고정하는 제2 고정부재를 포함하는 로터리 킬른.
- 청구항 8에 있어서,상기 로터리 킬른은,상기 온도측정부에 의해 측정된 온도와, 상기 보조 온도측정부에 의해 측정된 온도를 수신하는 수신부; 및상기 수신부에 의해 수신된 온도측정부의 온도와 보조 온도측정부의 온도가 기 설정된 입력값 보다 작거나 또는 크면 불량 신호를 발생시키는 검사부를 더 포함하는 로터리 킬른.
- 청구항 9에 있어서,상기 로터리 킬른은,상기 검사부에 의해 불량 신호가 발생하면, 회전튜브의 가열 온도를 제어하여 온도측정부의 온도와 보조 온도측정부의 온도가 기 설정된 입력값 내에 포함되도록 조절하는 제어부를 더 포함하는 로터리 킬른.
- 청구항 3에 있어서,복수개의 제1 온도센서는, 상기 회전튜브의 내둘레 반경 방향으로 배치되면서 회전튜브에 투입된 원료 분말의 온도와, 원료 분말이 없는 공간의 온도 측정을 통해 온도 분포를 감지하는 로터리 킬른.
- 청구항 11에 있어서,상기 온도측정부는,복수개의 제1 온도센서에 의해 감지된 상기 회전튜브의 내둘레 반경 방향에 대한 온도 분포를 통해 상기 회전튜브에 투입된 원료 분말의 충진량을 검출하는 검출부재를 더 포함하고,상기 검출부재는, 복수개의 제1 온도센서가 회전튜브의 반경 방향으로 위치한 상태에서 원료 분말의 온도를 감지한 제1 온도센서를 검출하고, 검출한 제1 온도센서의 개수에 해당하는 입력된 충진량 데이터를 선택하여 원료 분말 충진량을 계산하는 로터리 킬른.
- 청구항 1에 있어서,상기 로터리 킬른은,상기 회전튜브에 의해 회전하는 원료 분말을 교반하는 교반 조립체를 더 포함하며,상기 교반 조립체는,상기 회전튜브에 의해 회전하는 원료 분말을 교반하는 교반부; 및상기 교반부를 상기 회전튜브의 일 단부에 결합하는 결합부를 포함하고,상기 결합부는,상기 회전튜브의 일 단부에 지지되고, 상기 교반부가 결합되는 링 형태의 지지편, 및상기 지지편을 상기 회전튜브의 일 단부에 착탈 가능하게 결합하는 고정수단을 포함하는 로터리 킬른.
- 청구항 13에 있어서,상기 교반부는,원료 분말을 교반하는 하나 이상의 교반편을 포함하고,상기 교반편은,기 설정된 간격으로 마련되는 2개 이상의 회전체; 및상호 대응하는 회전체를 연결하고, 회전튜브에 의해 회전하는 원료 분말을 교반하는 교반봉을 포함하는 로터리 킬른.
- 청구항 14에 있어서,상기 회전체는, 회전튜브의 내주면에 지지되지 않도록 상기 회전튜브의 내주면 직경 보다 작은 직경을 가지는 로터리 킬른.
- 청구항 14에 있어서,상기 교반편이 2개 이상으로 마련되면, 상기 교반부는, 상호 대응하는 교반편을 연결하고, 상호 대응하는 교반편 사이에 위치한 원료 분말을 교반하는 보조 교반봉을 더 포함하는 로터리 킬른.
- 청구항 1에 있어서,상기 회전튜브는, 이종의 금속을 융착시켜서 일체화된 복합 금속(clad metal)으로 마련되는 로터리 킬른.
- 청구항 17에 있어서,상기 이종의 금속물질은 금속물질과 비철금속물질로 마련되는 로터리 킬른.
- 청구항 17에 있어서,상기 이종의 금속은, 상기 회전튜브의 내측에 위치한 내부 금속물질, 상기 회전튜브의 외측에 위치한 외부 금속물질를 포함하며,상기 내부 금속물질은 상기 외부 금속물질 보다 얇은 두께를 가지는 로터리 킬른.
- 청구항 19에 있어서,상기 회전튜브는, 원료 분말이 투입되는 입구부와, 원료 분말이 배출되는 배출부가 형성되고,상기 내부 금속물질은, 상기 회전튜브의 입구부에서 배출부로 갈수록 두께가 점차적으로 증대되게 마련되는 로터리 킬른.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23803843.4A EP4491990A4 (en) | 2022-05-10 | 2023-05-10 | ROTATING OVEN |
| US18/858,985 US20250290696A1 (en) | 2022-05-10 | 2023-05-10 | Rotary Kiln |
| JP2024563420A JP2025515341A (ja) | 2022-05-10 | 2023-05-10 | ロータリーキルン |
| CN202380034397.3A CN118974501A (zh) | 2022-05-10 | 2023-05-10 | 回转窑 |
Applications Claiming Priority (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20220057237 | 2022-05-10 | ||
| KR10-2022-0057237 | 2022-05-10 | ||
| KR10-2022-0060126 | 2022-05-17 | ||
| KR20220060126 | 2022-05-17 | ||
| KR20220061554 | 2022-05-19 | ||
| KR10-2022-0061554 | 2022-05-19 | ||
| KR20220069410 | 2022-06-08 | ||
| KR10-2022-0069410 | 2022-06-08 | ||
| KR1020230059992A KR20230157888A (ko) | 2022-05-10 | 2023-05-09 | 로터리 킬른 |
| KR10-2023-0059992 | 2023-05-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023219420A1 true WO2023219420A1 (ko) | 2023-11-16 |
Family
ID=88730704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2023/006363 Ceased WO2023219420A1 (ko) | 2022-05-10 | 2023-05-10 | 로터리 킬른 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20250290696A1 (ko) |
| EP (1) | EP4491990A4 (ko) |
| JP (1) | JP2025515341A (ko) |
| WO (1) | WO2023219420A1 (ko) |
Citations (6)
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| JPH0638320Y2 (ja) * | 1988-06-01 | 1994-10-05 | 株式会社香蘭社 | 溶湯用温度センサー |
| JP2001272173A (ja) * | 2000-03-27 | 2001-10-05 | Sumitomo Heavy Ind Ltd | ロータリーキルン |
| JP2004011990A (ja) * | 2002-06-05 | 2004-01-15 | Sumitomo Metal Mining Co Ltd | ロータリーキルンの燃焼制御装置および制御方法 |
| JP2005315510A (ja) * | 2004-04-28 | 2005-11-10 | Sumitomo Metal Ind Ltd | 加熱炉及び温度計並びに炉内温度制御方法 |
| JP2020508873A (ja) * | 2016-12-23 | 2020-03-26 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | 複合管の製造方法 |
| KR102134672B1 (ko) * | 2018-10-17 | 2020-07-27 | 진수곤 | 양극 활물질의 코팅층 열처리에 적합한 로터리 킬른 |
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| JP3241040B2 (ja) * | 1990-11-21 | 2001-12-25 | 富士通株式会社 | 加熱処理装置 |
| JP3173146B2 (ja) * | 1992-07-10 | 2001-06-04 | 株式会社明電舎 | ガス絶縁開閉装置 |
| US5456761A (en) * | 1993-07-15 | 1995-10-10 | Alcan International Limited | High temperature and abrasion resistant temperature measuring device |
| US6765531B2 (en) * | 1999-01-08 | 2004-07-20 | Trueposition, Inc. | System and method for interference cancellation in a location calculation, for use in a wireless location system |
| KR101630923B1 (ko) * | 2014-06-18 | 2016-06-16 | 주식회사 포스코 | 로터리 킬른 환원로를 활용한 환원 방법 |
| CN105333968B (zh) * | 2015-09-24 | 2018-11-30 | 中冶长天国际工程有限责任公司 | 一种回转窑温度检测装置 |
-
2023
- 2023-05-10 EP EP23803843.4A patent/EP4491990A4/en active Pending
- 2023-05-10 JP JP2024563420A patent/JP2025515341A/ja active Pending
- 2023-05-10 US US18/858,985 patent/US20250290696A1/en active Pending
- 2023-05-10 WO PCT/KR2023/006363 patent/WO2023219420A1/ko not_active Ceased
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0638320Y2 (ja) * | 1988-06-01 | 1994-10-05 | 株式会社香蘭社 | 溶湯用温度センサー |
| JP2001272173A (ja) * | 2000-03-27 | 2001-10-05 | Sumitomo Heavy Ind Ltd | ロータリーキルン |
| JP2004011990A (ja) * | 2002-06-05 | 2004-01-15 | Sumitomo Metal Mining Co Ltd | ロータリーキルンの燃焼制御装置および制御方法 |
| JP2005315510A (ja) * | 2004-04-28 | 2005-11-10 | Sumitomo Metal Ind Ltd | 加熱炉及び温度計並びに炉内温度制御方法 |
| JP2020508873A (ja) * | 2016-12-23 | 2020-03-26 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | 複合管の製造方法 |
| KR102134672B1 (ko) * | 2018-10-17 | 2020-07-27 | 진수곤 | 양극 활물질의 코팅층 열처리에 적합한 로터리 킬른 |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2025515341A (ja) | 2025-05-14 |
| EP4491990A4 (en) | 2026-03-25 |
| US20250290696A1 (en) | 2025-09-18 |
| EP4491990A1 (en) | 2025-01-15 |
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