WO2024138323A1 - 二次电池及电子装置 - Google Patents
二次电池及电子装置 Download PDFInfo
- Publication number
- WO2024138323A1 WO2024138323A1 PCT/CN2022/142030 CN2022142030W WO2024138323A1 WO 2024138323 A1 WO2024138323 A1 WO 2024138323A1 CN 2022142030 W CN2022142030 W CN 2022142030W WO 2024138323 A1 WO2024138323 A1 WO 2024138323A1
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- WIPO (PCT)
- Prior art keywords
- secondary battery
- material layer
- active material
- insulating member
- region
- Prior art date
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/105—Pouches or flexible bags
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/178—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for pouch or flexible bag cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/184—Sealing members characterised by their shape or structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/186—Sealing members characterised by the disposition of the sealing members
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/471—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof
- H01M50/474—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof characterised by their position inside the cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/536—Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the second pole ear has a second bending portion bent toward the second direction, and the second bending portion provides a function of reducing the impact of the electrode assembly when the second pole ear is impacted by an external force, reduces the pulling force between the fourth connection part and the third region, reduces the risk of secondary battery failure, and improves the safety of the secondary battery.
- the second pole piece includes a second current collector, a third active material layer and a fourth active material layer
- the second current collector includes a third surface and a fourth surface opposite to each other, the third active material layer is disposed on the third surface, and the fourth active material layer is disposed on the fourth surface
- the third surface includes a third region, the third active material layer is provided with a second groove exposing the third region
- the fourth surface includes a fourth region corresponding to the third region, and the fourth region is covered by the fourth active material layer.
- FIG2 is a schematic diagram of one of the situations after FIG1 is cut along the cutting line AA;
- FIG19 is a schematic diagram of another situation after FIG1 is cut along the cutting line AA;
- a secondary battery 100 provided in one embodiment of the present application includes a packaging bag 110, an electrode assembly 120, and a first pole ear 130.
- the packaging bag 110 is provided with a receiving cavity 111 and a sealing edge 112 for sealing the receiving cavity 111.
- the receiving cavity 111 is used to receive the electrode assembly 120.
- One end of the first pole ear 130 is connected to the electrode assembly 120, and the other end of the first pole ear 130 extends out of the packaging bag 110 from the sealing edge 112.
- the accompanying drawings show that the electrode assembly 120 adopts a winding structure, but the structure of the electrode assembly 120 of the present application is not limited to the winding structure, and it can also adopt a stacked structure.
- FIG. 5 is a schematic diagram after cutting along section line BB of FIG. 1 , the first pole piece 121 includes a first current collector 1211, a first active material layer 1212 and a second active material layer 1213, the first current collector 1211 includes a first surface 12111 and a second surface 12112 arranged opposite to each other, the first active material layer 1212 is arranged on the first surface 12111 of the first current collector 1211, and the second active material layer 1213 is arranged on the second surface 12112 of the first current collector 1211.
- the second connection portion 133 is at least partially provided in the first groove 1212a, thereby reducing the risk of the thickness of the secondary battery 100 becoming thicker due to the thickness of the first pole tab 130, and thus helping to improve the energy density of the secondary battery 100.
- the second active material layer 1213 is provided in the second region 1211b opposite to the first region 1211a, thereby reducing the risk of a poor interface between the first pole piece 121 and the second pole piece 122 caused by uneven thickness due to the double-sided grooves of the first pole piece 121.
- the second connection part 133 can be connected by welding by laser irradiation, or by setting a conductive adhesive to connect the second connection part 133 to the first region 1211a.
- other connection methods are also possible, and are not limited to the connection methods mentioned here, as long as the second connection part 133 can be connected to the first region 1211a.
- the second connection part 133 is connected by welding to the first region 1211a by laser irradiation. This is conducive to forming a more reliable connection between the second connection part 133 and the first region 1211a, while reducing the impact of welding on the second active material layer 1213 set in the second region 1211b.
- the packaging bag 110 is made of a light and flexible material
- the secondary battery 100 using the packaging bag 110 as the outer shell has a higher energy density, but it is easily deformed when subjected to an external force, causing the first pole ear 130 of the battery 100 to be easily pulled.
- the installation method of the first pole ear 130 and the electrode assembly 120 of the present application can reduce the risk of the first pole ear 130 being separated from the first pole piece 121 when the first pole ear 130 is pulled by an external force, which helps to improve the reliability of the secondary battery made using the packaging bag 110.
- the first current collector 1211 is provided with a first notch 1211e formed by being recessed in a direction from the first side 1211c toward the second side 1211d, and the first notch 1211e at least partially overlaps with the second connection portion 133 along the second direction Y.
- the risk of the first active material layer 1212 existing at the edge of the first region 1211a of the first pole piece 121 cut in the slitting process is reduced, thereby reducing the risk of the thickness of the overlapped portion of the second connection portion 133 and the first region 1211a being increased due to the residual first active material layer 1212, which helps to improve the energy density of the secondary battery 100.
- the secondary battery 100 also includes a first insulating member 150, the first insulating member 150 is at least partially disposed on the first pole ear surface 1301 located at the first bending portion 132, and the first insulating member 150 includes a first insulating edge 151 away from the first pole piece 121 in the first direction X, and a second insulating edge 152 arranged opposite to the first insulating edge 151 in the first direction X.
- the risk of burrs on the first bent portion 132 piercing the packaging bag 110 is reduced, the risk of the first bent portion 132 and the packaging bag 110 being short-circuited is reduced, and the risk of the first bent portion 132 being impacted and short-circuited with the second electrode 122 when the secondary battery 100 falls is reduced, which helps to improve the safety of the secondary battery 100.
- the secondary battery 100 further includes a sealing member 160
- the sealing member 160 includes a packaging portion 161, a first extension portion 162 and a second extension portion 163
- the packaging portion 161 is used to be sealed and connected with the sealing edge 112
- the first extension portion 162 extends from the packaging portion 161 toward the inside of the packaging bag 110
- the second extension portion 163 extends from the packaging portion 161 toward the outside of the packaging bag 110.
- the material of the packaging portion 161, the first extension portion 162 and the second extension portion 163 includes at least one of polyethylene, polypropylene, polyethylene terephthalate, polyurethane or ethylene-propylene copolymer.
- first extension portion 162 includes a first portion 1621, which is disposed on the first tab surface 1301 and abuts against one end of the first insulating member 150. It should be understood that the first portion 1621 abuts against one end of the first insulating member 150, including the following two solutions:
- the first portion 1621 partially overlaps with the first insulating member 150 in the second direction Y, that is, the first insulating member 150 at least covers a portion of the first portion 1621, which is beneficial to enhancing the reliability of the connection between the first insulating member 150 and the first tab 130.
- the area where the first insulating member 150 overlaps with the first portion 1621 can reduce the risk of the first portion 1621 being separated from the first tab surface 1301, which is beneficial to improving the sealing performance of the secondary battery 100.
- the dimension between the end edge of the first portion 1621 in the direction opposite to the first direction X and the first insulating edge 151 is L 1
- the dimension between the second insulating edge 152 and the first edge 1211c in the first direction X is L 11 , which satisfies 1mm ⁇ L 1 , 0mm ⁇ L 11 .
- the first insulating member 150 covers an appropriate area of the first portion 1621 and the first pole piece 121 , reducing the risk of the first insulating member 150 being separated from the first pole tab 130 during a drop, which is beneficial to improving the sealing performance.
- the first portion 1621 and the first insulating member 150 are in contact with each other between their end surfaces in the first direction X. At this time, the first portion 1621 and the first insulating member 150 do not overlap in the second direction Y, which is conducive to covering the first pole ear surface 1301 as much as possible, reducing the risk of burrs on the first pole ear surface 1301 being exposed and piercing the packaging bag 110, which is conducive to improving the safety performance of the secondary battery 100; and it can also reduce the risk of the first insulating member 150 entering the sealing edge 112 when the sealing edge 112 is formed in the packaging bag 110, thereby affecting the sealing reliability.
- one end of the first insulating member 150 extends in a direction opposite to the first direction X, so that the first insulating member 150 covers a portion of the second active material layer 1213, which is conducive to reducing the risk of the first insulating member 150 being separated from the first pole ear surface 1301, and during the falling process, the first insulating member 150 can suppress the bending of the first bending portion 132 to reduce the risk of separation of the second connecting portion 133 from the first region 1211a. At the same time, during the falling process, the first insulating member 150 can also reduce the risk of the first bending portion 132 squeezing the second active material layer 1213 and causing material shedding.
- the first insulating member 150 and the first portion 1621 are an integral member.
- the first portion 1621 partially extends and replaces the original first insulating member 150, which can reduce the risk of burrs on the first bent portion 132 piercing the shell.
- the packaging portion 161 and the first portion 1621 of the first extension portion 162 are an integral member, the first portion 1621 can suppress the bending of the first bent portion 132 under the constraint of the packaging portion 161, thereby enhancing the stability of the connection between the sealing member 160 and the first pole tab 130 and improving the reliability of the secondary battery 100.
- the secondary battery 100 further includes a second insulating member 170, and the second insulating member 170 is disposed on the second pole ear surface 1302 of the first bending portion 132.
- the second insulating member 170 can block the burrs of the first pole ear 130 on the second pole ear surface 1302, reduce the risk of the packaging bag 110 being punctured by the burrs, and help improve the safety performance of the secondary battery 100.
- the second insulating member 170 can inhibit the bending of the first bending portion 132, which is conducive to reducing the deformation degree of the first bending portion 132 during the falling process, reducing the impact force of the electrode assembly 120 on the sealing edge 112, reducing the risk of the sealing edge 112 being broken, and helping to improve the reliability of the secondary battery 100.
- the second insulating member 170 includes a third insulating edge 171 away from the first pole piece 121 in the first direction X, and a fourth insulating edge 172 arranged opposite to the third insulating edge 171 in the first direction X.
- the dimension between the end edge of the second portion 1622 in the direction opposite to the first direction X and the third insulating edge 171 is L 2
- the dimension between the fourth insulating edge 172 and the first edge 1211c in the first direction X is L 22 , which satisfies L 2 ⁇ 3mm and L 22 ⁇ 6mm.
- the second insulating member 170 covers an appropriate area of the second portion 1622 and the first pole piece 121, reducing the impact of the second insulating member 170 and the second portion 1622 covering too large an area on the sealing performance of the secondary battery 100 and also reducing the impact of the second insulating member 170 and the first pole piece 121 covering too large an area on the energy density of the secondary battery.
- one end of the second insulating member 170 extends in a direction opposite to the first direction X, so that the second insulating member 170 covers at least a portion of the first groove 1212a.
- the second insulating member 170 covers at least a portion of the second connection portion 133 located in the first groove 1212a, which is conducive to the second insulating member 170 being more firmly arranged on the first bending portion 132, and in the process of falling, the second insulating member 170 reduces the risk of partial material of the first active material layer 1212 falling off due to the side wall of the first groove 1212a being squeezed.
- the second insulating member 170 completely covers the first groove 1212a, which can further restrict the second connection portion 133 and inhibit the second connection portion 133 from detaching from the first area 1211a, which is more conducive to improving the stability of the connection between the second connection portion 133 and the first area 1211a, and can reduce the risk of burrs on the inner wall of the first groove 1212a piercing the isolation film 123.
- the dimension L 1 between the end edge of the first portion 1621 in the direction opposite to the first direction X and the first insulating edge 151, the dimension L 11 between the second insulating edge 152 and the first edge 1211c in the first direction X, the dimension L 2 between the end edge of the second portion 1622 in the direction opposite to the first direction X and the third insulating edge 171, and the dimension L 22 between the fourth insulating edge 172 and the first edge 1211c in the first direction X are all measured when the first pole tab 130 is in an unfolded state.
- the first pole sheet 121 is in a wound state, the first pole sheet 121 should be unfolded before measuring these distances, as shown in Figures 6-7. At this time, the first pole tab 130 is relatively perpendicular to the first current collector 1211.
- the second insulating member 170 may be an insulating tape, and the second insulating member 170 includes a substrate layer and an adhesive layer disposed on the substrate layer, and the adhesive layer is used to bond to the second tab surface 1302.
- the substrate layer may be made of materials including polypropylene, polyethylene terephthalate, polyimide, etc.
- the adhesive layer may be made of materials including acrylate, rubber, silicone, polyurethane, or polyolefin.
- the second insulating member 170 may also be other materials, not limited to the insulating tape mentioned here, as long as insulation and bonding can be achieved.
- the first insulating member 150 and the first portion 1621 are an integral component
- the second insulating member 170 and the second portion 1622 are an integral component, which is more conducive to reducing the degree of deformation of the first bending portion 132, thereby prolonging the time for the electrode assembly 120 to impact the sealing edge 112 during the falling process, which is conducive to reducing the impact force of the electrode assembly 120 on the sealing edge 112, reducing the risk of the sealing edge 112 being broken open, and improving the reliability of the secondary battery 100.
- the angle formed by the first bending portion 132 and the second direction Y is ⁇ . It should be understood that, since the shape of the first bending portion 132 can be non-linear, the angle formed by the first bending portion 132 and the second direction Y refers to the angle between the line connecting the first and tail ends of the first bending portion 132 and the second direction Y.
- a comparison group and an experimental group are set up for drop test for comparison.
- the comparison group is a group in which the first bending portion 132 is bent in the opposite direction of the second direction Y
- the experimental group is a group in which the first bending portion 132 is bent in the second direction Y and the angle ⁇ has different values.
- the test conditions of each group of experiments are that 10 cells are tested for 5 rounds at a height of 1m with 6 sides and 4 corners touching the ground.
- the passing condition is that the sealing edge of the cell is not broken after falling, and the voltage drop is less than 50mV.
- the experimental results obtained from the experiments are as follows:
- Experimental Group 2 20 1.5 3 3920 7/10 Experimental Group 3 30 1.5 3 3920 10/10 Experimental Group 4 45 1.5 3 3920 10/10 Experimental Group 5 50 1.5 3 3920 10/10 Experimental Group 6 60 1.5 3 3920 10/10 Experimental Group 7 70 1.5 3 3920 10/10 Experimental Group 8 75 1.5 3 3920 5/10 Experimental Group 9 45 1.5 7 3890 10/10 Experimental Group 10 45 1.5 0 3920 6/10 Experimental Group 11 45 0 3 3920 5/10 Experimental Group 12 45 3.5 3 3920 4/10 Experimental Group 13 45 0 3 3920 10/10
- the second insulating member 170 and the sealing member 160 in experimental groups 1-12 are designed to be separated, and the second insulating member 170 and the sealing member 160 in experimental group 13 are integrated components.
- the partial overlap between the second insulating member 170 and the first pole piece 121 is beneficial to improving the pass rate of the battery cell, that is, the partial overlap between the second insulating member 170 and the first pole piece 121 is beneficial to improving the reliability and safety performance of the battery cell.
- the second pole piece 122 may be provided with grooves on both sides, that is, the current collector part of the second pole piece 122 is not covered with an active material layer, or it may adopt the same structure as the first pole piece 121, or it may be other structures, and the specific structure may be selected according to actual needs.
- the second pole piece 122 adopts a structural design similar to that of the first pole piece 121, specifically, the second pole piece 122 includes a second current collector 1221, a third active material layer 1222 and a fourth active material layer 1223, the second current collector 1221 includes a third surface 12211 and a fourth surface 12212 arranged oppositely, the third active material layer 1222 is arranged on the third surface 12211 of the second current collector 1221, and the fourth active material layer 1223 is arranged on the fourth surface 12212 of the second current collector 1221.
- Figure 16-17 is a schematic diagram of the second pole piece 122 and the second pole tab 140 in an unfolded state.
- the extension direction of the width side of the second pole piece 122 is the same as the first direction X.
- the direction in which the length side of the second pole piece 122 extends is the fourth direction U.
- the third surface 12211 of the second current collector 1221 includes a third region 1221a.
- the third active material layer 1222 is provided with a second groove 1222a that exposes the third region 1221a.
- the fourth surface 12212 of the second current collector 1221 includes a fourth region 1221b opposite to the third region 1221a.
- the fourth region 1221b is covered by the fourth active material layer 1223.
- the second current collector 1221 is not provided with the third active material layer 1222 in the third region 1221a, so that the second pole piece 122 forms a second groove 1222a.
- the secondary battery 100 further includes a second pole tab 140, which includes a third connecting portion 141, a second bending portion 142, and a fourth connecting portion 143 connected in sequence, wherein the fourth connecting portion 143 is at least partially located in the second groove 1222a and connected to the third region 1221a.
- the two opposite surfaces of the second pole tab 140 are a third pole tab surface 1401 and a fourth pole tab surface 1402.
- the third connection portion 141 extends out of the packaging bag 110 from the sealing edge 112. At this time, the third connection portion 141 directly serves as an electrode of one polarity of the secondary battery 100, which can be a positive electrode or a negative electrode. Correspondingly, the first connection portion 131 serves as an electrode of the other polarity of the secondary battery 100.
- the first pole piece 121 has a winding starting edge 1210 along the winding direction, and a plane parallel to the plurality of flat portions 121a and passing through the winding starting edge 1210 is defined as the winding center plane P. Observed along the first direction X, the first pole tab 130 and the second pole tab 140 are located on both sides of the winding center plane P, thereby reducing the risk of the second connecting portion 133 and the fourth connecting portion 143 being too close in the second direction Y to affect the sealing effect of the sealing edge 112.
- first groove 1212a and the second groove 1222a do not overlap in the second direction Y.
- the third direction Z is a direction perpendicular to the first direction X and the second direction Y.
- the second pole piece 122 may be provided with grooves on both sides, as shown in FIG20, which is different from the structure in which the second pole piece 122 is provided with grooves on one side in the above embodiment, the fourth active material layer 1223 is provided with a third groove 1223a that exposes at least part of the fourth region 1221b, and the third groove 1223a is arranged opposite to the second groove 1222a. In other words, the fourth region 1221b is at least partially not covered by the fourth active material layer 1223.
- the second bent portion 142 provides a function of mitigating impact on the electrode assembly 120 when the second pole ear 140 is impacted by external force, thereby reducing the pulling force between the fourth connecting portion 143 and the third area 1221a, reducing the risk of failure of the secondary battery 100, and improving the safety of the secondary battery 100.
- the third insulating member 180 can extend in a direction opposite to the first direction X and cover at least a portion of the third groove 1223a to reduce the risk of burrs on the second current collector 1221 in the fourth area 1221b piercing the isolation film 123 and causing a short circuit. At the same time, it can also reduce the risk of material falling off in the third groove 1223a, which is beneficial to improving the safety and stability of the secondary battery 100.
- the electronic device 300 provided in another embodiment of the present application includes the secondary battery 100 in the above embodiment.
- the electronic device 300 of the present application is not particularly limited, and it can be any electronic device known in the prior art.
- the electronic device 300 includes but is not limited to a laptop computer, a pen-input computer, a mobile computer, an e-book player, a portable phone, a portable fax machine, a portable copier, a portable printer, a head-mounted stereo headset, a video recorder, a liquid crystal television, a portable cleaner, a portable CD player, a mini-disc, a transceiver, an electronic notepad, a calculator, a memory card, a portable recorder, a radio, a backup power supply, a motor, a car, a motorcycle, a power-assisted bicycle, a bicycle, a lighting device, a toy, a game console, a clock, an electric tool, a flashlight, a camera, a large household battery and a lithium-i
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Secondary Cells (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Cell Separators (AREA)
Abstract
Description
| 序号 | β | L 2 | L 22 | 电池容量 | 测试结果 |
| 对比组1 | 15 | 1.5 | 3 | 3920 | 0/10 |
| 实验组1 | 15 | 1.5 | 3 | 3920 | 5/10 |
| 实验组2 | 20 | 1.5 | 3 | 3920 | 7/10 |
| 实验组3 | 30 | 1.5 | 3 | 3920 | 10/10 |
| 实验组4 | 45 | 1.5 | 3 | 3920 | 10/10 |
| 实验组5 | 50 | 1.5 | 3 | 3920 | 10/10 |
| 实验组6 | 60 | 1.5 | 3 | 3920 | 10/10 |
| 实验组7 | 70 | 1.5 | 3 | 3920 | 10/10 |
| 实验组8 | 75 | 1.5 | 3 | 3920 | 5/10 |
| 实验组9 | 45 | 1.5 | 7 | 3890 | 10/10 |
| 实验组10 | 45 | 1.5 | 0 | 3920 | 6/10 |
| 实验组11 | 45 | 0 | 3 | 3920 | 5/10 |
| 实验组12 | 45 | 3.5 | 3 | 3920 | 4/10 |
| 实验组13 | 45 | 0 | 3 | 3920 | 10/10 |
Claims (20)
- 一种二次电池,包括包装袋、电极组件以及第一极耳,所述电极组件收容于所述包装袋内,所述包装袋设有密封边,所述电极组件包括第一极片、第二极片和隔离膜,所述隔离膜设置于所述第一极片与所述第二极片之间;其中,所述第一极片包括第一集流体、第一活性材料层和第二活性材料层,所述第一集流体包括相对的第一表面和第二表面,所述第一活性材料层设于所述第一表面,所述第二活性材料层设于所述第二表面;所述第一表面包括第一区域,所述第一活性材料层设有显露出所述第一区域的第一凹槽;所述第二表面包括与所述第一区域对应的第二区域,所述第二区域被所述第二活性材料层所覆盖;所述第一极耳包括依次连接的第一连接部、第一弯折部和第二连接部,所述第一连接部从所述密封边伸出所述包装袋外,所述第二连接部至少部分位于所述第一凹槽内并连接所述第一区域;定义所述第一连接部伸出所述包装袋外的方向为第一方向,所述第一区域到所述第二区域的方向为第二方向,所述第一方向垂直于所述第二方向,所述第一弯折部相对于所述第二连接部朝向所述第二方向弯折。
- 根据权利要求1所述的二次电池,其中,定义与所述第一方向和所述第二方向均垂直的方向为第三方向,从所述第三方向观察,所述第一弯折部与所述第二方向所形成的锐角为β,20°≤β≤70°。
- 根据权利要求2所述的二次电池,其中,30°≤β≤60°。
- 根据权利要求1所述的二次电池,其中,所述第一极耳包括相对的第一极耳表面和第二极耳表面,位于所述第二连接部的第一极耳表面连接所述第一区域;所述二次电池包括密封件,所述密封件包括封装部以及第一延伸部,所述封装部用于与所述密封边密封连接,所述第一延伸部自所述封装部朝向所述包装袋内延伸,所述第一延伸部包括第一部分,所述第一部分设于所述第一极耳表面;所述二次电池还包括第一绝缘件,所述第一绝缘件至少部分设于位于所述第一弯折部的第一极耳表面,所述第一绝缘件的一端与所述第一部分抵接。
- 根据权利要求4所述的二次电池,其中,所述第一绝缘件至少覆盖部分 所述第一部分。
- 根据权利要求5所述的二次电池,其中,所述第一绝缘件沿着与所述第一方向相反的方向延伸,以使所述第一绝缘件覆盖部分所述第二活性材料层。
- 根据权利要求4所述的二次电池,其中,所述第一绝缘件与所述第一部分为一体式构件。
- 根据权利要求1所述的二次电池,其中,所述第一集流体包括在所述第一方向上相对的第一边和第二边,所述第一极耳从所述第一边伸出所述第一集流体;所述第一集流体设有沿所述第一边朝向所述第二边的方向凹陷的第一凹口,在所述第二方向上,所述第二连接部与第一凹口至少部分重叠。
- 根据权利要求1所述的二次电池,其中,通过激光照射所述第二连接部使得所述第二连接部与所述第一区域焊接连接。
- 根据权利要求4-9任意一项所述的二次电池,其中,所述第一延伸部还包括设于所述第二极耳表面的第二部分;所述二次电池还包括第二绝缘件,所述第二绝缘件至少部分设于位于所述第一弯折部的第二极耳表面,所述第二绝缘件的一端与所述第二部分抵接。
- 根据权利要求10所述的二次电池,其中,所述第二绝缘件至少覆盖部分所述第二部分。
- 根据权利要求11所述的二次电池,其中,所述第二绝缘件的另一端沿着与所述第一方向相反的方向延伸,以使所述第二绝缘件至少覆盖部分所述第一凹槽。
- 根据权利要求11所述的二次电池,其中,所述第二绝缘件与所述第二部分为一体式构件。
- 根据权利要求1所述的二次电池,其中,所述第二极片包括第二集流体、第三活性材料层和第四活性材料层,所述第二集流体包括相对的第三表面和第四表面,所述第三活性材料层设于所述第三表面,所述第四活性材料层设于所述第四表面;所述第三表面包括第三区域,所述第三活性材料层设有显露出所述第三区域的第二凹槽;所述第四表面包括与所述第三区域对应的第四区域,所述第四区域至少部分未被所述第四活性材料层所覆盖;所述二次电池还包括第二极耳,所述第二极耳包括依次连接的第三连接部、第二弯折部和第四连接部,所述第三连接部从所述密封边伸出所述包装袋外,所述第四连接部至少部分位于所述第二凹槽内并连接所述第三区域,所述第四连接部通过超声波焊接或电阻焊接与所述第三区域连接;所述第二方向为所述第三区域到第四区域的方向,所述第二弯折部朝向所述第二方向弯折。
- 根据权利要求1所述的二次电池,其中,所述第二极片包括第二集流体、第三活性材料层和第四活性材料层,所述第二集流体包括相对的第三表面和第四表面,所述第三活性材料层设于所述第三表面,所述第四活性材料层设于所述第四表面;所述第三表面包括第三区域,所述第三活性材料层设有显露出所述第三区域的第二凹槽;所述第四表面包括与所述第三区域对应的第四区域,所述第四区域被所述第四活性材料层所覆盖;所述二次电池还包括第二极耳,所述第二极耳包括依次连接的第三连接部、第二弯折部和第四连接部,所述第三连接部从所述密封边伸出所述包装袋外,所述第四连接部至少部分位于所述第二凹槽内并连接所述第三区域,所述第四连接部通过激光焊接与所述第三区域连接;所述第二方向为所述第三区域到第四区域的方向,所述第二弯折部朝向所述第二方向弯折。
- 根据权利要求15所述的二次电池,其中,所述第一极片、第二极片和隔离膜叠置并卷绕形成卷绕结构;沿所述第二方向,所述第二连接部和所述第四连接部位于所述卷绕结构的两侧,且所述第一凹槽与所述第二凹槽不重叠。
- 根据权利要求1所述的二次电池,其中,所述第一极片为正极极片,所述第二极片为负极极片,所述第一集流体为铝箔;在所述第一方向上,所述第二极片超出所述第一极片,所述隔离膜超出所述第二极片。
- 根据权利要求4所述的二次电池,其中,所述密封件包含聚乙烯、聚丙烯、聚氨酯、聚对苯二甲酸乙二醇酯或乙烯-丙烯共聚物中的至少一种;和/或所述第一绝缘件包括基材层和设于所述基材层上的粘接层。
- 根据权利要求1所述的二次电池,其中,所述二次电池还包括粘接所述包装袋和所述电极组件的粘结件,所述粘结件粘接于所述包装袋的与所述第一区域相对的内表面。
- 一种电子装置,其特征在于,包括如权利要求1-19中任意一项所述的二次电池。
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| PCT/CN2022/142030 WO2024138323A1 (zh) | 2022-12-26 | 2022-12-26 | 二次电池及电子装置 |
| EP22969480.7A EP4632938A4 (en) | 2022-12-26 | 2022-12-26 | SECONDARY BATTERY AND ELECTRONIC DEVICE |
| CN202280010843.2A CN116964857A (zh) | 2022-12-26 | 2022-12-26 | 二次电池及电子装置 |
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| CN119029276A (zh) * | 2024-09-30 | 2024-11-26 | 宁德新能源科技有限公司 | 二次电池、用电设备及极片的制备方法 |
| CN119108592A (zh) * | 2024-08-30 | 2024-12-10 | 宁德新能源科技有限公司 | 二次电池、用电设备及二次电池的制备方法 |
| CN119153753A (zh) * | 2024-09-30 | 2024-12-17 | 宁德新能源科技有限公司 | 二次电池、用电设备及极片的制造方法 |
| CN119231045A (zh) * | 2024-10-24 | 2024-12-31 | 宁德新能源科技有限公司 | 二次电池及用电装置 |
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| WO2026040732A1 (zh) * | 2024-08-21 | 2026-02-26 | 宁德新能源科技有限公司 | 极片、电极组件及电化学装置 |
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| CN117276820B (zh) * | 2023-11-14 | 2024-03-19 | 宁德新能源科技有限公司 | 电极组件、电化学装置和电子设备 |
| WO2025199922A1 (zh) * | 2024-03-29 | 2025-10-02 | 宁德新能源科技有限公司 | 二次电池和电子装置 |
| CN118712681A (zh) * | 2024-06-24 | 2024-09-27 | 宁德新能源科技有限公司 | 二次电池及电子装置 |
| WO2026000096A1 (zh) * | 2024-06-24 | 2026-01-02 | 宁德新能源科技有限公司 | 二次电池和电子装置 |
| CN118801054A (zh) * | 2024-06-29 | 2024-10-18 | 宁德新能源科技有限公司 | 二次电池及电子装置 |
| CN119069826A (zh) * | 2024-08-29 | 2024-12-03 | 宁德新能源科技有限公司 | 二次电池和电子装置 |
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| CN119029276A (zh) * | 2024-09-30 | 2024-11-26 | 宁德新能源科技有限公司 | 二次电池、用电设备及极片的制备方法 |
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| EP4632938A1 (en) | 2025-10-15 |
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| EP4632938A4 (en) | 2026-02-18 |
| CN116964857A (zh) | 2023-10-27 |
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