WO2024138542A1 - 电池单体、电池及用电装置 - Google Patents
电池单体、电池及用电装置 Download PDFInfo
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- WO2024138542A1 WO2024138542A1 PCT/CN2022/143463 CN2022143463W WO2024138542A1 WO 2024138542 A1 WO2024138542 A1 WO 2024138542A1 CN 2022143463 W CN2022143463 W CN 2022143463W WO 2024138542 A1 WO2024138542 A1 WO 2024138542A1
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- insulating layer
- battery cell
- electrode sheet
- cell according
- positive electrode
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/249—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for aircraft or vehicles, e.g. cars or trains
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
- H01M50/461—Separators, membranes or diaphragms characterised by their combination with electrodes with adhesive layers between electrodes and separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- a battery cell comprising at least one electrode assembly, the electrode assembly comprising a positive electrode sheet, a negative electrode sheet, a separator, an insulating layer and a glue layer;
- the positive electrode sheet, the separator and the negative electrode sheet are stacked and wound, and the electrode assembly has a bending area;
- At least a portion of the insulating layer and at least a portion of the adhesive layer are arranged in the bending area, and the insulating layer is bonded to the positive electrode sheet or the negative electrode sheet through the adhesive layer; in the thickness direction of the insulating layer, the projected area of the adhesive layer is smaller than the projected area of the insulating layer.
- the battery cell provided in the embodiment of the present application can firmly and reliably bond the insulating layer to the bending part of any circle of the positive electrode sheet or the negative electrode sheet through the adhesive layer, so that the insulating layer can be permanently and reliably stabilized in the bending area during the use of the battery cell, which can effectively reduce the risk of displacement and falling off of the insulating layer, thereby ensuring that the insulating layer can be permanently, stably and reliably effective at a specific position during the use of the battery cell.
- the negative impact of the adhesive layer on the extension and deformation properties of the insulating layer can be effectively reduced during the winding and pre-pressing of the electrode assembly and during the use of the battery cell, so that the insulating layer can be extended and deformed adaptively with the electrode sheet, which can facilitate the insulating layer to be durable and reliable during the use of the battery cell, and can effectively reduce the risk of tearing defects in the insulating layer during the use of the battery cell, and can correspondingly ensure and extend the service life of the insulating layer.
- the insulating layer especially the edge of the insulating layer, can be firmly and reliably bonded to the bent part of any circle of positive pole piece or negative pole piece through multiple colloids, especially the colloids arranged near the edge of the insulating layer, so that the insulating layer can be permanently and reliably stabilized and play its role.
- the colloid is a strip-shaped colloid, and a plurality of colloids are arranged at intervals along the width direction of the insulating layer, or a plurality of colloids are arranged at intervals along the length direction of the insulating layer.
- the number of colloids and the occupied area can be effectively reduced, so that the negative impact of the adhesive layer on the extension performance and deformation performance of the insulating layer can be effectively reduced, so that the insulating layer can be extended and deformed adaptively with the pole piece, which can be conducive to ensuring the effectiveness and service life of the insulating layer.
- the colloid is a block-shaped colloid, and at least a portion of the colloid is distributed at each corner of the insulating layer.
- the insulating layer especially the corners and edges of the insulating layer, can be firmly and reliably bonded to the bent part of any circle pole piece through multiple block colloids, especially the block colloids distributed at the corners of the insulating layer, so that the insulating layer can be permanently and reliably stabilized and effective.
- the colloid is block-shaped and multiple block colloids can be optimally arranged on one side of the insulating layer, it is beneficial to effectively reduce the number of colloids and the occupied area on the basis of ensuring the fastening effect of the glue layer on the insulating layer, thereby effectively reducing the negative impact of the glue layer on the extension performance and deformation performance of the insulating layer, so that the insulating layer can be extended and deformed adaptively with the pole piece, which is beneficial to ensure the effectiveness and service life of the insulating layer.
- multiple block colloids can be spaced apart adaptively with the insulating layer, so as to ensure that the fastening effect of the glue layer on the insulating layer is durable and effective.
- the adhesive layer is a hot melt adhesive resistant to electrolyte.
- a hot melt adhesive with the characteristics of rapid bonding, firm bonding, and stable performance can be used to form an adhesive layer, so as to conveniently, quickly, and reliably firmly bond the insulating layer to the bent portion of the pole piece.
- it can also ensure that the adhesive layer can play a lasting and effective fastening effect on the insulating layer during the use of the battery cell.
- the ratio of the projected area of the adhesive layer to the projected area of the insulating layer is 20% to 50%.
- the phenomenon of "dendrites directly causing internal short circuit of the battery cell” can be effectively delayed between the innermost positive electrode sheet and the second innermost negative electrode sheet, and the phenomenon of "dendrites heating up due to short circuit and melting the diaphragm around the dendrite, causing the positive electrode sheet part and the negative electrode sheet part where the diaphragm melts directly contact and short circuit” can be effectively delayed, thereby correspondingly extending the service life of the battery cell and correspondingly improving the safety of the battery cell.
- the bent parts of the positive electrode sheet and the negative electrode sheet i.e., the parts of the electrode sheet corresponding to the bending area
- the radius of curvature will be smaller as the inner circle is formed, which will cause the positive active material in the bent part of the positive electrode sheet to partially fall off (i.e., powdering will occur), and the negative active material in the bent part of the negative electrode sheet will also fall off.
- the radius of curvature of the negative electrode sheet of any circle is relatively smaller than the radius of curvature of the positive electrode sheet of the same circle, the powdering phenomenon of the bent part of the negative electrode sheet during bending will be relatively serious.
- the dendrites will generate heat and melt the diaphragm portion around the dendrite, causing the diaphragm defects to expand, resulting in direct contact and short circuit between the positive and negative pole pieces at the place where the diaphragm melts, thereby aggravating the short circuit phenomenon and seriously affecting the safety of the battery cell.
- FIG. 1 is a schematic diagram of the structure of a vehicle provided in some embodiments of the present application.
- the vehicle can be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle can be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc.
- a battery 1 is arranged inside the vehicle, and the battery 1 can be arranged at the bottom, head or tail of the vehicle.
- the battery 1 is used to power the vehicle, for example, the battery 1 can be used as an operating power source for the vehicle.
- the vehicle may also include a controller 2 and a motor 3, and the controller 2 is used to control the battery 1 to power the motor 3, for example, for the starting, navigation and working power requirements of the vehicle during driving.
- FIG. 2 is a schematic diagram of an exploded view of a battery 1 provided in some embodiments of the present application.
- the battery 1 includes a battery cell 100 and a box 200, wherein the battery cell 100 is contained in the box 200.
- the box 200 is used to provide a storage space for the battery cell 100, and the box 200 can adopt a variety of structures.
- the box 200 can include a first part 201 and a second part 202, wherein the first part 201 and the second part 202 cover each other, and the first part 201 and the second part 202 jointly define a storage space for accommodating the battery cell 100.
- the electrode terminal 50 can be used to electrically connect to the electrode assembly 10 for outputting or inputting electrical energy.
- a pressure relief mechanism (not shown in the figure) for releasing the internal pressure when the internal pressure or temperature of the battery cell reaches a threshold value can also be provided on the end cap 40.
- an insulating member (not shown) may be provided inside the end cap 40 to isolate the electrical connection components in the housing 30 from the end cap 40 to reduce the risk of short circuit.
- the insulating member may be plastic, rubber, etc.
- the positive electrode sheet 11 is a continuous positive electrode sheet 11
- the negative electrode sheet 12 is a continuous negative electrode sheet 12
- the separator 13 is a continuous separator 13.
- Two continuous separators 13 are provided. Before winding, one of the continuous separators 13 is provided between the continuous positive electrode sheet 11 and the continuous negative electrode sheet 12, and the other continuous separator 13 is provided on the side of the continuous negative electrode sheet 12 away from the continuous positive electrode sheet 11, or on the side of the continuous positive electrode sheet 11 away from the continuous negative electrode sheet 12.
- the multiple colloids 151 at least some of the colloids 151 are distributed in the edge area of the insulating layer 14, that is, at least some of the colloids 151 are arranged close to the edge of the insulating layer 14.
- one colloid 151 may be arranged close to one side edge of the insulating layer 14.
- four colloids 151 may be arranged close to four side edges of the insulating layer 14, respectively.
- the number of colloids 151 and the occupied area can be effectively reduced, so that the negative impact of the adhesive layer 15 on the extension performance and deformation performance of the insulating layer 14 can be effectively reduced, so that the insulating layer 14 can be extended and deformed adaptively with the electrode, which is conducive to ensuring the effectiveness and service life of the insulating layer 14.
- the plurality of strip-shaped colloids 151 can be spaced apart, extended and deformed adaptively with the insulating layer 14 , thereby ensuring that the adhesive layer 15 can permanently and reliably fasten the insulating layer 14 .
- the colloid 151 is a strip-shaped colloid 151 , and a plurality of colloids 151 are arranged at intervals along the length direction a of the insulating layer 14 .
- the colloid 151 is a strip-shaped colloid 151, that is, the colloid 151 is extended in a strip shape.
- a plurality of colloids 151 are arranged at intervals along the length direction a of the insulating layer 14, that is, a plurality of colloids 151 are arranged in sequence at intervals along the length direction a of the insulating layer 14.
- the extension direction of the colloid 151 intersects with the length direction a of the insulating layer 14, for example, the extension direction of the colloid 151 may be parallel to the width direction b of the insulating layer 14.
- multiple strip-shaped colloids 151 can be arranged in sequence along the length direction a of the insulating layer 14, so that multiple colloids 151 can be optimally arranged on one side of the insulating layer 14, especially the two colloids 151 that are farthest apart along the length direction a of the insulating layer 14 can be respectively arranged close to the two side edges of the insulating layer 14. Based on this, on the one hand, it can be ensured that each strip-shaped colloid 151 can firmly and reliably bond the insulating layer 14, especially the two side edges of the insulating layer 14, to the bending part of any circle electrode, so that the insulating layer 14 can be permanently and reliably stabilized and play its role.
- the number of colloids 151 and the occupied area can be effectively reduced, so that the negative impact of the adhesive layer 15 on the extension performance and deformation performance of the insulating layer 14 can be effectively reduced, so that the insulating layer 14 can be extended and deformed adaptively with the electrode, which is conducive to ensuring the effectiveness and service life of the insulating layer 14.
- the plurality of strip-shaped colloids 151 can be spaced apart, extended and deformed adaptively with the insulating layer 14 , thereby ensuring that the adhesive layer 15 can permanently and reliably fasten the insulating layer 14 .
- the colloid 151 is a block-shaped colloid 151 , and at least a portion of the colloid 151 is distributed at each corner of the insulating layer 14 .
- the colloid 151 is a block-shaped colloid 151 , for example, it may be a round block-shaped colloid 151 , or for example, it may be a rectangular block-shaped colloid 151 .
- the multiple block colloids 151 at least some of the block colloids 151 are distributed at the corners of the insulating layer 14.
- the insulating layer 14 has four corners on one side along the thickness direction, and four or more block colloids 151 may be respectively arranged at the four corners of the insulating layer 14.
- the block colloids 151 distributed at the corners of the insulating layer 14 may be arranged close to the edge of the insulating layer 14.
- the insulating layer 14, especially the corners and edges of the insulating layer 14, can be firmly and reliably bonded to the bent part of any circle pole piece through multiple block colloids 151, especially the block colloids 151 distributed at the corners of the insulating layer 14, so that the insulating layer 14 can be permanently and reliably stabilized and play its role.
- the colloid 151 is block-shaped, and multiple block colloids 151 can be optimally arranged on one side of the insulating layer 14, it is beneficial to effectively reduce the number of colloids 151 and the occupied area on the basis of ensuring the fastening effect of the glue layer 15 on the insulating layer 14, so that the negative impact of the glue layer 15 on the extension performance and deformation performance of the insulating layer 14 can be effectively reduced, so that the insulating layer 14 can be extended and deformed adaptively with the pole piece, which is beneficial to ensure the effectiveness and service life of the insulating layer 14.
- the plurality of block-shaped colloids 151 can be adaptively spaced apart with the insulating layer 14 , thereby ensuring that the overall fastening effect of the adhesive layer 15 on the insulating layer 14 is durable and effective.
- the adhesive layer 15 is a hot melt adhesive resistant to the electrolyte 20 .
- hot melt adhesive is a plastic adhesive that is solid at room temperature and can be quickly bonded after being heated and melted. Hot melt adhesive has the characteristics of rapid bonding, firm bonding, stable performance and low cost.
- the adhesive layer 15 can be formed by hot melt adhesive with the characteristics of rapid bonding, firm bonding, and stable performance, so as to conveniently, quickly, and reliably firmly bond the insulating layer 14 to the bent portion of the pole piece.
- the adhesive layer 15 can play a lasting and effective fastening effect on the insulating layer 14 during the use of the battery cell.
- the ratio of the projected area of the adhesive layer 15 to the projected area of the insulating layer 14 is 20% to 50%.
- the area ratio of the glue layer 15 relative to the insulating layer 14 can be effectively reduced on the basis of ensuring the fastening effect of the glue layer 15 on the insulating layer 14, thereby effectively reducing the negative impact of the glue layer 15 on the extension and deformation properties of the insulating layer 14, thereby facilitating the insulating layer 14 to extend and deform adaptively with the pole piece, facilitating the insulating layer 14 to perform its function durably and reliably during the use of the battery cell, effectively reducing the risk of tearing defects in the insulating layer 14 during the use of the battery cell, and effectively ensuring and extending the service life of the insulating layer 14.
- the thickness of the adhesive layer 15 is 2 um to 8 um.
- the thickness of the adhesive layer 15 refers to the dimension of the adhesive layer 15 along the thickness direction thereof, that is, the dimension of the adhesive layer 15 along the thickness direction of the insulating layer 14 .
- the thickness of the glue layer 15 can be effectively reduced while ensuring the fastening effect of the glue layer 15 on the insulating layer 14, thereby facilitating the protection and improvement of the energy density of the electrode assembly 10 and the battery cell.
- At least one insulating layer 14 is bonded to the inner side of the innermost positive electrode plate 112 through the adhesive layer 15 .
- an insulating layer 14 may be provided in one bending area 17, or multiple bending areas 17 may be provided with insulating layers 14. In the bending area 17 provided with the insulating layer 14, at least one insulating layer 14 is bonded to the inner side of the bent portion of the innermost positive electrode plate 112 through the adhesive layer 15.
- the bent portion of the innermost positive electrode sheet 112 and the bent portion of the innermost negative electrode sheet 122 will be subjected to greater bending stress and will be more likely to lose powder, resulting in metal precipitation between the bent portion of the innermost positive electrode sheet 112 and the bent portion of the innermost negative electrode sheet 122.
- the bent portion of the innermost positive electrode sheet 112 is relatively located outside the bent portion of the innermost negative electrode sheet 122, metal precipitation is likely to occur from the bent portion of the innermost negative electrode sheet 122 during the charging process of the battery cell.
- the growing dendrites can be insulated and blocked by the insulating layer 14 arranged on the inner side of the bent part of the innermost circle positive electrode sheet 112 to prevent the dendrites from directly contacting and conducting the positive electrode sheet 11 and the negative electrode sheet 12, thereby effectively delaying the phenomenon of "dendrites directly causing internal short circuit of the battery cell” between the innermost circle positive electrode sheet 112 and the innermost circle negative electrode sheet 122 where metal precipitates are easily generated, and effectively delaying the phenomenon of "dendrites generating heat due to short circuit and melting the diaphragm 13 around the dendrites, causing direct contact and short circuit between the positive electrode sheet 11 and the negative electrode sheet 12 at the place where the diaphragm 13 melts", thereby correspondingly extending the service life of
- the insulating layer 14 disposed inside the bent portion of the innermost positive electrode sheet 112 can buffer the extrusion stress borne by the bent portion of the innermost positive electrode sheet 112, so as to reduce the risk of a reduction in active material due to a tear defect in the bent portion of the innermost positive electrode sheet 112; and even the tensile stress borne by the bent portion of the innermost negative electrode sheet 122 can be buffered, so as to reduce the risk of a reduction in active material due to a tear defect in the bent portion of the innermost negative electrode sheet 122.
- the risk of aggravating the metal precipitation phenomenon due to the reduction in active material can be effectively reduced, and the growth rate of the dendrites between the innermost positive electrode sheet 112 and the innermost negative electrode sheet 122 can be effectively alleviated, so as to correspondingly extend the service life of the battery cell and improve the safety of the battery cell.
- At least one insulating layer 14 is bonded to the outer side of the innermost positive electrode plate 112 through the adhesive layer 15 .
- an insulating layer 14 may be provided in one bending area 17, or multiple bending areas 17 may be provided with insulating layers 14. In the bending area 17 provided with the insulating layer 14, at least one insulating layer 14 is bonded to the outer side of the bent portion of the innermost positive electrode sheet 112 through the adhesive layer 15.
- the tensile stress borne by the bent portion of the innermost positive electrode sheet 112 can be buffered by the insulating layer 14 disposed outside the bent portion of the innermost positive electrode sheet 112 during the winding and pre-pressing of the electrode assembly 10 and during the use of the battery cell, so as to reduce the risk of tearing defects in the bent portion of the innermost positive electrode sheet 112 leading to a reduction in active materials; and even the compressive stress borne by the bent portion of the second innermost negative electrode sheet 123 can be buffered, so as to reduce the risk of tearing defects in the bent portion of the second innermost negative electrode sheet 123 leading to a reduction in active materials.
- the risk of aggravating the metal precipitation phenomenon due to the reduction in active materials can be effectively reduced, and the growth rate of the dendrites between the innermost positive electrode sheet 112 and the second innermost negative electrode sheet 123 can be effectively alleviated, so as to correspondingly extend the service life of the battery cell and correspondingly improve the safety of the battery cell.
- the second inner circle negative electrode sheet 123 is a circle of negative electrode sheets 12 located outside the innermost circle positive electrode sheet 112.
- the active ions provided by the outer surface of the innermost circle positive electrode sheet 112 can move to the second inner circle negative electrode sheet 123 and be embedded in the negative active material of the second inner circle negative electrode sheet 123.
- the insulating layer 14 disposed outside the bent portion of the innermost positive electrode sheet 112 can be used to insulate and block the dendrites growing toward it, so as to prevent the dendrites from directly contacting and conducting the innermost positive electrode sheet 112 and the second innermost negative electrode sheet 123.
- the phenomenon of "dendrites directly causing internal short circuits in the battery cell” can be effectively delayed between the innermost positive electrode sheet 112 and the second innermost negative electrode sheet 123, and the phenomenon of "dendrites generating heat due to short circuits melt the diaphragm 13 around the dendrites, causing the positive electrode sheet 11 and the negative electrode sheet 12 to directly contact and short circuit at the place where the diaphragm 13 melts" can be effectively delayed, thereby correspondingly extending the service life of the battery cell and correspondingly improving the safety of the battery cell.
- the bending area 17 is provided with two insulating layers 14, one of which is bonded to the inner side of the innermost positive electrode plate 112 through the glue layer 15, and the other insulating layer 14 is bonded to the outer side of the innermost positive electrode plate 112 through the glue layer 15.
- the bending zone 17 can effectively delay the risk of short circuit through two insulating layers 14 in the "innermost positive electrode sheet 112 and the innermost negative electrode sheet 122" and “innermost positive electrode sheet 112 and the second innermost negative electrode sheet 123" where metal precipitation is easy to occur and the metal precipitation is relatively serious, and effectively relieve the compression stress and tensile stress at the bending part of the innermost positive electrode sheet 112 which is subjected to large bending stress and prone to tearing defects, thereby reducing the risk of bending and tearing, thereby effectively extending the service life of the battery cell and effectively improving the safety of the battery cell.
- the number of insulating layers 14 can also be reduced, thereby ensuring and improving the energy density of the electrode assembly 10 and the battery cell.
- the electrode assembly 10 has a main body region 16 and a bending region 17 disposed at the end side of the main body region 16.
- the insulating layer 14 has a bending section 141 bent at the bending region 17, and an extension section 142 connected to the end of the bending section 141 and disposed at the main body region 16.
- the electrode assembly 10 in a rolled structure has a main area 16 and a bending area 17.
- the main area 16 is a relatively straight part of the rolled structure that is relatively located in the middle, while the bending area 17 is a bent part of the rolled structure that is located at the end side of the main area 16.
- the insulating layer 14 Since the insulating layer 14 is bonded to the preset position of the continuous positive electrode sheet 11 or the continuous negative electrode sheet 12 by the adhesive layer 15 before winding, by adopting the above scheme, the setting area of the insulating layer 14 can be extended accordingly, and the preset position of the insulating layer 14 on the continuous positive electrode sheet 11 or the continuous negative electrode sheet 12 has a wider tolerance range, thereby effectively ensuring that when the electrode assembly 10 is wound, the insulating layer 14 can retain the bent section 141 clamped between the bent part of the electrode sheet and the diaphragm 13, and the extended section 142 that can extend to the main area 16 according to the position tolerance, thereby effectively reducing the accuracy requirements for the preset position of the insulating layer 14 on the continuous positive electrode sheet 11 or the continuous negative electrode sheet 12, and effectively ensuring and improving the production yield of the electrode assembly 10.
- the insulating layer 14 is provided with a plurality of holes. Since the projection area of the adhesive layer 15 in the thickness direction of the insulating layer 14 is smaller than the projection area of the insulating layer 14 in the thickness direction thereof, at least part of the plurality of holes of the insulating layer 14 is not blocked by the adhesive layer 15. The holes not blocked by the adhesive layer 15 are available for the active ions to penetrate freely.
- the active ions can freely penetrate the pores of the insulating layer 14 and the diaphragm 13, and move between the positive electrode sheet 11 and the negative electrode sheet 12. This can effectively ensure that the setting of the insulating layer 14 will not have a significant impact on the charge and discharge process of the battery cell, and can effectively ensure the charge and discharge performance of the battery cell.
- the absolute value of the difference between the porosity of the insulating layer 14 and the porosity of the diaphragm 13 is less than or equal to 25%.
- the porosity of the insulating layer 14 may be greater than the porosity of the diaphragm 13, and the difference between the porosity of the insulating layer 14 and the porosity of the diaphragm 13 is less than or equal to 25%.
- the porosity of the insulating layer 14 is 50%
- the porosity of the diaphragm 13 is 35%
- the difference between the porosity of the insulating layer 14 and the porosity of the diaphragm 13 is 15%.
- the porosity of the insulating layer 14 can be made to be not much different from the porosity of the diaphragm 13. Based on this, active ions can freely and normally penetrate the insulating layer 14 and the diaphragm 13, thereby effectively ensuring that the setting of the insulating layer 14 will not have a significant impact on the charging and discharging process of the battery cell, and effectively ensuring the charging and discharging performance of the battery cell.
- the porosity of the insulating layer 14 can be set to be similar to the porosity of the diaphragm 13, so that the active ions can freely and normally penetrate the insulating layer 14 and the diaphragm 13, and move between the positive electrode plate 11 and the negative electrode plate 12, thereby effectively ensuring that the setting of the insulating layer 14 will not have a significant impact on the charging and discharging process of the battery cell, and effectively ensuring the charging and discharging performance of the battery cell.
- the insulating layer 14 Since the insulating layer 14 is arranged in the bending area 17, the insulating layer 14 is subjected to a certain tensile force during the winding and pre-pressing of the electrode assembly 10 and during the use of the battery cell. Based on this, by adopting the above scheme, it can be ensured that the insulating layer 14 has sufficient tensile strength in its width direction b, which can effectively reduce the risk of fracture and cracking defects of the insulating layer 14 under the action of tension, thereby ensuring and improving the insulation barrier effect of the insulating layer 14 on dendrites growing from the defects of the diaphragm 13, and effectively reducing the risk of dendrites continuing to grow along the fracture and cracking defects of the insulating layer 14, thereby correspondingly extending the service life of the battery cell and correspondingly improving the safety of the battery cell.
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Abstract
Description
Claims (25)
- 一种电池单体,其中,所述电池单体包括至少一个电极组件,所述电极组件包括正极极片、负极极片、隔膜、绝缘层和胶层;所述正极极片、所述隔膜和所述负极极片层叠并卷绕设置,所述电极组件具有弯折区;所述绝缘层的至少一部分和所述胶层的至少一部分设置于所述弯折区,所述绝缘层通过所述胶层粘接至所述正极极片或所述负极极片;在所述绝缘层的厚度方向上,所述胶层的投影面积小于所述绝缘层的投影面积。
- 根据权利要求1所述的电池单体,其中,所述胶层包括多个胶体,至少部分所述胶体分布于所述绝缘层的边沿区域。
- 根据权利要求2所述的电池单体,其中,所述胶体为条状胶体,多个所述胶体沿所述绝缘层的宽度方向间隔设置,或多个所述胶体沿所述绝缘层的长度方向间隔设置。
- 根据权利要求2所述的电池单体,其中,所述胶体为块状胶体,至少部分所述胶体分布于所述绝缘层的各角部。
- 根据权利要求1-4中任一项所述的电池单体,其中,所述胶层为耐电解液的热熔胶。
- 根据权利要求1-4中任一项所述的电池单体,其中,在所述绝缘层的厚度方向上,所述胶层的投影面积与所述绝缘层的投影面积的比值为20%~50%。
- 根据权利要求1-4中任一项所述的电池单体,其中,所述胶层的厚度为2 um ~8 um。
- 根据权利要求1-7中任一项所述的电池单体,其中,所述弯折区中,至少一个所述绝缘层通过所述胶层粘接在最内圈的所述正极极片的内侧。
- 根据权利要求1-7中任一项所述的电池单体,其中,所述弯折区中,至少一个所述绝缘层通过所述胶层粘接在最内圈的所述正极极片的外侧。
- 根据权利要求1-7中任一项所述的电池单体,其中,所述弯折区设有两个所述绝缘层,其中一个所述绝缘层通过所述胶层粘接在最内圈的所述正极极片的内侧,另外一个所述绝缘层通过所述胶层粘接在最内圈的所述正极极片的外侧。
- 根据权利要求1-10中任一项所述的电池单体,其中,所述电极组件具有主体区以及设置于所述主体区的端侧的弯折区;所述绝缘层具有弯曲设置于所述弯折区的弯曲段,以及与所述弯曲段的端部连接且设于所述主体区的延伸段。
- 根据权利要求1-11中任一项所述的电池单体,其中,所述绝缘层设有多个孔。
- 根据权利要求12所述的电池单体,其中,所述绝缘层的孔隙率与所述隔膜的孔隙率的差值的绝对值小于或等于25%。
- 根据权利要求13所述的电池单体,其中,所述绝缘层的孔隙率与所述隔膜的孔隙率的差值的绝对值小于或等于10%。
- 根据权利要求12所述的电池单体,其中,所述绝缘层为聚烯烃隔膜。
- 根据权利要求12所述的电池单体,其中,所述绝缘层的孔隙率为40%~50%。
- 根据权利要求12所述的电池单体,其中,所述绝缘层的孔的孔径为A,所述绝缘层的厚度为B,24≤B/A≤400。
- 根据权利要求17所述的电池单体,其中,所述绝缘层的孔的孔径A为0.05 um~0.5 um。
- 根据权利要求17所述的电池单体,其中,所述绝缘层的厚度B为12 um~20 um。
- 根据权利要求12-19中任一项所述的电池单体,其中,在所述绝缘层的厚度方向上,所述胶层避让所述孔。
- 根据权利要求1-20中任一项所述的电池单体,其中,所述绝缘层在其宽度方向上的抗张强度大于或等于1000 kgf / cm 2。
- 根据权利要求1-20中任一项所述的电池单体,其中,所述绝缘层在其宽度方向上的延伸率大于或等于10%。
- 根据权利要求1-20中任一项所述的电池单体,其中,所述绝缘层在105℃的收缩率为0~3%。
- 一种电池,其中,所述电池包括如权利要求1-23中任一项所述的电池单体。
- 一种用电装置,其中,所述用电装置包括如权利要求24所述的电池,或如权利要求1-23中任一项所述的电池单体。
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| EP22969691.9A EP4571928A4 (en) | 2022-12-29 | 2022-12-29 | BATTERY COMPONENT, BATTERY AND ELECTRICAL DEVICE |
| CN202280094277.8A CN118922981A (zh) | 2022-12-29 | 2022-12-29 | 电池单体、电池及用电装置 |
| PCT/CN2022/143463 WO2024138542A1 (zh) | 2022-12-29 | 2022-12-29 | 电池单体、电池及用电装置 |
| US18/949,912 US20250079532A1 (en) | 2022-12-29 | 2024-11-15 | Battery cell, battery, and electric apparatus |
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| PCT/CN2022/143463 WO2024138542A1 (zh) | 2022-12-29 | 2022-12-29 | 电池单体、电池及用电装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN212810367U (zh) * | 2020-08-21 | 2021-03-26 | 宁德时代新能源科技股份有限公司 | 电极组件、电池单体、电池和用电装置 |
| US20220246992A1 (en) * | 2021-02-04 | 2022-08-04 | Contemporary Amperex Technology Co., Limited | Electrode assembly, battery cell, battery, and manufacturing device and method for electrode assembly |
| CN115020632A (zh) * | 2022-08-10 | 2022-09-06 | 江苏时代新能源科技有限公司 | 正极极片及其制备方法、电极组件、电池单体和电池 |
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| JP4060576B2 (ja) * | 2001-11-20 | 2008-03-12 | 松下電器産業株式会社 | 扁平形電池 |
| EP3244475B1 (en) * | 2015-09-02 | 2021-01-13 | Lg Chem, Ltd. | Separation membrane comprising adhesive coating parts with different adhesion forces, and electrode assembly comprising same |
| CN112803062B (zh) * | 2021-04-08 | 2021-08-03 | 江苏时代新能源科技有限公司 | 电池单体、电池、用电设备及电池单体的制造方法 |
| CN216120372U (zh) * | 2021-08-05 | 2022-03-22 | 宁德时代新能源科技股份有限公司 | 电极组件、电池单体、电池和用电装置 |
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- 2022-12-29 WO PCT/CN2022/143463 patent/WO2024138542A1/zh not_active Ceased
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN212810367U (zh) * | 2020-08-21 | 2021-03-26 | 宁德时代新能源科技股份有限公司 | 电极组件、电池单体、电池和用电装置 |
| US20220246992A1 (en) * | 2021-02-04 | 2022-08-04 | Contemporary Amperex Technology Co., Limited | Electrode assembly, battery cell, battery, and manufacturing device and method for electrode assembly |
| CN115020632A (zh) * | 2022-08-10 | 2022-09-06 | 江苏时代新能源科技有限公司 | 正极极片及其制备方法、电极组件、电池单体和电池 |
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| EP4571928A4 (en) | 2026-01-21 |
| EP4571928A1 (en) | 2025-06-18 |
| US20250079532A1 (en) | 2025-03-06 |
| CN118922981A (zh) | 2024-11-08 |
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