AP9901723A0 - Homogeneous oxidation catalysis using metal complexes. - Google Patents

Homogeneous oxidation catalysis using metal complexes.

Info

Publication number
AP9901723A0
AP9901723A0 APAP/P/1999/001723A AP9901723A AP9901723A0 AP 9901723 A0 AP9901723 A0 AP 9901723A0 AP 9901723 A AP9901723 A AP 9901723A AP 9901723 A0 AP9901723 A0 AP 9901723A0
Authority
AP
ARIPO
Prior art keywords
target compound
lewis acid
catalyst
metal complexes
site
Prior art date
Application number
APAP/P/1999/001723A
Inventor
Terrance J Collins
Scott W Gordon-Wylie
Christine G Woomer
Colin P Horwitz
Enrich S UFFELMAN
Original Assignee
Univ Carnegie Mellon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Carnegie Mellon filed Critical Univ Carnegie Mellon
Publication of AP9901723A0 publication Critical patent/AP9901723A0/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/39—Actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present method provides a method of transferring oxygent to at least one oxidizable site on a target compound. The method includes the steps of selectively oxidizing an oxidizable site on a target compound by reacting in solution; the target compound, a source of oxygen atoms, a source of a lewis acid, such as a proton, alkali, alkaline earth, rare earth, transition metal or main group metal ion, and a catalyst. The catalyst has general structure (i)wherein z is preferably n, but may include o and mo is a transition metal-oxo species. The lewis acid binds to a bidentate secondary site on the ch1 substituent to form a lewis acid-catalyst complex.
APAP/P/1999/001723A 1997-06-20 1998-06-18 Homogeneous oxidation catalysis using metal complexes. AP9901723A0 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87975297A 1997-06-20 1997-06-20
PCT/US1998/012749 WO1998058735A1 (en) 1997-06-20 1998-06-18 Homogeneous oxidation catalysis using metal complexes

Publications (1)

Publication Number Publication Date
AP9901723A0 true AP9901723A0 (en) 1999-12-31

Family

ID=25374825

Family Applications (1)

Application Number Title Priority Date Filing Date
APAP/P/1999/001723A AP9901723A0 (en) 1997-06-20 1998-06-18 Homogeneous oxidation catalysis using metal complexes.

Country Status (13)

Country Link
EP (1) EP0991468A1 (en)
JP (1) JP2002505688A (en)
KR (1) KR20010013986A (en)
CN (1) CN1267238A (en)
AP (1) AP9901723A0 (en)
AU (1) AU8152998A (en)
BR (1) BR9810754A (en)
CA (1) CA2295006A1 (en)
IL (1) IL133484A0 (en)
NO (1) NO996282L (en)
OA (1) OA11237A (en)
PL (1) PL337523A1 (en)
WO (1) WO1998058735A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
JP4104966B2 (en) * 2002-03-06 2008-06-18 花王株式会社 Bleaching catalyst
KR100561058B1 (en) * 2004-09-23 2006-03-17 삼성토탈 주식회사 Catalyst for olefin polymerization containing phenoxy ligands and olefin (co) polymerization method using the same
JP5002761B2 (en) * 2007-03-09 2012-08-15 国立大学法人大阪大学 Oxoporphyrin-based electrode catalyst material
CN104785296B (en) * 2015-04-17 2017-03-08 中国石油大学(华东) A liquid cobalt sulfonated phthalocyanine catalyst for liquefied petroleum gas sweetening
CN106082419B (en) * 2016-05-10 2019-05-31 北京服装学院 Method and application of macrocyclic amide metal complexes for degrading wastewater containing organic pollutants
CN106111199B (en) * 2016-06-21 2018-10-12 中南民族大学 The nanocrystalline preparation and application of more sulfur-bearing aza porphyrin arrays
CN112675908A (en) * 2020-12-23 2021-04-20 清华大学 Aerobic oxidation method of alcohols
CN119977974A (en) * 2024-12-23 2025-05-13 河北工业大学 A benzimidazole-modified nickel phthalocyanine catalyst and its preparation method and application

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
BR9810754A (en) 2000-08-15
NO996282D0 (en) 1999-12-17
KR20010013986A (en) 2001-02-26
AU8152998A (en) 1999-01-04
NO996282L (en) 2000-02-21
WO1998058735A1 (en) 1998-12-30
JP2002505688A (en) 2002-02-19
PL337523A1 (en) 2000-08-28
CA2295006A1 (en) 1998-12-30
IL133484A0 (en) 2001-04-30
CN1267238A (en) 2000-09-20
OA11237A (en) 2003-05-27
EP0991468A1 (en) 2000-04-12

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