AR024357A1 - Un reactor, en particular para reacciones exotermicas y una unidad modular - Google Patents
Un reactor, en particular para reacciones exotermicas y una unidad modularInfo
- Publication number
- AR024357A1 AR024357A1 ARP000102939A ARP000102939A AR024357A1 AR 024357 A1 AR024357 A1 AR 024357A1 AR P000102939 A ARP000102939 A AR P000102939A AR P000102939 A ARP000102939 A AR P000102939A AR 024357 A1 AR024357 A1 AR 024357A1
- Authority
- AR
- Argentina
- Prior art keywords
- heat exchanger
- side wall
- reactor
- spiral
- tubes
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/04—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being spirally coiled
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00141—Coils
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2210/00—Heat exchange conduits
- F28F2210/10—Particular layout, e.g. for uniform temperature distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Fluid Mechanics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente se relaciona con un reactor, en particular para reacciones exotérmicas, del tipo que comprende: una carcasa (2) de forma substancialmentecilíndrica, por lo menos un lecho catalítico (3) contenido en la carcasa, que comprende una pared lateral cilíndrica externa (4), que conforma un espacio libre(8) con dicha carcasa, y una pared lateral cilíndrica interna (5) coaxial con respecto a la anterior, un intercambiador de calor (13) en dicho lecho (3); dondedicho intercambiador de calor (13) está formado por una pluralidad de tubos (15) en la forma de una espiral, un serpentín o semejante, que están encomunicacion con colectores de alimentacion y descarga (14, 16) para un fluido de enfriamiento. Más particularmente, dicho intercambiador de calor (13)comprende una pluralidad de unidades modulares superpuestas y estructuralmente independientes (20), cada una de las cuales incluye por lo menos dos tubos (15)en la forma de una espiral, un serpentín o semejante, dispuestos transversalmente al eje de la carcasa y que envuelven porciones correspondientes (25) de dichapared lateral interna (5) de dicho lecho catalítico (3) y provista de porciones de conexion respectivas (22, 23) con dichos colectores de alimentacion ydescarga (14, 16).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99111538A EP1060788A1 (en) | 1999-06-15 | 1999-06-15 | Isothermal catalytic reactor for exothermic or endothermic heterogeneous reactions |
| PCT/IB2000/000636 WO2000076653A1 (en) | 1999-06-15 | 2000-05-12 | Reactor, in particular for exothermic reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR024357A1 true AR024357A1 (es) | 2002-10-02 |
Family
ID=8238355
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000102939A AR024357A1 (es) | 1999-06-15 | 2000-06-14 | Un reactor, en particular para reacciones exotermicas y una unidad modular |
| ARP000102940A AR024358A1 (es) | 1999-06-15 | 2000-06-14 | Reactor isotermico para reacciones en fase heterogenea exotermicas o endotermicas |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000102940A AR024358A1 (es) | 1999-06-15 | 2000-06-14 | Reactor isotermico para reacciones en fase heterogenea exotermicas o endotermicas |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6926873B1 (es) |
| EP (3) | EP1060788A1 (es) |
| JP (2) | JP4630511B2 (es) |
| CN (2) | CN1152738C (es) |
| AR (2) | AR024357A1 (es) |
| AU (2) | AU773146B2 (es) |
| DE (2) | DE60021747T2 (es) |
| DK (2) | DK1225975T3 (es) |
| WO (2) | WO2000076653A1 (es) |
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1376040A1 (en) * | 2002-06-28 | 2004-01-02 | Methanol Casale S.A. | Multiservice heat exchange unit |
| US7232848B2 (en) | 2002-09-09 | 2007-06-19 | Conocophillips Company | Gas agitated multiphase reactor with stationary catalyst solid phase |
| GB0301323D0 (en) | 2003-01-21 | 2003-02-19 | Johnson Matthey Plc | Methanol synthesis |
| EP1447128A1 (en) * | 2003-02-17 | 2004-08-18 | Methanol Casale S.A. | Method for carrying out chemical reactions in pseudo-isothermal conditions |
| EP1477220A1 (en) * | 2003-05-16 | 2004-11-17 | Methanol Casale S.A. | Chemical reactor |
| US7082573B2 (en) * | 2003-07-30 | 2006-07-25 | America Online, Inc. | Method and system for managing digital assets |
| MY140160A (en) * | 2004-01-28 | 2009-11-30 | Shell Int Research | Heat exchanger for carrying out an exothermic reaction |
| EP1563900A1 (en) * | 2004-02-12 | 2005-08-17 | Methanol Casale S.A. | Pseudo-isothermal chemical reactor for heterogenous chemical reactions |
| DE102004052447A1 (de) * | 2004-10-26 | 2006-04-27 | Alex Von Rohr | Energiespeicher, Wärmetauscheranordnung für einen Energiespeicher, Verfahren zum Betreiben eines Energiespeichers, Energiespeichersystem sowie Verfahren zum Betreiben eines Energiespeichersystems |
| US20060260789A1 (en) * | 2005-05-18 | 2006-11-23 | Yasuaki Nakagawa | Heat exchange unit and heat exchanger using the heat exchange unit |
| GB0510823D0 (en) | 2005-05-27 | 2005-07-06 | Johnson Matthey Plc | Methanol synthesis |
| US20100105847A1 (en) | 2006-01-24 | 2010-04-29 | Intertape Polymer Corp. | Plug flow bulk polymerization of vinyl monomers |
| US7829640B2 (en) * | 2006-08-30 | 2010-11-09 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
| US7906598B2 (en) * | 2006-08-30 | 2011-03-15 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
| CN100425933C (zh) * | 2006-10-23 | 2008-10-15 | 杨文� | 转化分流式热交换器 |
| US20080237090A1 (en) * | 2007-03-30 | 2008-10-02 | Nicholas Musich | Process and system for redcuing the olefin content of a hydrocarbon feed gas and production of a hydrogen-enriched gas therefrom |
| ITVR20070114A1 (it) * | 2007-08-07 | 2009-02-08 | I C I Caldaie S P A | Struttura di reattore chimico |
| RU2371243C1 (ru) * | 2008-04-28 | 2009-10-27 | Дмитрий Львович Астановский | Каталитический реактор |
| WO2010005018A1 (ja) * | 2008-07-10 | 2010-01-14 | 株式会社アルバック | 凍結乾燥装置及び凍結乾燥方法 |
| JP6022770B2 (ja) * | 2008-10-13 | 2016-11-09 | ブルー キューブ アイピー エルエルシー | 塩素化及び/又はフッ素化プロペンの製造方法 |
| US7871587B2 (en) * | 2008-12-23 | 2011-01-18 | Mks Instruments, Inc. | Reactive chemical containment system |
| JP5782038B2 (ja) * | 2009-10-09 | 2015-09-24 | ダウ グローバル テクノロジーズ エルエルシー | 等温多管式反応器及び該反応器を組み込んだプロセス |
| JP5767231B2 (ja) | 2009-10-09 | 2015-08-19 | ダウ グローバル テクノロジーズ エルエルシー | 塩素化及び/又はフッ素化されたプロペン及びより高級なアルケンを製造するプロセス |
| CN102665890B (zh) * | 2009-10-09 | 2016-02-24 | 蓝立方知识产权公司 | 生产氯化和/或氟化丙烯和高级烯烃的绝热活塞流反应器及方法 |
| BR112012007916A2 (pt) * | 2009-10-09 | 2019-09-24 | Dow Global Technologies Llc | processo de etapa para a produção de propenos clorados ou fluorados e processo para preparar 1,1,3,3 - tetrafluorprop-1-eno |
| DE102011014640B4 (de) * | 2010-03-26 | 2015-07-16 | Jürgen Falkenstein | Kühlungs-Vorrichtung für Photovoltaikelemente sowie Verfahren zum Einbinden dieser in ein Gebäude-Heizsystem |
| EA015285B1 (ru) * | 2010-11-26 | 2011-06-30 | Закрытое Акционерное Общество "Карбоника-Ф" | Реактор для переработки твердого топлива |
| RU2010148300A (ru) * | 2010-11-26 | 2012-06-10 | Закрытое Акционерное Общество "Карбоника-Ф" (Ru) | Реактор для переработки твердого топлива |
| US9328974B2 (en) * | 2011-02-21 | 2016-05-03 | Kellogg Brown & Root Llc | Particulate cooler |
| US8946495B2 (en) * | 2011-05-22 | 2015-02-03 | Fina Technology, Inc. | Process for alkylation of toluene to form styrene and ethylbenzene |
| WO2012166394A1 (en) | 2011-05-31 | 2012-12-06 | Dow Global Technologies, Llc | Process for the production of chlorinated propenes |
| JP6212035B2 (ja) | 2011-05-31 | 2017-10-11 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンの製造方法 |
| JP6267114B2 (ja) | 2011-06-08 | 2018-01-24 | ダウ アグロサイエンシィズ エルエルシー | 塩素化および/またはフッ素化プロペンを生成するためのプロセス |
| CN103717557A (zh) | 2011-08-07 | 2014-04-09 | 陶氏环球技术有限责任公司 | 生产氯化的丙烯的方法 |
| CN108929192A (zh) | 2011-08-07 | 2018-12-04 | 蓝立方知识产权有限责任公司 | 生产氯化的丙烯的方法 |
| IN2014CN03748A (es) | 2011-11-21 | 2015-09-25 | Dow Global Technologies Llc | |
| JP6050375B2 (ja) | 2011-12-02 | 2016-12-21 | ブルー キューブ アイピー エルエルシー | クロロアルカンの製造方法 |
| CA2856545A1 (en) | 2011-12-02 | 2013-06-06 | Dow Global Technologies Llc | Process for the production of chlorinated alkanes |
| JP6170068B2 (ja) | 2011-12-13 | 2017-07-26 | ブルー キューブ アイピー エルエルシー | 塩素化プロパン及びプロペンの製造方法 |
| IN2014CN04418A (es) | 2011-12-22 | 2015-09-04 | Dow Global Technologies Llc | |
| WO2013096706A1 (en) | 2011-12-23 | 2013-06-27 | Dow Global Technologies, Llc | Process for the production of alkenes and/or aromatic compounds |
| US9598334B2 (en) | 2012-09-20 | 2017-03-21 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| EP2897930A1 (en) | 2012-09-20 | 2015-07-29 | Dow Global Technologies LLC | Process for the production of chlorinated propenes |
| CA2885329A1 (en) | 2012-09-30 | 2014-03-04 | Dow Global Technologies Llc | Weir quench and processes incorporating the same |
| US10065157B2 (en) | 2012-10-26 | 2018-09-04 | Blue Cube Ip Llc | Mixer and processes incorporating the same |
| CN103044195B (zh) * | 2012-11-30 | 2015-10-21 | 河南心连心化肥有限公司 | 低压甲醇的合成方法 |
| JP6247311B2 (ja) | 2012-12-18 | 2017-12-13 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンを生成するための方法 |
| CA2894168C (en) | 2012-12-19 | 2018-04-24 | Dow Global Technologies Llc | Process for the production of chlorinated propenes |
| CA2901450A1 (en) | 2013-02-27 | 2014-09-04 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| CA2903760C (en) | 2013-03-09 | 2018-02-20 | Blue Cube Ip Llc | Process for the production of chlorinated alkanes |
| CN103752224B (zh) * | 2014-01-02 | 2015-05-20 | 衢州昀睿工业设计有限公司 | 具有螺旋预热通道的合成反应器 |
| CN105642197A (zh) * | 2014-09-24 | 2016-06-08 | 楼韧 | 一种大型反应器及其装置和工艺 |
| JP2017536229A (ja) | 2014-10-30 | 2017-12-07 | サビック グローバル テクノロジーズ ベスローテン フエンノートシャップ | 径方向に設置された冷却板を備えた反応器、及びそれを使用した方法 |
| US10035120B2 (en) | 2014-10-31 | 2018-07-31 | Sabic Global Technologies B.V. | Reactors for separating wax products from lightweight gaseous products of a reaction |
| US9958211B2 (en) | 2015-03-12 | 2018-05-01 | Bayotech, Inc. | Nested-flow heat exchangers and chemical reactors |
| CN105964201B (zh) * | 2016-07-12 | 2018-06-29 | 浙江金氟隆化工装备有限公司 | 一种基于滚塑四氟工艺的钢衬f40反应釜 |
| CA3200543C (en) | 2017-07-28 | 2025-11-18 | Fluid Handling Llc | FLUID CONVEYING METHODS FOR SPIRAL HEAT EXCHANGERS WITH A LATTICE CROSS-SECTION MANUFACTURED BY ADDITIVE MANUFACTURING |
| US10981141B2 (en) * | 2018-06-21 | 2021-04-20 | Battelle Memorial Institute | Enhanced microchannel or mesochannel devices and methods of additively manufacturing the same |
| DE102018007737A1 (de) * | 2018-10-01 | 2020-04-02 | Hitachi Zosen Inova Etogas Gmbh | Festbettanordnung |
| US11920873B2 (en) * | 2018-10-09 | 2024-03-05 | Linde Gmbh | Wound heat exchanger, method for producing a wound heat exchanger and method for exchanging heat between a first fluid and a second fluid |
| CN109289713B (zh) * | 2018-10-18 | 2021-04-20 | 辽宁石油化工大学 | 一种蚊香盘管等温反应器及使用方法 |
| CN109539556A (zh) * | 2019-01-16 | 2019-03-29 | 佛山市无火发热新能源科技有限公司 | 甲醇催化加热装置及加热方法 |
| CN109539555B (zh) * | 2019-01-16 | 2024-09-10 | 深圳市睿碒科技有限公司 | 甲醇催化加热设备及加热方法 |
| CN109701455B (zh) * | 2019-02-25 | 2024-05-03 | 南京国昌化工科技有限公司 | 一种等温等流速双水冷卧式反应器 |
| CN110375564B (zh) * | 2019-07-10 | 2024-08-30 | 南京科技职业学院 | 一种夹套换热器 |
| WO2021149013A1 (en) | 2020-01-24 | 2021-07-29 | Cri Hf | Load-following reactor system, associated facilities, and method of operating the same |
| WO2022153214A1 (en) * | 2021-01-15 | 2022-07-21 | Cri, Ehf | Methanol synthesis reactor |
| US12491484B2 (en) | 2021-01-15 | 2025-12-09 | CRI, hf | Reactor for synthesis of methanol or other products |
| EP4355716A1 (en) | 2021-06-17 | 2024-04-24 | ExxonMobil Chemical Patents Inc. | Processes for dehydrogenating alkane and alkyl aromatic hydrocarbons |
| CN113385110B (zh) * | 2021-07-19 | 2025-01-24 | 上海方民科技有限公司 | 一种模块化固定床反应器 |
| JP7727437B2 (ja) * | 2021-08-04 | 2025-08-21 | 東洋エンジニアリング株式会社 | 反応器及びそれを用いたアンモニア分解混合物の製造方法 |
| CN114247386B (zh) * | 2021-11-24 | 2023-10-13 | 中国五环工程有限公司 | 一种蒸发式等温加氢反应方法及蒸发式等温反应系统 |
| WO2023148605A1 (en) | 2022-02-01 | 2023-08-10 | CRI, hf | Heat integration |
| CN116592670A (zh) * | 2023-05-25 | 2023-08-15 | 佛山市云雄科技有限公司 | 免焊接螺旋换热器 |
| PL448654A1 (pl) * | 2024-05-22 | 2025-11-24 | Centrum Transferu I Promocji Technologii Spółka Z Ograniczoną Odpowiedzialnością | Autotermiczny modułowy reaktor katalityczny ze spiralnym systemem rekuperacji do usuwania metanu o niskich stężeniach ze strumieni o dużym przepływie, zwłaszcza w podziemnych wyrobiskach kopalń |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB391444A (en) * | 1931-10-26 | 1933-04-26 | British Celanese | Improvements in or relating to the manufacture of acetaldehyde |
| US2248993A (en) * | 1936-05-08 | 1941-07-15 | Houdry Process Corp | Apparatus for controlling chemical reactions |
| FR841683A (fr) * | 1937-08-05 | 1939-05-24 | Cie Francaise Procedes Houdry | Moyens pour le traitement, en phase vapeur, d'hydrocarbures, et autres applications analogues |
| DE855258C (de) * | 1949-05-02 | 1952-11-10 | Ici Ltd | Verfahren und Apparatur zur Durchfuehrung chemischer Reaktionen |
| CA878266A (en) * | 1969-04-21 | 1971-08-17 | Brants Henry | Heat exchanger |
| US3663179A (en) * | 1970-04-20 | 1972-05-16 | Chemical Construction Corp | Apparatus for exothermic catalytic reactions |
| AT362397B (de) * | 1976-10-13 | 1981-05-11 | Schober Robert Dipl Ing Dr Tec | Vorrichtung zur erhoehung des ammoniakaufbaues bei der katalytischen ammoniaksynthese |
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| ZA938618B (en) * | 1992-11-20 | 1994-08-04 | Shell Res Ltd | Reactor and process for highly exothermic of endothermic reactions |
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-
1999
- 1999-06-15 EP EP99111538A patent/EP1060788A1/en not_active Withdrawn
-
2000
- 2000-05-12 US US10/009,773 patent/US6926873B1/en not_active Expired - Lifetime
- 2000-05-12 EP EP00925516A patent/EP1225975B1/en not_active Expired - Lifetime
- 2000-05-12 JP JP2001502971A patent/JP4630511B2/ja not_active Expired - Lifetime
- 2000-05-12 WO PCT/IB2000/000636 patent/WO2000076653A1/en not_active Ceased
- 2000-05-12 DE DE60021747T patent/DE60021747T2/de not_active Expired - Lifetime
- 2000-05-12 CN CNB008089469A patent/CN1152738C/zh not_active Expired - Lifetime
- 2000-05-12 DK DK00925516T patent/DK1225975T3/da active
- 2000-05-12 AU AU44236/00A patent/AU773146B2/en not_active Expired
- 2000-06-14 AU AU54049/00A patent/AU773016B2/en not_active Expired
- 2000-06-14 AR ARP000102939A patent/AR024357A1/es unknown
- 2000-06-14 AR ARP000102940A patent/AR024358A1/es unknown
- 2000-06-14 JP JP2001502970A patent/JP4651889B2/ja not_active Expired - Lifetime
- 2000-06-14 DE DE60017907T patent/DE60017907T2/de not_active Expired - Lifetime
- 2000-06-14 DK DK00938789T patent/DK1194222T3/da active
- 2000-06-14 US US10/009,783 patent/US6958135B1/en not_active Expired - Lifetime
- 2000-06-14 CN CN00808947.7A patent/CN1234450C/zh not_active Expired - Lifetime
- 2000-06-14 EP EP00938789A patent/EP1194222B1/en not_active Expired - Lifetime
- 2000-06-14 WO PCT/EP2000/005470 patent/WO2000076652A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP1194222B1 (en) | 2005-02-02 |
| DE60021747T2 (de) | 2006-06-01 |
| EP1194222A1 (en) | 2002-04-10 |
| EP1060788A1 (en) | 2000-12-20 |
| DE60017907T2 (de) | 2006-03-30 |
| DK1194222T3 (da) | 2005-06-13 |
| CN1152738C (zh) | 2004-06-09 |
| CN1234450C (zh) | 2006-01-04 |
| CN1355725A (zh) | 2002-06-26 |
| CN1355724A (zh) | 2002-06-26 |
| US6958135B1 (en) | 2005-10-25 |
| WO2000076652A1 (en) | 2000-12-21 |
| AR024358A1 (es) | 2002-10-02 |
| US6926873B1 (en) | 2005-08-09 |
| AU5404900A (en) | 2001-01-02 |
| AU4423600A (en) | 2001-01-02 |
| DK1225975T3 (da) | 2005-12-05 |
| JP2003524518A (ja) | 2003-08-19 |
| WO2000076653A1 (en) | 2000-12-21 |
| JP4651889B2 (ja) | 2011-03-16 |
| AU773146B2 (en) | 2004-05-20 |
| EP1225975A1 (en) | 2002-07-31 |
| AU773016B2 (en) | 2004-05-13 |
| JP4630511B2 (ja) | 2011-02-09 |
| JP2003501253A (ja) | 2003-01-14 |
| DE60017907D1 (en) | 2005-03-10 |
| DE60021747D1 (de) | 2005-09-08 |
| EP1225975B1 (en) | 2005-08-03 |
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