AR043231A1 - Heterociclos n-aril nitrogenados sustituidos y su uso como herbicidas - Google Patents
Heterociclos n-aril nitrogenados sustituidos y su uso como herbicidasInfo
- Publication number
- AR043231A1 AR043231A1 ARP040100517A ARP040100517A AR043231A1 AR 043231 A1 AR043231 A1 AR 043231A1 AR P040100517 A ARP040100517 A AR P040100517A AR P040100517 A ARP040100517 A AR P040100517A AR 043231 A1 AR043231 A1 AR 043231A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- optionally
- cyano
- halogen
- alkoxy
- Prior art date
Links
- 229910052757 nitrogen Inorganic materials 0.000 title abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title 2
- 239000004009 herbicide Substances 0.000 title 1
- 229910052736 halogen Inorganic materials 0.000 abstract 11
- 150000002367 halogens Chemical class 0.000 abstract 11
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 10
- 125000000217 alkyl group Chemical group 0.000 abstract 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 5
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 5
- -1 nitro, chloro, bromo, cyano, thiocarbamoyl Chemical group 0.000 abstract 5
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- 239000001301 oxygen Substances 0.000 abstract 5
- 229910052717 sulfur Inorganic materials 0.000 abstract 5
- 239000011593 sulfur Substances 0.000 abstract 5
- 125000003545 alkoxy group Chemical group 0.000 abstract 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 2
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 1
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000005108 alkenylthio group Chemical group 0.000 abstract 1
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 1
- 125000005278 alkyl sulfonyloxy group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000005530 alkylenedioxy group Chemical group 0.000 abstract 1
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 1
- 125000005109 alkynylthio group Chemical group 0.000 abstract 1
- 125000002618 bicyclic heterocycle group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 1
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- 125000000464 thioxo group Chemical group S=* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/10—Spiro-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Procedimientos para su preparación y a su uso como agentes para el tratamiento de las plantas. Reivindicación 1: Compuestos de la fórmula (1), en la que: R1 significa hidrógeno, ciano o halógeno; R2 significa nitro, cloro, bromo, ciano, tiocarbamoilo, o significa alquilo o alcoxi con, respectivamente C1-6, sustituidos respectiva y opcionalmente, con halógeno; R3 y R4 significan juntos con el átomo de N, con el que están unidos, heterocícilo monocíclico o bicíclico (con inclusión de espirocíclico) con hasta 10 átomos de carbono, hasta 5 átomos de N y, opcionalmente, además un átomo de O o un átomo de S y que, opcionalmente, contiene 1 ó 2 agrupamientos oxo (C=O), agrupamientos tioxo (C=S) o agrupamientos sulfonilo (SO2) y que, opcionalmente, está sustituido con hidroxilo, con amino, con nitro, con ciano, con carbamoílo, con tiocarbamoilo, con formilo, con halógeno C1-6, con ciano-alquilo (C1-6), con haloalquilo C1-6, con alcoxi(C1-6)-alquilo(C1-6), con alquilo(C1-6)-carbonil-alquilo (C1-6), con alcoxi(C1-6)-carbonil-alquilo (C1-6), con alcoxi C1-6, con haloalcoxi C1-6, con alquiltio C1-6, con haloalquiltio C1-6, con alquilsulfinilo C1-6, con haloalquilsulfinilo C1-6, con alquilsulfonilo C1-6, con haloalquilsulfonilo C1-6, con alquilo(C1-6)-carbonilo, con haloalquilo(C1-6)-carbonilo, alcoxi(C1-6)-carbonilo, con haloalcoxi-carbonilo (C1-6), con alquilamino(C1-6)-carbonilo, con di(alquilo C1-4)-amino-carbonilo, con di-(alquilo C1-4)-amino-sulfonilo, con alquilendioxi C1-3, con haloalquilendioxi C1-3 o con cicloalquilo C3-6; y Z significa uno de los agrupamientos heterocíclicos de resto de grupo de fórmula (2), donde Q1 significa O (oxígeno) o S (azufre); Q2 significa O (oxígeno) o S (azufre); R5 significa hidrógeno, hidroxilo, amino, ciano, o significa alquilo, alcoxi o alcoxicarbonilo con, respectivamente, C1-6 en los grupos alquilo sustituidos respectiva y opcionalmente con ciano, con halógeno o con alcoxi C1-6, significa alquenilo o alquinilo con, respectivamente, C2-6 sustituidos respectivamente, opcionalmente, con ciano, con halógeno o con alcoxi-carbonilo (C1-6), significa cicloalquilo o cicloalquilalquilo con, respectivamente, C3-6 en el grupo cicloalquilo y, opcionalmente, C1-4 en la porción alquilo sustituidos respectiva y opcionalmente con ciano, con halógeno o con alquilo C1-4, o significa fenilo o fenil-alquilo (C1-4) sustituidos respectiva y opcionalmente con ciano, con nitro, con halógeno, con alquilo C1-4, con haloalquilo C1-4, con alcoxi C1-4 o con haloalcoxi C1-4; y R6 significa hidrógeno, amino, nitro, ciano, carboxilo, carbamoílo, tiocarbamoilo, halógeno, significa alquilo, alcoxi, alcoxicarbonilo, alquiltio, alquilsulfinilo, alquilsulfonilo, alquilsulfoniloxi, alquilamino o dialquilamino con, respectivamente, C1-6 en los grupos alquilo sustituidos respectiva y opcionalmente con ciano, con halógeno o con alcoxi C1-4, significa alquenilo, alquinilo, alqueniloxi, alquiniloxi, alqueniltio o alquiniltio con, respectivamente, C2-6 sustituidos respectiva y opcionalmente con ciano o con halógeno, o significa cicloalquilo o cicloalquilo con, respectivamente, C3-6 en el grupo cicloalquilo y, opcionalmente, C1-4 en la porción alquilo sustituidos respectiva y opcionalmente con ciano, con halógeno o con alquilo C1-4, significando, en caso dado, dos restos contiguos -R5 Y R5, R6 Y R6 o R5 y R6- en conjunto alcanodiilo o alquenodiilo con, respectivamente, hasta 6 átomos de carbono sustituidos, opcionalmente y/o interrumpidos, opcionalmente, con O (oxígeno), con S (azufre) o con un agrupamiento de la serie que consiste de -SO-, -SO2-, -NH- o -N(alquilo C1-4)- al principio (o al final), o dentro de la cadena hidrocarbonada, Y1 significa O (oxígeno), S (azufre), SO, SO2, NH, N(alquilo C1-4) o metileno e Y2 significa un enlace sencillo o significa O (oxígeno), S (azufre), SO, SO2, NH o N(alquilo C1-4), siendo diferentes Y1 e Y2 en cada caso particular.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10307142A DE10307142A1 (de) | 2003-02-20 | 2003-02-20 | Substituierte N-Aryl-Stickstoffheterocyclen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR043231A1 true AR043231A1 (es) | 2005-07-20 |
Family
ID=32797566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP040100517A AR043231A1 (es) | 2003-02-20 | 2004-02-19 | Heterociclos n-aril nitrogenados sustituidos y su uso como herbicidas |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060148649A1 (es) |
| EP (1) | EP1599465A1 (es) |
| AR (1) | AR043231A1 (es) |
| BR (1) | BRPI0407710A (es) |
| CA (1) | CA2516590A1 (es) |
| DE (1) | DE10307142A1 (es) |
| MX (1) | MXPA05008862A (es) |
| WO (1) | WO2004074274A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4038054A1 (en) | 2019-10-01 | 2022-08-10 | Bayer Aktiengesellschaft | Pyrimidinedione derivatives |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US356863A (en) * | 1887-02-01 | alletf | ||
| US4868321A (en) * | 1983-11-04 | 1989-09-19 | Fmc Corporation | Isothiocyanate intermediates |
| US5136868A (en) * | 1983-11-04 | 1992-08-11 | Fmc Corporation | Herbicidal 1-aryl-4-substituted-1,4-dihydro-5h-tetrazol-5-ones and sulfur analogs thereof |
| US6906006B1 (en) * | 1988-11-23 | 2005-06-14 | Bayer Aktiengesellschaft | N-arly-substituted nitrogen-containing heterocycles, processes and novel intermediates for their preparation, and their use as herbicides and plant growth regulators |
| DE3839480A1 (de) * | 1988-11-23 | 1990-05-31 | Bayer Ag | N-aryl-stickstoffheterocyclen, verfahren sowie neue zwischenprodukte zu ihrer herstellung und ihre verwendung als herbizide und pflanzenwuchsregulatoren |
| DE4238125A1 (de) * | 1992-11-12 | 1994-05-19 | Bayer Ag | Substituierte Triazolinone |
| US5281571A (en) * | 1990-10-18 | 1994-01-25 | Monsanto Company | Herbicidal benzoxazinone- and benzothiazinone-substituted pyrazoles |
| US5600016A (en) * | 1990-10-18 | 1997-02-04 | Monsanto Company | Benzoyl derivatives and synthesis thereof |
| JP3089621B2 (ja) * | 1990-12-17 | 2000-09-18 | 日産化学工業株式会社 | ウラシル誘導体 |
| US5532416A (en) * | 1994-07-20 | 1996-07-02 | Monsanto Company | Benzoyl derivatives and synthesis thereof |
| US5880290A (en) * | 1994-01-31 | 1999-03-09 | Monsanto Company | Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity |
| GB9412603D0 (en) * | 1994-06-23 | 1994-08-10 | Sandoz Ltd | Organic compounds |
| US5587485A (en) * | 1994-07-20 | 1996-12-24 | Monsanto Company | Heterocyclic- and carbocyclic- substituted benzoic acids and synthesis thereof |
| US5869688A (en) * | 1994-07-20 | 1999-02-09 | Monsanto Company | Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity |
| US5726126A (en) * | 1995-06-02 | 1998-03-10 | American Cyanamid Company | 1-(3-heterocyclyphenyl)-S-triazine-2,6,6-oxo or thiotrione herbicidal agents |
| US5705644A (en) * | 1996-07-24 | 1998-01-06 | American Cyanamid Company | 1-(3-heterocyclphenyl)-s-triazine-2,4,6-oxo or thiotrione herbicidal agents |
| CZ146196A3 (en) * | 1995-06-02 | 1997-05-14 | American Cyanamid Co | 1-(3-heterocyclylphenyl)-s-triazin-2,4,6-oxo or thiotriones and herbicidal agent based thereon |
| US5698708A (en) * | 1996-06-20 | 1997-12-16 | Monsanto Company | Preparation of substituted 3-aryl-5-haloalkyl-pyrazoles having herbicidal activity |
| US5679791A (en) * | 1996-07-25 | 1997-10-21 | American Cyanamid Company | 1-(3-heterocyclylphenyl)-s-triazine-2,4,6-oxo or thiotrione herbicidal agents |
| US6444615B1 (en) * | 2000-04-18 | 2002-09-03 | Dow Agrosciences Llc | Herbicidal imidazolidinetrione and thioxo-imidazolidinediones |
| DE10135043A1 (de) * | 2001-07-11 | 2003-01-30 | Bayer Cropscience Gmbh | Substituierte 3-Heteroaryl(amino- oder oxy)-pyrrolidin-2-one, Verfahren zu deren Herstellung und Verwendung als Herbizide oder als Pflanzenwachstumsregulatoren |
-
2003
- 2003-02-20 DE DE10307142A patent/DE10307142A1/de not_active Withdrawn
-
2004
- 2004-02-10 BR BRPI0407710-5A patent/BRPI0407710A/pt not_active IP Right Cessation
- 2004-02-10 WO PCT/EP2004/001198 patent/WO2004074274A1/de not_active Ceased
- 2004-02-10 US US10/546,128 patent/US20060148649A1/en not_active Abandoned
- 2004-02-10 CA CA002516590A patent/CA2516590A1/en not_active Abandoned
- 2004-02-10 EP EP04709586A patent/EP1599465A1/de not_active Withdrawn
- 2004-02-10 MX MXPA05008862A patent/MXPA05008862A/es unknown
- 2004-02-19 AR ARP040100517A patent/AR043231A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1599465A1 (de) | 2005-11-30 |
| WO2004074274A1 (de) | 2004-09-02 |
| BRPI0407710A (pt) | 2006-02-14 |
| US20060148649A1 (en) | 2006-07-06 |
| MXPA05008862A (es) | 2006-02-17 |
| CA2516590A1 (en) | 2004-09-02 |
| DE10307142A1 (de) | 2004-09-02 |
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