AR087331A1 - Composiciones concentradas de agentes tensioactivos basados en acilamido graso - Google Patents
Composiciones concentradas de agentes tensioactivos basados en acilamido grasoInfo
- Publication number
- AR087331A1 AR087331A1 ARP120102710A ARP120102710A AR087331A1 AR 087331 A1 AR087331 A1 AR 087331A1 AR P120102710 A ARP120102710 A AR P120102710A AR P120102710 A ARP120102710 A AR P120102710A AR 087331 A1 AR087331 A1 AR 087331A1
- Authority
- AR
- Argentina
- Prior art keywords
- hydrogen
- fatty
- acilamide
- weight
- agents based
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- -1 alkylcarbamido Chemical group 0.000 abstract 2
- 239000012141 concentrate Substances 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 125000006289 hydroxybenzyl group Chemical group 0.000 abstract 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 125000004001 thioalkyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Se provee un concentrado de agente tensioactivo que incluye (i) desde el 35% hasta el 90% en peso de un agente tensioactivo basado en acilamido C8-22 que tiene la estructura de fórmula (1) en donde, R es un radical alquilo C7-22 saturado o no saturado; R2 es hidrógeno, CH2COOX o un radical alquilo C1-5; R3 es hidrógeno; R4 se selecciona entre el grupo que consiste en (CH2)mCO2X, (CH2)mSO3X, CH2NR2(CH2)mOH y radicales glucosilo; R5 se selecciona entre el grupo que consiste en hidrógeno, hidroxifenilo, hidroxialquilo C1-6, alquilo C1-10, bencilo, hidroxibencilo, alquilcarbamido, tioalquilo, y radicales carboxílicos; X se selecciona entre hidrógeno, iones metálicos, sales de amina y radicales alquilo C1-4; y el valor de m está comprendido entre 0y 6 y, además, (ii) desde el 10 hasta el 60% en peso de poliol y (iii) desde 1 hasta el 20% en peso de ácidos grasos C8-22 y en el cual, el concentrado tiene un pH que abarca desde 9 hasta 13.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161512434P | 2011-07-28 | 2011-07-28 | |
| US13/343,731 US20130029899A1 (en) | 2011-07-28 | 2012-01-05 | Concentrated fatty acyl amido surfactant compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR087331A1 true AR087331A1 (es) | 2014-03-19 |
Family
ID=47597709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP120102710A AR087331A1 (es) | 2011-07-28 | 2012-07-26 | Composiciones concentradas de agentes tensioactivos basados en acilamido graso |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20130029899A1 (es) |
| EP (1) | EP2737038B1 (es) |
| CN (1) | CN104321418B (es) |
| AR (1) | AR087331A1 (es) |
| BR (1) | BR112014001526B1 (es) |
| EA (1) | EA025478B9 (es) |
| WO (1) | WO2013014264A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8658589B2 (en) * | 2011-07-28 | 2014-02-25 | Conopco, Inc. | Fatty acyl amido based surfactant concentrates |
| EP2870136B1 (en) | 2012-07-03 | 2018-10-24 | Stepan Company | Process for preparing n-acyl amino acid salts |
| WO2015025223A2 (en) * | 2013-07-08 | 2015-02-26 | Rhodia Operations | Low-temperature phase-stable acyl glycinate compositions |
| EP3036214B1 (en) | 2013-08-19 | 2018-02-28 | Stepan Company | Process for preparing n-acyl amino acid salts |
| JP6592874B2 (ja) * | 2013-11-11 | 2019-10-23 | 味の素株式会社 | グリセリンおよびグリシンを含む組成物 |
| US10647782B2 (en) | 2015-09-11 | 2020-05-12 | DDP Specialty Electronic Materials US, Inc. | Polyalkoxy fatty compound |
| WO2017044366A1 (en) | 2015-09-11 | 2017-03-16 | Dow Global Technologies Llc | Polyalkoxy fatty compound |
| PL3478655T3 (pl) | 2016-06-29 | 2021-03-22 | Evonik Operations Gmbh | Sposób wytwarzania tenzydów |
| MX383597B (es) | 2016-07-27 | 2025-03-04 | Unilever Ip Holdings B V | Composiciones para el cuidado personal que comprenden derivados de amida y acido graso |
| CN110642904B (zh) * | 2019-10-10 | 2021-03-23 | 北京工商大学 | 一种含氨基酸和葡萄糖的表面活性剂制备方法 |
| CN110642898B (zh) * | 2019-10-10 | 2021-03-23 | 北京工商大学 | 一种n-脂肪酰基氨基酸酰胺糖胺及其制备工艺 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4328131A (en) * | 1976-12-02 | 1982-05-04 | Colgate-Palmolive Company | Elastic detergent bar of improved elevated temperature stability |
| US4812253A (en) * | 1985-05-13 | 1989-03-14 | The Procter & Gamble Company | Ultra mild skin cleansing composition |
| US5154849A (en) | 1990-11-16 | 1992-10-13 | The Procter & Gamble Company | Mild skin cleansing toilet bar with silicone skin mildness/moisturizing aid |
| AU1877192A (en) * | 1991-03-21 | 1992-10-21 | Procter & Gamble Company, The | Mild personal cleansing bars with improved processability |
| US5294363A (en) * | 1991-09-23 | 1994-03-15 | The Procter & Gamble Company | Mild personal cleansing bar composition with balanced surfactants, fatty acids, and paraffin wax |
| US5300249A (en) * | 1991-09-23 | 1994-04-05 | The Procter & Gamble Company | Mild personal cleansing bar composition with balanced surfactants, fatty acids, and paraffin wax |
| US5529712A (en) * | 1993-03-30 | 1996-06-25 | Ajinomoto Co., Inc. | Detergent composition |
| DE4337031C2 (de) * | 1993-10-29 | 1995-11-30 | Henkel Kgaa | Stückseifen |
| US5510050A (en) | 1993-11-08 | 1996-04-23 | The Procter & Gamble Company | Improved acyl isethionate skin cleansing bar containing liquid polyols and magnesium soap |
| US5496493A (en) | 1994-05-10 | 1996-03-05 | The Procter & Gamble Company | Ultra mild personal cleansing bar containing smaller-sized particulate wax |
| US5710295A (en) * | 1995-06-06 | 1998-01-20 | Hampshire Chemical Corp. | Preparation of alkali metal acyl amino acids |
| US6395692B1 (en) * | 1996-10-04 | 2002-05-28 | The Dial Corporation | Mild cleansing bar compositions |
| FR2786187B1 (fr) * | 1998-11-19 | 2001-11-09 | Univ Paris Curie | Composes du type 2-acylamino-2-deoxy-glucono-1,5-lactone, procede d'obtention, compositions les comportant et utilisations |
| US6297205B1 (en) * | 1999-08-30 | 2001-10-02 | Amway Corporation | Monohydric alcohol-free transparent moisturizing bar soap |
| US20050176615A1 (en) * | 2002-06-25 | 2005-08-11 | Koichi Kinoshita | Detergent compositions |
| WO2005033255A1 (ja) * | 2003-10-03 | 2005-04-14 | Ajinomoto Co., Inc. | 洗浄剤組成物及びその製造方法 |
| JP4696507B2 (ja) * | 2004-09-13 | 2011-06-08 | 味の素株式会社 | 洗浄剤組成物 |
-
2012
- 2012-01-05 US US13/343,731 patent/US20130029899A1/en not_active Abandoned
- 2012-07-26 AR ARP120102710A patent/AR087331A1/es unknown
- 2012-07-27 CN CN201280035208.6A patent/CN104321418B/zh active Active
- 2012-07-27 EP EP12740170.1A patent/EP2737038B1/en active Active
- 2012-07-27 EA EA201490362A patent/EA025478B9/ru not_active IP Right Cessation
- 2012-07-27 BR BR112014001526-0A patent/BR112014001526B1/pt active IP Right Grant
- 2012-07-27 WO PCT/EP2012/064768 patent/WO2013014264A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013014264A1 (en) | 2013-01-31 |
| EA025478B1 (ru) | 2016-12-30 |
| CN104321418A (zh) | 2015-01-28 |
| EA201490362A1 (ru) | 2014-05-30 |
| US20130029899A1 (en) | 2013-01-31 |
| EA025478B9 (ru) | 2017-08-31 |
| CN104321418B (zh) | 2018-02-16 |
| BR112014001526B1 (pt) | 2021-03-02 |
| BR112014001526A2 (pt) | 2017-02-14 |
| EP2737038A1 (en) | 2014-06-04 |
| EP2737038B1 (en) | 2015-09-30 |
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