AR246280A1 - Procedimiento para preparar polibutenos con reactividad realzada. - Google Patents

Procedimiento para preparar polibutenos con reactividad realzada.

Info

Publication number
AR246280A1
AR246280A1 AR88312832A AR31283288A AR246280A1 AR 246280 A1 AR246280 A1 AR 246280A1 AR 88312832 A AR88312832 A AR 88312832A AR 31283288 A AR31283288 A AR 31283288A AR 246280 A1 AR246280 A1 AR 246280A1
Authority
AR
Argentina
Prior art keywords
feed
weight
isobutylene
procedure
polybuteno
Prior art date
Application number
AR88312832A
Other languages
English (en)
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22474744&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR246280(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of AR246280A1 publication Critical patent/AR246280A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B2275/00—Other engines, components or details, not provided for in other groups of this subclass
    • F02B2275/14—Direct injection into combustion chamber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO PARA LA PREPARACION DE UN POLIBUTENO CON REACTIVIDAD REALZADA, UN CONTENIDO TOTAL DE DOBLE ENLACE TERMINAL DE 40%, BASADO EN LA INSATURACION TEORICA TOTAL DEL POLIBUTENO, CONTENIENDO DICHO POLIBUTENO 50% EN PESO DE UNIDADES DE ISOBUTILENO BASADAS EN EL PESO MOLECULAR DEL POLIBUTENO, COMPRENDE: (1) PONER EN CONTACTO UNA ALIMENTACION 10% EN PESO DE ISOBUTILENO, BASADO EN EL PESO DE LA ALIMENTACION, CON UN CATALIZADOR BF3 EN UNA MANERA Y BAJO CONDICIONES SUFICIENTES PARA POLIMERIZAR CATIONICAMENTE DICHA ALIMENTACION EN LA FASE LIQUIDA PARA FORMAR DICHO POLIBUTENO,LLEVANDOSE A CABO LA POLIMERIZACION A UNA TEMPERATURA DE -20*C HASTA +25*C EN PRESENCIA DE UN PROMOTOR CATALITICO (A) A UN TIEMPO DE POLIMERIZACION PROMEDIO DE 12 HASTA 40 MINUTOS, (B) A UNA RELACION DE MILIMOLES DE BF3 A MOLES DE ISOBUTILENO EN LA ALIMENTACION DE 0,1:1 HASTA 5:1 Y (C) A UNA CONVERSION DE ISOBUTILENO DE 70%; Y (2) ENFRIAR INMEDIATAMENTE EL PRODUCTO DE POLIBUTENO CON UN MEDIO REFRIGERANTE SUF ICIENTE PARA DESACTIVAR DICHO CATALIZADOR BF3.
AR88312832A 1987-12-22 1988-12-22 Procedimiento para preparar polibutenos con reactividad realzada. AR246280A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/136,867 US4849572A (en) 1987-12-22 1987-12-22 Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647)

Publications (1)

Publication Number Publication Date
AR246280A1 true AR246280A1 (es) 1994-07-29

Family

ID=22474744

Family Applications (1)

Application Number Title Priority Date Filing Date
AR88312832A AR246280A1 (es) 1987-12-22 1988-12-22 Procedimiento para preparar polibutenos con reactividad realzada.

Country Status (11)

Country Link
US (1) US4849572A (es)
EP (1) EP0322241B1 (es)
JP (1) JP2807887B2 (es)
KR (1) KR0140716B1 (es)
AR (1) AR246280A1 (es)
AT (1) ATE113618T1 (es)
BR (1) BR8806789A (es)
CA (1) CA1290093C (es)
DE (2) DE3843631B4 (es)
FR (1) FR2624865B1 (es)
GB (1) GB2211854B (es)

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EP0322241B1 (en) 1994-11-02
DE3843631A1 (de) 1989-07-06
DE3852011D1 (de) 1994-12-08
CA1290093C (en) 1991-10-01
GB2211854B (en) 1991-07-10
KR0140716B1 (ko) 1998-07-01
JPH01259011A (ja) 1989-10-16
JP2807887B2 (ja) 1998-10-08
ATE113618T1 (de) 1994-11-15
DE3852011T2 (de) 1995-03-09
US4849572A (en) 1989-07-18
FR2624865A1 (fr) 1989-06-23
EP0322241A3 (en) 1991-06-12
DE3843631B4 (de) 2006-04-13
GB2211854A (en) 1989-07-12
GB8829972D0 (en) 1989-02-15
KR890009990A (ko) 1989-08-05
BR8806789A (pt) 1989-08-29
EP0322241A2 (en) 1989-06-28
FR2624865B1 (fr) 1993-08-06

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