AT109083B - Process for the production of hot cathodes from hafnium. - Google Patents

Process for the production of hot cathodes from hafnium.

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Publication number
AT109083B
AT109083B AT109083DA AT109083B AT 109083 B AT109083 B AT 109083B AT 109083D A AT109083D A AT 109083DA AT 109083 B AT109083 B AT 109083B
Authority
AT
Austria
Prior art keywords
hafnium
production
hot cathodes
hot
cathodes
Prior art date
Application number
Other languages
German (de)
Original Assignee
Siemens Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Ag filed Critical Siemens Ag
Application granted granted Critical
Publication of AT109083B publication Critical patent/AT109083B/en

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  • Manufacture And Refinement Of Metals (AREA)

Description

  

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   Es ist bereits vorgeschlagen worden, Glühkathoden aus Hafnium oder Hafniumlegierungen herzustellen. Auch ist vorgesehlagen worden.   @berzüge aus Metallen mit spezifisch   hoher Elektronenemission durch Reduktion einer Verbindung des betreffenden Metalles herzustellen. 



   Gemäss der Erfindung erhält man besonders wirksame Glühkathoden aus Hafnium, wenn man auf 
 EMI1.2 
 mit Hilfe eines Alkalimetalles herstellt. Man kann beispielsweise von Oxyd des Hafniums ausgehen und das Oxyd durch Alkalimetalle reduzieren. Ein besonderer Vorteil des Verfahrens gemäss der Erfindung besteht darin, dass das   Reduktionsmittel schon bei verhältnismässig niedrigen Temperaturen   verdampft und deshalb leicht von der   Glühkathode   entfernt werden kann. so dass es die Elektronenemission des   Hafniums   nicht   beeinträchtigt.   Es hat sich nämlich gezeigt. dass die Emissionsfähigkeit der Glühkathode von der Art ihrer Reduktion abhängt.

   Es ist nicht gleichgültig, ob man zur Reduktion Alkalimetalle oder 
 EMI1.3 
   Reduktionsmittels   die Emissionsfähigkeit herabgesetzt, was wahrscheinlich auf Karbidbildung zurückzuführen ist. Bei der Verwendung von Alkalimetallen als Reduktionsmittel dagegen geht einerseits die Reduktion rasch vor sich und anderseits kann   man   durch eine verhältnismässig geringe Erhitzung der Kathode erreichen, dass das Reduktionsmittel verdampft. 



    PATENT-ANSPRL'CHH:     1.   Verfahren zur Herstellung von Glühkathoden aus Hafnium, bei dem ein Glühfaden aus hochschmelzendem Metall mit einem Überzug aus Hafnium versehen wird, dadurch gekennzeichnet, dass ein. eine Hafniumverbindung enthaltender Überzug des   Glühfadens durch   ein Alkalimetall reduziert wird 

**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.



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   It has already been proposed to produce hot cathodes from hafnium or hafnium alloys. It has also been proposed. @ Produce coatings from metals with a specifically high electron emission by reducing a compound of the metal in question.



   According to the invention, particularly effective hot cathodes made of hafnium are obtained when one is on
 EMI1.2
 with the help of an alkali metal. One can, for example, start from the oxide of hafnium and reduce the oxide with alkali metals. A particular advantage of the method according to the invention is that the reducing agent evaporates even at relatively low temperatures and can therefore be easily removed from the hot cathode. so that it does not affect the electron emission of the hafnium. Because it has been shown. that the emissivity of the hot cathode depends on how it is reduced.

   It does not matter whether one goes for reduction or alkali metals
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   Reducing agent reduced the emissivity, which is probably due to carbide formation. When using alkali metals as reducing agents, on the one hand, the reduction proceeds quickly and, on the other hand, a relatively low heating of the cathode can cause the reducing agent to evaporate.



    PATENT-ANSPRL'CHH: 1. A method for the production of hot cathodes made of hafnium, in which a filament made of high-melting metal is provided with a coating of hafnium, characterized in that a. a coating of the filament containing a hafnium compound is reduced by an alkali metal

** WARNING ** End of DESC field may overlap beginning of CLMS **.

 

Claims (1)

EMI1.4 **WARNUNG** Ende CLMS Feld Kannt Anfang DESC uberlappen**. EMI1.4 ** WARNING ** End of CLMS field may overlap beginning of DESC **.
AT109083D 1924-12-17 1925-10-14 Process for the production of hot cathodes from hafnium. AT109083B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE109083X 1924-12-17

Publications (1)

Publication Number Publication Date
AT109083B true AT109083B (en) 1928-03-10

Family

ID=5651594

Family Applications (1)

Application Number Title Priority Date Filing Date
AT109083D AT109083B (en) 1924-12-17 1925-10-14 Process for the production of hot cathodes from hafnium.

Country Status (1)

Country Link
AT (1) AT109083B (en)

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