AT128247B - Process for the production of high-melting wax products similar to carnauba wax. - Google Patents
Process for the production of high-melting wax products similar to carnauba wax.Info
- Publication number
- AT128247B AT128247B AT128247DA AT128247B AT 128247 B AT128247 B AT 128247B AT 128247D A AT128247D A AT 128247DA AT 128247 B AT128247 B AT 128247B
- Authority
- AT
- Austria
- Prior art keywords
- production
- wax
- carnauba wax
- melting
- products similar
- Prior art date
Links
- 238000002844 melting Methods 0.000 title claims description 10
- 239000004203 carnauba wax Substances 0.000 title claims description 8
- 235000013869 carnauba wax Nutrition 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 239000001993 wax Substances 0.000 title claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 150000002314 glycerols Chemical class 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- ROOBHHSRWJOKSH-UHFFFAOYSA-N hentriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO ROOBHHSRWJOKSH-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- KOZAWTKVXJYUKG-UHFFFAOYSA-N pentatriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO KOZAWTKVXJYUKG-UHFFFAOYSA-N 0.000 description 2
- DMCJFWXGXUEHFD-UHFFFAOYSA-N pentatriacontan-18-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCC DMCJFWXGXUEHFD-UHFFFAOYSA-N 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- VETNMUXXCNEZFK-UHFFFAOYSA-N Montanone Natural products CC1CC(OC(=O)C)C2C(OC(=O)C2=C)C3C1C(=O)C=C3C VETNMUXXCNEZFK-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- VETNMUXXCNEZFK-OYBMWFINSA-N [(3aR,4S,6S,6aS,9aR,9bR)-6,9-dimethyl-3-methylidene-2,7-dioxo-4,5,6,6a,9a,9b-hexahydro-3aH-azuleno[4,5-b]furan-4-yl] acetate Chemical compound O=C(O[C@@H]1[C@H]2C(=C)C(=O)O[C@@H]2[C@H]2C(C)=CC(=O)[C@H]2[C@@H](C)C1)C VETNMUXXCNEZFK-OYBMWFINSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- -1 ceryl palmitate Chemical compound 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- ODSVXDFDFCXJDV-UHFFFAOYSA-N tritetracontan-22-one Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCCCCCC ODSVXDFDFCXJDV-UHFFFAOYSA-N 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Landscapes
- Developing Agents For Electrophotography (AREA)
- Fats And Perfumes (AREA)
Description
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Verfahren zur Herstellung von dem Carnaubawachs ähnlichen hochschmelzenden Wachsprodukten.
Es ist bekannt, dass das im wesentlichen aus dem 12-oxystearinsäuretriglyeerid bestehende hydrierte (gehärtete) Rizinusöl einen Schmelzpunkt besitzt, der dem des Carnaubawachses sehr nahe liegt. Trotzdem aber ist das Produkt an Stelle des Camaubawachses nicht verwendbar, da es, in seiner
EMI1.1
lässt. Auch besitzt es nicht das Bindungsvermögen für Lösungsmittel, welches das Carnaubawachs gerade für die Zwecke der Fabrikation von Schuhcreme, Bohnermassen u. dgl. geeignet macht. Eine aus einem Teil gehärteten Rizinusöl und drei Teilen Terpentinöl hergestellte Schuhcreme lässt jedenfalls das glatte Aussehen einer Carnaubawachscreme vermissen, zeigt kristallinische Ausscheidungen und lässt sich beispielsweise durch Fingerdruck leicht in das kristallinische Glycerid und das verwandte Lösungsmittel trennen.
Es wurde nun aber gefunden, dass man das gehärtete Rizinusöl dennoch vorzüglich zur Herstellung carnaubawachsähnlicher Präparationen verwenden kann, wenn man dasselbe gleichzeitig mit hochmolekularen und hochschmelzenden Oxo-oder Oxyverbindungen der Fettreihe bzw. deren Derivaten zusammenschmilzt oder in Anwendung bringt. Die so erhaltenen Produkte besitzen Aussehen, Bruch und Lösungsmittel (Terpentin) bindungsvermögen des echten Carnaubawachses und sind auch äusserlich kaum von diesem zu unterscheiden. Die Schmelzpunkte liegen ebenfalls denen des Carnaubawachses sehr nahe.
Ein für die Herstellung von Schuhcreme und Bohnermassen durchaus geeignetes Produkt erhält
EMI1.2
artige Masse ohne kristallinische Ausscheidungen, die alle Eigenschaften der heute als Schuhputzmittel, Bohnermassen u. dgl. üblichen Fabrikate aufweist. An Stelle des hier benutzten Behenons können mit gleichem Erfolge auch die Ketone anderer Fettsäuren, wie beispielsweise das Stearon (F = 880) oder Montanon, Verwendung finden.
Die gleichen Erfolge erzielt man aber auch, wenn an Stelle der Ketone hochschmelzende Alkohole der aliphatischen Reihe, wie beispielsweise Pentatriakontanol (18) (F = 920), Hentriakontanol (16) (F = 85'60) u. a., oder hochschmelzende Derivate solcher Alkohole, wie beispielsweise der Oxalsäuredimyricylester (F=91 ) oder der Palmitinsäurecerylester (F=79 ), verwendet werden. Auch ist es keineswegs nötig, lediglich chemisch reine Produkte zu verarbeiten, ein geringer Säuregehalt oder andere Verunreinigungen wirken in keiner Weise störend, wenn nur der Schmelzpunkt der Zusatzstoffe 700 nicht wesentlich unterschreitet.
Gegebenenfalls sind daher auch Zusatzstoffe verwendbar, die, wie oxydiertes Montanwachs, erhebliche Mengen hochsehmelzender ketonartiger Verbindungen u. dgl. enthalten.
An Stelle des gehärteten Rizinusöles können schliesslich in gleicher Weise auch die Glykolester oder die Mono-und Diglyceride der 12-Oxystearinsäure verwandt werden, die sich in ihrem Schmelzpunkt nur wenig von dem des Triglycerids unterscheiden.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for the production of high-melting wax products similar to carnauba wax.
It is known that the hydrogenated (hardened) castor oil consisting essentially of 12-oxystearic acid triglyceride has a melting point which is very close to that of carnauba wax. Nevertheless, the product cannot be used in place of the camauba wax because it, in its
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leaves. It also does not have the ability to bind solvents, which carnauba wax is used for the production of shoe polish, floor polish and the like. Like. Makes suitable. A shoe polish made from one part hardened castor oil and three parts turpentine oil lacks the smooth appearance of a carnauba wax cream, shows crystalline precipitates and can easily be separated into the crystalline glyceride and the related solvent, for example by pressing your finger.
It has now been found, however, that the hydrogenated castor oil can still be used excellently for the production of carnauba wax-like preparations if it is melted or used simultaneously with high-molecular and high-melting oxo or oxy compounds of the fat series or their derivatives. The products obtained in this way have the appearance, breakage and solvent (turpentine) binding capacity of real carnauba wax and can hardly be distinguished from it externally. The melting points are also very close to those of carnauba wax.
A product that is perfectly suitable for the production of shoe polish and floor polish is obtained
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like mass without crystalline precipitations, which has all the properties of today's shoe polish, floor polish, etc. Like. Usual makes. Instead of the behenon used here, the ketones of other fatty acids, such as stearon (F = 880) or montanone, can also be used with the same success.
The same successes are also achieved if, instead of the ketones, high-melting alcohols of the aliphatic series, such as, for example, pentatriacontanol (18) (F = 920), hentriacontanol (16) (F = 85'60) and the like. a., or high-melting derivatives of such alcohols, such as dimyricyl oxalate (F = 91) or ceryl palmitate (F = 79), can be used. It is also by no means necessary to process only chemically pure products; a low acid content or other impurities have no disruptive effect if only the melting point of the additives is not significantly below 700.
If necessary, additives can therefore also be used which, like oxidized montan wax, considerable amounts of high-boiling ketone-like compounds and the like. like. included.
Finally, instead of the hardened castor oil, the glycol esters or the mono- and diglycerides of 12-oxystearic acid, which differ only slightly in their melting point from that of the triglyceride, can also be used in the same way.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE128247X | 1930-02-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT128247B true AT128247B (en) | 1932-05-10 |
Family
ID=5662463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT128247D AT128247B (en) | 1930-02-15 | 1930-12-22 | Process for the production of high-melting wax products similar to carnauba wax. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT128247B (en) |
-
1930
- 1930-12-22 AT AT128247D patent/AT128247B/en active
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