AT153320B - Process for the production of oil-soluble bismuth salts of organic acids. - Google Patents
Process for the production of oil-soluble bismuth salts of organic acids.Info
- Publication number
- AT153320B AT153320B AT153320DA AT153320B AT 153320 B AT153320 B AT 153320B AT 153320D A AT153320D A AT 153320DA AT 153320 B AT153320 B AT 153320B
- Authority
- AT
- Austria
- Prior art keywords
- oil
- organic acids
- bismuth salts
- acid
- production
- Prior art date
Links
- 150000001621 bismuth Chemical class 0.000 title claims description 8
- 150000007524 organic acids Chemical class 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 235000005985 organic acids Nutrition 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 2
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229960001138 acetylsalicylic acid Drugs 0.000 description 1
- REKWPXFKNZERAA-UHFFFAOYSA-K bismuth;2-carboxyphenolate Chemical compound [Bi+3].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O REKWPXFKNZERAA-UHFFFAOYSA-K 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- XIKIUQUXDNHBFR-UHFFFAOYSA-N monobenzyl phthalate Chemical compound OC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 XIKIUQUXDNHBFR-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229960003424 phenylacetic acid Drugs 0.000 description 1
- 239000003279 phenylacetic acid Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Herstellung von öllöslichen Wismutsalzen organischer Säuren.
EMI1.1
<Desc/Clms Page number 2>
2. Man löst 34 g Camphenilansäure und 18 g Acetylsalicylsäure zusammen als Natriumsalze in 150 em3 Wasser und lässt dazu eine Lösung von 49 g Wismutnitrat in 450 cm3 20%iger Mannitlösung fliessen. Die Weiterverarbeitung geschieht nach Beispiel 1.
In ähnlicher Weise können unter anderm die gemischten Wismutsalze aus 2 Mol Camphenilansäure und 1 Mol Ölsäure oder 2 Mol Campholytsäure und 1 Mol Stearinsäure oder 2 Mol Naphthensäure und 1 Mol Phthalsäuremonobenzylester oder 2 Mol Camphenilansäure und 1 Mol Oleylsarkosin oder 2 Mol Camphenilansäure und 1 Mol Phenylessigsäure usw. hergestellt werden.
3. In 150 g Olivenöl werden 60 g Camphenilansäure aufgelöst und diese Lösung so lange mit 10 g Wismutsalicylat erwärmt, bis Lösung eingetreten ist. Die Lösung ist klar und stabil.
4. 31 g Campholytsäure und 14 g Salicylsäure werden zusammen in einer Mischung von 75 em3 Glycerin und 75 cm3 Wasser als Natronsalze gelöst ; dazu lässt man eine Lösung von 49 g Wismutnitrat
EMI2.1
PATENT-ANSPRÜCHE :
1. Verfahren zur Herstellung von öllöslichen Wismutsalzen organischer Säuren, dadurch gekennzeichnet, dass man als Säurekomponente zwei verschiedene organische Säuren verwendet, von denen nur eine für sich befähigt ist, leicht öllösliche Wismutsalze zu bilden.
<Desc / Clms Page number 1>
Process for the production of oil-soluble bismuth salts of organic acids.
EMI1.1
<Desc / Clms Page number 2>
2. 34 g of camphenilanic acid and 18 g of acetylsalicylic acid are dissolved together as sodium salts in 150 cubic meters of water and a solution of 49 g of bismuth nitrate in 450 cm3 of 20% mannitol solution is allowed to flow. The further processing takes place according to example 1.
Similarly, the mixed bismuth salts of 2 moles of camphenilanic acid and 1 mole of oleic acid or 2 moles of campholytic acid and 1 mole of stearic acid or 2 moles of naphthenic acid and 1 mole of monobenzyl phthalate or 2 moles of camphenilanic acid and 1 mole of oleylsarcosine or 2 moles of camphenilanic acid and 1 mole of phenylacetic acid can be used in a similar manner . getting produced.
3. 60 g of camphenilanic acid are dissolved in 150 g of olive oil and this solution is heated with 10 g of bismuth salicylate until it has dissolved. The solution is clear and stable.
4. 31 g of campholytic acid and 14 g of salicylic acid are dissolved together as sodium salts in a mixture of 75 cubic meters of glycerine and 75 cm3 of water; a solution of 49 g of bismuth nitrate is allowed to do so
EMI2.1
PATENT CLAIMS:
1. A process for the preparation of oil-soluble bismuth salts of organic acids, characterized in that two different organic acids are used as the acid component, only one of which is capable of forming readily oil-soluble bismuth salts.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE153320T | 1934-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT153320B true AT153320B (en) | 1938-05-10 |
Family
ID=29412252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT153320D AT153320B (en) | 1934-05-04 | 1935-05-02 | Process for the production of oil-soluble bismuth salts of organic acids. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT153320B (en) |
-
1935
- 1935-05-02 AT AT153320D patent/AT153320B/en active
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