AT220911B - Process for colored enamelling of aluminum and aluminum alloys - Google Patents

Process for colored enamelling of aluminum and aluminum alloys

Info

Publication number
AT220911B
AT220911B AT117660A AT117660A AT220911B AT 220911 B AT220911 B AT 220911B AT 117660 A AT117660 A AT 117660A AT 117660 A AT117660 A AT 117660A AT 220911 B AT220911 B AT 220911B
Authority
AT
Austria
Prior art keywords
sep
aluminum
colored
enamelling
probably
Prior art date
Application number
AT117660A
Other languages
German (de)
Inventor
Hans Dr Kyri
Horst Dr Weber
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Application granted granted Critical
Publication of AT220911B publication Critical patent/AT220911B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0009Pigments for ceramics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Glass Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Description

  

   <Desc/Clms Page number 1> 
 



  Verfahren zur farbigen Emaillierung von Aluminium und
Aluminiumlegierungen 
 EMI1.1 
 

 <Desc/Clms Page number 2> 

 unddioxydhaItigen   Aluminiumemailfritte   und 7   Gew.-Teilen eines TiO2-Rutilwei#pigmentes   nass vermahlen. 



  Der entstandene Schlicker wird auf Aluminiumblech aufgetragen, getrocknet und bei 5400C 6 Minuten lang eingebrannt. Das Email zeigt eine leuchtend zitronengelbe Farbe. Der Farbton entspricht dem monochromatischen Spektrallicht der Wellenlänge   571-573 mit.   Die Farbe zeigt eine Sättigung von 0, 51 bis 0, 53 Anteilen und eine Helligkeit von 56 bis 58%. Farbton, Sättigung und Helligkeit wurden durch trichromatische Farbmessung nach den Vorschriften des DIN-Blattes 5033 bestimmt. Als Mass für die Sättitung wird der spektrale Farbanteil   Pe   verwendet. Die Helligkeitswerte entsprechen den Hellbezugswerten A. 



   Beispiel2 :7Gew.-TeileeinesockerorangegefärbtenRutil-FarbkörpersderchemischenZusammensetzung 0,05 CoO. 0,06 Sb2O2 (x > 3. vermutlich 4).   TiO   werden mit 100 Gew.-Teilen einer bleiund titandioxydhaltigen Aluminiumemailfritte nass vermahlen. Der entstandene Schlicker wird auf Aluminiumblech aufgetragen, getrocknet und bei 5400C 6 Minuten lang eingebrannt. Das Email zeigt eine Ockerorange-Farbe des Farbtons von 579 bis 582   mg,   der Sättigung von 0, 56 bis 0, 58 Anteilen und der Helligkeit von 24 bis 25%. 
 EMI2.1 
 eis piel 3 : 7 Gew. -Teile eines dunkelbraun gefärbten Rutil-Farbkörpers der chemischen Zusam-Aluminiumblech aufgetragen, getrocknet und bei 5400C 6 Minuten lang eingebrannt.

   Das Email zeigt eine tiefbraune Farbe des Farbtons von 592 bis 596   mg,   der Sättigung von 0, 26 bis 0, 30 Anteilen und der Helligkeit von 10 bis   le.   



   Tabelle :
Gitterkonstanten einiger Rutil-Pigmente 
 EMI2.2 
 
<tb> 
<tb> Pigment <SEP> a <SEP> (A) <SEP> c <SEP> (A) <SEP> c/a
<tb> TiO2-Rutil <SEP> 4,58 <SEP> 2,95 <SEP> 0,644
<tb> 0, <SEP> 05 <SEP> Ni <SEP> 0. <SEP> 0, <SEP> 04 <SEP> SbO <SEP> (x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 646 <SEP> 
<tb> O, <SEP> 075NiO. <SEP> 0, <SEP> 06 <SEP> Sbpx <SEP> (x <SEP> = <SEP> > <SEP> 3, <SEP> vermutlich <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 60 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP> 
<tb> 0, <SEP> 05 <SEP> CoO. <SEP> 0, <SEP> 04 <SEP> SbzOx <SEP> (x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4). <SEP> TiO2 <SEP> 4,59 <SEP> 2,96 <SEP> 0,645
<tb> 0, <SEP> 075 <SEP> CoO. <SEP> 0, <SEP> 06 <SEP> SbzOx <SEP> (x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4).

   <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP> 
<tb> 0, <SEP> 05 <SEP> CuO. <SEP> 0,04 <SEP> Sb2Ox <SEP> (x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4). <SEP> TiO2 <SEP> 4,59 <SEP> 2,97 <SEP> 0,646
<tb> 0,075 <SEP> CuO <SEP> . <SEP> 0,06 <SEP> Sb2Ox(x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 60 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP> 
<tb> 0,05 <SEP> MnO <SEP> . <SEP> 0,04 <SEP> Sb2O <SEP> (x <SEP> = <SEP> > 3, <SEP> vermutlich <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 96 <SEP> 0, <SEP> 645 <SEP> 
<tb> 




   <Desc / Clms Page number 1>
 



  Process for colored enamelling of aluminum and
Aluminum alloys
 EMI1.1
 

 <Desc / Clms Page number 2>

 Wet-mill anddioxide-containing aluminum enamel frit and 7 parts by weight of a TiO2 rutile white pigment.



  The resulting slip is applied to aluminum sheet, dried and baked at 5400C for 6 minutes. The enamel shows a bright lemon yellow color. The hue corresponds to the monochromatic spectral light with wavelength 571-573. The color shows a saturation of 0.51 to 0.53 parts and a lightness of 56 to 58%. Hue, saturation and lightness were determined by trichromatic color measurement according to the regulations of DIN sheet 5033. The spectral color component Pe is used as a measure of the saturation. The brightness values correspond to the brightness reference values A.



   Example 2: 7 parts by weight of a rocky orange-colored rutile stain of the chemical composition 0.05 CoO. 0.06 Sb2O2 (x> 3. probably 4). TiO is wet-ground with 100 parts by weight of an aluminum enamel frit containing lead and titanium dioxide. The resulting slip is applied to aluminum sheet, dried and baked at 5400C for 6 minutes. The enamel shows an ocher orange color of the hue from 579 to 582 mg, the saturation from 0.56 to 0.58 parts and the lightness from 24 to 25%.
 EMI2.1
 Eis piel 3: 7 parts by weight of a dark brown colored rutile color body of the chemical composite aluminum sheet applied, dried and baked at 5400C for 6 minutes.

   The enamel shows a deep brown color of the hue from 592 to 596 mg, the saturation from 0.26 to 0.30 parts and the lightness from 10 to le.



   Table :
Lattice constants of some rutile pigments
 EMI2.2
 
<tb>
<tb> pigment <SEP> a <SEP> (A) <SEP> c <SEP> (A) <SEP> c / a
<tb> TiO2 rutile <SEP> 4.58 <SEP> 2.95 <SEP> 0.644
<tb> 0, <SEP> 05 <SEP> Ni <SEP> 0. <SEP> 0, <SEP> 04 <SEP> SbO <SEP> (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 646 <SEP>
<tb> O, <SEP> 075NOK. <SEP> 0, <SEP> 06 <SEP> Sbpx <SEP> (x <SEP> = <SEP>> <SEP> 3, <SEP> probably <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 60 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP>
<tb> 0, <SEP> 05 <SEP> CoO. <SEP> 0, <SEP> 04 <SEP> SbzOx <SEP> (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4). <SEP> TiO2 <SEP> 4.59 <SEP> 2.96 <SEP> 0.645
<tb> 0, <SEP> 075 <SEP> CoO. <SEP> 0, <SEP> 06 <SEP> SbzOx <SEP> (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4).

   <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP>
<tb> 0, <SEP> 05 <SEP> CuO. <SEP> 0.04 <SEP> Sb2Ox <SEP> (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4). <SEP> TiO2 <SEP> 4.59 <SEP> 2.97 <SEP> 0.646
<tb> 0.075 <SEP> CuO <SEP>. <SEP> 0.06 <SEP> Sb2Ox (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 60 <SEP> 2, <SEP> 97 <SEP> 0, <SEP> 647 <SEP>
<tb> 0.05 <SEP> MnO <SEP>. <SEP> 0.04 <SEP> Sb2O <SEP> (x <SEP> = <SEP>> 3, <SEP> probably <SEP> 4). <SEP> TiO <SEP> 4, <SEP> 59 <SEP> 2, <SEP> 96 <SEP> 0, <SEP> 645 <SEP>
<tb>


 

Claims (1)

PATENTANSPRUCH : Verfahren zur farbigen Emaillierung von Aluminium und Aluminiumlegierungen, dadurch gekennzeichnet, dass man zu dieser Emaillierung blei- und titandioxydhaltige Emails vor dem Auftragen und Einbrennen mit Farbkörpern mischt, die Rutil-Struktur besitzen und der chemischen Zusammensetzung EMI2.3 PATENT CLAIM: Process for colored enamelling of aluminum and aluminum alloys, characterized in that enamels containing lead and titanium dioxide are mixed with pigments which have a rutile structure and the chemical composition before application and baking EMI2.3
AT117660A 1959-03-28 1960-02-16 Process for colored enamelling of aluminum and aluminum alloys AT220911B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF28062A DE1191524B (en) 1959-03-28 1959-03-28 Process for colored enamelling of aluminum or aluminum alloys using colored bodies

Publications (1)

Publication Number Publication Date
AT220911B true AT220911B (en) 1962-04-25

Family

ID=7092727

Family Applications (1)

Application Number Title Priority Date Filing Date
AT117660A AT220911B (en) 1959-03-28 1960-02-16 Process for colored enamelling of aluminum and aluminum alloys

Country Status (5)

Country Link
AT (1) AT220911B (en)
BE (1) BE588904A (en)
CH (1) CH386202A (en)
DE (1) DE1191524B (en)
FR (1) FR1251189A (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2033707A (en) * 1934-04-16 1936-03-10 Harshaw Chem Corp Vitreous enamel opacifier
DE1031081B (en) * 1954-03-05 1958-05-29 Titan Gmbh Color-stable, titanium dioxide-containing enamels

Also Published As

Publication number Publication date
CH386202A (en) 1964-12-31
FR1251189A (en) 1961-01-13
DE1191524B (en) 1965-04-22
BE588904A (en) 1960-07-18

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