AT236019B - Lubricant for rolling non-ferrous metals - Google Patents
Lubricant for rolling non-ferrous metalsInfo
- Publication number
- AT236019B AT236019B AT121262A AT121262A AT236019B AT 236019 B AT236019 B AT 236019B AT 121262 A AT121262 A AT 121262A AT 121262 A AT121262 A AT 121262A AT 236019 B AT236019 B AT 236019B
- Authority
- AT
- Austria
- Prior art keywords
- lubricant
- mixture
- oil
- mineral oil
- coolant
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title description 17
- 239000002184 metal Substances 0.000 title description 17
- 239000000314 lubricant Substances 0.000 title description 13
- 238000005096 rolling process Methods 0.000 title description 8
- -1 ferrous metals Chemical class 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims description 17
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000002480 mineral oil Substances 0.000 description 16
- 239000002826 coolant Substances 0.000 description 15
- 235000010446 mineral oil Nutrition 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 230000009977 dual effect Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 238000005097 cold rolling Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- LXWZXEJDKYWBOW-UHFFFAOYSA-N 2,4-ditert-butyl-6-[(3,5-ditert-butyl-2-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)C)C(C)(C)C)O)=C1O LXWZXEJDKYWBOW-UHFFFAOYSA-N 0.000 description 1
- ZZZRZBIPCKQDQR-UHFFFAOYSA-N 2,4-ditert-butyl-6-methylphenol Chemical compound CC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O ZZZRZBIPCKQDQR-UHFFFAOYSA-N 0.000 description 1
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- UZHDGDDPOPDJGM-UHFFFAOYSA-N Stigmatellin A Natural products COC1=CC(OC)=C2C(=O)C(C)=C(CCC(C)C(OC)C(C)C(C=CC=CC(C)=CC)OC)OC2=C1O UZHDGDDPOPDJGM-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000015241 bacon Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940059904 light mineral oil Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Landscapes
- Lubricants (AREA)
Description
<Desc/Clms Page number 1>
Schmiermittel für das Walzen von Nichteisenmetallen
EMI1.1
<Desc/Clms Page number 2>
male Waschen nur schwer zu entfernen sind. Zusammengesetzte Mineralöle der bisher verwendeten Art verursachen sogar eine noch stärkere Verfärbung und Fleckenbildung des Nichteisenmetalls während des
Walzprozesses als die nicht zusammengesetzten Mineralöle. Die zusammengesetzten Öle, die Fette und fette Öle enthalten, wie Talg, Speck und Öle daraus, sind weiterhin wegen der Schwierigkeiten ungün-
5 stig, die bei dem Waschen der gewalzten Werkstücke auftreten.
Gegenstand der Erfindung ist daher, in einem Dual-Prozess zum Walzen von Nichteisenmetallen ein solches Schmiermittel aufzutragen, welches keine Verfärbung oder Fleckenbildung der gewalzten Metal- le verursacht und dessen Schmiereigenschaften derart sind, dass es in geringen Mengen angewendet wer- den kann, so dass auf den gewalzten Metallblechen ein dünner Ölfilm zurückbleibt, wodurch die von Zu- 10 fälligkeiten abhängige Wäsche mit Lösungsmittel wegfällt.
Das Ziel der Erfindung wird durch die Verwendung einer Mischung erreicht, die einen überwiegenden
Anteil eines nichtemulgierbaren, im wesentlichen aromatenfreien Mineralöls und einen untergeordneten
EMI2.1
eines Kühlmittels und eines Schmiermittels erfolgendes Verfahren zum Walzen von Nichteisenmetallen.
15 Das nichtemulgierbareMineralöl, welches von Aromaten frei ist, kann ein mit Phenol oder Furfurol hochraffiniertes Mineralöl mit einem Siedepunkt von 175 bis 3450C und einer SSU-Viskosität bei 37, 8 C von 40 bis 100 sein.
Ein besonders geeignetes Basisöl ist ein im wesentlichen nichtaromatisches Mineralöl mit einer SSU-
Viskosität von 40 bis 80 bei 37, 8 C.
20 Zu dem Basisöl können 20-40 Gew.-%, vorzugsweise 25-30 Gew.-lo, einer ungesättigten Fett- säure, wie Ölsäure, Linolsäure, Linolensäure, Erucasäure, Ricinolsäure und Mischungen dieser, zugesetzt werden.
Falls notwendig, können zu dem vorstehend genannten Schmiermittelgemisch noch 0, 05-1 Gew. oder mehr, vorzugsweise 0, 1-0, 5 Gew.-feines öllöslichen Trialkylmonophenols oder-bisphenols zu- 25 gesetzt werden.
EMI2.2
gruppen in der 2, 4- oder 2, 6-Stellung werden bevorzugt verwendet, beispielsweise 2, 4-Ditert. butyl- - 6-methyl-phenol und 2, 6-Ditert. butyl-4-methyl-phenol.
35 Schmierend wirkende Mischungen, die nach der Erfindung angewendet werden können, sind z. B. die folgenden : 1"Mineralöl (40 SSU bei 37, 8 C) + 30% Ölsäure II - Mineralöl (40 SSU bei 37, 8 C) + 30% Ölsäure + 0, 1% 2, 6-Ditert. butyl-4-methyl-phenol 40 m - Mineralöl (40 SSU bei 37. 80C) + 30% Ölsäure +
EMI2.3
1% Bis (2-hydroxy-3, 5-ditert. butyl-phenyl) methanIV - Mineralöl (45 SSU bei 37. SoC ; Sprühbasisöl) +
30% Ölsäure.
Das Mineralölgemisch wird auf die Oberflächen der Bearbeitungswalzen durch Wischen, Sprühen oder 45 Bürsten unmittelbar vor dem Eintreten der Streifen aus dem Nichteisenmetall, das gewalzt werden soll, oder auf die Oberfläche des Nichteisenmetalls selbst. unmittelbar bevor es kaltgewalzt wird, durch Bür- sten oder Sprühen oder sonstige geeignete Massnahmen aufgebracht. Im zuletzt erwähnten Fall muss ge- nügend Zeit gelassen werden, damit sich das Schmiermittel gleichmässig auf der Metalloberfläche aus- breiten kann.
50 Das Kühlmittel, welches Wasser oder eine Emulsion sein kann, wird getrennt aufgebracht. Es wird auf die vorderen und hinteren Enden der Walzen aufgetragen, so dass diese mit dem Kühlmittel überspült werden, bevor der Überzug aus nichtemulgierbarem Schmieröl aufgebracht wird oder bevor das mit dem
<Desc/Clms Page number 3>
nichtemulgierbaren Mineralöl überzogene Werkstück durch die Walzen hindurchgeführt und auf die gewünschten Dimensionen verringert wird.
Besonders brauchbare Kühlmittel sind Öl-in-Wasser-Emulsionen.
EMI3.1
ser-Emulsionen, welche Sulfonate und übliche Rostverhinderer. wie Alkanolamine, enthalten, sind billige und brauchbare Kühlmittel zur Anwendung bei dem erfindungsgemässen Dual-Prozess. Öl-in-Wasser- Emulsions-Kühlmittel, welche besonders brauchbar sind, bestehen aus einem Ölkonzentrat (X), das kleinere Mengen (insgesamt 18-20%) Sulfonat und Triäthanolamin in einer Leichtmineralölbasis enthält, wobei das Sulfonat in überwiegender Menge und das Triäthanolamin in einer Menge von 0. 1 bis 1% vorliegt. Dieses. Ölkonzentrat stellt ein vorzügliches und billiges Kühlmittel (Y) dar.
Bei Durchführung des Walzverfahrens wird das Schmiermittel (z. B. die Mischung I oder II) auf die Vorderseiten der Arbeitswalzen oder auf die zu walzende Aluminiumfläche vor deren Durchtritt durch die Walzen aufgetragen, u. zw. entweder durch Wischen. -Bürsten oder Sprühen. Wenn das Metall, das gleichmässig mit dem Schmiermittel überzogen ist, zwischen den Walzen hindurchgeführt wird, kann das Kühl - mittel, welches Wasser oder vorzugsweise eine Emulsion, wie ein Kühlmittel vom Typ Y ist, für sich getrennt direkt auf die Vorder-, Rück- und Unterseite der Arbeitswalzen aufgebracht werden, so dass diese überflutet werden und so ein Maximum an Kühlwirkung erzielt wird.
Die stark oberflächenaktiv wirkende Ölmischung benetzt die Walzen bevorzugt im Vergleich zu dem Emulsions-Kühlmittel. Dieses kann durch geeignete Anbringung von Prallblechen daran gehindert werden, an der gleichen Stelle mit den Walzen in Berührung zu kommen, wo das Schmieröl aufgebracht wird.
Das erfindungsgemäss verwendete Schmiermittel verhindert bei Anwendung in der beschriebenen
Weise eine Metallaufnahme durch die Walzen, es begünstigt ein richtiges Zugreifen der Walzen, es ver- hindert ein Gleiten und ergibt eine vorzügliche Oberflächenausbildung bei stark verringertem Energie- verbrauch. Aluminium, das nach dem Dual-Prozess gemäss der Erfindung behandelt worden ist, kann ohne eine zusätzliche Behandlung, wie Waschen, und ohne Erzeugung von Flecken oder Verfärbung der
Aluminiumflächen vergütet werden.
Das Dual-Verfahren zum Walzen von Aluminium wurde in einer Aluminiumfabrik zum Kaltwalzen von Aluminium auf einem Schmitz-Walzenstuhl angewendet. Die Oberfläche des Aluminiums wurde vor dem Einführen des Werkstückes in die Walze bei Raumtemperatur mit der Mineralölmischung IV überzogen und sobald die gleichmässig überzogene Aluminiumfläche durch die Walzen hindurchlief, wurden die Walzen mit einem 7%gen Öl-in-Wasser-Emulsions-Kühlmittel (Y) überspült.
Die Dicke des Werkstückes wurde um 35% vermindert, wobei eine Energie von 43 Amps. erforderlich war ; dabei trat kein Ablösen von Metall oder keine Beschädigung der Walzen auf und die Oberfläche war fleckenfrei und in vorzüglichem
Zustand, Bei Anwendung des Dual-Prozesses zum Kaltwalzen von Aluminium, wie vorstehend beschrieben, und bei Anwendung von Mineralölmischung 1I als Schmiermittel sowie Wasser als Kühlmittel ergab sich eineDickenminderung von 44 bis 60% bei einem Kraftverbrauch von 43bis 115 Amps.. ohne Aufnahme von Metall, Fleckenbildung oder sonstigen unerwünschten Wirkungen.
Bei dem Versuch, die Ölmischungen I - IV allein oder Wasser oder eine Emulsion vom Typ des Kühlmittels Y oder eine andere geeignete Emulsion sowohl als Schmiermittel als auch als Kühlmittel zum Kaltwalzen von Aluminium zu verwenden, ergab sich Aufnahme von Metall durch die Walzen, Ritzbildung. Fleckenbildung auf der Oberfläche u. dgl. Das Dual-Verfahren nach der Erfindung kann mit gleichem Vorteil auch zum Heisswalzen von Aluminium oder zum Ziehen von Nichteisenmetallen angewendet werden.
PATENTANSPRÜCHE :
1. Verwendung einer Mischung, welche einen überwiegenden Anteil an einem nichtemulgierbaren, im wesentlichen aromatenfreie Mineralöl und einen untergeordneten Anteil einer ungesättigten C, Fettsäure enthält, als Schmiermittel für ein unter getrennter Anwendung eines Kühlmittels und eines Schmiermittels erfolgendes Verfahren zum Walzen von Nichteisenmetallen.
2. Verwendung einer Mischung, in welcher das Mineralöl eine SSU-Viskosität von 40 bis 100, vorzugsweise von 40 bis 80, bei 37. 80C aufweist. für den Zweck nach Anspruch 1.
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Lubricant for rolling non-ferrous metals
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Male washes are difficult to remove. Compound mineral oils of the type previously used cause even greater discoloration and staining of the non-ferrous metal during the
Rolling process than the non-compound mineral oils. The compound oils containing fats and fatty oils, such as sebum, bacon and oils from them, are still unsuitable because of the difficulties.
5 stig that occur when washing the rolled workpieces.
The object of the invention is therefore to apply such a lubricant in a dual process for rolling non-ferrous metals which does not cause discoloration or staining of the rolled metals and whose lubricating properties are such that it can be used in small amounts so that A thin film of oil remains on the rolled metal sheets, eliminating the need to wash with solvents, which is dependent on coincidences.
The object of the invention is achieved through the use of a mixture which has a predominant
Part of a non-emulsifiable, essentially aromatic-free mineral oil and a subordinate one
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a method for rolling non-ferrous metals using a coolant and a lubricant.
The non-emulsifiable mineral oil, which is free from aromatics, can be a mineral oil highly refined with phenol or furfural with a boiling point of 175 to 3450C and an SSU viscosity at 37.8C of 40 to 100.
A particularly suitable base oil is an essentially non-aromatic mineral oil with an SSU
Viscosity from 40 to 80 at 37.8 C.
20-40% by weight, preferably 25-30% by weight, of an unsaturated fatty acid such as oleic acid, linoleic acid, linolenic acid, erucic acid, ricinoleic acid and mixtures thereof can be added to the base oil.
If necessary, 0.05-1% by weight or more, preferably 0.1-0.5% by weight, of fine oil-soluble trialkyl monophenol or bisphenol can be added to the aforementioned lubricant mixture.
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groups in the 2,4 or 2,6 position are preferably used, for example 2,4-di-tert. butyl- - 6-methyl-phenol and 2,6-di-tert. butyl-4-methyl-phenol.
35 Lubricating mixtures that can be used according to the invention are, for. B. the following: 1 "mineral oil (40 SSU at 37.8 C) + 30% oleic acid II - mineral oil (40 SSU at 37.8 C) + 30% oleic acid + 0.1% 2, 6-di-tert. Butyl- 4-methyl-phenol 40 m - mineral oil (40 SSU at 37. 80C) + 30% oleic acid +
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1% bis (2-hydroxy-3, 5-di-tert-butyl-phenyl) methane IV - mineral oil (45 SSU at 37th SoC; spray base oil) +
30% oleic acid.
The mineral oil mixture is applied to the surfaces of the machining rolls by wiping, spraying or brushing immediately before the entry of the strips of non-ferrous metal to be rolled or onto the surface of the non-ferrous metal itself immediately before it is cold-rolled, by brushing or spraying or other suitable measures are applied. In the last-mentioned case, enough time must be allowed for the lubricant to spread evenly over the metal surface.
50 The coolant, which can be water or an emulsion, is applied separately. It is applied to the front and rear ends of the rollers so that the coolant is flushed over them before the coating of non-emulsifiable lubricating oil is applied or before the
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non-emulsifiable mineral oil coated workpiece is passed through the rollers and reduced to the desired dimensions.
Oil-in-water emulsions are particularly useful coolants.
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ser emulsions, which sulfonates and common rust inhibitors. such as alkanolamines, are cheap and useful coolants for use in the dual process according to the invention. Oil-in-water emulsion coolants, which are particularly useful, consist of an oil concentrate (X) containing minor amounts (18-20% total) of sulfonate and triethanolamine in a light mineral oil base, with the sulfonate predominating and the triethanolamine is present in an amount of 0.1 to 1%. This. Oil concentrate is an excellent and cheap coolant (Y).
When the rolling process is carried out, the lubricant (e.g. mixture I or II) is applied to the front of the work rolls or to the aluminum surface to be rolled before it passes through the rolls, and the like. between either by wiping. -Brush or spray. When the metal, which is evenly coated with the lubricant, is passed between the rollers, the coolant, which is water or preferably an emulsion, such as a Y-type coolant, can be separately applied directly to the front, back and underside of the work rolls are applied so that they are flooded and a maximum of cooling effect is achieved.
The oil mixture, which has a strong surface-active effect, wets the rollers preferentially in comparison to the emulsion coolant. This can be prevented by suitable attachment of baffle plates from coming into contact with the rollers at the same point where the lubricating oil is applied.
The lubricant used according to the invention prevents when used in the described
In this way, metal is picked up by the rollers, it facilitates correct grip of the rollers, it prevents sliding and results in an excellent surface finish with greatly reduced energy consumption. Aluminum that has been treated according to the dual process according to the invention can be used without additional treatment, such as washing, and without producing stains or discoloration of the
Aluminum surfaces are remunerated.
The dual process for rolling aluminum was used in an aluminum factory for cold rolling aluminum on a Schmitz roll mill. The surface of the aluminum was coated with the mineral oil mixture IV at room temperature before the workpiece was inserted into the roller and as soon as the evenly coated aluminum surface ran through the rollers, the rollers were cooled with a 7% oil-in-water emulsion coolant (Y ) flooded.
The thickness of the workpiece was reduced by 35%, with an energy of 43 amps. was required; there was no detachment of metal or no damage to the rollers and the surface was free of stains and in excellent condition
Condition, When using the dual process for cold rolling aluminum, as described above, and when using mineral oil mixture 1I as lubricant and water as coolant, there was a reduction in thickness of 44 to 60% with a power consumption of 43 to 115 amps .. without absorbing metal , Staining or other undesirable effects.
When attempting to use the oil blends I-IV alone or water or an emulsion of the coolant Y type or another suitable emulsion as both a lubricant and a coolant for cold rolling aluminum, metal uptake by the rolls resulted in scoring. Spotting on the surface and the like Like. The dual process according to the invention can be used with the same advantage for hot rolling aluminum or for drawing non-ferrous metals.
PATENT CLAIMS:
1. Use of a mixture which contains a predominant proportion of a non-emulsifiable, essentially aromatic-free mineral oil and a minor proportion of an unsaturated C, fatty acid, as a lubricant for a process for rolling non-ferrous metals using a coolant and a lubricant separately.
2. Use of a mixture in which the mineral oil has an SSU viscosity of 40 to 100, preferably 40 to 80, at 37.80C. for the purpose of claim 1.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT121262A AT236019B (en) | 1962-02-13 | 1962-02-13 | Lubricant for rolling non-ferrous metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT121262A AT236019B (en) | 1962-02-13 | 1962-02-13 | Lubricant for rolling non-ferrous metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT236019B true AT236019B (en) | 1964-09-25 |
Family
ID=3509039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT121262A AT236019B (en) | 1962-02-13 | 1962-02-13 | Lubricant for rolling non-ferrous metals |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT236019B (en) |
-
1962
- 1962-02-13 AT AT121262A patent/AT236019B/en active
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