AT32193B - Process for the production of a combustible binder from hydrocarbons, preferably for fuel briquettes. - Google Patents
Process for the production of a combustible binder from hydrocarbons, preferably for fuel briquettes.Info
- Publication number
- AT32193B AT32193B AT32193DA AT32193B AT 32193 B AT32193 B AT 32193B AT 32193D A AT32193D A AT 32193DA AT 32193 B AT32193 B AT 32193B
- Authority
- AT
- Austria
- Prior art keywords
- hydrocarbons
- production
- fuel briquettes
- combustible binder
- nitric
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 4
- 239000011230 binding agent Substances 0.000 title claims description 3
- 239000000446 fuel Substances 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004166 Lanolin Substances 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 3
- 239000010428 baryte Substances 0.000 claims description 3
- 229910052601 baryte Inorganic materials 0.000 claims description 3
- 229940039717 lanolin Drugs 0.000 claims description 3
- 235000019388 lanolin Nutrition 0.000 claims description 3
- 239000008280 blood Substances 0.000 claims description 2
- 210000004369 blood Anatomy 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000012000 cholesterol Nutrition 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 210000003608 fece Anatomy 0.000 claims 1
- -1 feces Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012320 chlorinating reagent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000000802 nitrating effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Herstellung eines brennbaren Bindemittels aus Kohlenwasserstoffen vorzugsweise für Brennstoffbriketts.
EMI1.1
Das Verfahren beruht darauf, dass Kohlenwasserstoffe, wie z. B. Petroleumrückstände, in Gegenwart von geeigneten starken Kondensationsmitteln mit solchen Stoffen zusammen-
EMI1.2
oder chlorierenden Mitteln erhalten werden. Vorzugsweise werden organische Stoffe tierischer Herkunft, wie z. B. Talg, Lanolin, Cholesterin u. dgl., weiter auch Rückstände von der Wollwäscherei, Blut, Exkremonte, zerschnittenes Fleisch usw. benutzt. Wenn man diese Körper mit nitrierenden oder chlorierenden Mitteln, wie z. B. Salpeter-Schwefelsäure oder Salpeter-Salzsäure, behandelt, so erhält man Nitro-und Chiorderivate, die mit den Kohlenwasserstoffen zusammen bindend wirken.
Von den Kohlenwasserstoffen werden vorzugsweise diejenigen verwendet, die ein spezifisches Gewicht von 0#75-0#90 besitzen, wie z. B. Rückstände von der Mineralöldestillation, aber auch Hohmineralöle. Als Zuschläge kann man Ätzbaryt, @tzkalk, Ätznatron, Zinkchlorid, gegebenen-
EMI1.3
Beispiel : 100 A : y rohes Lanolin werden mit 2 kg eines Gemisches aus 2 Teilen Schwefelsäure und 3 Teilen roher Salpetersäure bei erhöhter Temperatur kräftig durchgearbeitet, bis kleine Mengen nitroser Dämpfe auftretfn. Darauf wird schnell etwas Alkalilösung hinzugefügt, um die Reaktion zum Stillstand zu bringen und ein Verkohlen der Masse zu verhindern.
Darauf wird das Reaktionsprodukt gepresst und getrocknet und mit 1000 A'l schweren Mineralölen in Gegenwart von 1 kg Baryt oder einer äquivalenten Menge Atzkalk im Autoklaven bei 300- 60ut C erhitzt, wobei man dafür Sorge trägt, dass die sich bildenden Dämpfe und Gase austreten können. Die Reaktion wird solange fortgesetzt, bis die Masse dio gewünschte Beschaffenheit angenommen hat. Diese hängt von dem beabsichtigten Verwendungszweck der Masse ab ; je nach den damit zur Bindung zu bringenden Stoffen wird die Masse in einem mehr oder weniger klebrigen Zustande gelassen oder bis zur Bildung eines nach dem Erstarren vollkommen trocknenden Stoffes
EMI1.4
<Desc / Clms Page number 1>
Process for the production of a combustible binder from hydrocarbons, preferably for fuel briquettes.
EMI1.1
The method is based on the fact that hydrocarbons, such as. B. petroleum residues, in the presence of suitable strong condensing agents together with such substances.
EMI1.2
or chlorinating agents. Preferably organic substances of animal origin, such as. B. tallow, lanolin, cholesterol and the like. Like., Also residues from the wool laundry, blood, excrement, cut meat, etc. used. If these bodies are treated with nitrating or chlorinating agents, such as B. nitric-sulfuric acid or nitric-hydrochloric acid treated, nitro and chio derivatives are obtained which have a binding effect with the hydrocarbons.
Of the hydrocarbons, those are preferably used which have a specific gravity of 0 # 75-0 # 90, such as. B. residues from mineral oil distillation, but also high mineral oils. Caustic barite, quicklime, caustic soda, zinc chloride, and given
EMI1.3
Example: 100 A: y crude lanolin is vigorously worked through with 2 kg of a mixture of 2 parts of sulfuric acid and 3 parts of crude nitric acid at an elevated temperature until small amounts of nitrous vapors appear. A little alkali solution is then quickly added to stop the reaction and prevent the mass from charring.
The reaction product is then pressed and dried and heated with 1000 A'l heavy mineral oils in the presence of 1 kg of barite or an equivalent amount of caustic lime in an autoclave at 300-60 ° C, taking care that the vapors and gases that are formed can escape . The reaction is continued until the mass has assumed the desired consistency. This depends on the intended use of the mass; Depending on the substances to be bonded with it, the mass is left in a more or less sticky state or until a substance is formed that completely dries after solidification
EMI1.4
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT32193T | 1905-05-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT32193B true AT32193B (en) | 1908-03-10 |
Family
ID=3547190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT32193D AT32193B (en) | 1905-05-31 | 1905-05-31 | Process for the production of a combustible binder from hydrocarbons, preferably for fuel briquettes. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT32193B (en) |
-
1905
- 1905-05-31 AT AT32193D patent/AT32193B/en active
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