AT403297B - Verfahren zur selektiven abtrennung von morpholin - Google Patents

Verfahren zur selektiven abtrennung von morpholin Download PDF

Info

Publication number: AT403297B
Authority: AT; Austria
Prior art keywords: methylmorpholine; morpholine; nmmo; cation exchanger; oxide
Prior art date: 1995-08-18

Application number

AT140395A

Other languages

German (de)

English (en)

Other versions

ATA140395A (de

Original Assignee

Chemiefaser Lenzing Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-08-18

Filing date

1995-08-18

Publication date

1997-12-29

1995-08-18 Priority to AT140395A priority Critical patent/AT403297B/de

1995-08-18 Application filed by Chemiefaser Lenzing Ag filed Critical Chemiefaser Lenzing Ag

1996-08-16 Priority to JP9508733A priority patent/JPH10508318A/ja

1996-08-16 Priority to CN96191128A priority patent/CN1071750C/zh

1996-08-16 Priority to EP96926960A priority patent/EP0783497A1/fr

1996-08-16 Priority to CA 2202153 priority patent/CA2202153A1/fr

1996-08-16 Priority to AU66954/96A priority patent/AU700207B2/en

1996-08-16 Priority to PCT/AT1996/000146 priority patent/WO1997007108A1/fr

1996-08-16 Priority to BR9606585A priority patent/BR9606585A/pt

1997-04-17 Priority to NO19971753A priority patent/NO310572B1/no

1997-04-17 Priority to US08/843,850 priority patent/US6113799A/en

1997-05-15 Publication of ATA140395A publication Critical patent/ATA140395A/de

1997-12-29 Application granted granted Critical

1997-12-29 Publication of AT403297B publication Critical patent/AT403297B/de

Links

YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 title claims description 80
238000000034 method Methods 0.000 title claims description 64
238000000926 separation method Methods 0.000 title claims description 9
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 99
LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 claims description 57
150000001412 amines Chemical class 0.000 claims description 36
150000001768 cations Chemical class 0.000 claims description 31
ZKXDGKXYMTYWTB-UHFFFAOYSA-N N-nitrosomorpholine Chemical compound O=NN1CCOCC1 ZKXDGKXYMTYWTB-UHFFFAOYSA-N 0.000 claims description 28
238000007254 oxidation reaction Methods 0.000 claims description 19
230000003647 oxidation Effects 0.000 claims description 18
239000007864 aqueous solution Substances 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
239000000243 solution Substances 0.000 claims description 13
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
239000007800 oxidant agent Substances 0.000 claims description 5
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
229910052753 mercury Inorganic materials 0.000 claims description 3
238000006243 chemical reaction Methods 0.000 claims description 2
125000000542 sulfonic acid group Chemical group 0.000 claims description 2
230000003247 decreasing effect Effects 0.000 claims 1
238000001556 precipitation Methods 0.000 description 11
239000000126 substance Substances 0.000 description 9
229920002678 cellulose Polymers 0.000 description 8
239000001913 cellulose Substances 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 8
239000002253 acid Substances 0.000 description 7
150000003512 tertiary amines Chemical class 0.000 description 7
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000002351 wastewater Substances 0.000 description 6
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000007857 degradation product Substances 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
238000000465 moulding Methods 0.000 description 4
150000004005 nitrosamines Chemical class 0.000 description 4
239000000835 fiber Substances 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
230000005855 radiation Effects 0.000 description 3
239000012465 retentate Substances 0.000 description 3
238000001223 reverse osmosis Methods 0.000 description 3
239000003643 water by type Substances 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
229960005070 ascorbic acid Drugs 0.000 description 2
235000010323 ascorbic acid Nutrition 0.000 description 2
239000011668 ascorbic acid Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000010828 elution Methods 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000004128 high performance liquid chromatography Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
238000011084 recovery Methods 0.000 description 2
QEVHRUUCFGRFIF-MDEJGZGSSA-N reserpine Chemical compound O([C@H]1[C@@H]([C@H]([C@H]2C[C@@H]3C4=C(C5=CC=C(OC)C=C5N4)CCN3C[C@H]2C1)C(=O)OC)OC)C(=O)C1=CC(OC)=C(OC)C(OC)=C1 QEVHRUUCFGRFIF-MDEJGZGSSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000010409 thin film Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
229920000875 Dissolving pulp Polymers 0.000 description 1
239000007836 KH2PO4 Substances 0.000 description 1
229920000433 Lyocell Polymers 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
-1 are combined Substances 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000001212 derivatisation Methods 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000003480 eluent Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
235000019796 monopotassium phosphate Nutrition 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
239000000047 product Substances 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
230000008961 swelling Effects 0.000 description 1
231100000167 toxic agent Toxicity 0.000 description 1
239000003440 toxic substance Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
- C07D295/28—Nitrogen atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Physical Water Treatments (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

AT140395A 1995-08-18 1995-08-18 Verfahren zur selektiven abtrennung von morpholin AT403297B (de)

Priority Applications (10)

Application Number	Priority Date	Filing Date	Title
AT140395A AT403297B (de)	1995-08-18	1995-08-18	Verfahren zur selektiven abtrennung von morpholin
CN96191128A CN1071750C (zh)	1995-08-18	1996-08-16	选择性分离吗啉的方法
EP96926960A EP0783497A1 (fr)	1995-08-18	1996-08-16	Procede pour la separation selective de morpholine
CA 2202153 CA2202153A1 (fr)	1995-08-18	1996-08-16	Procede pour la separation selective de morpholine
JP9508733A JPH10508318A (ja)	1995-08-18	1996-08-16	モルホリンの選択的な分離方法
AU66954/96A AU700207B2 (en)	1995-08-18	1996-08-16	Process for selective separation of morpholine
PCT/AT1996/000146 WO1997007108A1 (fr)	1995-08-18	1996-08-16	Procede pour la separation selective de morpholine
BR9606585A BR9606585A (pt)	1995-08-18	1996-08-16	Processo para a separação seletiva de morfolina
NO19971753A NO310572B1 (no)	1995-08-18	1997-04-17	Fremgangsmåte for selektiv fraskillelse av morfolin ved hjelp av en regenererbar kationebytter
US08/843,850 US6113799A (en)	1995-08-18	1997-04-17	Process for selective separation of morpholine

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
AT140395A AT403297B (de)	1995-08-18	1995-08-18	Verfahren zur selektiven abtrennung von morpholin

Publications (2)

Publication Number	Publication Date
ATA140395A ATA140395A (de)	1997-05-15
AT403297B true AT403297B (de)	1997-12-29

Family

ID=3513141

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT140395A AT403297B (de)	1995-08-18	1995-08-18	Verfahren zur selektiven abtrennung von morpholin

Country Status (9)

Country	Link
EP (1)	EP0783497A1 (fr)
JP (1)	JPH10508318A (fr)
CN (1)	CN1071750C (fr)
AT (1)	AT403297B (fr)
AU (1)	AU700207B2 (fr)
BR (1)	BR9606585A (fr)
CA (1)	CA2202153A1 (fr)
NO (1)	NO310572B1 (fr)
WO (1)	WO1997007108A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19842556C2 (de) *	1998-09-17	2003-02-06	Alceru Schwarza Gmbh	Verfahren zur Herstellung von cellulosischen Formkörpern

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN111801319A (zh) *	2018-03-15	2020-10-20	巴斯夫欧洲公司	从包含甲氧基乙醇和吗啉的混合物中移除甲氧基乙醇的方法
CN110563669A (zh) *	2019-10-09	2019-12-13	四川鸿鹏新材料有限公司	一种提高吗啉纯度的方法及装置
CN112480035A (zh) *	2020-10-28	2021-03-12	华茂伟业绿色科技股份有限公司	N-甲基吗啉及其纯化方法、氧化甲基吗啉及其制备方法
CN114539186A (zh) *	2021-07-02	2022-05-27	华茂伟业绿色科技股份有限公司	Nmmo的纯化方法、系统及得到的nmmo水合物晶体

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DD259863A1 (de) *	1987-04-06	1988-09-07	Schwarza Chemiefaser	Verfahren zur herstellung waessriger, reiner n-methylmorpholin-n-oxid-loesungen
EP0402347A1 (fr) *	1989-06-08	1990-12-12	Lenzing Aktiengesellschaft	Procédé pour l'élimination d'amines
DD254199B5 (de) *	1986-12-04	1994-01-05	Thueringische Faser Ag Schwarz	Verfahren zur reinigung waessriger n-methylmorpholin-n-oxyd-loesungen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DD274435B5 (de) *	1988-08-02	1996-10-31	Thueringisches Inst Textil	Verfahren zur Rueckgewinnung von N-Methylmorpholin-N-Oxid
AT392915B (de) *	1990-03-28	1991-07-10	Chemiefaser Lenzing Ag	Verfahren zum abtrennen von wasser aus einer verduennten waesserigen loesung von n-methylmorpholin-n-oxid, n-methylmorpholin und/oder morpholin

1995
- 1995-08-18 AT AT140395A patent/AT403297B/de not_active IP Right Cessation
1996
- 1996-08-16 WO PCT/AT1996/000146 patent/WO1997007108A1/fr not_active Ceased
- 1996-08-16 JP JP9508733A patent/JPH10508318A/ja not_active Ceased
- 1996-08-16 CA CA 2202153 patent/CA2202153A1/fr not_active Abandoned
- 1996-08-16 CN CN96191128A patent/CN1071750C/zh not_active Expired - Fee Related
- 1996-08-16 AU AU66954/96A patent/AU700207B2/en not_active Ceased
- 1996-08-16 EP EP96926960A patent/EP0783497A1/fr not_active Ceased
- 1996-08-16 BR BR9606585A patent/BR9606585A/pt not_active Application Discontinuation
1997
- 1997-04-17 NO NO19971753A patent/NO310572B1/no not_active IP Right Cessation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DD254199B5 (de) *	1986-12-04	1994-01-05	Thueringische Faser Ag Schwarz	Verfahren zur reinigung waessriger n-methylmorpholin-n-oxyd-loesungen
DD259863A1 (de) *	1987-04-06	1988-09-07	Schwarza Chemiefaser	Verfahren zur herstellung waessriger, reiner n-methylmorpholin-n-oxid-loesungen
EP0402347A1 (fr) *	1989-06-08	1990-12-12	Lenzing Aktiengesellschaft	Procédé pour l'élimination d'amines

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19842556C2 (de) *	1998-09-17	2003-02-06	Alceru Schwarza Gmbh	Verfahren zur Herstellung von cellulosischen Formkörpern

Also Published As

Publication number	Publication date
BR9606585A (pt)	1997-10-28
CA2202153A1 (fr)	1997-02-27
NO971753D0 (no)	1997-04-17
CN1071750C (zh)	2001-09-26
AU700207B2 (en)	1998-12-24
EP0783497A1 (fr)	1997-07-16
NO971753L (no)	1997-04-17
NO310572B1 (no)	2001-07-23
CN1165514A (zh)	1997-11-19
WO1997007108A1 (fr)	1997-02-27
ATA140395A (de)	1997-05-15
JPH10508318A (ja)	1998-08-18
AU6695496A (en)	1997-03-12

Legal Events

Date	Code	Title	Description
1997-01-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties
2006-01-15	ELJ	Ceased due to non-payment of the annual fee

Publication	Publication Date	Title
DE69224843T2 (de)	1998-09-03	Verfahren zur reinigung wässriger lösungenvon amine-n-oxiden
EP0695324B1 (fr)	1997-10-29	Procede de production de corps moules en cellulose
EP3527696A1 (fr)	2019-08-21	Procédé de traitement et de valorisation d'une eau de processus salée
AT394707B (de)	1992-06-10	Verfahren und vorrichtung zur herstellung von ozonhaeltigen loesungen und gasen
AT406588B (de)	2000-06-26	Verfahren zur herstellung cellulosischer fasern
AT403297B (de)	1997-12-29	Verfahren zur selektiven abtrennung von morpholin
AT402512B (de)	1997-06-25	Verfahren zur aufarbeitung einer wässrigen prozessflüssigkeit des aminoxidverfahrens
EP0783606B1 (fr)	2004-05-26	Procede de purification d'une solution aqueuse d'un oxyde d'amine tertiaire
AT404033B (de)	1998-07-27	Verfahren zur herstellung einer wässrigen lösung von n-methylmorpholin-n-oxid
EP0434662B1 (fr)	1994-09-21	Procédé pour blanchir des matières cellulosiques et installation pour la mise en oeuvre de ce procédé
EP0488988B1 (fr)	1993-09-15	Procédé de purification de solutions aqueuses de méthyl-morpholine-N-oxide-N
EP0787153B1 (fr)	1997-12-29	Procede pour reutiliser un liquide de traitement aqueux issu du procede a l'oxyde d'amine
DE1792666B1 (de)	1971-04-08	Verfahren zum Entfernen von abgelagertem elementarem Schwefel auf festen Oxydationskatalysatoren
DE2426117C3 (de)	1978-07-27	Verfahren zum mehrstufigen kontinuierlichen Aufbereiten von organische Farbstoffe und Produktionshilfsmittel enthaltenden neutralen Färbereiabwassern mittels Ozon unter Turbulenz
DE1016647B (de)	1957-09-26	Verfahren zur Entfernung von Thiocyanat aus Abwaessern
WO2009074434A2 (fr)	2009-06-18	Procédé pour épurer les fumées produites lors de la production de chlorure cyanurique
AT401779B (de)	1996-11-25	Verfahren zur herstellung cellulosischer formkörper und regenerierte lösung
DE4002014A1 (de)	1990-08-02	Abwasserreinigung mit ozon
DE2933430C2 (fr)	1988-01-07
WO2000015887A1 (fr)	2000-03-23	Procede de traitement et de purification de solutions aqueuses d'un aminoxyde tertiaire
CH643216A5 (de)	1984-05-30	Verfahren zur rueckgewinnung von brom aus abfallfluessigkeit.
DE945407C (de)	1956-07-05	Verfahren zur Gewinnung und Reindarstellung von Bacitracin
AT401184B (de)	1996-07-25	Verfahren zur reinigung wässriger lösungen tertiärer aminoxide
DE2419326C3 (de)	1979-10-18	Verfahren zur Herabsetzung des Kalziumgehalts von natriumbasischer Sulfitablaugen
DE413683C (de)	1925-05-12	Verfahren zur Vorbehandlung von Hautabfaellen fuer die Leimfabrikation

AT403297B - Verfahren zur selektiven abtrennung von morpholin - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (10)

Applications Claiming Priority (1)

Publications (2)

Family

ID=3513141

Family Applications (1)

Country Status (9)

Cited By (1)

Families Citing this family (4)

Citations (3)

Family Cites Families (2)

Patent Citations (3)

Cited By (1)

Also Published As

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