ATA445283A - Verfahren zur herstellung eines neuen stabilen homogenen rhodium-hydrierungs-katalysators und dessen anwendung - Google Patents
Verfahren zur herstellung eines neuen stabilen homogenen rhodium-hydrierungs-katalysators und dessen anwendungInfo
- Publication number
- ATA445283A ATA445283A AT0445283A AT445283A ATA445283A AT A445283 A ATA445283 A AT A445283A AT 0445283 A AT0445283 A AT 0445283A AT 445283 A AT445283 A AT 445283A AT A445283 A ATA445283 A AT A445283A
- Authority
- AT
- Austria
- Prior art keywords
- stable homogeneous
- producing
- application
- hydrogenation catalyst
- new stable
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052703 rhodium Inorganic materials 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229960003722 doxycycline Drugs 0.000 abstract 1
- XQTWDDCIUJNLTR-CVHRZJFOSA-N doxycycline monohydrate Chemical compound O.O=C1C2=C(O)C=CC=C2[C@H](C)[C@@H]2C1=C(O)[C@]1(O)C(=O)C(C(N)=O)=C(O)[C@@H](N(C)C)[C@@H]1[C@H]2O XQTWDDCIUJNLTR-CVHRZJFOSA-N 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- 238000009905 homogeneous catalytic hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000707 stereoselective effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
- C07C237/24—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring of the carbon skeleton
- C07C237/26—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring of the carbon skeleton of a ring being part of a condensed ring system formed by at least four rings, e.g. tetracycline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PT198276061A PT76061A (en) | 1982-12-30 | 1982-12-30 | Stable homogeneous hydrogenation rhodium catalyst - useful in high yield prodn. of doxycycline by stereospecific hydrogenation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ATA445283A true ATA445283A (de) | 1990-12-15 |
| AT392922B AT392922B (de) | 1991-07-10 |
Family
ID=20083240
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT4452/83A AT392922B (de) | 1982-12-30 | 1983-12-20 | Verfahren zur herstellung eines neuen stabilen homogenen rhodium-hydrierungs-katalysators und dessen anwendung |
| AT87304279T ATE65429T1 (de) | 1982-12-30 | 1987-05-14 | Rhodiumhydrierungskatalysatoren. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT87304279T ATE65429T1 (de) | 1982-12-30 | 1987-05-14 | Rhodiumhydrierungskatalysatoren. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US4857235A (de) |
| EP (1) | EP0283616B1 (de) |
| KR (1) | KR900004206B1 (de) |
| AT (2) | AT392922B (de) |
| BE (1) | BE1000671A3 (de) |
| CA (1) | CA1218058A (de) |
| ES (1) | ES2023413B3 (de) |
| FR (1) | FR2612803B1 (de) |
| HU (1) | HU196143B (de) |
| IE (1) | IE56512B1 (de) |
| PT (2) | PT76061A (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU198173B (en) * | 1987-09-18 | 1989-08-28 | Chinoin Gyogyszer Es Vegyeszet | Process for producing doxycycline |
| EP0372313B1 (de) * | 1988-12-02 | 1997-03-05 | Hoechst Aktiengesellschaft | Sulfonierte Phenylphosphane enthaltende Komplexverbindungen |
| PT91333B (pt) * | 1989-07-31 | 1995-05-04 | Hovione Sociedade Quimica Sa | Processo para a preparacao de um complexo de rodio |
| EP0499329B1 (de) * | 1991-02-15 | 1994-05-04 | Shell Internationale Researchmaatschappij B.V. | Katalytisches System für die Carbonylierung |
| GB9111583D0 (en) * | 1991-05-30 | 1991-07-24 | Shell Int Research | Carbonylation catalyst system |
| US5258546A (en) * | 1991-05-30 | 1993-11-02 | Shell Oil Company | Carbonylation catalyst system |
| EP0565800A2 (de) * | 1991-12-31 | 1993-10-20 | Plurichemie Anstalt | Verfahren zur Gewinnung von Edelmetallen und tertiären Aminen |
| US5334791A (en) * | 1992-05-22 | 1994-08-02 | Ligands Inc. | Hydrogenation process with transition metal catalysts derived from bifunctional phosphorus-nitrogen ligands |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US32535A (en) * | 1861-06-11 | Cane seat for chaiks | ||
| CA668581A (en) * | 1963-08-13 | R. D. Mccormick Jerry | Process for the catalytic reduction of 6-hydroxy hydronaphthacenes | |
| GB1154937A (en) * | 1966-08-10 | 1969-06-11 | Ici Ltd | Hydrogenation Process |
| AT277315B (de) * | 1967-03-28 | 1969-12-29 | Otto Haemmerle Maschb | Einrichtung zur Bereitstellung des Schleppgutes für Schleppseilförderanlagen |
| US3755194A (en) * | 1969-02-12 | 1973-08-28 | O Eremenko | Hydrogenation catalyst |
| NL167676C (nl) * | 1969-06-11 | 1982-01-18 | Shell Int Research | Werkwijze voor de bereiding van aldehyden resp. ketonen door katalytische dehydrogenering van primaire resp. secundaire alcoholen, alsmede werkwijze voor het bereiden van een daarbij te gebruiken katalysator. |
| CA942743A (en) * | 1970-07-03 | 1974-02-26 | Ivan Villax | Process for producing 6-methylenetetracyclines and 6-deoxytetracyclines |
| NL7109740A (de) * | 1971-02-24 | 1972-08-28 | ||
| US3956177A (en) * | 1971-08-20 | 1976-05-11 | Phillips Petroleum Company | Rhodium hydroformylation catalyst |
| US4207258A (en) * | 1972-02-24 | 1980-06-10 | Ankerfarm S.P.A. | Process for the preparatin of α-6-deoxytetracyclines |
| SE435619C (sv) * | 1973-02-01 | 1985-11-18 | Pfizer | Forfarande for framstellning av en 6alfa-deoxitetracyklin |
| US4001321A (en) * | 1975-06-26 | 1977-01-04 | Pfizer Inc. | Preparation of α-6-deoxytetracyclines |
| US3962131A (en) * | 1975-01-28 | 1976-06-08 | Pfizer Inc. | Rhodium containing catalyst and use thereof in preparation of 6-deoxy-5-oxytetracycline |
| US3978000A (en) * | 1975-03-19 | 1976-08-31 | American Cyanamid Company | Catalysts based on carbon supports |
| FR2416821A2 (fr) * | 1977-06-02 | 1979-09-07 | Montagner Rene | Perfectionnement aux procedes et installations d'embarquement de passagers sur une structure porteuse mobile suspendue, notamment de remontee mecanique |
| FR2408388A1 (fr) * | 1977-11-10 | 1979-06-08 | Ugine Kuhlmann | Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation |
| US4288634A (en) * | 1978-04-10 | 1981-09-08 | Toa Nenryo Kogyo Kabushiki Kaisha | Novel rhodium compounds and process for producing the same |
| JPS5594390A (en) * | 1979-01-08 | 1980-07-17 | Toyo Soda Mfg Co Ltd | Preparation of catalyst |
| US4743699A (en) * | 1982-01-19 | 1988-05-10 | Plurichemie Anstalt | Homogeneous catalytic system and a process for the preparation of same |
| US4500458A (en) * | 1982-01-19 | 1985-02-19 | Plurichemie Anstalt | Process for the preparation of α-6-deoxytetracyclines |
| USRE32535E (en) | 1982-01-19 | 1987-10-27 | Plurichemie Anstalt | Process for the preparation of α-6-deoxytetracyclines |
| PT79774A (en) * | 1984-12-28 | 1985-01-01 | Joao Emerico Villax | Process to prepare rhodium catalysts and applications thereof |
| US4560804A (en) * | 1982-09-21 | 1985-12-24 | Exxon Research & Engineering Co. | Catalytic process for the manufacture of ketones |
-
1982
- 1982-12-30 PT PT198276061A patent/PT76061A/pt unknown
-
1983
- 1983-04-05 CA CA000425254A patent/CA1218058A/en not_active Expired
- 1983-06-15 HU HU832127A patent/HU196143B/hu unknown
- 1983-12-20 AT AT4452/83A patent/AT392922B/de not_active IP Right Cessation
- 1983-12-23 IE IE3061/83A patent/IE56512B1/en not_active IP Right Cessation
-
1987
- 1987-03-25 PT PT76061A patent/PT76061B1/pt unknown
- 1987-05-14 ES ES87304279T patent/ES2023413B3/es not_active Expired - Lifetime
- 1987-05-14 AT AT87304279T patent/ATE65429T1/de not_active IP Right Cessation
- 1987-05-14 EP EP87304279A patent/EP0283616B1/de not_active Expired - Lifetime
- 1987-05-15 US US07/050,932 patent/US4857235A/en not_active Expired - Lifetime
- 1987-06-25 BE BE8700710A patent/BE1000671A3/fr not_active IP Right Cessation
- 1987-07-10 FR FR878709869A patent/FR2612803B1/fr not_active Expired
- 1987-11-26 KR KR1019870013370A patent/KR900004206B1/ko not_active Expired
-
1989
- 1989-03-13 US US07/322,176 patent/US4911865A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2612803B1 (fr) | 1989-06-16 |
| PT76061A1 (pt) | 1987-04-01 |
| US4911865A (en) | 1990-03-27 |
| AT392922B (de) | 1991-07-10 |
| IE833061L (en) | 1984-06-30 |
| HUT34375A (en) | 1985-03-28 |
| KR880010820A (ko) | 1988-10-24 |
| IE56512B1 (en) | 1991-08-28 |
| EP0283616A1 (de) | 1988-09-28 |
| ES2023413B3 (es) | 1992-01-16 |
| EP0283616B1 (de) | 1991-07-24 |
| PT76061A (en) | 1983-01-01 |
| KR900004206B1 (ko) | 1990-06-18 |
| CA1218058A (en) | 1987-02-17 |
| US4857235A (en) | 1989-08-15 |
| HU196143B (en) | 1988-10-28 |
| BE1000671A3 (fr) | 1989-03-07 |
| ATE65429T1 (de) | 1991-08-15 |
| PT76061B1 (pt) | 1990-02-12 |
| FR2612803A1 (fr) | 1988-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ELJ | Ceased due to non-payment of the annual fee |