ATE129522T1 - Mit einer aus neutralisierter,carbonsäure-festen, ineinandergreifenden masche hergestellter geformter festkörper. - Google Patents

Mit einer aus neutralisierter,carbonsäure-festen, ineinandergreifenden masche hergestellter geformter festkörper.

Info

Publication number
ATE129522T1
ATE129522T1 AT92904074T AT92904074T ATE129522T1 AT E129522 T1 ATE129522 T1 AT E129522T1 AT 92904074 T AT92904074 T AT 92904074T AT 92904074 T AT92904074 T AT 92904074T AT E129522 T1 ATE129522 T1 AT E129522T1
Authority
AT
Austria
Prior art keywords
neutralized
carbonic acid
solid
interlocking mesh
shaped
Prior art date
Application number
AT92904074T
Other languages
German (de)
English (en)
Inventor
Mark Leslie Kacher
James Eden Taneri
James Berger Camden
Paul Edward Vest
Sylvia Jean Bowles
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/782,956 external-priority patent/US5340492A/en
Application filed by Procter & Gamble filed Critical Procter & Gamble
Application granted granted Critical
Publication of ATE129522T1 publication Critical patent/ATE129522T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0069—Laundry bars
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Materials For Medical Uses (AREA)
AT92904074T 1990-11-26 1991-11-20 Mit einer aus neutralisierter,carbonsäure-festen, ineinandergreifenden masche hergestellter geformter festkörper. ATE129522T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61782790A 1990-11-26 1990-11-26
US07/782,956 US5340492A (en) 1990-11-26 1991-11-01 Shaped solid made with a rigid, interlocking mesh of neutralized carboxylic acid

Publications (1)

Publication Number Publication Date
ATE129522T1 true ATE129522T1 (de) 1995-11-15

Family

ID=27088104

Family Applications (1)

Application Number Title Priority Date Filing Date
AT92904074T ATE129522T1 (de) 1990-11-26 1991-11-20 Mit einer aus neutralisierter,carbonsäure-festen, ineinandergreifenden masche hergestellter geformter festkörper.

Country Status (27)

Country Link
EP (1) EP0559837B1 (fr)
JP (1) JPH06503122A (fr)
KR (1) KR100226393B1 (fr)
CN (1) CN1036529C (fr)
AR (1) AR247426A1 (fr)
AT (1) ATE129522T1 (fr)
AU (1) AU657295B2 (fr)
BR (1) BR9107125A (fr)
CA (1) CA2095351C (fr)
CZ (1) CZ283495B6 (fr)
DE (1) DE69114143T2 (fr)
DK (1) DK0559837T3 (fr)
EG (1) EG19580A (fr)
ES (1) ES2079180T3 (fr)
FI (1) FI932366L (fr)
GR (1) GR3017892T3 (fr)
HU (1) HU215484B (fr)
IE (1) IE72087B1 (fr)
MA (1) MA22349A1 (fr)
MX (1) MX9102229A (fr)
NO (1) NO931848L (fr)
NZ (1) NZ240709A (fr)
PT (1) PT99606A (fr)
RU (1) RU2080365C1 (fr)
SG (1) SG59939A1 (fr)
SK (1) SK52693A3 (fr)
WO (1) WO1992009679A1 (fr)

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WO1998016611A1 (fr) * 1996-10-11 1998-04-23 The Procter & Gamble Company Compositions de pains de lessive comprenant de l'alcool dihydrique
JP3227694B2 (ja) * 1996-12-11 2001-11-12 花王株式会社 枠練り石鹸組成物
WO1998027193A1 (fr) * 1996-12-16 1998-06-25 The Procter & Gamble Company Composition d'hygiene personnelle, sous forme de pain, contenant du lauroyl-lactylate de sodium
US6680285B2 (en) * 2000-12-21 2004-01-20 Unilever Home & Personal Care Usa A Division Of Conopco, Inc. Skin cleansing bar with high levels of liquid emollient
US6630432B2 (en) * 2001-04-18 2003-10-07 Unilever Home & Personal Care Usa, Division Of Conopco Processable soap based bars comprising soaps of α hydroxy acid and minimum amount of free fatty acid and/or monoglyceride
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WO2004029058A1 (fr) * 2002-09-25 2004-04-08 Sankyo Company, Limited Composition medicinale permettant d'inhiber une augmentation de la concentration sanguine de la gastrine
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EP2875114B1 (fr) 2012-07-23 2016-03-02 Unilever N.V. Procédé de préparation de composition de savon dans un mélangeur de soc
CN106544157A (zh) * 2016-11-02 2017-03-29 广州精点高分子材料制品有限公司 一种美容洁面皂及其制备方法
CN107245391A (zh) * 2016-12-25 2017-10-13 池州市建东生物科技有限公司 一种皮肤病专用肥皂
EP3743494B1 (fr) 2018-01-26 2025-08-06 Ecolab Usa Inc. Tensioactif liquide solidifié à base d'oxyde d'amine avec un liant comprenant de l'urée et un support optionnel
WO2019148071A1 (fr) 2018-01-26 2019-08-01 Ecolab Usa Inc. Tensioactifs anioniques liquides solidifiants
CA3089629A1 (fr) 2018-01-26 2019-08-01 Ecolab Usa Inc. Solidification de tensioactifs liquides d'oxyde d'amine, de betaine et/ou de sultaine ayant un vehicule
US12138328B2 (en) 2020-04-10 2024-11-12 The Procter & Gamble Company Rheological solid composition
US12122979B2 (en) 2020-04-10 2024-10-22 The Procter & Gamble Company Cleaning article with preferential rheological solid composition
WO2021216288A1 (fr) 2020-04-10 2021-10-28 The Procter & Gamble Company Outil de nettoyage avec une composition solide rhéologique
WO2021207438A1 (fr) * 2020-04-10 2021-10-14 The Procter & Gamble Company Produit de soin buccal comprenant une composition solide rhéologique
EP4132476A1 (fr) 2020-04-10 2023-02-15 The Procter & Gamble Company Composition orale solide rhéologique
WO2021207440A1 (fr) 2020-04-10 2021-10-14 The Procter & Gamble Company Composition de matière solide rhéologique
US11833237B2 (en) 2021-03-09 2023-12-05 The Procter & Gamble Company Method for enhancing scalp active deposition
EP4098243A1 (fr) * 2021-05-31 2022-12-07 BIC Violex Single Member S.A. Composition solide d'aide au rasage
CA3235997A1 (fr) * 2022-08-12 2024-02-15 Matthew Lawrence Lynch Compositions solides solubles
EP4569073A1 (fr) * 2022-08-12 2025-06-18 The Procter & Gamble Company Compositions solides solubles
WO2024036117A1 (fr) * 2022-08-12 2024-02-15 The Procter & Gamble Company Compositions à faible teneur en eau
CN117916355A (zh) * 2022-08-12 2024-04-19 宝洁公司 低含水量组合物
JP2024543276A (ja) * 2022-08-12 2024-11-20 ザ プロクター アンド ギャンブル カンパニー 固体溶解性組成物
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Also Published As

Publication number Publication date
JPH06503122A (ja) 1994-04-07
FI932366A0 (fi) 1993-05-25
EP0559837A1 (fr) 1993-09-15
NZ240709A (en) 1995-04-27
CN1036529C (zh) 1997-11-26
ES2079180T3 (es) 1996-01-01
KR100226393B1 (ko) 1999-10-15
RU2080365C1 (ru) 1997-05-27
CA2095351C (fr) 1998-12-15
HU9301532D0 (en) 1993-09-28
AR247426A1 (es) 1994-12-29
HUT76489A (en) 1997-09-29
NO931848L (no) 1993-07-23
EP0559837B1 (fr) 1995-10-25
FI932366A7 (fi) 1993-05-25
FI932366L (fi) 1993-05-25
AU657295B2 (en) 1995-03-09
DE69114143D1 (de) 1995-11-30
CA2095351A1 (fr) 1992-05-27
CZ98793A3 (en) 1994-07-13
NO931848D0 (no) 1993-05-21
EG19580A (en) 1995-08-30
CN1062759A (zh) 1992-07-15
MA22349A1 (fr) 1992-07-01
HU215484B (hu) 1999-01-28
BR9107125A (pt) 1993-11-09
PT99606A (pt) 1992-10-30
SK52693A3 (en) 1994-01-12
WO1992009679A1 (fr) 1992-06-11
HK1006179A1 (en) 1999-02-12
GR3017892T3 (en) 1996-01-31
AU9176391A (en) 1992-06-25
CZ283495B6 (cs) 1998-04-15
MX9102229A (es) 1992-07-08
IE72087B1 (en) 1997-03-12
DE69114143T2 (de) 1996-04-25
IE914094A1 (en) 1992-06-03
SG59939A1 (en) 1999-02-22
DK0559837T3 (da) 1996-03-04

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