ATE132157T1 - Verfahren zur herstellung von metallocenen - Google Patents

Verfahren zur herstellung von metallocenen

Info

Publication number
ATE132157T1
ATE132157T1 AT90870205T AT90870205T ATE132157T1 AT E132157 T1 ATE132157 T1 AT E132157T1 AT 90870205 T AT90870205 T AT 90870205T AT 90870205 T AT90870205 T AT 90870205T AT E132157 T1 ATE132157 T1 AT E132157T1
Authority
AT
Austria
Prior art keywords
metallocenes
producing
producing metallocenes
alkyllithium
metallocene
Prior art date
Application number
AT90870205T
Other languages
English (en)
Inventor
Abbas Razavi
Original Assignee
Fina Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Research filed Critical Fina Research
Application granted granted Critical
Publication of ATE132157T1 publication Critical patent/ATE132157T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT90870205T 1989-10-30 1990-10-30 Verfahren zur herstellung von metallocenen ATE132157T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP89870164 1989-10-30

Publications (1)

Publication Number Publication Date
ATE132157T1 true ATE132157T1 (de) 1996-01-15

Family

ID=8203288

Family Applications (1)

Application Number Title Priority Date Filing Date
AT90870205T ATE132157T1 (de) 1989-10-30 1990-10-30 Verfahren zur herstellung von metallocenen

Country Status (8)

Country Link
US (1) US5117020A (de)
JP (1) JP2813057B2 (de)
KR (1) KR0160267B1 (de)
AT (1) ATE132157T1 (de)
CA (1) CA2029153C (de)
DE (1) DE69024463T2 (de)
ES (1) ES2081971T3 (de)
WO (1) WO1991006551A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5594078A (en) * 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
NL9101502A (nl) * 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.
ES2113900T3 (es) * 1992-06-13 1998-05-16 Targor Gmbh Proceso para la preparacion de catalizadores de metalocenos quirales, puenteados del tipo bisindenilo.
US5200537A (en) * 1992-08-03 1993-04-06 Ethyl Corporation Process for preparing metallocenes
EP0645393B1 (de) * 1993-09-20 2000-01-05 Albemarle Corporation Aluminoxanen mit einer erhöhten katalytischen Aktivität
US5563284A (en) * 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
FR2725993B1 (fr) * 1994-10-21 1996-11-29 Atochem Elf Sa Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
PT835886E (pt) * 1996-10-09 2004-05-31 Atofina Res Processo para a preparacao e utilizacao de compostos de dicloreto de (bis(indenil)etano)zirconio meso/racemico
IT1290856B1 (it) * 1996-12-19 1998-12-14 Enichem Spa Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine
ID19264A (id) * 1996-12-20 1998-06-28 Union Carbide Chem Plastic Pro-katalisator dan pengolahan untuk membuatnya
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
US6107501A (en) * 1997-01-30 2000-08-22 Fina Technology, Inc. Synthesis of metallocenes and enrichment of their rac isomer
US5942462A (en) * 1997-10-20 1999-08-24 Akzo Nobel N.V. Process for preparing group 6 metal-based olefin polymerization catalyst component
RU2139883C1 (ru) * 1998-12-18 1999-10-20 Государственный научный центр Российской Федерации Государственный научно-исследовательский институт химии и технологии элементоорганических соединений Способ получения бис-(циклопентадиенил)хрома

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US4851598A (en) * 1987-12-28 1989-07-25 Brandeis University Method of preparing metallocene compounds
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5036034A (en) * 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene

Also Published As

Publication number Publication date
US5117020A (en) 1992-05-26
CA2029153C (en) 2001-07-17
WO1991006551A1 (en) 1991-05-16
KR920701222A (ko) 1992-08-11
DE69024463D1 (de) 1996-02-08
JP2813057B2 (ja) 1998-10-22
KR0160267B1 (ko) 1999-01-15
ES2081971T3 (es) 1996-03-16
CA2029153A1 (en) 1992-05-02
DE69024463T2 (de) 1996-06-20
JPH03271298A (ja) 1991-12-03

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Legal Events

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UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee