ATE159231T1 - Verfahren zur herstellung von mischungen von wasserstoff und kohlenmonoxid oder von wasserstoff aus methan - Google Patents

Verfahren zur herstellung von mischungen von wasserstoff und kohlenmonoxid oder von wasserstoff aus methan

Info

Publication number
ATE159231T1
ATE159231T1 AT94917197T AT94917197T ATE159231T1 AT E159231 T1 ATE159231 T1 AT E159231T1 AT 94917197 T AT94917197 T AT 94917197T AT 94917197 T AT94917197 T AT 94917197T AT E159231 T1 ATE159231 T1 AT E159231T1
Authority
AT
Austria
Prior art keywords
hydrogen
pct
methane
carbon monoxide
sec
Prior art date
Application number
AT94917197T
Other languages
English (en)
Inventor
Looij Francine Van
John Wilhelm Geus
Original Assignee
Gastec Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19862400&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE159231(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Gastec Nv filed Critical Gastec Nv
Application granted granted Critical
Publication of ATE159231T1 publication Critical patent/ATE159231T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/392Metal surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)
AT94917197T 1993-05-13 1994-05-16 Verfahren zur herstellung von mischungen von wasserstoff und kohlenmonoxid oder von wasserstoff aus methan ATE159231T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL9300833A NL9300833A (nl) 1993-05-13 1993-05-13 Werkwijze voor de produktie van waterstof/koolmonoxide mengsels of waterstof uit methaan.

Publications (1)

Publication Number Publication Date
ATE159231T1 true ATE159231T1 (de) 1997-11-15

Family

ID=19862400

Family Applications (1)

Application Number Title Priority Date Filing Date
AT94917197T ATE159231T1 (de) 1993-05-13 1994-05-16 Verfahren zur herstellung von mischungen von wasserstoff und kohlenmonoxid oder von wasserstoff aus methan

Country Status (12)

Country Link
US (1) US5714092A (de)
EP (1) EP0738235B1 (de)
JP (1) JPH09502414A (de)
AT (1) ATE159231T1 (de)
AU (1) AU6858694A (de)
DE (1) DE69406311T2 (de)
DK (1) DK0738235T3 (de)
ES (1) ES2110757T3 (de)
GR (1) GR3025614T3 (de)
NL (1) NL9300833A (de)
NO (1) NO954543L (de)
WO (1) WO1994026656A1 (de)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5905180A (en) 1996-01-22 1999-05-18 Regents Of The University Of Minnesota Catalytic oxidative dehydrogenation process and catalyst
JPH09315801A (ja) * 1996-03-26 1997-12-09 Toyota Motor Corp 燃料改質方法と燃料改質装置ならびに該燃料改質装置を備えた燃料電池システム
FR2768424B1 (fr) * 1997-09-01 1999-10-29 Albin Czernichowski Assistance electrique d'oxydation partielle d'hydrocarbures legers par l'oxygene
WO1999011572A1 (en) * 1997-09-01 1999-03-11 Laxarco Holding Limited Electrically assisted partial oxidation of light hydrocarbons by oxygen
US6254807B1 (en) * 1998-01-12 2001-07-03 Regents Of The University Of Minnesota Control of H2 and CO produced in partial oxidation process
PL190848B1 (pl) * 1998-07-08 2006-02-28 Toyota Motor Co Ltd Urządzenie do reformowania paliwa
US6080301A (en) 1998-09-04 2000-06-27 Exxonmobil Research And Engineering Company Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins
US6475960B1 (en) 1998-09-04 2002-11-05 Exxonmobil Research And Engineering Co. Premium synthetic lubricants
NO317870B1 (no) * 1998-09-16 2004-12-27 Statoil Asa Fremgangsmate for a fremstille en H<N>2</N>-rik gass og en CO<N>2</N>-rik gass ved hoyt trykk
CA2282948A1 (en) 1998-09-16 2000-03-16 University Technologies International, Inc. Low temperature autothermal steam reformation of methane in a fluidized bed
US6613708B1 (en) * 1999-06-07 2003-09-02 Exxonmobil Chemical Patents Inc. Catalyst selectivation
AU2000246479A1 (en) * 2000-04-07 2001-10-23 Phillips Petroleum Company Process for preparing fischer-tropsch catalyst
US6436363B1 (en) * 2000-08-31 2002-08-20 Engelhard Corporation Process for generating hydrogen-rich gas
FR2817444B1 (fr) 2000-11-27 2003-04-25 Physiques Ecp Et Chimiques Generateurs et circuits electriques pour alimenter des decharges instables de haute tension
JP4098508B2 (ja) * 2001-08-20 2008-06-11 財団法人 ひろしま産業振興機構 炭化水素と水蒸気とを反応させるための触媒の製造方法および当該触媒を使用した炭化水素から水素を製造する方法
US20030096880A1 (en) * 2001-11-02 2003-05-22 Conoco Inc. Combustion deposited metal-metal oxide catalysts and process for producing synthesis gas
US6852668B2 (en) * 2001-12-03 2005-02-08 University Of Western Ont Catalyst for hydrocarbon reforming reaction
JP4102080B2 (ja) * 2002-02-13 2008-06-18 フジセラテック株式会社 燃料改質装置
US20030162846A1 (en) 2002-02-25 2003-08-28 Wang Shoou-L Process and apparatus for the production of synthesis gas
JP4316323B2 (ja) * 2002-10-04 2009-08-19 独立行政法人石油天然ガス・金属鉱物資源機構 炭化水素リフォーミング用触媒及びその製造方法
JP4870900B2 (ja) * 2003-02-24 2012-02-08 戸田工業株式会社 炭化水素分解用触媒及びその製造方法、並びに該炭化水素分解用触媒を用いた水素製造方法
US7125913B2 (en) * 2003-03-14 2006-10-24 Conocophillips Company Partial oxidation reactors and syngas coolers using nickel-containing components
JP4332724B2 (ja) * 2004-02-13 2009-09-16 戸田工業株式会社 オートサーマルリフォーミング触媒及びその製造方法、並びに該オートサーマルリフォーミング触媒を用いた水素の製造方法
WO2005097319A1 (en) * 2004-04-08 2005-10-20 Sulzer Metco (Canada) Inc. Supported catalyst for steam methane reforming and autothermal reforming reactions
JP4340892B2 (ja) * 2004-08-24 2009-10-07 戸田工業株式会社 炭化水素分解用触媒及びその製造法、該炭化水素分解用触媒を用いた水素の製造方法
JP4332733B2 (ja) * 2004-08-24 2009-09-16 戸田工業株式会社 炭化水素分解用触媒及び該炭化水素分解用触媒を用いた水素の製造方法
US8826834B2 (en) 2006-07-14 2014-09-09 Ceramatec, Inc. Apparatus and method of electric arc incineration
US8618436B2 (en) 2006-07-14 2013-12-31 Ceramatec, Inc. Apparatus and method of oxidation utilizing a gliding electric arc
EP2116105A4 (de) 2007-02-23 2014-04-16 Ceramatec Inc Keramikelektrode für einen gleitenden lichtbogen
DE102007038760B3 (de) * 2007-08-16 2009-01-02 Dge Dr.-Ing. Günther Engineering Gmbh Verfahren und Anlage zur Herstellung von Synthesegas aus Biogas
RU2381175C2 (ru) * 2007-11-30 2010-02-10 Общество С Ограниченной Ответственностью "Центр Кортэс" Способ получения водородометановой смеси
RU2438969C1 (ru) * 2010-05-13 2012-01-10 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения метановодородной смеси
JP6802353B2 (ja) * 2017-03-01 2020-12-16 Toyo Tire株式会社 メタンの二酸化炭素改質用触媒及びその製造方法、並びに合成ガスの製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB224765A (en) * 1924-01-23 1924-11-20 Louis Steinberger Improvements in or relating to hairpins
JPS55139837A (en) * 1979-04-18 1980-11-01 Fujimi Kenmazai Kogyo Kk Catalyst for steam modification of hydrocarbon
DE3382193D1 (de) * 1982-09-30 1991-04-11 Engelhard Corp Verfahren zur herstellung von wasserstoffreichem gas aus kohlenwasserstoffen.
GB2139644B (en) * 1983-04-06 1987-06-24 Ici Plc Synthesis gas
NL8800252A (nl) * 1988-02-02 1989-09-01 Veg Gasinstituut Nv Katalysator op drager voor het niet-selectief oxyderen van organische verbindingen, werkwijze voor het niet-selectief oxyderen van, in het bijzonder, organische verbindingen.
IT1242994B (it) * 1990-08-29 1994-05-23 Snam Progetti Processo catalitico per la produzione di gas di sintesi mediante reazione di combustione e di reforming degli idrocarburi
US5206202A (en) * 1991-07-25 1993-04-27 Corning Incorporated Catalyst device fabricated in situ and method of fabricating the device

Also Published As

Publication number Publication date
EP0738235A1 (de) 1996-10-23
EP0738235B1 (de) 1997-10-15
NO954543D0 (no) 1995-11-10
DK0738235T3 (da) 1998-05-18
GR3025614T3 (en) 1998-03-31
AU6858694A (en) 1994-12-12
US5714092A (en) 1998-02-03
NO954543L (no) 1995-11-10
JPH09502414A (ja) 1997-03-11
DE69406311D1 (de) 1997-11-20
NL9300833A (nl) 1994-12-01
ES2110757T3 (es) 1998-02-16
DE69406311T2 (de) 1998-04-23
WO1994026656A1 (en) 1994-11-24

Similar Documents

Publication Publication Date Title
ATE159231T1 (de) Verfahren zur herstellung von mischungen von wasserstoff und kohlenmonoxid oder von wasserstoff aus methan
US6887455B2 (en) Catalytic generation of hydrogen
DE60336444D1 (de) Verfahren zur Herstellung von Synthesegas
RU96100851A (ru) Способ выработки электроэнергии
ATE290998T1 (de) Verfahren zur autothermen dampfreformierung einer höhere kohlenwasserstoffe enthaltenden kohlenwasserstoffeinspeisung
JP2001519311A5 (de)
MY105861A (en) Process and apparatus for the production of heavier hydrocarbons from gaseous light hycarbons.
MY131482A (en) Process and apparatus for steam-methane reforming
EP0404712A3 (de) Brennstoffzellensystem
ATE270249T1 (de) Verfahren zur herstellung von synthesisgas unter verwendung von aus hydrotalcit abgeleiteten nickelkatalisatoren
NZ242569A (en) Process for the conversion of natural gas into higher hydrocarbons by reforming combined with a fischer-tropsch process
ATE396144T1 (de) Verfahren zur herstellung von langkettigen
CN85107305A (zh) 生产合成气的工艺过程
MX168297B (es) Procedimiento para la preparacion de un gas reductor
US6993911B2 (en) System for power generation in a process producing hydrocarbons
AU654612B2 (en) Process for producing a hydrogen-containing gas
MY106914A (en) Process for the activation of a catalyst
ATE65065T1 (de) Verfahren zur erzeugung eines wasserstoff enthaltenden gases aus kohlenwasserstoffen, wasserdampf und/ggf. kohlendioxid.
JP2885153B2 (ja) Sng製造用触媒材料及びsng製造方法
CN1320951C (zh) 利用部分催化氧化产生合成气的方法
RU2004138790A (ru) Способ получения углеводородов из газообразного углеводородного сырья
TW200633777A (en) Reforming catalyst for oxygen-containing hydrocarbon, method for producing hydrogen or synthesis gas using the same, and fuel cell system
RU95122561A (ru) Процесс получения смесей водород/оксид углерода или водорода из метана
KR960017501A (ko) 탄화수소로부터의 옥소가스(Oxo-gas)의 제조방법
Supply et al. Methanol via Methane (CH4) Catalytic Decomposition, and CO2

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee