ATE165583T1 - Verfahren und zusammensetzung für ein mikroemulsionsgel mit bleichenden und antiseptischen eigenschaften - Google Patents
Verfahren und zusammensetzung für ein mikroemulsionsgel mit bleichenden und antiseptischen eigenschaftenInfo
- Publication number
- ATE165583T1 ATE165583T1 AT93904604T AT93904604T ATE165583T1 AT E165583 T1 ATE165583 T1 AT E165583T1 AT 93904604 T AT93904604 T AT 93904604T AT 93904604 T AT93904604 T AT 93904604T AT E165583 T1 ATE165583 T1 AT E165583T1
- Authority
- AT
- Austria
- Prior art keywords
- oil
- water
- composition
- glycol ether
- phase
- Prior art date
Links
- 230000002421 anti-septic effect Effects 0.000 title abstract 2
- 238000004061 bleaching Methods 0.000 title abstract 2
- 239000004530 micro-emulsion Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 239000003921 oil Substances 0.000 abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 1
- ZQCIPRGNRQXXSK-UHFFFAOYSA-N 1-octadecoxypropan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCOCC(C)O ZQCIPRGNRQXXSK-UHFFFAOYSA-N 0.000 abstract 1
- MGYUQZIGNZFZJS-KTKRTIGZSA-N 2-[2-[(z)-octadec-9-enoxy]ethoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCOCCO MGYUQZIGNZFZJS-KTKRTIGZSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- 239000003974 emollient agent Substances 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 abstract 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 abstract 1
- 229940113096 isoceteth 20 Drugs 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 abstract 1
- 229940099570 oleth-2 Drugs 0.000 abstract 1
- 229940055577 oleyl alcohol Drugs 0.000 abstract 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- 229940078491 ppg-15 stearyl ether Drugs 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/068—Microemulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/902—Gelled emulsion
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Cosmetics (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/825,560 US5336432A (en) | 1992-01-24 | 1992-01-24 | Composition for microemulsion gel having bleaching and antiseptic properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE165583T1 true ATE165583T1 (de) | 1998-05-15 |
Family
ID=25244313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT93904604T ATE165583T1 (de) | 1992-01-24 | 1993-01-25 | Verfahren und zusammensetzung für ein mikroemulsionsgel mit bleichenden und antiseptischen eigenschaften |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5336432A (de) |
| EP (1) | EP0623094B1 (de) |
| JP (1) | JPH07503181A (de) |
| AT (1) | ATE165583T1 (de) |
| AU (1) | AU3590993A (de) |
| CA (1) | CA2128710A1 (de) |
| DE (1) | DE69318288T2 (de) |
| WO (1) | WO1993015018A1 (de) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5536438A (en) * | 1992-11-26 | 1996-07-16 | The Procter & Gamble Company | Multi-purpose liquid cleaning composition comprising nonionic surfactants of different HLB values |
| US5484597A (en) * | 1993-07-30 | 1996-01-16 | Chesebrough-Pond's Usa Co. | Clear hydroalcholic cosmetic microemulsions |
| US5902354A (en) * | 1994-04-12 | 1999-05-11 | The Procter & Gamble Company | Bleaching compositions |
| US6287545B1 (en) | 1994-12-19 | 2001-09-11 | Colgate-Palmolive Company | Hair conditioner compositions having improved freezing and freeze-thaw stability |
| AU704797B2 (en) * | 1994-12-19 | 1999-05-06 | Colgate-Palmolive Company, The | Hair conditioner compositions having improved freezing and freeze-thaw stability |
| US5776877A (en) * | 1995-05-25 | 1998-07-07 | The Clorox Company | Liquid peracid precursor colloidal dispersions: macroemulsions |
| US5954998A (en) * | 1995-05-25 | 1999-09-21 | The Clorox Company | Liquid peracid precursor colloidal dispersions: oil-core vesicles |
| US5792385A (en) * | 1995-05-25 | 1998-08-11 | The Clorox Company | Liquid peracid precursor colloidal dispersions: liquid crystals |
| US5681805A (en) * | 1995-05-25 | 1997-10-28 | The Clorox Company | Liquid peracid precursor colloidal dispersions: microemulsions |
| US5744062A (en) * | 1996-08-29 | 1998-04-28 | R.I.T.A. Corporation | Balanced emulsifier blends for oil-in-water emulsions |
| US5958984A (en) * | 1996-10-10 | 1999-09-28 | Devillez; Richard L. | Method and composition for skin treatment |
| US5736582A (en) * | 1996-10-10 | 1998-04-07 | Devillez; Richard L. | Method and composition for controlled delivery of nascent oxygen from hydrogen peroxide source for skin treatment |
| US6719988B2 (en) | 1997-02-21 | 2004-04-13 | The Regents Of The University Of California | Antiseptic compositions for inactivating prions |
| US20060008494A1 (en) * | 1997-02-21 | 2006-01-12 | The Regents Of The University Of California | Complete inactivation of infectious proteins |
| US6720355B2 (en) * | 1997-02-21 | 2004-04-13 | The Regents Of The University Of California | Sodium dodecyl sulfate compositions for inactivating prions |
| US6043209A (en) * | 1998-01-06 | 2000-03-28 | Playtex Products, Inc. | Stable compositions for removing stains from fabrics and carpets and inhibiting the resoiling of same |
| US6610751B1 (en) * | 2001-12-10 | 2003-08-26 | O'lenick, Jr. Anthony J. | Bimodal guerbet alkoxylates as emulsifiers |
| US6964782B1 (en) | 2002-07-23 | 2005-11-15 | Tec Labs, Inc. | Stable hydrogen peroxide compositions, products and methods of use |
| WO2004069220A1 (en) * | 2003-02-06 | 2004-08-19 | Dehli-Cleve Collection As | Peroxide compositions |
| US20050058673A1 (en) | 2003-09-09 | 2005-03-17 | 3M Innovative Properties Company | Antimicrobial compositions and methods |
| US20050271746A1 (en) * | 2004-05-18 | 2005-12-08 | Abbott Chun L | Topical treatments for abnormal biological conditions and method of topically treating such conditions |
| US20050282895A1 (en) * | 2004-06-21 | 2005-12-22 | Dosch Michael H | Antimicrobial compositions and methods of use thereof |
| AU2005279704B2 (en) | 2004-08-31 | 2010-05-13 | Stiefel Research Australia Pty Ltd | Microemulsion and sub-micron emulsion process and compositions |
| US8449867B2 (en) | 2004-08-31 | 2013-05-28 | Stiefel Research Australia Pty Ltd | Microemulsion and sub-micron emulsion process and compositions |
| US9028852B2 (en) | 2004-09-07 | 2015-05-12 | 3M Innovative Properties Company | Cationic antiseptic compositions and methods of use |
| US8198326B2 (en) | 2004-09-07 | 2012-06-12 | 3M Innovative Properties Company | Phenolic antiseptic compositions and methods of use |
| US20060051384A1 (en) * | 2004-09-07 | 2006-03-09 | 3M Innovative Properties Company | Antiseptic compositions and methods of use |
| US20060118416A1 (en) * | 2004-12-08 | 2006-06-08 | Honeywell International, Inc. | Electrochemical sensor system |
| BRPI0608691A2 (pt) | 2005-03-10 | 2010-12-07 | 3M Innovative Properties Company | composição antimicrobiana, e, métodos para matar ou inativar microorganismos em tecido da mucosa de um mamìfero, para tratar uma lesão ou ferimento infectado, para descolonização de microorganismos, para proporcionar eficácia antimicrobiana residual sobre uma superfìcie e para tratar uma condição |
| BRPI0608690B8 (pt) | 2005-03-10 | 2021-05-25 | 3M Innovative Properties Co | uso de uma composição antimicrobiana |
| US20070248557A1 (en) * | 2006-04-25 | 2007-10-25 | The Iams Company | Mild leave-on composition |
| DE102007041490A1 (de) * | 2007-08-31 | 2009-03-05 | Henkel Ag & Co. Kgaa | Blondiermittel und Blondierverfahren |
| US20090081136A1 (en) * | 2007-09-24 | 2009-03-26 | Deepak Sharma | Compositions Useful For Tooth Whitening |
| FR2940107B1 (fr) * | 2008-12-19 | 2011-03-18 | Oreal | Procede d'eclaircissement de matieres keratiniques mettant en oeuvre une emulsion comprenant un agent alcalin et une composition oxydante |
| US8569218B2 (en) * | 2011-03-07 | 2013-10-29 | Illinois Tool Works, Inc. | Cleaning composition containing polymer microemulsion |
| US8765658B2 (en) * | 2012-09-12 | 2014-07-01 | Carus Corporation | Method for making and using a stable cleaning composition |
| CN106236774A (zh) * | 2016-08-04 | 2016-12-21 | 陈广圣 | 一种多用途抗菌剂 |
| CN106237335A (zh) * | 2016-08-04 | 2016-12-21 | 陈广圣 | 一种皮肤病学领域用抗菌剂 |
| EP4392525A1 (de) * | 2021-11-22 | 2024-07-03 | Colgate-Palmolive Company | Brausezusammensetzungen und daraus hergestellte lösungen |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2886532A (en) * | 1954-04-15 | 1959-05-12 | Shell Dev | Hydrogen peroxide emulsions |
| US3114720A (en) * | 1960-06-06 | 1963-12-17 | Universal Oil Prod Co | Manufacture of spherical alumina |
| US4010872A (en) * | 1968-08-28 | 1977-03-08 | Dart Industries Inc. | Oxidation hair dye in a plural-fluids dispensing package |
| US3996341A (en) * | 1975-04-30 | 1976-12-07 | Fmc Corporation | Process for purifying trioctyl phosphate and use therefor |
| US4146499A (en) * | 1976-09-18 | 1979-03-27 | Rosano Henri L | Method for preparing microemulsions |
| US4184978A (en) * | 1977-05-04 | 1980-01-22 | C. J. Patterson Company | Stable water in oil emulsion systems for cosmetic and pharmaceutical preparations |
| FR2464745A1 (fr) * | 1979-09-06 | 1981-03-20 | Oxysynthese | Regeneration des catalyseurs de reconversion chimique utilises dans un procede cyclique de fabrication du peroxyde d'hydrogene |
| US4496473A (en) * | 1982-04-27 | 1985-01-29 | Interox Chemicals Limited | Hydrogen peroxide compositions |
| US4472291A (en) * | 1983-03-07 | 1984-09-18 | Rosano Henri L | High viscosity microemulsions |
| US5076954A (en) * | 1986-05-21 | 1991-12-31 | Colgate-Palmolive Company | Stable microemulsion cleaning composition |
| US4835002A (en) * | 1987-07-10 | 1989-05-30 | Wolf Peter A | Microemulsions of oil in water and alcohol |
| DE3732147A1 (de) * | 1987-09-24 | 1989-04-06 | Henkel Kgaa | Emulsionsfoermige wasserstoffperoxid-zubereitungen zum blondieren und oxidativen faerben der haare |
| US5017354A (en) * | 1988-09-02 | 1991-05-21 | Akzo America Inc. | Process for production of high purity silica gel |
| EP0384415B1 (de) * | 1989-02-23 | 1994-06-01 | Kao Corporation | Haarbehandlungsmittel |
| US4934457A (en) * | 1989-07-18 | 1990-06-19 | Wallender Kenneth D | Composition and method for stimulating wells |
| DE4023893A1 (de) * | 1990-07-27 | 1992-01-30 | Henkel Kgaa | Bleichendes fluessigwaschmittel |
| US5419847A (en) * | 1993-05-13 | 1995-05-30 | The Procter & Gamble Company | Translucent, isotropic aqueous liquid bleach composition |
| US5492540A (en) * | 1994-06-13 | 1996-02-20 | S. C. Johnson & Son, Inc. | Soft surface cleaning composition and method with hydrogen peroxide |
-
1992
- 1992-01-24 US US07/825,560 patent/US5336432A/en not_active Expired - Lifetime
-
1993
- 1993-01-25 DE DE69318288T patent/DE69318288T2/de not_active Expired - Fee Related
- 1993-01-25 WO PCT/US1993/000644 patent/WO1993015018A1/en not_active Ceased
- 1993-01-25 AU AU35909/93A patent/AU3590993A/en not_active Abandoned
- 1993-01-25 JP JP5513369A patent/JPH07503181A/ja active Pending
- 1993-01-25 EP EP93904604A patent/EP0623094B1/de not_active Expired - Lifetime
- 1993-01-25 CA CA002128710A patent/CA2128710A1/en not_active Abandoned
- 1993-01-25 AT AT93904604T patent/ATE165583T1/de active
-
1994
- 1994-08-08 US US08/287,087 patent/US5575948A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0623094A1 (de) | 1994-11-09 |
| AU3590993A (en) | 1993-09-01 |
| US5575948A (en) | 1996-11-19 |
| DE69318288T2 (de) | 1999-01-21 |
| DE69318288D1 (de) | 1998-06-04 |
| EP0623094B1 (de) | 1998-04-29 |
| CA2128710A1 (en) | 1993-08-05 |
| JPH07503181A (ja) | 1995-04-06 |
| US5336432A (en) | 1994-08-09 |
| EP0623094A4 (de) | 1995-04-26 |
| WO1993015018A1 (en) | 1993-08-05 |
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