ATE169902T1 - Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefine - Google Patents
Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefineInfo
- Publication number
- ATE169902T1 ATE169902T1 AT95901801T AT95901801T ATE169902T1 AT E169902 T1 ATE169902 T1 AT E169902T1 AT 95901801 T AT95901801 T AT 95901801T AT 95901801 T AT95901801 T AT 95901801T AT E169902 T1 ATE169902 T1 AT E169902T1
- Authority
- AT
- Austria
- Prior art keywords
- pct
- monoolefins
- monoolefine
- addition
- hydrogen cyanide
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 title 2
- 239000003054 catalyst Substances 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 239000012018 catalyst precursor Substances 0.000 abstract 2
- 150000005673 monoalkenes Chemical class 0.000 abstract 2
- 239000002841 Lewis acid Substances 0.000 abstract 1
- -1 acyclic aliphatic monoolefins Chemical class 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 238000005669 hydrocyanation reaction Methods 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
- C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
- C07C255/03—Mononitriles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15734293A | 1993-11-23 | 1993-11-23 | |
| US19896394A | 1994-02-18 | 1994-02-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE169902T1 true ATE169902T1 (de) | 1998-09-15 |
Family
ID=26854028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT95901801T ATE169902T1 (de) | 1993-11-23 | 1994-11-07 | Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefine |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US5688986A (de) |
| EP (1) | EP0730574B1 (de) |
| JP (1) | JP3553952B2 (de) |
| KR (1) | KR100263138B1 (de) |
| CN (2) | CN1145531C (de) |
| AT (1) | ATE169902T1 (de) |
| BR (1) | BR9408151A (de) |
| CA (1) | CA2177135C (de) |
| DE (1) | DE69412635T2 (de) |
| DK (1) | DK0730574T3 (de) |
| ES (1) | ES2122515T3 (de) |
| GR (1) | GR3027731T3 (de) |
| TW (1) | TW457244B (de) |
| WO (1) | WO1995014659A1 (de) |
Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR9507460A (pt) | 1994-04-14 | 1997-09-02 | Du Pont | Processo para hidrocianação e composição de precursor de catalisador |
| TW315370B (de) * | 1994-10-07 | 1997-09-11 | Du Pont | |
| US5821378A (en) * | 1995-01-27 | 1998-10-13 | E. I. Du Pont De Nemours And Company | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles |
| IN187044B (de) * | 1995-01-27 | 2002-01-05 | Du Pont | |
| FR2743010B1 (fr) * | 1995-12-29 | 1998-02-20 | Rhone Poulenc Fibres | Procede de preparation par hydrogenation de catalyseurs a base de metal de transition et de phosphine |
| DE19652273A1 (de) | 1996-12-16 | 1998-06-18 | Basf Ag | Monoolefinische C¶5¶-Mononitrile, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US6121184A (en) * | 1997-07-29 | 2000-09-19 | E. I. Du Pont De Nemours And Company | Supported bis(phosphorus) ligands |
| US5847191A (en) * | 1997-07-29 | 1998-12-08 | E. I. Du Pont De Nemours And Company | Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel |
| ZA986369B (en) * | 1997-07-29 | 2000-01-17 | Du Pont | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles. |
| US6229052B1 (en) | 1998-05-29 | 2001-05-08 | E. I. Du Pont De Nemours And Company | Hydroformylation of olefins using supported bis(phosphorus) ligands |
| DE19825212A1 (de) | 1998-06-05 | 1999-12-09 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
| WO2001007156A1 (en) | 1999-07-21 | 2001-02-01 | Uab Research Foundation | Metallacrown ether catalysts for hydroformylation |
| US6048996A (en) * | 1999-08-26 | 2000-04-11 | E. I. Du Pont De Nemours And Company | Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins |
| US6515161B1 (en) | 1999-09-20 | 2003-02-04 | E. I. Du Pont De Nemours And Company | Hydroformylation process utilizing multidentate phosphite ligands |
| US6380421B1 (en) | 1999-09-20 | 2002-04-30 | E. I. Du Pont De Nemours And Company | Multidentate phosphite ligands, catalytic compositions containing such ligands and catalytic processes utilizing such catalytic compositions |
| US6420611B1 (en) | 1999-09-20 | 2002-07-16 | E. I. Du Pont De Nemours And Company | Composition comprising polymeric phosphite |
| US6284865B1 (en) * | 1999-09-20 | 2001-09-04 | E. I. Du Pont De Nemours And Company | Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles |
| BR0014567A (pt) | 1999-09-20 | 2002-06-18 | Du Pont | Processo de hidrocianação, ligante de fosfito multidentado e composição de catalisador |
| DE10136488A1 (de) * | 2001-07-27 | 2003-02-06 | Basf Ag | Ni(O) enthaltendes Katalysatorsystem |
| US6660876B2 (en) | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
| US6489517B1 (en) | 2001-11-26 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Process for preparing 3,3′,6,6′-tetraalkyl-2,2′-biphenols and 3,3′,6,6′-tetraalkyl-5,5′-dihalo-2,2′-biphenols |
| JP4313674B2 (ja) * | 2001-11-26 | 2009-08-12 | インビスタ テクノロジーズ エス エイ アール エル | 担持されたビス（リン）配位子および触媒作用におけるそれらの使用 |
| TW593251B (en) | 2001-11-26 | 2004-06-21 | Du Pont | Process for preparing 3,3',5,5',6,6'-hexaalkyl-2,2'-biphenols, 3,3',4,4',5,5'-hexaalkyl-2,2'-biphenols and 3,3',4,4',5,5',6,6'-octaalkyl-2,2'-biphenols |
| US6893996B2 (en) | 2001-11-26 | 2005-05-17 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| US7196033B2 (en) * | 2001-12-14 | 2007-03-27 | Huntsman Petrochemical Corporation | Advances in amination catalysis |
| AR038161A1 (es) * | 2002-01-24 | 2004-12-29 | Basf Ag | Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos |
| DE60304034T2 (de) | 2002-03-11 | 2006-10-12 | Union Carbide Chemicals & Plastics Technology Corp., Danbury | Bisphosphit-ligande für carbonylierungsverfahren |
| DE60319725T2 (de) | 2002-10-15 | 2009-01-29 | Dow Technology Investments LLC, Midland | Bischelatligand und seine verwendung in carbonylierungs-verfahren |
| US6906218B2 (en) | 2002-12-18 | 2005-06-14 | Invista North America S.A.R.L. | Cyclohexane derivatives and methods for their preparation |
| FR2849027B1 (fr) * | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
| US6936171B2 (en) * | 2003-01-08 | 2005-08-30 | Invista North America S.A.R.L. | Process for catalyst recovery from hydrocyanation product mixtures |
| US6897329B2 (en) * | 2003-01-14 | 2005-05-24 | Invista North America S.A.R.L. | Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| FR2850966B1 (fr) | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
| US6844289B2 (en) * | 2003-04-08 | 2005-01-18 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst |
| FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
| FR2854892B1 (fr) | 2003-05-12 | 2005-06-24 | Rhodia Polyamide Intermediates | Procede de fabrication de dinitriles |
| EP2154127A3 (de) | 2003-09-11 | 2010-10-13 | Invista Technologies S.à.r.l. | Umwandlung von hydrocyanierten ungesättigten Carboxylsäurederivaten zu Aminen |
| DE10351000A1 (de) * | 2003-10-30 | 2005-06-09 | Basf Ag | Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen |
| DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
| DE102004004683A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Dinitrilen |
| US8119829B2 (en) | 2004-09-08 | 2012-02-21 | Invista North America S.A.R.L. | Process of hydrocyanation of unsaturated carboxylic acid derivatives |
| ES2532982T3 (es) | 2005-10-18 | 2015-04-06 | Invista Technologies S.À.R.L. | Proceso de preparación de 3-aminopentanonitrilo |
| WO2007109005A2 (en) | 2006-03-17 | 2007-09-27 | Invista Technologies S.A R.L. | Method for the purification of triorganophosphites by treatment with a basic additive |
| US7880028B2 (en) | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| US7919646B2 (en) | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| US7709673B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| US7659422B2 (en) * | 2006-07-14 | 2010-02-09 | Invista North America S.A.R.L. | Hydrocyanation process with reduced yield losses |
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| EP2146930A2 (de) | 2007-05-14 | 2010-01-27 | INVISTA Technologies S.à.r.l. | Hocheffizienter reaktor und entsprechendes verfahren |
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| EP2794047B1 (de) | 2011-12-21 | 2021-04-14 | INVISTA Textiles (U.K.) Limited | Regelung des extraktionslösungsmittels zur verminderung stabiler emulsionen |
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| KR20150035479A (ko) | 2011-12-21 | 2015-04-06 | 인비스타 테크놀러지스 에스.에이 알.엘. | 안정한 에멀젼을 감소시키기 위한 추출 용매 제어 |
| US9133223B2 (en) | 2011-12-21 | 2015-09-15 | Invista North America S.A.R.L. | Extraction solvent control for reducing stable emulsions |
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| RU2660899C2 (ru) * | 2011-12-30 | 2018-07-11 | Басф Се | Кристаллический сольват и несольватированные формы 6,6'-[[3,3',5,5'-тетракис(1,1-диметилэтил)-[1,1'-бифенил]-2,2'-диил]бис(окси)]бис-дибензо[d,f][1,3,2]-диоксафосфепина |
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| US9458185B2 (en) | 2012-02-10 | 2016-10-04 | The Regents Of The University Of California | First row metal-based catalysts for hydosilylation |
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| CN119095858A (zh) | 2022-08-02 | 2024-12-06 | 英威达纺织（英国）有限公司 | 双齿亚磷酸酯配体、含有此类配体的催化组合物以及利用此类催化组合物的催化方法 |
| EP4511380B1 (de) | 2022-08-02 | 2025-11-05 | INVISTA Textiles (U.K.) Limited | Arsen enthaltende liganden, katalytische zusammensetzungen die diese enthalten und katalytische verfahren, die solche katalytischen zusammensetzungen verwenden |
| WO2024028715A1 (en) * | 2022-08-02 | 2024-02-08 | Inv Nylon Chemicals Americas, Llc | Processes for producing nitriles and phosphorus-containing catalysts for use in such processes |
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-
1994
- 1994-11-07 CA CA002177135A patent/CA2177135C/en not_active Expired - Fee Related
- 1994-11-07 DK DK95901801T patent/DK0730574T3/da active
- 1994-11-07 KR KR1019960702713A patent/KR100263138B1/ko not_active Expired - Fee Related
- 1994-11-07 DE DE69412635T patent/DE69412635T2/de not_active Expired - Lifetime
- 1994-11-07 BR BR9408151A patent/BR9408151A/pt not_active IP Right Cessation
- 1994-11-07 WO PCT/US1994/012794 patent/WO1995014659A1/en not_active Ceased
- 1994-11-07 CN CNB011170700A patent/CN1145531C/zh not_active Expired - Lifetime
- 1994-11-07 AT AT95901801T patent/ATE169902T1/de not_active IP Right Cessation
- 1994-11-07 CN CN94194862A patent/CN1082946C/zh not_active Expired - Lifetime
- 1994-11-07 US US08/424,351 patent/US5688986A/en not_active Expired - Lifetime
- 1994-11-07 ES ES95901801T patent/ES2122515T3/es not_active Expired - Lifetime
- 1994-11-07 EP EP95901801A patent/EP0730574B1/de not_active Expired - Lifetime
- 1994-11-07 JP JP51508995A patent/JP3553952B2/ja not_active Expired - Fee Related
- 1994-11-08 TW TW083110338A patent/TW457244B/zh not_active IP Right Cessation
-
1996
- 1996-09-26 US US08/721,068 patent/US5723641A/en not_active Expired - Lifetime
-
1998
- 1998-08-26 GR GR980401912T patent/GR3027731T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0730574A1 (de) | 1996-09-11 |
| KR960705770A (ko) | 1996-11-08 |
| CN1327881A (zh) | 2001-12-26 |
| ES2122515T3 (es) | 1998-12-16 |
| US5723641A (en) | 1998-03-03 |
| GR3027731T3 (en) | 1998-11-30 |
| CN1145531C (zh) | 2004-04-14 |
| DE69412635T2 (de) | 1999-04-15 |
| JP3553952B2 (ja) | 2004-08-11 |
| BR9408151A (pt) | 1997-08-05 |
| CA2177135C (en) | 2005-04-26 |
| DE69412635D1 (de) | 1998-09-24 |
| CN1082946C (zh) | 2002-04-17 |
| EP0730574B1 (de) | 1998-08-19 |
| CA2177135A1 (en) | 1995-06-01 |
| JPH09505586A (ja) | 1997-06-03 |
| DK0730574T3 (da) | 1999-05-25 |
| TW457244B (en) | 2001-10-01 |
| WO1995014659A1 (en) | 1995-06-01 |
| US5688986A (en) | 1997-11-18 |
| CN1142224A (zh) | 1997-02-05 |
| KR100263138B1 (ko) | 2000-08-01 |
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