ATE176220T1 - Oligomerisierung und katalysator dafuer - Google Patents

Oligomerisierung und katalysator dafuer

Info

Publication number
ATE176220T1
ATE176220T1 AT95911261T AT95911261T ATE176220T1 AT E176220 T1 ATE176220 T1 AT E176220T1 AT 95911261 T AT95911261 T AT 95911261T AT 95911261 T AT95911261 T AT 95911261T AT E176220 T1 ATE176220 T1 AT E176220T1
Authority
AT
Austria
Prior art keywords
pct
zsm
sec
oligomerization
catalyst
Prior art date
Application number
AT95911261T
Other languages
English (en)
Inventor
Wim Herman Verrelst
Luc Roger Marc Martens
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9403367A external-priority patent/GB9403367D0/en
Priority claimed from GB9419664A external-priority patent/GB9419664D0/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ATE176220T1 publication Critical patent/ATE176220T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
AT95911261T 1994-02-22 1995-02-22 Oligomerisierung und katalysator dafuer ATE176220T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9403367A GB9403367D0 (en) 1994-02-22 1994-02-22 Oligomerization and catalysts therefor
GB9419664A GB9419664D0 (en) 1994-09-28 1994-09-28 Oligomerization and catalysts therefor

Publications (1)

Publication Number Publication Date
ATE176220T1 true ATE176220T1 (de) 1999-02-15

Family

ID=26304375

Family Applications (1)

Application Number Title Priority Date Filing Date
AT95911261T ATE176220T1 (de) 1994-02-22 1995-02-22 Oligomerisierung und katalysator dafuer

Country Status (11)

Country Link
US (1) US6143942A (de)
EP (1) EP0746538B1 (de)
JP (1) JPH09509207A (de)
KR (1) KR100364560B1 (de)
CN (1) CN1066426C (de)
AT (1) ATE176220T1 (de)
AU (1) AU681948B2 (de)
CA (1) CA2182994A1 (de)
DE (1) DE69507598T2 (de)
TW (1) TW363981B (de)
WO (1) WO1995022516A1 (de)

Families Citing this family (81)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059424C (zh) * 1994-11-23 2000-12-13 埃克森化学专利公司 应用沸石结合沸石催化剂的烃转化过程
GB9502342D0 (en) 1995-02-07 1995-03-29 Exxon Chemical Patents Inc Hydrocarbon treatment and catalyst therefor
GB0010433D0 (en) * 2000-04-28 2000-06-14 Exxon Chemical Patents Inc Alkene oligomerization process
US7112711B2 (en) 2000-04-28 2006-09-26 Exxonmobil Chemical Patents Inc. Alkene oligomerization process
US6875899B2 (en) * 2001-02-01 2005-04-05 Exxonmobil Chemical Patents Inc. Production of higher olefins
US20020103406A1 (en) 2001-02-01 2002-08-01 Georges Mathys Production of olefin dimers and oligomers
US7186874B2 (en) 2001-10-24 2007-03-06 Exxonmobil Chemical Patents Inc. Process for the oligomerization of olefins
AR036902A1 (es) * 2001-10-24 2004-10-13 Exxonmobil Chem Patents Inc Un proceso para la oligomerizacion de un material de alimentacion olefinico, usos de un limite en el nivel de azufre en el material de alimentacion, una mezcla oligomerica olefinica, y un ester o una composicion polimerica plastificada
US20030147604A1 (en) * 2002-02-01 2003-08-07 Tapia Alejandro L. Housing assembly for providing combined electrical grounding and fiber distribution of a fiber optic cable
US7183450B2 (en) * 2002-07-22 2007-02-27 Exxonmobil Chemical Patents Inc. Olefin oligomerization
JPWO2004022228A1 (ja) * 2002-09-09 2005-12-22 財団法人理工学振興会 オリゴマー化触媒及びそれを用いたオリゴマーの製造方法
US7196238B2 (en) * 2003-03-10 2007-03-27 Fortum Oyj Process for dimerizing light olefins
US7253330B2 (en) 2003-04-29 2007-08-07 Exxonmobil Chemical Patents Inc. Oligomerization process
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
US7586017B2 (en) 2003-12-18 2009-09-08 Exxonmobil Chemical Patents Inc. Hydrogenation
WO2005058787A1 (en) 2003-12-18 2005-06-30 Exxonmobil Chemical Patents Inc. Improvements in or relating to hydroformylation
GB0412139D0 (en) * 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
GB0412151D0 (en) 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
WO2006094006A2 (en) * 2005-02-28 2006-09-08 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization
GB0510887D0 (en) * 2005-05-31 2005-07-06 Exxonmobil Chem Patents Inc Oligomerization using molecular sieve catalysts
GB0511051D0 (en) * 2005-05-31 2005-07-06 Exxonmobil Chem Patents Inc Molecular sieve catalyst treatment
US7803332B2 (en) * 2005-05-31 2010-09-28 Exxonmobil Chemical Patents Inc. Reactor temperature control
GB0512377D0 (en) 2005-06-17 2005-07-27 Exxonmobil Chem Patents Inc Oligomerisation of olefins with zeolite catalyst
US7588738B2 (en) * 2005-08-23 2009-09-15 Exxonmobil Chemical Patents Inc. Series catalyst beds
US7572947B2 (en) * 2005-09-30 2009-08-11 Exxonmobil Chemical Patents Inc. Oligomerization reaction
CN100432192C (zh) * 2005-10-19 2008-11-12 中国石油化工股份有限公司 一种柴油馏分临氢降凝催化剂及其制备方法
CN100457868C (zh) * 2005-10-19 2009-02-04 中国石油化工股份有限公司 一种润滑油临氢脱蜡催化剂及其制备方法
CN100457867C (zh) * 2005-10-19 2009-02-04 中国石油化工股份有限公司 一种临氢脱蜡催化剂及其制备方法
US7501548B2 (en) 2006-03-10 2009-03-10 Exxonmobil Chemical Patents Inc. Oligomerization of isobutene-containing feedstocks
US8049054B2 (en) 2006-05-19 2011-11-01 Shell Oil Company Process for the preparation of C5 and/or C6 olefin
US8168842B2 (en) 2006-05-19 2012-05-01 Shell Oil Company Process for the alkylation of a cycloalkene
US7615673B2 (en) 2006-09-08 2009-11-10 Catalytic Distillation Technologies Propylene oligomerization process
WO2009065851A1 (en) 2007-11-19 2009-05-28 Shell Internationale Research Maatschappij B.V. Process for the preparation of an olefin
WO2009065870A1 (en) 2007-11-19 2009-05-28 Shell Internationale Research Maatschappij B.V. Process for the preparation of an olefinic product
KR20100095004A (ko) 2007-12-03 2010-08-27 게보 인코포레이티드 재생 조성물
US8193402B2 (en) 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
US7649123B2 (en) * 2008-01-15 2010-01-19 Catalytic Distillation Technologies Propylene oligomerization process
US8153854B2 (en) * 2008-06-06 2012-04-10 Catalytic Distillation Technologies Gasoline alkylate RVP control
US8372930B2 (en) 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
US8283428B2 (en) * 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
US8399725B2 (en) 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
US8853483B2 (en) * 2008-12-02 2014-10-07 Catalytic Distillation Technologies Oligomerization process
CN102264679B (zh) 2008-12-22 2014-07-23 国际壳牌研究有限公司 制备甲醇和/或二甲醚的方法
US8124819B2 (en) * 2009-01-08 2012-02-28 Catalytic Distillation Technologies Oligomerization process
US8492603B2 (en) * 2009-01-12 2013-07-23 Catalytic Distillation Technologies Selectivated isoolefin dimerization using metalized resins
EP2269734A1 (de) 2009-07-03 2011-01-05 BP Corporation North America Inc. Modifizierter Zeolitkatalysator
ES2391700T3 (es) 2009-07-03 2012-11-29 Bp Corporation North America Inc. Procedimiento de oligomerización de alquenos
WO2011011852A1 (en) * 2009-07-29 2011-02-03 Karl Chuang Process for making higher olefins
US8853117B2 (en) 2009-08-28 2014-10-07 Exxonmobil Chemical Patents Inc. Method of making a molecular sieve of MFS framework type with controllable average size
US8921590B2 (en) 2009-12-15 2014-12-30 Exxonmobil Chemical Patents Inc. Oligomerisation process
BR112012016883A2 (pt) 2010-01-08 2018-06-05 Gevo Inc metodos integrados de preparar produsot quimicos renovaveis
DE102010005704A1 (de) 2010-01-26 2011-07-28 Süd-Chemie AG, 80333 Verbesserter Katalysator auf Zeolithbasis zur Herstellung von Olefinen und zur Oligomerisierung von Olefinen
US8373012B2 (en) 2010-05-07 2013-02-12 Gevo, Inc. Renewable jet fuel blendstock from isobutanol
EP3569310A1 (de) 2010-05-14 2019-11-20 BP Oil International Limited Alken-oligomerisierungsverfahren
US20120022224A1 (en) 2010-07-22 2012-01-26 Geraldine Tosin Particles Including Zeolite Catalysts And Their Use In Oligomerization Processes
WO2012033562A1 (en) 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudates including zeolite catalysts and their use in oligomerization processes
EP2699618A4 (de) 2011-04-19 2014-12-17 Gevo Inc Variationen einer prins-reaktion zur herstellung von 2,5-dimethylhexadien aus isobutanol
US9505685B2 (en) 2011-07-25 2016-11-29 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013885A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
US9428427B2 (en) 2011-07-25 2016-08-30 Exxonmobil Chemical Patents Inc. Process for nitrile removal from hydrocarbon feeds
US9550705B2 (en) 2011-07-25 2017-01-24 Exxonmobill Chemical Patents Inc. Olefin oligomerization process
WO2013013887A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
CN103889938B (zh) 2011-10-31 2016-08-17 埃克森美孚化学专利公司 烯烃低聚方法
FR2986799B1 (fr) * 2012-02-15 2015-02-06 IFP Energies Nouvelles Procede de conversion d'une charge lourde, mettant en oeuvre une unite de craquage catalytique et une etape d'hydrogenation selective de l'essence issue du craquage catalytique
ES2443539B1 (es) 2012-07-19 2014-12-04 Consejo Superior De Investigaciones Científicas (Csic) Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39
CN104117387B (zh) * 2013-04-23 2016-07-06 上海碧科清洁能源技术有限公司 一种zsm-22/zsm-5混合分子筛催化剂及其制备和应用
CN105283416B (zh) * 2013-06-10 2018-04-20 埃克森美孚化学专利公司 制备分子筛的方法
JP2018508557A (ja) 2015-03-20 2018-03-29 エクソンモービル ケミカル パテンツ インコーポレイテッド オレフィン含有炭化水素供給物をオリゴマー化生成物または水素化オリゴマー化生成物に変換する方法
CN106675621B (zh) * 2015-11-09 2018-04-10 中国石油化工股份有限公司 一种劣质汽油非临氢改质的方法
WO2017223546A1 (en) * 2016-06-24 2017-12-28 Albemarle Corporation Mesoporous zsm-22 for increased propylene production
WO2018236471A1 (en) 2017-06-23 2018-12-27 Exxonmobil Chemical Patents Inc. Olefin oligomerization processes and related zeolites and structure directing agents
JP6975635B2 (ja) * 2017-12-27 2021-12-01 旭化成株式会社 Mwf型ゼオライト
CN112867701A (zh) 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
EP3867213A4 (de) 2018-10-17 2022-08-24 ExxonMobil Chemical Patents Inc. Oligomerisierung von olefinen
WO2020157216A1 (en) * 2019-01-31 2020-08-06 Basf Se Catalyzed process for the dimerization of alkenes
RU2709818C1 (ru) * 2019-02-18 2019-12-23 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Способ получения олигомеров пент-1-ена в присутствии иерархического цеолита н-y
JP2021028312A (ja) * 2019-08-09 2021-02-25 出光興産株式会社 プロピレン3量体及びプロピレン3量体の製造方法
CN112316974B (zh) * 2020-11-06 2023-01-03 东华工程科技股份有限公司 一种双功能催化剂及其制备方法和应用
US20250019607A1 (en) * 2021-11-05 2025-01-16 Purdue Research Foundation Methods for thermal oligomerization to liquid fuel range products

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US4032432A (en) * 1975-08-28 1977-06-28 Mobil Oil Corporation Conversions of hydrocarbons
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
US4324940A (en) * 1980-04-09 1982-04-13 Mobil Oil Corporation Shape selective acid catalyzed reactions of olefins over crystalline zeolites
US4417088A (en) * 1981-09-25 1983-11-22 Chevron Research Company Oligomerization of liquid olefins
US5243112A (en) * 1982-04-30 1993-09-07 Mobil Oil Corp. Lubricant range hydrocarbons from light olefins
US4417086A (en) * 1982-04-30 1983-11-22 Chevron Research Company Efficient fluidized oligomerization
US4973781A (en) * 1982-11-17 1990-11-27 Mobil Oil Corporation Zeolite ZSM-57 and catalysis therewith
US4481177A (en) * 1982-12-09 1984-11-06 Mobil Oil Corporation Synthesis of zeolite ZSM-22 with a heterocyclic organic compound
US4975401A (en) * 1983-05-02 1990-12-04 Mobil Oil Corporation ZSM-5/ZSM-12 catalyst mixture for cracking alkylbenzenes
US4642404A (en) * 1984-01-23 1987-02-10 Mobil Oil Corporation Conversion of olefins and paraffins to higher hydrocarbons
US4556477A (en) * 1984-03-07 1985-12-03 Mobil Oil Corporation Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks
US4575416A (en) * 1984-07-16 1986-03-11 Mobil Oil Corporation Hydrodewaxing with mixed zeolite catalysts
BR8504010A (pt) * 1984-08-21 1986-06-10 Mobil Oil Corp Processo para preparacao de zeolito cristalino poroso sintetico e processo para efetuar conversao catalitica de carga organica
US4826804A (en) * 1987-06-04 1989-05-02 Uop Catalyst for oligomerization process
US4754096A (en) * 1987-07-13 1988-06-28 Mobil Oil Corporation Production of high viscosity index lubricating oils from lower olefins
AU613954B2 (en) * 1987-10-07 1991-08-15 Mobil Oil Corporation Olefin oligomerization
US4919896A (en) * 1987-12-28 1990-04-24 Mobil Oil Corporation Multistage catalytic reactor system for production of heavy hydrocarbons
DE3914817C2 (de) * 1989-05-05 1995-09-07 Huels Chemische Werke Ag Verfahren zur Oligomerisierung von Olefinen
GB9114390D0 (en) * 1991-07-03 1991-08-21 Shell Int Research Hydrocarbon conversion process and catalyst composition
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
SG47070A1 (en) * 1992-06-05 1998-03-20 Exxon Chemical Patents Inc Zsm-22 zeolite

Also Published As

Publication number Publication date
CN1141621A (zh) 1997-01-29
KR100364560B1 (ko) 2003-02-17
AU681948B2 (en) 1997-09-11
US6143942A (en) 2000-11-07
EP0746538B1 (de) 1999-01-27
CA2182994A1 (en) 1995-08-24
KR970701164A (ko) 1997-03-17
WO1995022516A1 (en) 1995-08-24
DE69507598D1 (de) 1999-03-11
TW363981B (en) 1999-07-11
AU1891495A (en) 1995-09-04
JPH09509207A (ja) 1997-09-16
DE69507598T2 (de) 1999-09-02
CN1066426C (zh) 2001-05-30
EP0746538A1 (de) 1996-12-11

Similar Documents

Publication Publication Date Title
DE69507598D1 (de) Oligomerisierung und katalysator dafuer
WO2000050470A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
WO2001083571A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
BR9408323A (pt) Derivados de rapamicina
FR2804622B1 (fr) Composition catalytique pour la dimerisation, la codimerisation et l'oligomerisation des olefines
AU2099397A (en) Cosmetic, dermopharmaceutical or veterinary compositions for disinfecting human or animal skin
DE69130320D1 (de) Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
AU2733997A (en) N-(amidinophenyl)-n'-(subst.)-3h-2,4-benzodiazepin-3-one derivatives as factor xa inhibitors
SE9401879L (sv) Anordning vid telekommunikationssystem
DE3470526D1 (en) Small olefin interconversions
BR0003995A (pt) Transmissor possuindo um primeiro e um segundo modo de operação
RU95102329A (ru) Способ и стабилизированная каталитическая система для получения олефинов
EP1262177A3 (de) Medizinische Verwendung thyromimetischer Verbindungen gegen Haarausfall und Zusammensetzungen
DE69614741D1 (de) Katalysator für die Oligomerisation von Olefinen, Verfahren zur Herstellung desselben und seine Anwendung zur Oligomerisation von Olefinen
ATE169445T1 (de) Verwendung von gelformulierungen als beizmittel
ATE175590T1 (de) Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen
ES2191208T3 (es) Oxiimino-pregnano-carbolactonas.
IT8821551A0 (it) Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo.
MX9704050A (es) P-amidinobencilamidas de dipeptido novedosas con radicales sulfonilo o aminosulfonilo en terminal n.
BR0108536A (pt) Processo de epoxidação direta empregando composição de catalisador melhorado
FR2835521B1 (fr) Composition catalytique contenant un aluminoxane pour la dimerisation, la co-dimerisation et l'oligomerisation des olefines
ES2168208B1 (es) Catalizadores de craqueo basados en zeolitas.
NO20023877L (no) Katalysatorforbehandling i et reaksjonssystem for oksygenatet til olefiner
EA199900265A2 (ru) Способ получения катализатора циглера-натта для полимеризации альфа-олефинов в растворе, катализатор и способ полимеризации в растворе смеси
ATE295167T1 (de) Schwefelpentafluorophenylpyrazole zur kontrolle von ektoparasitenbefall

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties