ATE180181T1 - Verfahren zur entfernung von schwefeldioxid aus gasströmen unter herstellung von alpha-hemihydrat-gips - Google Patents

Verfahren zur entfernung von schwefeldioxid aus gasströmen unter herstellung von alpha-hemihydrat-gips

Info

Publication number: ATE180181T1
Authority: AT; Austria
Prior art keywords: hemihydrate gypsum; sulfur dioxide; removing sulfur; alpha; gas streams
Prior art date: 1992-12-31

Application number

AT93109063T

Other languages

English (en)

Inventor

John W College

Original Assignee

Eastroc Technologies Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-31

Filing date

1993-06-04

Publication date

1999-06-15

1993-06-04 Application filed by Eastroc Technologies Llc filed Critical Eastroc Technologies Llc

1999-06-15 Application granted granted Critical

1999-06-15 Publication of ATE180181T1 publication Critical patent/ATE180181T1/de

Links

RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title abstract 4
238000000034 method Methods 0.000 title abstract 2
ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 title 1
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 abstract 2
230000003647 oxidation Effects 0.000 abstract 2
238000007254 oxidation reaction Methods 0.000 abstract 2
238000005201 scrubbing Methods 0.000 abstract 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
239000012736 aqueous medium Substances 0.000 abstract 1
239000011575 calcium Substances 0.000 abstract 1
229910052791 calcium Inorganic materials 0.000 abstract 1
GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 abstract 1
235000010261 calcium sulphite Nutrition 0.000 abstract 1
229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
235000019341 magnesium sulphate Nutrition 0.000 abstract 1
239000002609 medium Substances 0.000 abstract 1
230000001590 oxidative effect Effects 0.000 abstract 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/464—Sulfates of Ca from gases containing sulfur oxides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Environmental & Geological Engineering (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Geology (AREA)
Biomedical Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Treating Waste Gases (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

AT93109063T 1992-12-31 1993-06-04 Verfahren zur entfernung von schwefeldioxid aus gasströmen unter herstellung von alpha-hemihydrat-gips ATE180181T1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/999,621 US5312609A (en)	1992-12-31	1992-12-31	Method of sulfur dioxide removal from gaseous streams with α-hemihydrate gypsum product formation

Publications (1)

Publication Number	Publication Date
ATE180181T1 true ATE180181T1 (de)	1999-06-15

Family

ID=25546539

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT93109063T ATE180181T1 (de)	1992-12-31	1993-06-04	Verfahren zur entfernung von schwefeldioxid aus gasströmen unter herstellung von alpha-hemihydrat-gips

Country Status (11)

Country	Link
US (1)	US5312609A (de)
EP (1)	EP0604701B1 (de)
JP (1)	JPH06226042A (de)
AT (1)	ATE180181T1 (de)
CA (1)	CA2097996C (de)
DE (1)	DE69325008T2 (de)
DK (1)	DK0604701T3 (de)
ES (1)	ES2131541T3 (de)
LV (1)	LV12413B (de)
PL (1)	PL175063B1 (de)
TR (1)	TR27345A (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2147059C (en) *	1994-04-28	1999-08-10	John W. College	Magnesium-enhanced sulfur dioxide scrubbing with gypsum formation
US5824273A (en) *	1995-06-23	1998-10-20	Mitsubishi Jukogyo Kabushiki Kaisha	Gas refining system
US5614158A (en) *	1995-10-20	1997-03-25	Dravo Lime Company	Process for removing sulfur dioxide from gases and producing gypsum and purified magnesium hydroxide
FI102959B (fi) *	1996-09-23	1999-03-31	Kemira Agro Oy	Menetelmä magnesiumsulfiitin tai magnesiumvetysulfiitin hapettamiseksi
US6068822A (en) *	1997-03-24	2000-05-30	Mitsubishi Heavy Industries, Ltd.	Desulforization method and desulfurization apparatus in geothermal power plant
US6197200B1 (en)	1999-05-11	2001-03-06	Eastroc Llc	Method of purifying flue gas waste slurries for use in gypsum production
US6572832B2 (en) *	2001-03-27	2003-06-03	Carmeuse North America Services, Inc.	Method of removing sulfur dioxide from a gaseous stream in a wet scrubbing unit
US6695018B2 (en) *	2002-06-10	2004-02-24	The Babcock & Wilcox Company	Collection scoop for flue gas desulfurization systems with bleed streams or ex situ forced oxidation
CN100382873C (zh) *	2003-06-06	2008-04-23	浙江大学	常压盐溶液法制取α-半水脱硫石膏工艺
US7273579B2 (en) *	2004-01-28	2007-09-25	United States Gypsum Company	Process for production of gypsum/fiber board
US20070088112A1 (en) *	2005-10-05	2007-04-19	Hooks Henry E	Fire retardant compositions
US8173090B2 (en)	2010-07-08	2012-05-08	Air Products And Chemicals, Inc.	Sorbent use with oxyfuel sour compression
JP6519610B2 (ja) *	2017-06-30	2019-05-29	宇部興産株式会社	石膏及びその製造方法、セメント組成物及びその製造方法、ならびに地盤改良材
JP6763419B2 (ja) *	2018-08-08	2020-09-30	宇部興産株式会社	セメント組成物の製造方法、及びセメント組成物の製造システム
JP6958682B2 (ja) *	2018-08-08	2021-11-02	宇部興産株式会社	セメント組成物の製造方法、及びセメント組成物の製造システム
CN110090540B (zh) *	2019-04-19	2021-05-14	华南理工大学	一种硅酸钙板生产过程中的废气净化除臭工艺及装置

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3637347A (en) *	1969-07-31	1972-01-25	Combustion Eng	Air pollution control system with chemical recovery
US3919393A (en) *	1973-03-08	1975-11-11	Dravo Corp	Process for sulfur dioxide removal from combustion gases
US3919394A (en) *	1973-05-14	1975-11-11	Dravo Corp	Process for the removal of oxides of sulfur from a gaseous stream
US4046856A (en) *	1974-03-15	1977-09-06	Kawasaki Jukogyo Kabushiki Kaisha	Method for removing sulfur oxide from stack gas
JPS5140399A (en) *	1974-10-03	1976-04-05	Taki Chemical	Aryusankarushiumuno shorihoho
GB1547422A (en) *	1975-03-31	1979-06-20	Japan Government	Manufacture of gypsum
DE3331838A1 (de) *	1983-09-03	1985-03-21	Gottfried Bischoff Bau kompl. Gasreinigungs- und Wasserrückkühlanlagen GmbH & Co KG, 4300 Essen	Verfahren zur umsetzung des rueckstandes aus rauchgas-entschwefelungsanlagen zu alphahalbhydrat-gipskristallen
JPS6090027A (ja) *	1983-10-25	1985-05-21	Kureha Chem Ind Co Ltd	排煙脱硫方法
DK189784D0 (da) *	1984-04-12	1984-04-12	Niro Atomizer As	Fremgangsmaade og apparat til behandling af biprodukter fra roeggasafsvovlning
CA1258961A (en) *	1984-09-17	1989-09-05	Yoshihiko Kudo	PROCESS FOR PRODUCING .alpha.-FORM GYPSUM HEMIHYDRATE
JPS61207620A (ja) *	1985-03-13	1986-09-16	Toray Ind Inc	ポリエステル繊維
DE3522495A1 (de) *	1985-06-24	1987-01-02	Heinrich Quante	Verfahren zur drucklosen herstellung von alphagips-halbhydrat und vorrichtung zur durchfuehrung des verfahrens
EP0294415B1 (de) *	1986-12-18	1990-10-03	GEBHARD, Georg, Dr.	Verfahren zur in-situ-gewinnung von calciumsulfathalbhydrat und/oder calciumsulfat (anhydrit) aus dem wäscher einer nassen rauchgasentschwefelungsanlage
DE3844938C2 (de) *	1987-05-22	1996-09-19	Pro Mineral Ges	Verfahren zur Erzeugung von Calciumsulfat-Alphahalbhydrat aus feinteiligem Calciumsulfat und dessen Verwendung
GB2205089B (en) *	1987-05-22	1991-03-13	Rhein Westfael Elect Werk Ag	Process for production of calcium sulphate alpha-hemihydrate
KR970005867B1 (ko) *	1988-11-18	1997-04-21	유나이티드 스테이트 집섬 캄파니	석고 합성물 및 그 제조방법
US4976936A (en) *	1989-08-18	1990-12-11	Dravo Lime Company	Flue gas desulfurization with oxidation of calcium sulfite in FGD discharges
US5084255A (en) *	1991-03-26	1992-01-28	Dravco Lime Company	Sulfur dioxide removal process with gypsum and magnesium hydroxide production

1992
- 1992-12-31 US US07/999,621 patent/US5312609A/en not_active Expired - Lifetime
1993
- 1993-06-04 EP EP93109063A patent/EP0604701B1/de not_active Expired - Lifetime
- 1993-06-04 ES ES93109063T patent/ES2131541T3/es not_active Expired - Lifetime
- 1993-06-04 DK DK93109063T patent/DK0604701T3/da active
- 1993-06-04 AT AT93109063T patent/ATE180181T1/de not_active IP Right Cessation
- 1993-06-04 DE DE69325008T patent/DE69325008T2/de not_active Expired - Lifetime
- 1993-06-08 CA CA002097996A patent/CA2097996C/en not_active Expired - Lifetime
- 1993-07-27 TR TR00645/93A patent/TR27345A/xx unknown
- 1993-10-19 PL PL93300755A patent/PL175063B1/pl unknown
- 1993-11-19 JP JP5291016A patent/JPH06226042A/ja active Pending
1999
- 1999-08-04 LV LVP-99-115A patent/LV12413B/en unknown

Also Published As

Publication number	Publication date
JPH06226042A (ja)	1994-08-16
DE69325008T2 (de)	1999-09-16
CA2097996C (en)	1998-11-10
PL175063B1 (pl)	1998-10-30
DK0604701T3 (da)	1999-06-23
US5312609A (en)	1994-05-17
LV12413A (lv)	2000-01-20
TR27345A (tr)	1995-01-13
LV12413B (en)	2000-06-20
EP0604701B1 (de)	1999-05-19
PL300755A1 (en)	1994-07-11
DE69325008D1 (de)	1999-06-24
CA2097996A1 (en)	1994-07-01
EP0604701A1 (de)	1994-07-06
ES2131541T3 (es)	1999-08-01

Legal Events

Date	Code	Title	Description
2000-02-15	UEP	Publication of translation of european patent specification
2005-03-15	REN	Ceased due to non-payment of the annual fee

Publication	Publication Date	Title
ATE180181T1 (de)	1999-06-15	Verfahren zur entfernung von schwefeldioxid aus gasströmen unter herstellung von alpha-hemihydrat-gips
DE68916104D1 (de)	1994-07-21	Verfahren zur Entschwefelung eines Schwefeldioxyd enthaltenden Gasstromes.
EP0414094A3 (en)	1991-06-26	Flue gas desulfurization
ATE129924T1 (de)	1995-11-15	Verfahren zur entfernung von schwefeldioxid unter bildung von gips und magnesiumhydroxid.
DE69415872D1 (de)	1999-02-25	Teiloxydationsverfahren zur Herstellung eines Stromes von heissem gereinigten Gas
DE68903569D1 (de)	1993-01-07	Verfahren zur konvertierung und beseitigung von schwefelverbindungen aus einem co-enthaltenden gas.
ATE263613T1 (de)	2004-04-15	Verfahren und vorrichtung zur gewinnung von schwefel aus schwefelwasserstoff enthaltenden gasströmen
ATE44660T1 (de)	1989-08-15	Verfahren zur abtrennung von schadstoffen aus abgasen.
ATE109370T1 (de)	1994-08-15	Verfahren zum entfernen von schwefeldioxyd aus rauchgasen.
DE69500717D1 (de)	1997-10-23	Magnesium-unterstützte Auswaschung von Schwefeldioxid mit Herstellung von Gips
DE69005282D1 (de)	1994-01-27	Schwefeldioxidentfernung aus Rauchgasen mit Sulfitoxidationsunterdrückung.
ATE137419T1 (de)	1996-05-15	Verfahren zur auswaschung von schwefeldioxid und herstellung von gereinigtem magnesiumhydroxid
ATE156725T1 (de)	1997-08-15	Verfahren zur reinigung von kondensierbaren organischen verunreinigungen enthaltenden gasen
DE58903743D1 (de)	1993-04-15	Verfahren zur herstellung chloridarmer gipsprodukte aus calciumhaltigen rueckstaenden von abgasreinigungsanlagen.
ATE66164T1 (de)	1991-08-15	Verfahren zur regelung des wasserhaushalts von nassen rauchgasentschwefelungsanlagen.
JPS5771819A (en)	1982-05-04	Oxidation of calcium sulfite
DE3876180D1 (de)	1993-01-07	Verfahren zur umwandlung von calciumsulfatdihydrat in -g(a)-halbhydrat.
ATE69808T1 (de)	1991-12-15	Verfahren zur herstellung von dithiolen.
DE58902525D1 (de)	1992-11-26	Verfahren zur herstellung von abbindefaehigen calciumsulfaten aus calciumsulfat-dihydrat.
CA2133694A1 (en)	1995-04-26	Process for Producing Magnesium Sulfite Hexahydrate in a Flue Gas Desulfurization System
BR8906779A (pt)	1990-08-21	Membrana para a separacao de gases; processo para separar um componente de uma mistura gasosa de 02/n ou c02/ch4 contendo tal componente; e membrana de poliester para a separacao de gases
DE3761089D1 (de)	1990-01-11	Verfahren zur herstellung von methan in gegenwart eines schwefelbestaendigen katalysators und bei diesem verfahren zu verwendender katalysator.
ATE57172T1 (de)	1990-10-15	Verfahren zur in-situ-gewinnung von calciumsulfathalbhydrat und/oder calciumsulfat (anhydrit) aus dem waescher einer nassen rauchgasentschwefelungsanlage.